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Articles 31 - 60 of 114
Full-Text Articles in Fresh Water Studies
Evolution Of The Freshwater Sardinella, Sardinella Tawilis (Clupeiformes: Clupeidae), In Taal Lake, Philippines And Identification Of Iits Marine Sister-Species, Sardinella Hualiensis, Demian Willette, Kent E. Carpenter, Mudjekeewis Santos
Evolution Of The Freshwater Sardinella, Sardinella Tawilis (Clupeiformes: Clupeidae), In Taal Lake, Philippines And Identification Of Iits Marine Sister-Species, Sardinella Hualiensis, Demian Willette, Kent E. Carpenter, Mudjekeewis Santos
Biological Sciences Faculty Publications
We identify the sister species of the world's only freshwater sardinella, Sardinella tawilis (Herre, 1927) of Taal Lake, Philippines as the morphologically-similar marine Taiwanese sardinella Sardinella hualiensis (Chu and Tsai, 1958). Evidence of incomplete lineage sorting and a species tree derived from three mitochondrial genes and one nuclear gene indicate that S. tawilis diverged from S. hualiensis in the late Pleistocene. Neutrality tests, mismatch distribution analysis, sequence diversity indices, and species tree analysis indicate populations of both species have long been stable and that the divergence between these two lineages occurred prior to the putative 18th century formation of Taal …
Evaluating The Contribution Of Groundwater To Wetland Water Budgets Central Piedmont Virginia, Kerby Morgan Dobbs
Evaluating The Contribution Of Groundwater To Wetland Water Budgets Central Piedmont Virginia, Kerby Morgan Dobbs
OES Theses and Dissertations
In the Piedmont region of Virginia, development pressures are increasing the demand for mitigation wetlands but appropriate construction sites are relatively scarce due to local topography and geology. Many existing water budget models used for planned mitigation sites exhibit considerable error when estimating groundwater fluxes, particularly for historical years that lack hydraulic head data. This difficulty has led many planners to neglect or underestimate the contribution of groundwater to wetland water budgets, resulting in mitigation sites that fail to create the appropriate hydrology for the desired vegetation community. However, reliable estimations of groundwater input contributing to wetland water budgets can …
Assessing The Release Of Bioactive Trace Elements From Coal Fly Ash Into Natural Fresh Waters, Candace E. Wall
Assessing The Release Of Bioactive Trace Elements From Coal Fly Ash Into Natural Fresh Waters, Candace E. Wall
OES Theses and Dissertations
Each year a significant amount of coal fly ash enters the environment, where it can potentially cause adverse effects by releasing a range of bioactive trace elements. In this context, environmental studies have largely focused on the leaching of trace elements from the coal ash in landfills by rainwater and groundwater, while there has been relatively little study of the release of bioactive trace elements from coal fly ash deposited in natural fresh waters such as rivers and lakes. Furthermore, the batch leaching methods that have been used to study the interaction of rainwater and groundwater with coal ash in …
Fish Species Distribution In Seagrass Habitats Of Chesapeake Bay Are Structured By Abiotic And Biotic Factors, Jason J. Schaffler, Jacques Van Montfrans, Cynthia M. Jones, Robert J. Orth
Fish Species Distribution In Seagrass Habitats Of Chesapeake Bay Are Structured By Abiotic And Biotic Factors, Jason J. Schaffler, Jacques Van Montfrans, Cynthia M. Jones, Robert J. Orth
OES Faculty Publications
Seagrass habitats have long been known to serve as nursery habitats for juvenile fish by providing refuges from predation and areas of high forage abundance. However, comparatively less is known about other factors structuring fish communities that make extensive use of seagrass as nursery habitat. We examined both physical and biological factors that may structure the juvenile seagrass-associated fish communities across a synoptic-scale multiyear study in lower Chesapeake Bay. Across 3years of sampling, we collected 21,153 fish from 31 species. Silver Perch Bairdiella chrysoura made up over 86% of all individuals collected. Nine additional species made up at least 1% …
Phytoplankton In Virginia Lakes And Reservoirs, Harold G. Marshall
Phytoplankton In Virginia Lakes And Reservoirs, Harold G. Marshall
Virginia Journal of Science
This study involves a phytoplankton summer/autumn survey in 46 Virginia lakes and reservoirs during 2010-2012. A total of 307 taxa were identified which included several filamentous and colonial cyanabacteria in bloom concentrations. With the exception of one natural lake, the other sites sampled represent impoundments created decades ago, with the majority presently classified as meso- or eutrophic. Among the cyanobacteria were 6 known toxin producers (Anabaena circinalis, Anabaena spiroides, Aphanizomenon flos-aquae, Cylindrospermopsis raciborskii, Limnothrix redekei, and Microcystis aeruginosa). The study characterizes phytoplankton populations in these aging freshwater habitats taken from a large number …
Phytoplankton In Virginia Lakes And Reservoirs, Harold G. Marshall
Phytoplankton In Virginia Lakes And Reservoirs, Harold G. Marshall
Biological Sciences Faculty Publications
This study involves a phytoplankton summer/autumn survey in 46 Virginia lakes and reservoirs during 2010-2012. A total of 307 taxa were identified which included several filamentous and colonial cyanabacteria in bloom concentrations. With the exception of one natural lake, the other sites sampled represent impoundments created decades ago, with the majority presently classified as meso- or eutrophic. Among the cyanobacteria were 6 known toxin producers (Anabaena circinalis, Anabaena spiroides, Aphanizomenon flos-aquae, Cylindrospermopsis raciborskii, Limnothrix redekei, and Microcystis aeruginosa). The study characterizes phytoplankton populations in these aging freshwater habitats taken from a large number …
A Preliminary Examination Of An In Situ Dual Dye Approach To Measuring Light Fluxes In Lotic Systems, Elizabeth C. Minor, Elizabeth James, Jay A. Austin, Veronica Nelson, Ryan Lusk, Kenneth Mopper
A Preliminary Examination Of An In Situ Dual Dye Approach To Measuring Light Fluxes In Lotic Systems, Elizabeth C. Minor, Elizabeth James, Jay A. Austin, Veronica Nelson, Ryan Lusk, Kenneth Mopper
Chemistry & Biochemistry Faculty Publications
Light is a critical parameter in aquatic ecosystems, affecting primary production and in situ photochemistry. However, measuring light exposure for suspended particles or dissolved components in a dynamic water column can be challenging with existing Eulerian approaches. Here, we assess the simultaneous deployment of two dyes differing in photolability (rhodamine WT and fluorescein) as a Lagrangian measure of sunlight exposure in a lotic system. Fluorescein is sensitive to light exposure; rhodamine WT is relatively photostable. We examined dye fluorescence at various pH, salinity, and temperature conditions. We also tested dye photolability as a function of pH and wavelength range. In …
Late Holocene Sedimentation And Paleoenvironmental History For The Tidal Marshes Of The Potomac And Rappahannock Rivers, Tributaries To Chesapeake Bay, Neil E. Tibert, J. Bradford Hubeny, Mark Abbott, Joseph M. Kiker, Lindsay J. Walker, Shawn Mckenzie
Late Holocene Sedimentation And Paleoenvironmental History For The Tidal Marshes Of The Potomac And Rappahannock Rivers, Tributaries To Chesapeake Bay, Neil E. Tibert, J. Bradford Hubeny, Mark Abbott, Joseph M. Kiker, Lindsay J. Walker, Shawn Mckenzie
Virginia Journal of Science
Instrumental tide gauge records indicate that the modern rates of sea-level rise in the Chesapeake Bay more than double the global average of 1.2-1.5 mm yr-1. The primary objective for this study is to establish a relative depositional history for the tidal marshes of the Potomac and Rappahannock Rivers that will help us improve our understanding of processes that influence sedimentation in the proximal tributaries of Chesapeake Bay. Marsh cores were collected from Blandfield Point VA, Tappahannock VA, and Potomac Creek VA. The sedimentary facies include: 1) a lower unit of organic-poor, grey clay with fine sand and silt layers …
A Centennial Record Of Paleosalinity Change In The Tidal Reaches Of The Potomac And Rappahannock Rivers, Tributaries To Chesapeake Bay, Neil E. Tibert, Lindsay J. Walker, William P. Patterson, J. Bradford Hubeny, Emma Jones, Olivia R. Cooper
A Centennial Record Of Paleosalinity Change In The Tidal Reaches Of The Potomac And Rappahannock Rivers, Tributaries To Chesapeake Bay, Neil E. Tibert, Lindsay J. Walker, William P. Patterson, J. Bradford Hubeny, Emma Jones, Olivia R. Cooper
Virginia Journal of Science
Gravity and push cores from the Potomac and Rappahannock Rivers (Virginia Tidewater) were collected from central and proximal estuarine zones with known seasonal salinity stratification. The lowermost microfossil associations in the cores comprise alternating ostracode populations of Cyprideis salebrosa and Cytheromorpha. This microfossil association gives way to an oligohaline association dominated by the freshwater ostracode Darwinula stevensoni. Stable oxygen isotope values (δ18O) of Rapphannock Cyprideis salebrosa are highly variable ranging between -6.6 to -3.2‰ VPDB. δ18O values for Potomac Cytheromorpha fuscata range from -8.2 to -3.2‰ VPDB. Positive excursions in δ18O values …
Fecal Indicator Bacteria In Knitting Mill Creek With A Comparison Of Methods Used To Enumerate E. Coli, Manju Nagarajan
Fecal Indicator Bacteria In Knitting Mill Creek With A Comparison Of Methods Used To Enumerate E. Coli, Manju Nagarajan
OES Theses and Dissertations
This research seeks to evaluate the impact of an urban, multi-use neighborhood on the bacteriological quality of water in Knitting Mill Creek, a blind arm of the Lafayette River, a sub-estuary of the lower Chesapeake Bay. A principal objective was to determine the effects of rainfall, a surrogate for run-off, on water-column concentrations of fecal-indicator bacteria (FIB). I collected water samples weekly (September 2009-December 2010) and biweekly (January 2010-December 2011) at a storm-sewer outfall and a nearby marina and quantified their E. coli and enterococci concentrations using Colilert-18 and Enterolert, most-probable-number assays. In addition, I took monthly samples for these …
Δ13c Is A Signature Of Light Availability And Photosynthesis In Seagrass, Xingping Hu, David J. Burdige, Richard C. Zimmerman
Δ13c Is A Signature Of Light Availability And Photosynthesis In Seagrass, Xingping Hu, David J. Burdige, Richard C. Zimmerman
OES Faculty Publications
We explored the role of light-saturated (carbon-limited) photosynthesis on δ¹³C of turtlegrass (Thalassia testudinum Banks ex Konig) populations from the clear, blue waters of the Great Bahama Bank and the turbid, green waters of Florida Bay using field observations and radiative transfer models. Consistent with numerous previous observations, leaf δ¹³C decreased significantly with water depth in both regions. However the δ¹³C for Bahamas turtlegrass was 3 parts per thousand heavier than that for Florida Bay turtlegrass at equivalent depths, and broadband irradiance explained even less of the δ¹³C variations than depth. Instead, leaf δ¹³C showed a stronger relationship to …
Cyanobacteria Dominance In The Oligohaline Waters Of Back Bay, Virginia, Harold G. Marshall
Cyanobacteria Dominance In The Oligohaline Waters Of Back Bay, Virginia, Harold G. Marshall
Biological Sciences Faculty Publications
Back Bay and its flora have historically been influenced by the interaction of freshwater flow in combination with frequent intrusion of saline water into its basin. These events have resulted in a dynamic environmental setting influencing the abundance and composition of its phytoplankton community. Dominating these oligohaline waters is a diverse representation and high abundance of freshwater filamentous and colonial cyanobacteria. These include the nonheterocystous Planktolyngbya contorta, Planktolyngbya limnetica, and Pseudanabaena limnetica, taxa implicated as bloom producers in Bay waters with N:P molar ratios ranging from 23:1 to 74:1.
Anaerobic Oxidation Of Methane And The Stoichiometry Of Remineralization Processes In Continental Margin Sediments, David J. Burdige, Tomoko Kamada
Anaerobic Oxidation Of Methane And The Stoichiometry Of Remineralization Processes In Continental Margin Sediments, David J. Burdige, Tomoko Kamada
OES Faculty Publications
In many coastal and continental margin sediments, pore-water property-property plots yield values of rc:s, the stoichiometric ratio of dissolved inorganic carbon (DIC) produced to sulfate reduced, that are lower than the commonly assumed value of 2. Remineralization of organic matter more reduced than CH2O can cause such observations, as can DIC loss due to authigenic carbonate precipitation. However, through studies of Santa Monica Basin sediments, we have observed that these observations could also be related to the occurrence of anaerobic oxidation of methane (AOM) in sediments. Specifically, using a reactive transport sediment model, we have shown …
Characterization Of Heterogeneities And Domains In Aquatic And Sedimentary Organic Matter By 1 H Spin Diffusion: Potential For Elucidating The Formation Mechanisms, Jingdong Mao, Xiaoyan Cao
Characterization Of Heterogeneities And Domains In Aquatic And Sedimentary Organic Matter By 1 H Spin Diffusion: Potential For Elucidating The Formation Mechanisms, Jingdong Mao, Xiaoyan Cao
Chemistry & Biochemistry Faculty Publications
Although the information on domains and heterogeneities of natural organic matter (NOM) can provide insights into its formation mechanisms, the appropriate solid-state NMR technique for measuring them is still lacking. The traditional technique requires mobility differences in NOM whereas NOM components are primarily rigid. We introduced a new 1H spin diffusion technique, 1H-13C two-dimensional heteronuclear correlation (2D HETCOR) NMR with 1H spin diffusion, for characterization of domains and heterogeneities in aquatic and sedimentary organic matter. It was achieved by collecting a series of 2D HETCOR spectra with a variable mixing time, tm', and …
A Mini-Electrodialysis System For Desalting Small Volume Saline Samples For Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Hongmei Chen, Aron Stubbins, Patrick G. Hatcher
A Mini-Electrodialysis System For Desalting Small Volume Saline Samples For Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Hongmei Chen, Aron Stubbins, Patrick G. Hatcher
Chemistry & Biochemistry Faculty Publications
An affordable, commercially available mini-electrodialysis (mini-ED) system has been evaluated for the efficient desalting of small volume samples of seawater before analysis by electrospray Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS). Mini-ED FT-ICR mass spectra were compared with spectra for samples that were treated by C18 solid phase extraction, a commonly used method for rapid sample preparation for this type of analysis. In this comparison, it is clear that mini-ED provides more representative molecular information, compared with C18 isolation, and recovers the overwhelming majority of peaks from salt-free samples, indicating that it adequately represents the …
Corrections To The Paper "Phytoplankton Productivity In The Tidal Regions Of Four Chesapeake Bay (Usa) Tributaries." Virginia Journal Of Science. 2007 58(4): 191-204, By K. K. Nesius, H. G. Marshall, And T.A. Egerton
Virginia Journal of Science
Necessary corrections associated with the paper "Phytoplankton productivity in the tidal regions of four Chesapeake Bay (USA) tributaries", originally published in Virginia Journal of Science Volume 58, Number 4, pages 191-204, in 2007, by K.K. Nesius, H.G. Marshall, and T.A. Egerton.
Temporal Controls On Dissolved Organic Matter And Lignin Biogeochemistry In A Pristine Tropical River, Democratic Republic Of Congo, Robert G. M. Spencer, Peter J. Hernes, Rosmarie Ruf, Andy Baker, Rachael Y. Dyda, Aron Stubbins, Johan Six
Temporal Controls On Dissolved Organic Matter And Lignin Biogeochemistry In A Pristine Tropical River, Democratic Republic Of Congo, Robert G. M. Spencer, Peter J. Hernes, Rosmarie Ruf, Andy Baker, Rachael Y. Dyda, Aron Stubbins, Johan Six
Chemistry & Biochemistry Faculty Publications
Dissolved organic carbon (DOC), lignin biomarkers, and the optical properties of dissolved organic matter (DOM) were measured in the Epulu River (northeast Democratic Republic of Congo) with the aim of investigating temporal controls on the quantity and chemical composition of DOM in a tropical rainforest river. Three different periods defined by stages of the hydrologic regime of the region, (1) post dry flushing period, (2) intermediary period, and (3) start of the dry period/post flush, were sampled. Temporal variability in DOM quantity and quality was observed with highest DOC, lignin concentration (Σ8) and carbon‐normalized (Λ8) values …
Mixing By Shear Instability At High Reynolds Number, W. R. Geyer, A. C. Lavery, M. E. Scully, J. H. Trowbridge
Mixing By Shear Instability At High Reynolds Number, W. R. Geyer, A. C. Lavery, M. E. Scully, J. H. Trowbridge
CCPO Publications
Shear instability is the dominant mechanism for converting fluid motion to mixing in the stratified ocean and atmosphere. The transition to turbulence has been well characterized in laboratory settings and numerical simulations at moderate Reynolds number-it involves "rolling up", i.e., overturning of the density structure within the cores of the instabilities. In contrast, measurements in an energetic estuarine shear zone reveal that the mixing induced by shear instability at high Reynolds number does not primarily occur by overturning in the cores; rather it results from secondary shear instabilities within the zones of intensified shear separating the cores. This regime is …
Effluent Organic Nitrogen (Eon): Bioavailability And Photochemical And Salinity-Mediated Release, Deborah A. Bronk, Quinn N. Roberts, Marta P. Sanderson, Elizabeth A. Canuel, Patrick G. Hatcher, Rajaa Mesfioui, Katherine C. Filippino, Margaret R. Mulholland, Nancy G. Love
Effluent Organic Nitrogen (Eon): Bioavailability And Photochemical And Salinity-Mediated Release, Deborah A. Bronk, Quinn N. Roberts, Marta P. Sanderson, Elizabeth A. Canuel, Patrick G. Hatcher, Rajaa Mesfioui, Katherine C. Filippino, Margaret R. Mulholland, Nancy G. Love
Chemistry & Biochemistry Faculty Publications
The goal of this study was to investigate three potential ways that the soluble organic nitrogen (N) fraction of wastewater treatment plant (WWTP) effluents, termed effluent organic N (EON), could contribute to coastal eutrophication - direct biological removal, photochemical release of labile compounds, and salinity-mediated release of ammonium (NH4+). Effluents from two WWTPs were used in the experiments. For the bioassays, EON was added to water from four salinities (∼0 to 30) collected from the James River (VA) in August 2008, and then concentrations of N and phosphorus compounds were measured periodically over 48 h. Bioassay results, based …
First Records Of Hypleurochilus Geminatus And Centropristis Philadelphica From Chesapeake Bay, Aimee D. Halvorson
First Records Of Hypleurochilus Geminatus And Centropristis Philadelphica From Chesapeake Bay, Aimee D. Halvorson
Virginia Journal of Science
During the fall of 2007, Centropris philadelphica (rock seabass) and Hypleurochilus geminatus (Crested blenny) were collected from Chesapeake Bay. These captures are significant as they represent the first substantiated record of C. philadelphica from Chesapeake Bay and only the second and third validated records of H. geminatus. Additionally, the first record of H. geminatus from Chesapeake Bay was only recently recognized since the specimen had been previously misidentified as Parablennius marmoreus (seaweed blenny). The collection of seven individuals of H. geminatus in 2007, from two locations, indicates that the species may be resident within the Chesapeake Bay estuary.
Phytoplankton Blooms: Their Occurrence And Composition Within Virginia's Tidal Tributaries, Harold G. Marshall, Todd A. Egerton
Phytoplankton Blooms: Their Occurrence And Composition Within Virginia's Tidal Tributaries, Harold G. Marshall, Todd A. Egerton
Virginia Journal of Science
Sporadic algal bloom development within a 10 year monitoring program in Virginia tidal tributaries of Chesapeake Bay is reviewed. These blooms were common events, characteristically producing a color signature to the surface water, typically short lived, occurring mainly from spring into autumn throughout different salinity regions of these rivers, and were produced primarily by dinoflagellates. The abundance threshold levels that would identify bloom status from a non-bloom presence were species specific, varied with the taxon's cell size, and ranged from ca. 10 to 104 cells mL-1. Among the most consistent sporadic bloom producers were the dinoflagellates Akashiwo …
Electrospray And Photoionization Mass Spectrometry For The Characterization Of Organic Matter In Natural Waters: A Qualitative Assessment, William C. Hockaday, Jeremiah M. Pucell, Alan G. Marshall, Jeffery A. Baldock, Patrick G. Hatcher
Electrospray And Photoionization Mass Spectrometry For The Characterization Of Organic Matter In Natural Waters: A Qualitative Assessment, William C. Hockaday, Jeremiah M. Pucell, Alan G. Marshall, Jeffery A. Baldock, Patrick G. Hatcher
Chemistry & Biochemistry Faculty Publications
Fourier-transform ion cyclotron resonance mass spectrometry (MS) has demonstrated potential to revolutionize the fields of limnology and chemical oceanography by identifying the individual molecular components of organic matter in natural waters. The use of MS for this purpose is made possible by the electrospray technique which successfully ionizes polar, nonvolatile organic molecules. Another recently developed ion source, atmospheric pressure photoionization (APPI), extends MS capabilities to less polar molecules. This article presents early results on the application of APPI MS to natural organic matter. We compare APPI MS and electrospray MS data for dissolved organic matter from Lake Drummond (Virginia, USA). …
Photochemical Degradation Of Dissolved Organic Matter And Dissolved Lignin Phenols From The Congo River, Robert G. M. Spencer, Aron Stubbins, Peter J. Hernes, Kenneth Mopper, Anthony K. Aufdenkampe, Rachael Y. Dyda, Vincent L. Mwamba, Arthur M. Mangangu, Jose N. Wabakanghanzi, Johan Six
Photochemical Degradation Of Dissolved Organic Matter And Dissolved Lignin Phenols From The Congo River, Robert G. M. Spencer, Aron Stubbins, Peter J. Hernes, Kenneth Mopper, Anthony K. Aufdenkampe, Rachael Y. Dyda, Vincent L. Mwamba, Arthur M. Mangangu, Jose N. Wabakanghanzi, Johan Six
Chemistry & Biochemistry Faculty Publications
Photochemical degradation of Congo River dissolved organic matter (DOM) was investigated to examine the fate of terrigenous DOM derived from tropical ecosystems. Tropical riverine DOM receives greater exposure to solar radiation, particularly in large river plumes discharging directly into the open ocean. Initial Congo River DOM exhibited dissolved organic carbon (DOC) concentration and compositional characteristics typical of organic rich blackwater systems. During a 57 day irradiation experiment, Congo River DOM was shown to be highly photoreactive with a decrease in DOC, chromophoric DOM (CDOM), lignin phenol concentrations (Σ8) and carbon-normalized yields (Λ8), equivalent to losses of ~45, 85–95, >95 and …
Phytoplankton Blooms: Their Occurence And Composition Within Virginia's Tidal Tributaries, Harold G. Marshall, Todd A. Egerton
Phytoplankton Blooms: Their Occurence And Composition Within Virginia's Tidal Tributaries, Harold G. Marshall, Todd A. Egerton
Biological Sciences Faculty Publications
Sporadic algal bloom development within a 10 year monitoring program in Virginia tidal tributaries of Chesapeake Bay is reviewed. These blooms were common events, characteristically producing a color signature to the surface water, typically short lived, occurring mainly from spring into autumn throughout different salinity regions of these rivers, and were produced primarily by dinoflagellates. The abundance threshold levels that would identify bloom status from a non-bloom presence were species specific, varied with the taxon's cell size, and ranged from ca. 10 to 10(4) cells mL(-1). Among the most consistent sporadic bloom producers were the dinoflagellates Akashiwo sanguinea, Cochlodinium …
The Use Of Extractable Lipofuscin For Age Determination Of Crustaceans: Reply To Sheehy (2008), H. Rodger Harvey, David H. Secor, Se-Jong Ju
The Use Of Extractable Lipofuscin For Age Determination Of Crustaceans: Reply To Sheehy (2008), H. Rodger Harvey, David H. Secor, Se-Jong Ju
OES Faculty Publications
The heterogeneous mixture of metabolic by-products termed lipofuscin (LF) or age pigments has long been known to accumulate in post mitotic cells with increasing age. In crustaceans several approaches have been developed over the years to track LF accumulation and provide a proxy for chronological age. Histological approaches have been traditionally used for LF determination of crustaceans (e.g. Sheehy et al. 1994, Mar Biol 121:237-245), but over the last decade extraction approaches for neural tissues have been introduced (Ju et al. 1999, Mar Ecol Prog Ser 185:171-179) and tested (Ju et al. 2001, Mar Ecol Prog Ser 224:197-205; 2003, Fish …
Naturally Present Fatty Acids As Internal Calibrants For Fourier Transform Mass Spectra Of Dissolved Organic Matter, Rachel L. Sleighter, Georgina A. Mckee, Zhanfei Liu, Patrick G. Hatcher
Naturally Present Fatty Acids As Internal Calibrants For Fourier Transform Mass Spectra Of Dissolved Organic Matter, Rachel L. Sleighter, Georgina A. Mckee, Zhanfei Liu, Patrick G. Hatcher
Chemistry & Biochemistry Faculty Publications
The analysis of dissolved organic matter ( DOM) by Fourier transform ion cyclotron resonance mass spectrometry ( FTICR- MS) has gained wide interest recently, driven primarily by its ultrahigh resolving power and mass accuracy. Accurate calibration of mass spectra is a key step to successfully decipher the DOM components. We propose a simple and accurate method to internally calibrate the peaks in the complex spectra without the need to add a calibrant. Mass spectra of DOM samples from the Dismal Swamp, Virginia, and the lower Chesapeake Bay display the presence of naturally occurring fatty acids which can be readily recognized …
Absorption Spectral Slopes And Slope Ratios As Indicators Of Molecular Weight, Source, And Photobleaching Of Chromophoric Dissolved Organic Matter, John R. Helms, Aron Stubbins, Jason D. Ritchie, Elizabeth C. Minor, David J. Kieber, Kenneth Mopper
Absorption Spectral Slopes And Slope Ratios As Indicators Of Molecular Weight, Source, And Photobleaching Of Chromophoric Dissolved Organic Matter, John R. Helms, Aron Stubbins, Jason D. Ritchie, Elizabeth C. Minor, David J. Kieber, Kenneth Mopper
Chemistry & Biochemistry Faculty Publications
A new approach for parameterizing dissolved organic matter ( DOM) ultraviolet-visible absorption spectra is presented. Two distinct spectral slope regions ( 275-295 nm and 350-400 nm) within log-transformed absorption spectra were used to compare DOM from contrasting water types, ranging from wetlands (Great Dismal Swamp and Suwannee River) to photobleached oceanic water ( Atlantic Ocean). On the basis of DOM size-fractionation studies ( ultrafiltration and gel filtration chromatography), the slope of the 275-295- nm region and the ratio of these slopes (SR; 275-295- nm slope : 350-400- nm slope) were related to DOM molecular weight ( MW) and …
Good Things Come In Small Packages: Tiny Plankton Producing Oxygen Near Dead Zone, Abbie Basile
Good Things Come In Small Packages: Tiny Plankton Producing Oxygen Near Dead Zone, Abbie Basile
Libraries Faculty & Staff Publications
(First paragraph) For many, the words “Lake Erie” bring to mind large things: big sport fish, sprawling waterfront homes, and an enormous body of water bordering four states and two countries. Similarly, much of the Lake Erie research of which the public is aware deals with larger biological organisms—larger algae and zooplankton, the small fish that eat the zooplankton, and the large fish that feed on those smaller fish. Over the years, the smaller lake life have been somewhat overlooked.
Marine And Freshwater Cyanophages In A Laurentian Great Lake: Evidence From Infectivity Assays And Molecular Analyses Of G20 Genes, Steven W. Wilhelm, Matthew J. Carberry, Melanie L. Eldridge, Leo Poorvin, Matthew A. Saxton, Martina A. Doblin
Marine And Freshwater Cyanophages In A Laurentian Great Lake: Evidence From Infectivity Assays And Molecular Analyses Of G20 Genes, Steven W. Wilhelm, Matthew J. Carberry, Melanie L. Eldridge, Leo Poorvin, Matthew A. Saxton, Martina A. Doblin
OES Faculty Publications
While it is well established that viruses play an important role in the structure of marine microbial food webs, few studies have directly addressed their role in large lake systems. As part of an ongoing study of the microbial ecology of Lake Erie, we have examined the distribution and diversity of viruses in this system. One surprising result has been the pervasive distribution of cyanophages that infect the marine cyanobacterial isolate Synechococcus sp. strain WH7803. Viruses that lytically infect this cyanobacterium were identified throughout the western basin of Lake Erie, as well as in locations within the central and eastern …
Fortnightly Variability At The Transition Between Two Sub-Estuaries, Mayra Lorena Riveron Enzastiga
Fortnightly Variability At The Transition Between Two Sub-Estuaries, Mayra Lorena Riveron Enzastiga
OES Theses and Dissertations
Profiles of current velocity from an Acoustic Doppler Current Profiler (ADCP) and of water salinity, temperature and density from a Conductivity-Temperature-Depth (CTD) recorder, were combined with surface salinity, temperature and density from a Conductivity-Temperature (CT) recorder to elucidate the fortnightly variability at the Lafayette River entrance. The Lafayette River connects at its mouth with the Elizabeth River, which is a tributary to the James River in the Chesapeake Bay. Data were collected in four experiments during consecutive spring and neap tides in the autumn of 2000, and in the spring of 2001. Each experiment was carried out for -25 hours …