Atmospheric Sciences Commons^™

Whole-Canopy Net Ecosystem Exchange And Water Use Efficiency In An Intermittent-Light Environment -- Dynamic Approach, Sergey Nikolayevich Kivalov

Legacy Theses & Dissertations (2009 - 2024)

An observed 20-30% increase in forest net ecosystem exchange (NEE) on partly cloudy days is often attributed to there being more uniform canopy illumination by diffuse radiation when clouds are present. However, the sky on such days is typically populated by fair-weather cumulus clouds, bringing dynamically changing shadow-to-light conditions on the order of minutes to the forest, with radiation alternating from 1000 W m^-2 in the clear sky to less than 400 W m^-2 in under-cloud shadows. These dynamically changing conditions cannot be investigated by the conventional time-averaged eddy-covariance flux method, which requires nearly steady-state turbulent conditions over much longer …

Polar Ozone Depletion: Mario J. Molina, Kirsten Oberg

Natural Sciences Student Research Presentations

This poster for the Natural Sciences Poster Session at Parkland College features the contribution of Mario J. Molina to the field of atmospheric chemistry, especially in regards to the formation and decomposition aspects of the ozone layer.

Biomass Burning In The Conterminous United States: A Comparison And Fusion Of Active Fire Observations From Polar-Orbiting And Geostationary Satellites For Emissions Estimation, Fangjun Li

Electronic Theses and Dissertations

Biomass burning is an important source of atmospheric greenhouse gases and aerosol emissions that significantly influence climate and air quality. Estimation of biomassburning emissions (BBE) has been limited to the conventional method in which parameters (i.e., burned area and fuel load) can be challenging to quantify accurately. Recent studies have demonstrated that the rate of biomass combustion is a linear function of fire radiative power (FRP), the instantaneous radiative energy released from actively burning fires, which provides a novel pathway to estimate BBE. To obtain accurate and timely BBE estimates for near real-time applications (i.e., air quality forecast), the satellite …

Convective Transport Of Tropical Marine Boundary Layer Species Into The Upper Troposphere And Relation To Species Lifetime: In Situ Measurements And Global Model Simulation, Sofia M. Chelpon

Dissertations and Theses

This study investigates the influence of tropical deep convection on distribution of trace gasses in the tropical upper troposphere (UT) using data from the Convective Transport of Active Species in the Tropics (CONTRAST) Experiment conducted over the tropical western Pacific during January and February of 2014. Fifty-five chemical species measured during the CONTRAST campaign are analyzed with lifetimes ranging from less than a day to several years. The vertical profiles of these species suggest that they fall into three main groups delineated by their lifetime: 1) very long-lived trace gases demonstrating a nearly constant vertical structure, 2) intermediate lifetime species …

Recommissioning Reddi: Reviving A Doppler Asymmetric Spatial Heterodyne Spectrometer For Observing Thermospheric Winds, Robert Kallio

Doctoral Dissertations and Master's Theses

The REd-line DASH Demonstration Instrument (REDDI) was designed to prove that a Doppler Asymmetric Spatial Heterodyne (DASH) spectrometer could be used to accurately measure thermospheric winds by observing the Doppler shift of the 630nm emission of oxygen in the thermosphere. In 2015, we began a project to redesign the input optics of REDDI to repurpose the instrument from a demonstration unit to a long duration instrument. Integration of REDDI into the INSpIRe (Investigating Near-Space Interaction Regions) trailer at Embry-Riddle Aeronautical University (ERAU), Daytona Beach, began in 2016 with assembly of the new input optics in 2017. REDDI and INSpIRe will …

Spectral Signatures Of Submicron Scale Light-Absorbing Impurities In Snow And Ice Using Hyperspectral Microscopy, Farra Dal Anna, Susan Kaspari, James Beach, Thomas D. Bucheli, Michael Schaepman, Margit Schwikowski

Geological Sciences Faculty Scholarship

Light-absorbing impurities (LAI) can darken snow and ice surfaces, reduce snow/ice albedo and accelerate melt. Efforts to allocate the relative contribution of different LAI to snow/ice albedo reductions have been limited by uncertainties in the optical properties of LAI. We developed a new method to measure LAI spectral reflectance at the submicron scale by modifying a Hyperspectral Imaging Microscope Spectrometer (HIMS). We present the instrument’s internal calibration, and the overall small influence of a particle’s orientation on its measured reflectance spectrum. We validated this new method through the comparison with a field spectroradiometer by measuring different standard materials. Measurements with …

Comparison Of Various Mean Field Formulations For Retrieving Refractive Indices Of Aerosol Particles Containing Inclusions, Kristin S. Dooley, Jessica Deyoung

Journal of the Arkansas Academy of Science

Application of effective medium approximation (EMA) methods to two-component systems are presented. Systems studied are composed of water, sulfate, soot, and dust as these are commonly encountered atmospheric aerosol components. Atmospheric models often employ EMAs to include internally mixed aerosols without the computational burden of exact theory. In the current work, several types of mixing rules (Maxwell-Garnet, Bruggeman, and coherent potential approximation) have been applied to various two-component internally mixed particles at 550 nm using volume fractions of the minor component below 0.1. As expected, results show that the formulations tested produce very similar effective refractive indices indicating that electric …

Global Sea-Level Budget 1993-Present, Wcrp Global Sea Level Budget Group, Benjamin Hamlington

CCPO Publications

Global mean sea level is an integral of changes occurring in the climate system in response to unforced climate variability as well as natural and anthropogenic forcing factors. Its temporal evolution allows changes (e.g.,acceleration) to be detected in one or more components. Study of the sea-level budget provides constraints on missing or poorly known contributions, such as the unsurveyed deep ocean or the still uncertain land water component. In the context of the World Climate Research Programme Grand Challenge entitled "Regional Sea Level and Coastal Impacts", an international effort involving the sea-level community worldwide has been recently initiated with the …

Evaluating The Effectiveness Of Current Atmospheric Refraction Models In Predicting Sunrise And Sunset Times, Teresa Wilson

Dissertations, Master's Theses and Master's Reports

The standard value for atmospheric refraction on the horizon of 34', used in all publicly available sunrise and sunset calculators, is found to be inadequate. The assumptions behind atmospheric models that predict this value fail to account for real meteorological conditions. The result is an uncertainty of one to five minutes in sunrise and sunset predictions at mid-latitudes (0° - 55° N/S). A sunrise/set calculator that interchanges the refraction component by varying the refraction model was developed. Two atmospheric refraction models of increasing complexity were tested along with the standard value. The predictions were compared with data sets of observed …

A Comparative Study Characterizing Traffic Related Air Pollutant Concentrations At Near-Road Communities In El Paso, Texas, Adan Rangel

Open Access Theses & Dissertations

Numerous scientific studies have demonstrated the influence of traffic related air pollution at near-road communities and the associated health risks for these populations. This study uses on-site air quality monitors to characterize air pollutants at near-road schools in El Paso, TX to understand children's exposure to traffic-related air pollutants. Ambient air monitoring stations were installed at Coldwell Elementary, Bliss Elementary, and a residential house located in close proximity to major inter-state roadways. In this study, air quality data for PM2.5, PM10, NO2, and O3 was collected over a period of nine weeks in Fall 2018. The spatial and temporal variability …

Mls Measurements Of Stratospheric Hydrogen Cyanide During The 2015-2016 El Niño Event, Hugh C. Pumphrey, Norbert Glatthor, Peter F. Bernath, Christopher D. Boone, James W. Hannigan, Ivan Ortega, Nathaniel J. Livesey, William G. Read

Chemistry & Biochemistry Faculty Publications

It is known from ground-based measurements made during the 1982-1983 and 1997-1998 El Niño events that atmospheric hydrogen cyanide (HCN) tends to be higher during such years than at other times. The Microwave Limb Sounder (MLS) on the Aura satellite has been measuring HCN mixing ratios since launch in 2004; the measurements are ongoing at the time of writing. The winter of 2015- 2016 saw the largest El Niño event since 1997-1998. We present MLS measurements of HCN in the lower stratosphere for the Aura mission to date, comparing the 2015- 2016 El Niño period to the rest of the …

Stratospheric Ozone And Hcl Trends (2000-2016): How Significant Is Recent Growth In Chlorinated Very Short-Lived Substances, Ryan Hossaini, Martyn Chipperfield, Peter Bernath, Anton Fernando, Sandip Dhomse, Wuhu Feng

Chemistry & Biochemistry Faculty Publications

[Introduction] Chlorinated very short-lived substances (VSLS), such as dichloromethane (CH₂CL₂), chloroform (CHCl₃₎ and perchloroethylene (C₂Cl₄) constitute a small, but growing source of stratospheric chlorine (e.g. WMO, 2014). High-altitude aircraft observations provide some constraint on the stratospheric source gas injection of chlorine from these compounds, though product gas injection - from VSLS-derived phosgene and HCl produced in the troposphere - is uncertain. Furthermore, in addition to an overall paucity of atmospheric VSLS observations, the impact of VSLS growth on stratospheric composition trends in the recent past (e.g. ozone, HCl) remains poorly constrained.

Analysis Of The Red And Green Optical Absorption Spectrum Of Gas Phase Ammonia, Nikolai F. Zobov, Phillip A. Coles, Roman I. Ovsyannikov, Aleksandra A. Kyuberis, Robert J. Hargreaves, Peter F. Bernath, Jonathan Tennyson, Sergei N. Yurchenko, Oleg L. Polyansky

Chemistry & Biochemistry Faculty Publications

Room temperature NH₃ absorption spectra recorded at the Kitt Peak National Solar Observatory in 1980 are analyzed. The spectra cover two regions in the visible: 15,200 - 15,700 cm^-1 and 17,950 - 18,250 cm^-1. These high overtone rotation-vibration spectra are analyzed using both combination differences and variational line lists. Two variational line lists were computed using the TROVE nuclear motion program: one is based on an ab initio potential energy surface (PES) while the other used a semi-empirical PES. Ab initio dipole moment surfaces are used in both cases. 95 energy levels with J = 1 …

Abrupt Changes In Wind Conditions At The Memphis International Airport, Nicholas E. Johnson

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Assessing The Effects Of Storm Depth On Tds Height Interpretation In Tornado Intensity Estimation, Andrew Lee

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Record Setting: The Origins Of Extreme Hail On 19 March 2018 During Vortex-Se, Dean Meyer

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Advances In The Hyperspectral Imaging Microscope Spectrometer Method, And Application For Measuring The Spectral Reflectance Of Light Absorbing Aerosols From The South Cascades, Colorado Rockies, And Iceland, Melanie Swick

All Master's Theses

Snow and glaciers are receding at a global scale. Warming temperatures are often identified as the dominant cause of this decline; however, deposition of light absorbing aerosols (LAA), including black carbon, mineral dust and organics onto snow and glacier surfaces can be an even larger driver of melt in some regions (Skiles et al., 2012). Attempts to partition the relative contribution of different types of LAA to snow and glacier melt has been limited by the uncertainties in the LAA optical properties (Kaspari et al., 2014). A new hyperspectral imaging microscope spectrometer (HIMS) method was recently developed to measure LAA …

Morphology And Mixing State Of Soot And Tar Balls: Implications For Optical Properties And Climate, Janarjan Bhandari

Dissertations, Master's Theses and Master's Reports

Soot particles form during incomplete combustion of carbonaceous materials. These particles strongly absorb light and directly affect Earth’s climate by warming our atmosphere. When freshly emitted, soot particles have a fractal-like morphology consisting of aggregates of carbon spherules. During atmospheric processing, soot aggregates interact with other materials present in our atmosphere (i.e., other aerosol or condensable vapors) and these interactions can result in the formation of coated, mixed or compacted soot particles with different morphologies. Any process that alters the morphology (shape, size and internal structure) and mixing state of soot also affects its optical properties, which in turn affect …

Investigation Of Microphysical Properties Of Laboratory And Atmospheric Clouds Using Digital In-Line Holography, Neel Desai

Dissertations, Master's Theses and Master's Reports

In this study, we attempt to perform in-cloud measurements, both in the laboratory using the Michigan Tech $\Pi$-chamber and in the atmosphere via the CSET field campaign. Atmospheric turbulence is believed to play a critical role in the growth, development and dissipation of clouds and it is important to study its effect in order to better understand and predict cloud properties such as albedo and lifetime. We use digital in-line holography to measure the effect of turbulence on cloud microphysical properties such as variations in droplet number concentration and droplet or ice particle size. In the first half, we study …

Wildfire Emissions In The Context Of Global Change And The Implications For Mercury Pollution, Aditya Kumar

Dissertations, Master's Theses and Master's Reports

Wildfires are episodic disturbances that exert a significant influence on the Earth system. They emit substantial amounts of atmospheric pollutants, which can impact atmospheric chemistry/composition and the Earth’s climate at the global and regional scales. This work presents a collection of studies aimed at better estimating wildfire emissions of atmospheric pollutants, quantifying their impacts on remote ecosystems and determining the implications of 2000s-2050s global environmental change (land use/land cover, climate) for wildfire emissions following the Intergovernmental Panel on Climate Change (IPCC) A1B socioeconomic scenario.

A global fire emissions model is developed to compile global wildfire emission inventories for major atmospheric …

Understanding The Food Water Nexus: Characterizing The Impact Of Climatological Anomalies On Agrosystems, Patrick M. Wurster Jr.

Graduate Student Theses, Dissertations, & Professional Papers

Climate variability at global and regional scales is escalating with increased atmospheric carbon and is expected to magnify the intensity and duration of meteorological extremes, especially droughts. From the many environmental stresses that diminish crop production (e.g., soil salinity, frost, soil erosion) drought is one of the most prevalent. This study focuses on the sensitivity of three key crops produced in the northwestern United States to climatological anomalies, while controlling for attribution using anomalies in price. The study differs from similar studies in that we focus on variability in production which captures both yield (tonnes/ha) and cropping area (ha), as …