Atmospheric Sciences Commons^™

Photochemistry Of Quinones And Combustion-Derived Particles, Desiree J. Sarmiento

Electronic Theses and Dissertations

Quinones are ubiquitous species that can be produced from the photochemical aging of combustion-derived particles (CDPs). Polycyclic aromatic hydrocarbons (PAHs) are a major component of CDPs and are precursors to quinones and other oxidized products (OPAHs). My work first expanded on the PAH and OPAH photochemistry research of Dr. John Haynes, who showed that anthracene (ANT) oxidizes into 1,4-naphthoquinone (1,4-NAPQ), 1,4-anthraquinone (1,4-ANTQ), and 9,10-anthraquinone (9,10-ANTQ), and of Dr. Heather Runberg, who demonstrated the ability of ANT and these quinones to generate reactive oxygen species (ROS). Then at the Pacific Northwest National Laboratory (PNNL), I was given the opportunity to investigate …

Influence Of Tropical Cyclones, Southwest Monsoon, And Tropical Cyclone-Enhanced Southwest Monsoon On Rainfall Variability Over The Western Coast Of The Philippines, Alwin Bathan, Lyndon Mark Olaguera, Faye Abigail T. Cruz, Jose Ramon T. Villarin, Joel T. Maquiling, Maria Obiminda L. Cambaliza, John A. Manalo, Jun Matsumoto

SOSE Affiliate: Manila Observatory

This study investigates the processes driving interannual variability of rainfall over the western coast of the Philippines during the peak southwest monsoon (SWM) months (July–September) from 1961 to 2022. Specifically, it describes how tropical cyclones (TC), SWM, and TC-enhanced SWM influence SWM rainfall variability. Rainfall measurements from 11 stations along the western coast of the Philippines were classified into three types: direct TC rainfall (PD), indirect TC rainfall (PI), and SWM rainfall (PSM). The yearly contributions of PD, PI, and PSM to SWM rainfall were estimated to be 15.4 %, 33.1 %, and 51.5 %, respectively. Furthermore, four rainfall variability …

High-Resolution Temperature Profiling In The Pi Chamber: Variability Of Statistical Properties Of Temperature Fluctuations, Robert Grosz, Kamal Kant Chandrakar, Raymond A. Shaw, Jesse C. Anderson, Will Cantrell, Szymon P. Malinowski

Michigan Tech Research Data

This study delves into the small-scale temperature structure inside the turbulent convection Pi Chamber under three temperature differences (10, 15, and 20 K) at Rayleigh number Ra ~ 10^9 and Prandtl number Pr = 0.7. We performed high-frequency measurements (2 kHz) with the UltraFast Thermometer (UFT) at selected points along the vertical axis. The miniaturized design of the sensor with a resistive platinum-coated tungsten wire, 2.5 μm thick and 3 mm long, mounted on a miniature wire probe, allowed for vertically undisturbed temperature
profiling through the chamber’s depth spanning from 8 cm above the bottom to 5 cm below the …

Pm2.5 Forecasting At U.S. Embassies And Consulates Worldwide Using Nasa Model Powered By Machine Learning, Junhyeon Seo, Alqamah Sayeed, Seohui Park, John Kerekes, Stephanie Christel, Mary Tran, Pawan Gupta

Articles

Air quality forecasting is crucial for public health, especially in rural, suburban, and developing areas lacking reliable monitoring data. Hybrid monitoring (surface, satellite, and models) offers a scalable, cost‐ effective solution for tracking pollution and trends. This work presents a machine learning model that integrates ground measurements with global model outputs assimilating satellite observations to forecast air quality. Ground measurements of fine particulate matter (PM2.5) from over 60 U.S. embassies and consulates were used to calibrate global model outputs for local air quality forecasting. Multi‐channel input data was prepared using the Goddard Earth Observing System forward processing for meteorology and …

Large-Scale Groundwater System Characterization Using Pressure Responses To Barometric Perturbations Caused By The 2022 Hunga Tonga-Hunga Ha'apai Volcanic Eruption, Anhua He, Yang Liu, Fan Zhang, Huamei Zhang, Ramesh P. Singh, Yanzhang Wang

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Hunga Tonga-Hunga Ha'apai volcanic erupted on 15 January 2022, causing Lamb waves to propagate throughout the global troposphere. However, reports on volcanic eruptions–pressure fluctuations and water level dynamics are lacking. We quantified the propagation processes of Lamb waves induced by the Tonga volcanic eruption. Barometric pressure data collected at 1-min intervals at 485 meteorological stations in China showed that the eruption induced an atmospheric pressure event with an amplitude of ∼2 hPa over an hour and a wave speed of 295 m/s. Concomitant groundwater levels were available at 338 wells to find the barometric response to the volcanic event. The …

Investigating The Role Of Aerosols In Extreme Precipitation Events Along The Gulf Coast Of The U.S.A., Wenjia Cao

LSU Doctoral Dissertations

Atmospheric aerosols have been found to influence tropical cyclone (TC) and flood event development. In this study, the Weather Research and Forecasting model is applied to investigate specific microphysical impacts and aerosol sensitivity to heavy precipitation and TC events in the U.S. Gulf Coastal area. The Thompson aerosol-aware scheme with regular and adjusted aerosol concentration scenarios is used to quantify precipitation, wind field, horizontal/vertical structures, and track variations, by aerosol mixing ratio. In general, results for the three storms analyzed (the 2016 Baton Rouge, Louisiana, flood event (Chapter 2); Hurricane Harvey in 2017 (Chapter 3); and an idealized storm event …

Estimating The Future Frequency Of Bonnet Carré Spillway Openings, Kayla Thomas

LSU Master's Theses

In the 2010s, the Bonnet Carré Spillway (BCS) in southeastern Louisiana, U.S.A., experienced an unprecedented uptick in openings to mitigate the possibility of flooding, including a record double-opening in 2019. Both the environmental consequences of BCS openings associated with nutrients that run from the Mississippi River into Lake Pontchartrain and the synoptic-scale meteorological conditions that necessitate these openings are poorly understood. With the unexpectedly frequent openings in recent years and the ever-present threat of climate change, it is vital to consider the future shift of synoptic-scale climate patterns and how it can relate to BCS openings. Understanding the potential for …

From Tree Rings To Streamflow: Reconstructing The Hydroclimatic History Of The Mississippi River Basin Over The Past Millennia, Brandon Mcdaniel

Theses and Dissertations

The Mississippi River Basin (MRB), the largest watershed in the United States, plays a central role in shaping regional hydroclimate. This study reconstructs streamflow variability in the MRB from the year 1200 to 2005 by applying principal component regression to streamflow data from 51 gauges and the North American Drought Atlas (NADA), a tree-ring-based reconstruction of the summer self-calibrating Palmer Drought Severity Index. Verification statistics indicated strong predictive skill across the domain. These findings provide critical insight into long-term hydroclimatic variability in the MRB and underscore the value of paleoclimate records for improving water resource assessments.

Dry And Wet Deposition Of Atmospheric Microplastics In Las Vegas, Nevada, Laine Adame

UNLV Theses, Dissertations, Professional Papers, and Capstones

Plastics have been one of the most widely used man-made materials since their inception, and production is expected to grow by five percent every year. Plastic waste has become a growing global environmental issue. Primary MPs are plastics that are created to be intentionally tiny for their specific functional purpose. Secondary microplastics (MPs) are byproducts of plastic waste occurring due to the breakdown of larger plastics resulting in the presence and accumulation of MPs in the environment. MPs are defined as tiny particles of plastic between 5 mm and 1 μm in size. MPs have been found in the deep …

Climate Constrains The Enhancement Of Co2 Fertilization On Forest Gross Primary Productivity, Xinyuan Wei, Daniel J. Hayes, Christopher R. Schwalm, Joshua B. Fisher, Deborah N. Huntzinger, Lei Ma, Rodrigo Vargas, Nathaniel A. Brunsell

Mathematics, Physics, and Computer Science Faculty Articles and Research

Forest gross primary production (GPP) is influenced by the interplay between climate conditions and atmospheric CO₂ levels, which interact in complex ways, generating both compensating and amplifying effects. In this study, eddy covariance flux measurements from 50 forest ecosystems were integrated with simulations from 14 terrestrial biosphere models to investigate how climate conditions and atmospheric CO₂ concentrations regulate forest GPP. This approach bridges site-level observations with biome-scale model estimates to develop a global understanding. Our findings suggest that in boreal and cold temperate regions, temperature primarily constrains the enhancement of the CO₂ fertilization on forest GPP; however, …

Interpreting Spatial And Temporal Variations In Global Air Quality Using A Chemical Transport Modeling Framework, Deepangsu Chatterjee

McKelvey School of Engineering Graduate Student Theses & Dissertations

Air quality is a major health concern. Exposure to fine particulate matter (PM2.5) and nitrogen oxides (NOx = NO + NO2) is a leading mortality risk factor across the world. Numerous cohort studies conducted over the past two decades have identified strong associations between ambient air pollution and human mortality, highlighting the adverse health effects of PM2.5 and NO2 exposure. My thesis includes three studies that contribute to a better understanding of air quality. In many regions, including South Asia, elevated emissions from various sectors and sparse ground monitoring are significant challenges. The concurrent development and use of the high-performance …

Global Sporadic-E Prediction And Climatology Using Deep Learning, J. A. Ellis, Daniel J. Emmons, M. B. Cohen

Faculty Publications

Sporadic-E (E_s) is an ionospheric phenomenon defined by strong layers of plasma which may interfere with radio wave propagation. In this work, we develop deep learning models to improve the understanding of E_s, including the presence, intensity and height of the layers. We developed three separate models. The first, building off earlier work in (J. A. Ellis et al., 2024, link in AFIT Scholar, 10.1029/2023sw003669), includes only the main features from radio occultation (RO) measurements. The second adds to that time, date, location, geomagnetic and solar indices, solar winds, x-ray flux, weather and lightning. A …

The Human Legacy: Agriculture, Civilizations, Strife, And Pandemics Changing Our Climate, Jacalyn M. Wittmer Malinowski

Climate Change and the Individual, 2025-26

For most of human history, climate has shaped our lives, while our influence on it remained minimal. However, the notion that early humans had no measurable impact on the climate before industrialization is inaccurate. Early in human history, activities – such as the rise of agriculture, the growth of civilizations, periods of conflict, and pandemics – altered greenhouse gas levels in the atmosphere. These changes contributed to significant periods of climate change long before the burning of fossil fuels set us on the path to today’s global climate crisis.

The Influence Of Complex Terrain On The Turin, New York Tornado Of 2023, Alex D. Kramer

Atmospheric and Environmental Sciences Honors Program

Although uncommon as compared to other regions of the United States, the Northeast does experience significant tornados; those rated F/EF3 and above, of which some have had profound impacts on the region. Due to the diverse topography of the region, including its many northsouth oriented river valleys, most of these significant tornados traversed considerable changes in elevation throughout their lifetime. This study seeks to better understand the impacts of local topography on the intensity and overall progression of a significant tornadic event through using the most recent Northeast EF3: the Turin, NY tornado. With the consideration of previous studies involving …

The Role Of The Neutral Wind In Observations Of High-Latitude Ionospheric Energy Transfer, Andrew M. Pepper

All Dissertations

Joule heating results from the collisional interaction between ions and neutrals and serves as a crucial mechanism for energy transfer between Earth's magnetosphere and ionosphere-thermosphere system, particularly at high latitudes. This dissertation investigates the modulation of Joule heating by altitude-resolved neutral winds, electric fields, and conductivity variations through multi-instrument observational analysis and modeling that incorporates both in-situ and ground-based sources to measure the main drivers of ion-neutral coupling. The observations presented consistently demonstrate a dual regulatory effect of the neutral wind on energy deposition that varies systematically with both geomagnetic activity level and proximity to auroral boundaries. In regions characterized …

The Petm: A Window Into Earth's Future Climate, Jacalyn M. Wittmer Malinowski

Climate Change and the Individual, 2025-26

The Paleocene-Eocene Thermal Maximum (PETM) is not just an event that occurred in Earth’s distant past (~55 million years ago) but is a crucial lesson for today’s meteoric climate change. The PETM offers a historical parallel of rapid flux of greenhouse gases into the atmosphere that caused global warming, ocean acidification, dramatic changes in weather, and extinctions. This global warming event was the result of 20,000 years of “rapid” warming (in geological terms) however, we are experiencing rates of warming that are 5-10x higher than PETM levels. We are not experiencing rapid warming today, in comparison to the past, we …

Trends And Transport Of Tropospheric Ozone From New York City To Connecticut In The Summer Of 2023, Michele Iraci

Honors Scholar Theses

Tropospheric Ozone, or O3, is a criteria pollutant contributing to most of Connecticut and New York City’s poor air quality days. It has adverse effects on human health, particularly for high-risk individuals. Ozone is produced by nitrogen oxides and volatile organic compounds from fuel combustion reacting with sunlight. The Ozone Transport Region (OTR) is a collection of states in the Northeast and Mid-Atlantic United States that experience cross-state pollution of O3. Connecticut has multiple days a year where O3 values exceed the National Ambient Air Quality Standards, requiring additional monitoring and standards because it falls in the OTR— partially due …

Simultaneous Observations Of Irregular Sporadic E Structures Using The Lwa And A Dps4d, Kenneth S. Obenberger, C. A. Taylor, Jonah J. Colman, Eugene Dao, J. Dowell, J. D. Eccles, Daniel J. Emmons, C. T. Fallen, J. M. Holmes, G. B. Taylor

Faculty Publications

Multi-instrument studies have recently shed new light on the morphology of sporadic E, especially intense sporadic E. Here we present simultaneous observations of dense sporadic E (E_s) structures using the Long Wavelength Array (LWA) radio telescopes and a Digisonde Portable Sounder 4D (DPS4D). Our coordinated observations show that the LWA radio telescopes in central New Mexico can reliably locate regions of dense Es structures as they pass over a Digisonde located over 500 km away in Texas. The LWA appears to be most sensitive to the densest E_s structures, which also appear to contain irregularities with vertical …

Global Ionospheric F Region Parameters From Gnss-Pod Limb Measurements: Evaluations And Comparisons With Two Empirical Models - Iri-2020 And Nequick-2, Nimalan Swarnalingam, Dong L. Wu, Dieter Bilitza, Daniel J. Emmons, Cornelius Csar Jude H. Salinas, Artem Smirnov, Yenca Migoya-Oru

Faculty Publications

An optimal estimation (OE) technique has recently been developed for F region electron density (Ne) using Global Navigation Satellite System (GNSS) limb sounding on low Earth orbit (LEO) satellites (COSMIC-2, Spire, and FengYun-3). This method provides unprecedented spatiotemporal sampling for global monthly Ne climatology within 100–500 km in 2 hr intervals. The global dataset, collected during mid to moderately high solar activity, is compared with leading models: IRI-2020 and NeQuick-2. Diurnal variations in summer, winter, and equinoctial months are examined for the F2-layer peak, as well as the topside and bottomside of the F region. The observed and modeled NmF2 …

Modulation Of The Pacific Meridional Mode On The Dipole Pattern Of The Conus Summertime Precipitation, Grace Affram

Student Research Symposium

Historically, the precipitation trend over the past few decades in the Contiguous United States (CONUS) exhibits a "Dry-West Wet-East" pattern; this is manifested by recent droughts/floods in the western/eastern US. However, it remains elusive what atmospheric phenomenon has potentially driven such a remarkable, and impactful precipitation pattern. Here we found that a coupled climate mode—the Pacific Meridional Mode (PMM) exerted strong impacts on the precipitation pattern over the CONUS during the summer season. We discovered a significant association between the PMM index and precipitation across the CONUS; this was manifested as a zonal dipole pattern—negative correlations in the western U.S. …

Identifying Saharan Air Layer Events And Their Relationship To Instability And Rainfall Patterns In The Tropical North Atlantic Ocean, Charles H. Dolce

LSU Master's Theses

Every year, strong North African winds across the Sahara loft dust particles and advect them westward within the Saharan Air Layer (SAL). These plumes of dust often reach the Caribbean Sea and can heavily affect regional weather patterns by suppressing convection. When concentrations are high, decreased rainfall can yield negative societal and ecological impacts, potentially leading to drought. The Puerto Rican early rainfall season (ERS), spanning from 1 April through 31 July, overlaps with Saharan dust migration periods, and systematically detecting instances of SAL activity near the island is important for understanding longer-term drought-forcing trends in the region.

Corridors of …

Water Holding Capacity Of Soil And Resilience To Drought, Taro Mieno

Cornhusker Economics

For the past two years, I have been involved in an NSF-funded research project titled “RII Track-2 FEC: Supporting Rural Livelihoods in the Water-Stressed Central High Plains.” The overarching goal of this project is to evaluate the potential of microbials and biochar to enhance soil water holding capacity (hereafter, WHC), thereby improving drought resilience in crop production and reducing irrigation demand to slow aquifer depletion. Visit the project website for more details. A key component of this research is assessing the economic viability of these interventions, a task for which I am responsible.

To understand the economic benefits of increasing …

Development And Application Of Self-Supervised Machine Learning For Smoke Plume And Active Fire Identification From The Fire Influence On Regional To Global Environments And Air Quality Datasets, Nicholas Lahaye, Anastasija Easley, Kyongsik Yun, Hugo Lee, Erik Linstead, Michael J. Garay, Olga V. Kalashnikova

Engineering Faculty Articles and Research

Fire Influence on Regional to Global Environments and Air Quality (FIREX-AQ) was a field campaign aimed at better understanding the impact of wildfires and agricultural fires on air quality and climate. The FIREX-AQ campaign took place in August 2019 and involved two aircraft and multiple coordinated satellite observations. This study applied and evaluated a self-supervised machine learning (ML) method for the active fire and smoke plume identification and tracking in the satellite and sub-orbital remote sensing datasets collected during the campaign. Our unique methodology combines remote sensing observations with different spatial and spectral resolutions. With as much as a 10% …

The Effects Of Snow Cover On The Dynamic Pressure Of Nuclear Detonation Blast Waves, Adam Card, Andrew W. Decker

Faculty Publications

Blast pressure is the primary military targeting metric for nuclear weapons. Any local conditions that affect blast pressure have the potential for altering nuclear plans, both from defensive and offensive standpoints. Understanding the impact of snow to the blast wave, therefore, provides a benefit both to military planners and to warfighters on the ground, for any operation occurring in arctic environments. No existing data provides a quantitative description of how snow on the ground affects a nuclear detonation blast wave passing over it. Similar blast waves passing over dust have experimentally proven to enhance blast pressure in a localized region.1 …

Acoustic-Gravity Wave Propagation Based On Solutions To The Generalized Multi-Component Transport Equations, Benedict PiñEyro

Doctoral Dissertations and Master's Theses

Nonlinear atmospheric models have provided important insight into acoustic waves generated by natural and man-made hazards, which may steepen into shocks or N-waves while also dissipating when propagating in the thermosphere. Although models have yielded results that agree with observations of ionospheric perturbations, dynamical models for the diffusive and stratified lower thermosphere often use single gas approximations with height-dependent physical properties that omit the dynamics of the major and minor constituents. Thus, the inter-species diffusion associated with these flows (e.g. variations of mean molecular weight, and specific heat) are not accounted for. This approximation is simpler and less computationally expensive …

Planetary Atmospheres, Ryan M. Johnson

Physics Theses & Dissertations

Planetary atmospheres are frequently studied using a number of spectroscopic methods. One of these is observing spectra to analyze what molecules are present or chemical reactions may be taking place. To this end, we have produced a line list of the electronic a¹Δ−X³Σ⁻ and b¹Σ⁺−X³Σ− transitions of SO. Additionally, a line list pure rovibrational transitions of the a¹Δ and X³Σ⁻ states were produced, but lacked the necessary experimental data for the b¹Σ⁺ state. These line lists can be used in further …

Characterizing Rainfall Variability Within A Series Of Storms Over Northern California In February 2017, Parker Jan Malek

Dissertations and Theses

In February 2017, a series of storms with associated atmospheric rivers (ARs) made landfall in the US state of California, dropping large amounts of precipitation over the Sierra Nevada Mountains and their western foothills. The rainfall from these ARs, long, narrow bands of water vapor that transport large amounts of water vapor from the tropics to the mid-latitudes, instigated the near-failure of the Oroville Dam located at the southeastern edge of the Feather watershed outside the city of Oroville in the state's Central Valley. This case study provides a synoptic and mesoscale diagnosis of the drivers of rainfall pulses that …

Urban Heat Dynamics In Pune: The Influence Of Land Cover And Local Climate, Arpit Tiwari, Preethi Nanjundan, Ravi Ranjan Kumar, Ananya Karmakar, Satyaban Bishoyi Ratna

Northeast Journal of Complex Systems (NEJCS)

Urban areas with high population density and extensive infrastructure development have been experiencing an increasing strain on the local heat budget, leading to a surge in heat-related illnesses and discomfort. This study examined the impact of climate and land use as heat islands in Pune, India, from 2012 to 2023 at six different locations representing varying degree of urbanization. Satellite land cover observations revealed that 55.17% of the total area was urbanized in the city itself, which was limited to 44.8% in 2012. This urbanization has significantly impacted the increasing tendency of maximum temperature (T_max; 0.13℃ to 1.63℃ …

Vertical Gradient In Atmospheric Particle Phase State: A Case Study Over The Alaskan Arctic Oil Fields, Nurun Nahar Lata, Zezhen Cheng, Darielle Dexheimer, Susan Mathai, Matthew A. Marcus, Kerri A. Pratt

Michigan Tech Publications

The phase state of atmospheric particles impacts atmospheric processes like heterogeneous reactions, cloud droplet activation, and ice nucleation, influencing Earth's climate. Factors like chemical composition, temperature, and relative humidity govern particle phase states. The Arctic atmosphere is stratified, with varying particle compositions, but vertical profiles of submicron phase states remain poorly understood due to limited aloft measurements. To address this, particle samples were collected via a tethered balloon system (TBS) at the U.S. Department of Energy Atmospheric Radiation Measurement Program's facility at Oliktok Point, Alaska, on November 19, 2020. Using an environmental scanning electron microscope with a tilted Peltier stage …

2024 Nhc Verification Report Preview: Atlantic Basin, John Cangialosi, Jon Martinez

National Oceanographic and Atmospheric Administration: Technical Reports and Related Materials

The National Hurricane Center (NHC) is nearing completion of the post-analysis of the 2024 Atlantic and eastern North Pacific basin tropical cyclones. The annual NHC Verification Report uses the post-analyzed information to verify the accuracy and biases of NHC forecasts and real-time model guidance, and the 2024 report will be available in the spring on NHC’s website - https://www.nhc.noaa.gov/verification/. This short review provides some of the preliminary highlights of NHC’s 2024 forecast performance in the Atlantic basin, which is based on a combination of post-analyzed and real time best track data. If interested in the forecast verification for individual …