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Full-Text Articles in Fresh Water Studies

Cytotoxicity And Mutagenicity Of Disinfection Byproduct Mixtures Formulated Using Free Chlorine And Monochloramine, Yonas Ghebremedhin Dec 2019

Cytotoxicity And Mutagenicity Of Disinfection Byproduct Mixtures Formulated Using Free Chlorine And Monochloramine, Yonas Ghebremedhin

Graduate Theses and Dissertations

Bioassays have been used extensively to assess various toxicity endpoints of drinking water disinfection byproducts (DBPs), but an emphasis on single compounds prevails. In this research, DBP mixtures were assessed using a cytotoxicity test with Chinese Hamster Ovary (CHO) cells and an Ames fluctuation test with Salmonella typhimurium TA-98 and TA-100 with and without S9 rat liver homogenate. Seven whole mixture DBP concentrates were formulated using reconstituted natural organic matter (NOM) extracts from the Upper Mississippi River using scaled disinfectant dosing protocols with free chlorine and monochloramine in the presence and absence of added bromide. DBPs were identified by gas …


Removal Of Selected Pharmaceuticals And Personal Care Products In Wastewater Treatment Plant In Jordan, Othman Al-Mashaqbeh, Diya Alsafadi, Sahar Dalahmeh, Shannon L. Bartelt-Hunt, Daniel D. Snow Sep 2019

Removal Of Selected Pharmaceuticals And Personal Care Products In Wastewater Treatment Plant In Jordan, Othman Al-Mashaqbeh, Diya Alsafadi, Sahar Dalahmeh, Shannon L. Bartelt-Hunt, Daniel D. Snow

Nebraska Water Center: Faculty Publications

The largest wastewater treatment plant in Jordan was monitored in the summer to determine the removal of pharmaceuticals and personal care products (PPCPs). Grab samples were collected from the influent and effluent of As-Samra Wastewater Treatment Plant (WWTP). Liquid chromatography and tandem mass spectrometry (LC–MS/MS) were utilized to determine the concentrations of 18 compounds of pharmaceuticals and personal care products (PPCPs). The results showed that 14 compounds were detected in the collected samples from the influent and effluent of As-Samra WWTP. These compounds are 1,7-dimethylxanthine, amphetamine, acetaminophen, caffeine, carbamazepine, cimetidine, cotinine, diphenhydramine, methylenedioxymethamphetamine (MDMA), morphine, phenazone, sulfamethazine, sulfamethoxazole, thiabendazole, and …


Perchlorate Behavior In The Context Of Black Carbon And Metal Cogeneration Following Fireworks Emission At Oak Lake, Lincoln, Nebraska, Usa, Manish Kumar, Daniel D. Snow, Yusong Li, Patrick Shea Jul 2019

Perchlorate Behavior In The Context Of Black Carbon And Metal Cogeneration Following Fireworks Emission At Oak Lake, Lincoln, Nebraska, Usa, Manish Kumar, Daniel D. Snow, Yusong Li, Patrick Shea

Nebraska Water Center: Faculty Publications

The imprints of fireworks displays on the adjacent water body were investigated from the perspective of cogeneration of black carbon, metals and perchlorate (ClO4). In particular, the mixing and dissipation of ClO4 were studied at Oak Lake, Lincoln, Nebraska, following fireworks displays in 2015 and 2016. Following the display, ClO4 concentration in the water increased up to 4.3 μg/L and 4.0 μg/L in 2015 and 2016, respectively. A first-order model generally provided a good fit to the measured perchlorate concentrations from which the rate of dissipation was estimated as 0.07 d–1 in …


The Effects Of Reactant Concentration And Air Flow Rate In The Consumption Of Dissolved O2 During The Photochemistry Of Aqueous Pyruvic Acid, Alexis J. Eugene, Marcelo I. Guzman Mar 2019

The Effects Of Reactant Concentration And Air Flow Rate In The Consumption Of Dissolved O2 During The Photochemistry Of Aqueous Pyruvic Acid, Alexis J. Eugene, Marcelo I. Guzman

Chemistry Faculty Publications

The sunlight photochemistry of the organic chromophore pyruvic acid (PA) in water generates ketyl and acetyl radicals that contribute to the production and processing of atmospheric aerosols. The photochemical mechanism is highly sensitive to dissolved oxygen content, [O2(aq)], among other environmental conditions. Thus, herein we investigate the photolysis (λ ≥ 305 nm) of 10–200 mM PA at pH 1.0 in water covering the relevant range 0 ≤ [O2(aq)] ≤ 1.3 mM. The rapid consumption of dissolved oxygen by the intermediate photolytic radicals is monitored in real time with a dissolved oxygen electrode. …


Irrigation Water Quality—A Contemporary Perspective, Arindam Malakar, Daniel D. Snow, Chittaranjan Ray Jan 2019

Irrigation Water Quality—A Contemporary Perspective, Arindam Malakar, Daniel D. Snow, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

In the race to enhance agricultural productivity, irrigation will become more dependent on poorly characterized and virtually unmonitored sources of water. Increased use of irrigation water has led to impaired water and soil quality in many areas. Historically, soil salinization and reduced crop productivity have been the primary focus of irrigation water quality. Recently, there is increasing evidence for the occurrence of geogenic contaminants in water. The appearance of trace elements and an increase in the use of wastewater has highlighted the vulnerability and complexities of the composition of irrigation water and its role in ensuring proper crop growth, and …


Hydroclimate Drivers And Atmospheric Dynamics Of Floods, Nasser Najibi Jan 2019

Hydroclimate Drivers And Atmospheric Dynamics Of Floods, Nasser Najibi

Dissertations and Theses

Our preliminary survey showed that most of the recent flood-related studies did not formally explain the physical mechanisms of long-duration and large-peak flood events that can evoke substantial damages to properties and infrastructure systems. These studies also fell short of fully assessing the interactions of coupled ocean-atmosphere and land dynamics which are capable of forcing substantial changes to the flood attributes by governing the exceeding surface flow regimes and moisture source-sink relationships at the spatiotemporal scales important for risk management. This dissertation advances the understanding of the variability in flood duration, peak, volume, and timing at the regional to the …


Pawnee Dam Inflow Design Flood (Idf) Update And Stage-Frequency Curve Development Using Rmcrfa, Jennifer P. Christensen, Joshua J. Melliger Jan 2019

Pawnee Dam Inflow Design Flood (Idf) Update And Stage-Frequency Curve Development Using Rmcrfa, Jennifer P. Christensen, Joshua J. Melliger

United States Geological Survey: Water Reports and Publications

Pawnee Dam is one of the ten Salt Creek Dams designed and built in the 1960s to mitigate flooding in Lincoln, Nebraska. This short paper illustrates the update of the Pawnee Dam inflow design flood (IDF) through calibration to recent high flow events and the development of its stage-frequency or hydrologic loading curve with the U.S. Army Corps of Engineers’ Risk Management Center Reservoir Frequency Analysis (RMC-RFA) model. The IDF update follows Engineering Regulation 1110-8-2, Inflow Design Flood for Dams and Reservoirs, including unit hydrograph peaking and two antecedent pool elevations. Background information on the original design of the dam …