Fresh Water Studies Commons^™

Removal Of Selected Pharmaceuticals And Personal Care Products In Wastewater Treatment Plant In Jordan, Othman Al-Mashaqbeh, Diya Alsafadi, Sahar Dalahmeh, Shannon L. Bartelt-Hunt, Daniel D. Snow

Nebraska Water Center: Faculty Publications

The largest wastewater treatment plant in Jordan was monitored in the summer to determine the removal of pharmaceuticals and personal care products (PPCPs). Grab samples were collected from the influent and effluent of As-Samra Wastewater Treatment Plant (WWTP). Liquid chromatography and tandem mass spectrometry (LC–MS/MS) were utilized to determine the concentrations of 18 compounds of pharmaceuticals and personal care products (PPCPs). The results showed that 14 compounds were detected in the collected samples from the influent and effluent of As-Samra WWTP. These compounds are 1,7-dimethylxanthine, amphetamine, acetaminophen, caffeine, carbamazepine, cimetidine, cotinine, diphenhydramine, methylenedioxymethamphetamine (MDMA), morphine, phenazone, sulfamethazine, sulfamethoxazole, thiabendazole, and …

Engineered Carbon-Nanocatalyst Composites And Carbon Mixed ‎Matrix Membranes ‎For Water And Wastewater Treatment ‎, Mojtaba Abolhassani

Graduate Theses and Dissertations

Carbonaceous materials such as graphene oxide, and activated ‎carbon have a wide range of ‎applications in water and wastewater treatment due to the high surface ‎area, unique structure, ‎and chemical and thermal stability. Carbon-based materials can be used as a ‎membrane, an ‎adsorbent, a support for nanomaterials, or ‎as a filler within membranes to remove contaminants ‎from water. In this research, the specific carbon materials and how their properties influence their ‎use and performance in ‎specific engineering applications is explored. ‎

Here, membrane filtration and adsorption/degradation of the water and wastewater using carbon-‎based material are investigated. The research firstly focuses …

Perchlorate Behavior In The Context Of Black Carbon And Metal Cogeneration Following Fireworks Emission At Oak Lake, Lincoln, Nebraska, Usa, Manish Kumar, Daniel D. Snow, Yusong Li, Patrick Shea

Nebraska Water Center: Faculty Publications

The imprints of fireworks displays on the adjacent water body were investigated from the perspective of cogeneration of black carbon, metals and perchlorate (ClO₄^–). In particular, the mixing and dissipation of ClO₄^– were studied at Oak Lake, Lincoln, Nebraska, following fireworks displays in 2015 and 2016. Following the display, ClO₄^– concentration in the water increased up to 4.3 μg/L and 4.0 μg/L in 2015 and 2016, respectively. A first-order model generally provided a good fit to the measured perchlorate concentrations from which the rate of dissipation was estimated as 0.07 d^–1 in …

The Effects Of Reactant Concentration And Air Flow Rate In The Consumption Of Dissolved O2 During The Photochemistry Of Aqueous Pyruvic Acid, Alexis J. Eugene, Marcelo I. Guzman

Chemistry Faculty Publications

The sunlight photochemistry of the organic chromophore pyruvic acid (PA) in water generates ketyl and acetyl radicals that contribute to the production and processing of atmospheric aerosols. The photochemical mechanism is highly sensitive to dissolved oxygen content, [O₂(aq)], among other environmental conditions. Thus, herein we investigate the photolysis (λ ≥ 305 nm) of 10–200 mM PA at pH 1.0 in water covering the relevant range 0 ≤ [O₂(aq)] ≤ 1.3 mM. The rapid consumption of dissolved oxygen by the intermediate photolytic radicals is monitored in real time with a dissolved oxygen electrode. …

Irrigation Water Quality—A Contemporary Perspective, Arindam Malakar, Daniel D. Snow, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

In the race to enhance agricultural productivity, irrigation will become more dependent on poorly characterized and virtually unmonitored sources of water. Increased use of irrigation water has led to impaired water and soil quality in many areas. Historically, soil salinization and reduced crop productivity have been the primary focus of irrigation water quality. Recently, there is increasing evidence for the occurrence of geogenic contaminants in water. The appearance of trace elements and an increase in the use of wastewater has highlighted the vulnerability and complexities of the composition of irrigation water and its role in ensuring proper crop growth, and …

Pawnee Dam Inflow Design Flood (Idf) Update And Stage-Frequency Curve Development Using Rmcrfa, Jennifer P. Christensen, Joshua J. Melliger

United States Geological Survey: Water Reports and Publications

Pawnee Dam is one of the ten Salt Creek Dams designed and built in the 1960s to mitigate flooding in Lincoln, Nebraska. This short paper illustrates the update of the Pawnee Dam inflow design flood (IDF) through calibration to recent high flow events and the development of its stage-frequency or hydrologic loading curve with the U.S. Army Corps of Engineers’ Risk Management Center Reservoir Frequency Analysis (RMC-RFA) model. The IDF update follows Engineering Regulation 1110-8-2, Inflow Design Flood for Dams and Reservoirs, including unit hydrograph peaking and two antecedent pool elevations. Background information on the original design of the dam …

Hydroclimate Drivers And Atmospheric Dynamics Of Floods, Nasser Najibi

Dissertations and Theses

Our preliminary survey showed that most of the recent flood-related studies did not formally explain the physical mechanisms of long-duration and large-peak flood events that can evoke substantial damages to properties and infrastructure systems. These studies also fell short of fully assessing the interactions of coupled ocean-atmosphere and land dynamics which are capable of forcing substantial changes to the flood attributes by governing the exceeding surface flow regimes and moisture source-sink relationships at the spatiotemporal scales important for risk management. This dissertation advances the understanding of the variability in flood duration, peak, volume, and timing at the regional to the …

Transition Pathways To Sustainable Agricultural Water Management: A Review Of Integrated Modeling Approaches, Erin M.K. Haacker, Vaishali Sharda, Amanda M. Cano, R. Aaron Hrozencik, Agustin Nunez, Zachary Zambreski, Soheil Nozari, Garvey Engulu B, Smith, Lacey Moore, Sumit Sharma, Prasanna Gowda, Chittaranjan Ray, Meagan Schipanski, Reagan Waskom

Nebraska Water Center: Faculty Publications

Agricultural water management (AWM) is an interdisciplinary concern, cutting across traditional domains such as agronomy, climatology, geology, economics, and sociology. Each of these disciplines has developed numerous process-based and empirical models for AWM. However, models that simulate all major hydrologic, water quality, and crop growth processes in agricultural systems are still lacking. As computers become more powerful, more researchers are choosing to integrate existing models to account for these major processes rather than building new cross-disciplinary models. Model integration carries the hope that, as in a real system, the sum of the model will be greater than the parts. However, …

Simulating The Impacts Of Irrigation Levels On Soybean Production In Texas High Plains To Manage Diminishing Groundwater Levels, Vaishali Sharda, Prasanna H. Gowda, Gary Marek, Isaya Kisekka, Chittaranjan Ray, Pradip Adhikari

Nebraska Water Center: Faculty Publications

There is an increasing need to strategize and plan irrigation systems under varied climatic conditions to support efficient irrigation practices while maintaining and improving the sustainability of groundwater systems. This study was undertaken to simulate the growth and production of soybean [Glycine max (L.)] under different irrigation scenarios. The objectives of this study were to calibrate and validate the CROPGRO-Soybean model under Texas High Plains’ (THP) climatic conditions and to apply the calibrated model to simulate the impacts of different irrigation levels and triggers on soybean production. The methodology involved combining short-term experimental data with long-term historical weather data (1951–2012), …

Environmental Fate And Microbial Effects Of Monensin, Lincomycin, And Sulfamethazine Residues In Soil, Matteo D'Alessio, Lisa M. Durso, Daniel N. Miller, Brian Woodbury, Chittaranjan Ray, Daniel D. Snow

Nebraska Water Center: Faculty Publications

The impact of commonly-used livestock antibiotics on soil nitrogen transformations under varying redox conditions is largely unknown. Soil column incubations were conducted using three livestock antibiotics (monensin, lincomycin and sulfamethazine) to better understand the fate of the antibiotics, their effect on nitrogen transformation, and their impact on soil microbial communities under aerobic, anoxic, and denitrifying conditions. While monensin was not recovered in the effluent, lincomycin and sulfamethazine concentrations decreased slightly during transport through the columns. Sorption, and to a limited extent degradation, are likely to be the primary processes leading to antibiotic attenuation during leaching. Antibiotics also affected microbial respiration …

Riverbank Filtration Impacts On Post Disinfection Water Quality In Small Systems—A Case Study From Auburn And Nebraska City, Nebraska, Matteo D'Alessio, Bruce Dvorak, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

Small water systems can experience a fluctuating quality of water in the distribution system after disinfection. As chlorine is the most common disinfectant for small systems, the occurrence of disinfection byproducts (DBPs) represents a common problem for these systems. Riverbank filtration (RBF) can be a valuable solution for small communities located on riverbanks. The objectives of this study were to evaluate (i) the improvements in water quality at two selected RBF systems, and (ii) the potential lower concentrations of DBPs, in particular, trihalomethanes (THMs), in small systems that use RBF. Two small communities in Nebraska, Auburn and Nebraska City, using …

Flow Analysis Through Collector Well Laterals: A Case Study From Sonoma County Water Agency, California, Matteo D'Alessio, John Lucio, Ernest Williams, James Warner, Donald Seymour, Jay Jasperse, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

The Sonoma County Water Agency (SWCA) uses six radial collector wells along the Russian River west of Santa Rosa, to provide water for several municipalities and water districts in north-western California. Three collector wells (1, 2, and 6) are located in the Wohler area, and three collector wells (3, 4, and 5) are located in the Mirabel area. The objective of this paper is to highlight the performance of the three collector wells located in the Mirabel area since their construction. The 2015 investigation showed a lower performance of Collectors 3 and 4 compared to their original performances after construction …

The Long Term Effect Of Agricultural, Vadose Zone And Climatic Factors On Nitrate Contamination In Nebraska’S Groundwater System, Pongpun Juntakut, Daniel D. Snow, Erin M.K. Haacker, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

A four-decade dataset (1974–2013) of 107,823 nitrate samples in 25,993 wells from western and eastern parts of Nebraska was used to assess long-term trends of groundwater nitrate concentration and decadal changes in the extent of groundwater nitrate-contaminated areas (NO₃-N≥10 mg N/L) over the entire state. Spatial statistics and regressions were used to investigate the relationships between groundwater nitrate concentrations and several potential natural and anthropogenic factors, including soil drainage capacities, vadose zone characteristics, crop production areas, and irrigation systems. The results of this study show that there is no statistically significant trend in groundwater nitrate concentrations …

Assessing The Feasibility Of Soil Infiltration Trenches For Highway Runoff Control On The Island Of Oahu, Hawaii, Martina Sobotkova, Jaromir Dusek, Ghasem Alavi, Laxman Sharma, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

The coastal waters of Hawaii are extremely important for recreation as well as for the health of the marine environment. Non-point source pollution from storm runoff poses a great threat to surface water quality in Hawaii. The State of Hawaii Department of Transportation (HDOT) includes infiltration trenches as a best management practice (BMP) option to reduce pollution caused by stormwater runoff. HDOT guidelines state that the implementation of BMPs is needed to reduce sediment and pollutant loads to streams and the ocean. In this study, the suitability of soils adjacent to highways on Oahu for the siting of infiltration trenches …

A Model To Predict Concentrations And Uncertainty For Mercury Species In Lakes, Ashley Hendricks

Dissertations, Master's Theses and Master's Reports

To increase understanding of mercury cycling, a seasonal mass balance model was developed to predict mercury concentrations in lakes and fish. Results indicate that seasonality in mercury cycling is significant and is important for a northern latitude lake. Models, when validated, have the potential to be used as an alternative to measurements; models are relatively inexpensive and are not as time intensive. Previously published mercury models have neglected to perform a thorough validation. Model validation allows for regulators to be able to make more informed, confident decisions when using models in water quality management. It is critical to quantify uncertainty; …

Use Of Long Term Weather Data And Spatially Delineated Field Attributes To Predict Water And Energy Conservation From Variable Rate Irrigation, Sahil Sharma

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

The declining levels of the Ogallala aquifer calls for more judicious use of water. Studies have shown that VRI has the potential for water savings. But adoption of VRI is still very low. The major reason is lack of information on the returns from the VRI systems and its feasibility in different fields. Also, a quantification of the required reduction in prices of VRI is necessary. So, an economic return analysis of VRI strategies was done to compare it to uniform irrigation management (UIM) using a water balance model based on long term weather data and field properties for a …

Suitability Of River Delta Sediment As Proppant, Missouri And Niobrara Rivers, Nebraska And South Dakota, 2015, Ronald B. Zelt, Christopher M. Hobza, Bethany L. Burton, Nathaniel J. Schaepe, Nadine M. Piatak-Hackley

United States Geological Survey: Water Reports and Publications

Document abstract

Sediment management is a challenge faced by reservoir managers who have several potential options, including dredging, for mitigation of storage capacity lost to sedimentation. As sediment is removed from reservoir storage, potential use of the sediment for socioeconomic or ecological benefit could potentially defray some costs of its removal. Rivers that transport a sandy sediment load will deposit the sand load along a reservoir-headwaters reach where the current of the river slackens progressively as its bed approaches and then descends below the reservoir water level. Given a rare combination of factors, a reservoir deposit of alluvial sand has …

Micro-Spi Sediment Profile Imaging Micro-Inspector, Andrew P. Corvin, Caleb T. Davies, Matt R. Ferrari

Mechanical Engineering

This project was proposed by Dr. Brian Paavo through a desire to more easily study the benthic sediment layers of the ocean. To do so, he asked us to build a simple and compact machine for use in sediment profile imagery (SPI). Although devices like this already exist, they are all large scale devices that require a ship with a crane to deploy, which is expensive and time consuming. Instead, he desired a “micro” SPI, which is capable of being deployed from a small vessel that can easily navigate shallow waters. Our interpretation of these requirements was as follows: a …

Understanding N-Nitrosodimethylamine Formation In Water: Chloramine Chemistry, Kinetics, And A Proposed Reaction Pathway, Huong Thu Pham

Graduate Theses and Dissertations

The formation of N-nitrosodimethylamine (NDMA) in drinking water systems is a concern because of its potential carcinogenicity and occurrence at toxicologically relevant levels. The postulated mechanism for NDMA formation involves a substitution between dichloramine and amine-based precursors to form an unsymmetrical dimethylhydrazine (UDMH), which is then oxidized by ground-state molecular oxygen to form NDMA. However, this latter reaction is spin forbidden, thus likely occurs at a slow rate. It is hypothesized that the reaction between monochloramine and hydroxylamine (a nitrification product) may form an intermediate, which is involved in the NDMA formation pathway. This intermediate may also be generated from …

Oxidation Of Substituted Catechols At The Air-Water Interface: Production Of Carboxylic Acids, Quinones, And Polyphenols, Elizabeth A. Pillar, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic activities contribute benzene, toluene, and anisole to the environment, which in the atmosphere are converted into the respective phenols, cresols, and methoxyphenols by fast gas-phase reaction with hydroxyl radicals (HO(•)). Further processing of the latter species by HO(•) decreases their vapor pressure as a second hydroxyl group is incorporated to accelerate their oxidative aging at interfaces and in aqueous particles. This work shows how catechol, pyrogallol, 3-methylcatechol, 4-methylcatechol, and 3-methoxycatechol (all proxies for oxygenated aromatics derived from benzene, toluene, and anisole) react at the air-water interface with increasing O3(g) during τc ≈ 1 μs contact time and contrasts their …

Compensatory Response Of Fathead Minnow Larvae Following A Pulsed In-Situ Exposure To A Seasonal Agricultural Runoff Event, Jonathan M. Ali, John Sangster, Daniel D. Snow, Shannon L. Bartelt-Hunt, Alan S. Kolok

Nebraska Water Center: Faculty Publications

Agriculturally-dominated waterways such as those found throughout the Midwestern United States often experience seasonal pulses of agrichemical contaminants which pose a potential hazard to aquatic organisms at varying life stages. The objective of this study was to characterize the developmental plasticity of fathead minnow larvae in a natural environment subject to a seasonal episodic perturbation in the form of a complex mixture of agricultural stressors. Fathead minnow larvae were maintained at the Elkhorn River Research Station for a 28-d in situ exposure to an agrichemical pulse event.Minnow larvae were sampled after 14 and 28 days to characterize developmental plasticity through …

Water–Soil–Vegetation Dynamic Interactions In Changing Climate, Xixi Wang, Xuefeng Chu, Tingxi Liu, Xiangju Cheng, Rich Whittecar

Civil & Environmental Engineering Faculty Publications

Previous studies of land degradation, topsoil erosion, and hydrologic alteration typically focus on these subjects individually, missing important interrelationships among these important aspects of the Earth's system. However, an understanding of water–soil–vegetation dynamic interactions is needed to develop practical and effective solutions to sustain the globe's eco-environment and grassland agriculture, which depends on grasses, legumes, and other fodder or soil-building crops. This special issue is intended to be a platform for a discussion of the relevant scientific findings based on experimental and/or modeling studies. Its 12 peer-reviewed articles present data, novel analysis/modeling approaches, and convincing results of water–soil–vegetation interactions under …

Spatiotemporal Distribution Of Eutrophication In Lake Tai As Affected By Wind, Wenhui Zhang, Qiujin Xu, Xixi Wang, Xiaozhen Hu, Cheng Wang, Yan Pang, Yanbin Hu, Yang Zhao, Xiao Zhao

Civil & Environmental Engineering Faculty Publications

One common hypothesis is that wind can affect concentrations of nutrients (i.e., nitrogen and phosphorus) and chlorophyll-a (Chl-a) in shallow lakes. However, the tests of this hypothesis have yet to be conclusive in existing literature. The objective of this study was to use long-term data to examine how wind direction and wind speed affect the spatiotemporal variations of total nitrogen (TN), total phosphorus (TP) and Chl-a in Lake Tai, a typical shallow lake located in east China. The results indicated that the concentrations of nutrients and Chl-a tended to decrease from the northwest to the southeast of Lake Tai, with …

Tidal-Fluvial And Estuarine Processes In The Lower Columbia River: Ii. Water Level Models, Floodplain Wetland Inundation, And System Zones, David A. Jay, Amy B. Borde, Heida Diefenderfer

Civil and Environmental Engineering Faculty Publications and Presentations

Spatially varying water-level regimes are a factor controlling estuarine and tidal-fluvial wetland vegetation patterns. As described in Part I, water levels in the Lower Columbia River and estuary (LCRE) are influenced by tides, river flow, hydropower operations, and coastal processes. In Part II, regression models based on tidal theory are used to quantify the role of these processes in determining water levels in the mainstem river and floodplain wetlands, and to provide 21-year inundation hindcasts. Analyses are conducted at 19 LCRE mainstem channel stations and 23 tidally exposed floodplain wetland stations. Sum exceedance values (SEVs) are used to compare wetland …

Chlorine Demand Shows Thresholds And Hierarchy With Source Water Quality At Beaver Lake, Arkansas, Jaime M. Gile

Graduate Theses and Dissertations

This study investigated the effects of source water quality in Beaver Lake on the amount of chlorine (Cl) needed to develop decision support system to help guide chlorination practices in pre-treatment of source water. Chlorine demand assays were performed on water samples from Beaver Lake collected from the intake structure at Beaver Water District from March 2014 through August 2015, and using data from these assays, the two points of interest in this study were the Cl dose at which Cl residuals began to accumulate and the mean Cl demand occurring after that dose. Three methods of analysis were used …

Trend Analysis Of Water Quality In Northwest Arkansas Streams Reflects Changes In The Watershed, Zachary Paul Simpson

Graduate Theses and Dissertations

Watershed export of nutrients, sediments, and chemicals impacts receiving waters. Changes within the watershed (e.g., anthropogenic or climatic) can alter the transport of constituents in streams. Stream monitoring is crucial for understanding these effects. This study developed a potential improvement to flow-adjusting constituent concentrations in streams, an important step of analyzing monitoring data in lotic systems for trends. The method incorporates a K-fold cross-validation procedure to optimize a model explaining the relationship between the concentration and streamflow, thus providing a valuable tool to researchers in water quality. Additionally, two case studies were conducted on watersheds located in northwest Arkansas using …

Evaluating A Measure-Calculate Method For Determining Sediment Oxygen Demand In Lakes, Adrian Beirise

Graduate Theses and Dissertations

A steady-state mass diffusion model used with simple measurable and calculable inputs for determining sediment oxygen demand (SOD) is compared to an intact core incubation (ICI) SOD method using samples from three lakes. The mass diffusion model coupled with inputs is known as the measure-calculate method (M-C) and is a potential alternative to existing methods for measuring SOD which are more complex, time-consuming, and costly. The M-C method requires inputs for volumetric sediment oxygen uptake (Ṅsed), sediment density and porosity, and water properties. Ṅsed was determined by suspending sediment in oxygen-saturated water with a DO probe and determining the steady …

Electrodeionization Versus Electrodialysis: A Clean-Up Of Produced Water In Hydraulic Fracturing, Brigitte Marie Rodgers

Graduate Theses and Dissertations

Electrodeionization (EDI) is a widely studied process ranging from applications in wastewater clean-up in the food and beverage industry to purifying organic compounds. To date, there are no apparent studies on applying this technology to produced wastewater recovered from hydraulic fracking sites. Water consumption within hydraulic fracturing sites can reach in the upwards of millions of gallons per site, so a need for a water recycling process becomes necessary within areas where water requirements are scarce. Implementation of an EDI module that is capable of handling high salt solutions from produced wastewater in subsequent fracturing practices will decrease overall water …

Drinking Water Treatment: Salt-Free Water “Softener” Options, Bruce I. Dvorak

Department of Civil and Environmental Engineering: Faculty Publications

New no-salt technologies may be effective in treating hard water, but consumers should carefully investigate product claims prior to buying a specific treatment device.

Hard water is not a health risk, but many Nebraska consumers find hard water to be a nuisance because of mineral buildup on plumbing fixtures, including water heaters; unsightly film on glass and crystal wares; and poor soap and/or detergent performance. Water described as “hard” contains high amounts of dissolved calcium and magnesium, which are positively charged contaminants called cations.

Water hardness often is expressed as grains of hardness per gallon of water (gpg) or milligrams …

Detection, Occurrence And Fate Of Emerging Contaminants In Agricultural Environments, Daniel D. Snow, David A. Cassada, Shannon L. Bartelt-Hunt, Xu Li, Matteo D'Alessio, Yun Zhang, Yuping Zhang, J. Brett Sallach

Nebraska Water Center: Faculty Publications

A total of 59 papers published in 2015 were reviewed ranging from detailed descriptions of analytical methods, to fate and occurrence studies, to ecological effects and sampling techniques for a wide variety of emerging contaminants likely to occur in agricultural environments. New methods and studies on veterinary pharmaceuticals, steroids, antibiotic resistance genes in agricultural environments continue to expand our knowledge base on the occurrence and potential impacts of these compounds. This review is divided into the following sections: Introduction, Analytical Methods, Steroid Hormones, Pharmaceutical Contaminants, Transformation Products, and “Antibiotic Resistance, Drugs, Bugs and Genes”.