Atmospheric Sciences Commons^™

The Spatiotemporal Distribution Of Air Pollutants And Their Relationship With Land-Use Patterns In Hangzhou City, China, Sheng Zheng, Xueyuan Zhou, Ramesh Singh, Yuzhe Wu, Yanmei Ye, Cifang Wu

Mathematics, Physics, and Computer Science Faculty Articles and Research

Air pollution contributes to a large fraction of the total mortality estimated under the global burden of disease project (GBD) of the World Health Organization (WHO). This paper discusses an integrated study to obtain the spatiotemporal characteristics of particulate matter (PM10 and PM2.5) and trace gases (O3, SO2, NO2, and CO) pollutants in Hangzhou City (China) for the years 2014–2016. Our detailed analysis shows a relationship between air pollutants and land-use/land-cover change. Air quality parameters (PM2.5 and PM10) and trace gases (SO2, NO2, and CO) show strong monthly variations in the months of January (higher values) and July (lower values). …

Improved Atmospheric Characterization For Hyperspectral Exploitation, Nathan P. Wurst

Theses and Dissertations

Airborne hyperspectral imaging (HSI) in the LWIR has shown utility in material detection and identification. This research seeks to determine the most effective methods to perform model-based atmospheric compensation of LWIR HSI data by comparing results obtained from different atmospheric profiles. The standard model for mid-latitude summer (MLS) and radiosonde data are compared to the National Operational Model Archive and Distribution System (NOMADS) numerical weather predictions and the Extreme and Percentile Environmental Reference Tables (ExPERT). The two latter atmospheric profiles are generated using the Laser Environmental Effects Definition and Reference (LEEDR) software. MLS has been a standard starting point for …

First Na Lidar Measurements Of Turbulence Heat Flux, Thermal Diffusivity, And Energy Dissipation Rate In The Mesopause Region, Yafang Guo, Alan Z. Liu, Chester S. Gardner

Publications

Turbulence is ubiquitous in the mesopause region, where the atmospheric stability is low and wave breaking is frequent. Measuring turbulence is challenging in this region and is traditionally done by rocket soundings and radars. In this work, we show for the first time that the modern Na wind/temperature lidar located at Andes Lidar Observatory in Cerro Pachón, Chile, is able to directly measure the turbulence perturbations in temperature and vertical wind between 85 and 100 km. Using 150 h of lidar observations, we derived the frequency (ω) and vertical wave number (m) spectra for both gravity …

Umphlett Qci June 2017, Natalie Umphlett

High Plains Regional Climate Center: Staff Publications

Highlights for the Basin

Temperature and Precipitation Anomalies

Snowpack and Streamflow

Historic Flooding in Missouri

Spring Conditions Impact Agriculture

3-Month Precipitation and Temperature Outlooks

U.S. Seasonal Drought Outlook

Comment On "Using An Adcp To Estimate Turbulent Kinetic Energy Dissipation Rate In Sheltered Coastal Waters", Ann E. Gargett

CCPO Publications

Greene et al. revisit the suggestion that the turbulent kinetic energy dissipation rate could be estimated through a "large-eddy estimate," employing acoustic measurements of velocity fields associated with the largest energy-containing scales of ocean turbulence. While the large-eddy estimate as originally proposed used vertical velocity and a vertical eddy length scale, Greene et al. chose instead to substitute a horizontal length scale for the latter. This comment argues that combining a horizontal scale for length with a vertical velocity scale produces a large-eddy estimate of the dissipation rate that is accurate only if the energy-containing eddies are isotropic, and that …

Depletion Of Ozone And Reservoir Species Of Chlorine And Nitrogen Oxide In The Lower Antarctic Polar Vortex Measured From Aircraft, T. Jurkat, C. Voigt, S. Kaufmann, J.-U. Grooß, H. Ziereis, A. Dörnbrack, P. Hoor, H. Bozem, A. Engel, H. Bönisch, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

Novel airborne in situ measurements of inorganic chlorine, nitrogen oxide species, and ozone were performed inside the lower Antarctic polar vortex and at its edge in September 2012. We focus on one flight during the Transport and Composition of the LMS/Earth System Model Validation (TACTS/ESMVal) campaign with the German research aircraft HALO (High-Altitude LOng range research aircraft), reaching latitudes of 65°S and potential temperatures up to 405 K. Using the early winter correlations of reactive trace gases with N₂O from the Atmospheric Chemistry Experiment-Fourier Transform Spectrometer (ACE-FTS), we find high depletion of chlorine reservoir gases up to ∼40% …

The Indianapolis Flux Experiment (Influx): A Test-Bed For Developing Urban Greenhouse Gas Emission Measurements, Kenneth J. Davis, Aijun Deng, Thomas Lauvaux, Natasha Miles, Scott Richardson, Daniel Sarmiento, Kevin R. Gurney, R Michael Hardesty, Timothy A. Bonin, W Alan Brewer, Brian K. Lamb, Paul B. Shepson, Rebecca M. Harvey, Maria Obiminda L. Cambaliza, Colm Sweeney, Jocelyn Turnbull, James Whetstone, Anna Karion

Physics Faculty Publications

The objective of the Indianapolis Flux Experiment (INFLUX) is to develop, evaluate and improve methods for measuring greenhouse gas (GHG) emissions from cities. INFLUX’s scientific objectives are to quantify CO2 and CH4 emission rates at 1 km2 resolution with a 10% or better accuracy and precision, to determine whole-city emissions with similar skill, and to achieve high (weekly or finer) temporal resolution at both spatial resolutions. The experiment employs atmospheric GHG measurements from both towers and aircraft, atmospheric transport observations and models, and activity-based inventory products to quantify urban GHG emissions. Multiple, independent methods for estimating urban emissions are a …

Proposed Legislation Seeks To Stimulate Investment In Coastal Resiliency, Jon Cawley

News Items

No abstract provided.

Concentrations And Size Distributions Of Bacteria-Containing Particles Over Oceans From China To The Arctic Ocean, Ming Li, Xiawei Yu, Hui Kang, Zhouqing Xie, Pengfei Zhang

Publications and Research

During the third China Arctic Research Expedition (July–September 2008), size-resolved measurements of bacteria-containing particles (BCPs) in the marine boundary layer (MBL) air were conducted during a cruise through the East China Sea, the Yellow Sea, the Japan Sea, the Okhotsk Sea, the Bering Sea, the Chukchi Sea, and the Arctic Ocean. The concentrations of total airborne BCPs (TBCPs), non-salt tolerant airborne BCPs (NSBCPs), and salt tolerant airborne BCPs (SBCPs) varied from 29 to 955 CFU m − 3 (CFU = Colony Forming Unit), 16 to 919 CFU m − 3 , and 4 to 276 CFU m − 3 , …

The Role Of Sulfur Dioxide In Stratospheric Aerosol Formation Evaluated By Using In Situ Measurements In The Tropical Lower Stratosphere, A. W. Rollins, T. D. Thornberry, L. A. Watts, P. Yu, K. H. Rosenlof, M. Mills, E. Baumann, F. R. Giorgetta, T. V. Bui, M. Höpfner, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

Stratospheric aerosols (SAs) are a variable component of the Earth's albedo that may be intentionally enhanced in the future to offset greenhouse gases (geoengineering). The role of tropospheric-sourced sulfur dioxide (SO₂) in maintaining background SAs has been debated for decades without in situ measurements of SO₂ at the tropical tropopause to inform this issue. Here we clarify the role of SO₂ in maintaining SAs by using new in situ SO₂ measurements to evaluate climate models and satellite retrievals. We then use the observed tropical tropopause SO₂ mixing ratios to estimate the global flux of …

Ab Initio Computation Of Radiative Properties Of Monatomic Hydrogen, Fanny Thomas

Doctoral Dissertations and Master's Theses

With renewed interest in planetary atmospheric entry, descent, and landing, NASA has noted a need for improved physics modeling in computational fluid dynamics. Uncertainty in experimental data used in radiation heat transfer computations leads to “over-engineering” of entry body heat shields, at large weight and cost penalties. There is interest in developing hypersonic thermophysics models from the known “first principles” of physics.

A method for computing high temperature gas emissivity and absorptivity from quantum mechanics principles is developed. The Schroedinger wave equation is cast as a discretized matrix eigenvalue problem which is solved using the ERAU parallel supercomputer. The numerical …

Solar Wind-Magnetosphere Coupling: A Global Perspective Of Reconnection In The Magnetotail, Miles Thomas Bengtson

Doctoral Dissertations and Master's Theses

We present a case study of the 25 December 2015 substorm which occurred between 08:15 and 08:45 Universal Time. During this interval, fast particle flows and field geometry consistent with magnetic reconnection were detected in the mid-tail region. An ejected plasmoid was observed by the lunar-orbiting Acceleration, Reconnection, Turbulence and Electrodynamics of Moon’s Interaction with the Sun (ARTEMIS) probes and corresponding dipolarization signature was observed by the Time History of Events and Macroscale Interactions During Substorms (THEMIS) spacecraft earthward of the reconnection site, which was determined to be approximately -33 RE. Ground signatures indicative of substorm activity were also observed …

Design And Characterization Of A Time-Of-Flight Mass Spectrometer For Composition Measurements In The Upper Atmosphere, E. Addison Everett

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The mesosphere/lower thermosphere (MLT) is perhaps the least understood region of Earth's atmosphere. Too high for balloons and winged aircraft, yet too low for satellites, direct access to the MLT to make in-situ measurements is via high-speed sounding rockets for brief periods of at most a few minutes. Mass spectrometers have previously been used to make composition measurements in this region. But, mass spectrometry in the MLT is difficult, mainly due to the ambient pressures here and also the high speeds and short flight durations of sounding rocket missions. Time-of-flight mass spectrometers (TOF-MS) are capable of making fast, accurate measurements …

A Global Study Of Gpp Focusing On Light-Use Efficiency In A Random Forest Regression Model, Suhua Wei, Chuixiang Yi, Wei Fang, George Hendrey

Publications and Research

Light-use efficiency (LUE) is at the core of mechanistic modeling of global gross primary production (GPP). However, most LUE estimates in global models are satellite based and coarsely measured with emphasis on environmental variables. Others are from eddy covariance towers with much greater spatial and temporal data quality and emphasis on mechanistic processes, but in a limited number of sites. In this study, we conducted a comprehensive global study of tower-based LUE from 237 FLUXNET towers, and scaled up LUEs from in situ tower level to global biome level. We integrated the tower-based LUE estimates with key environmental and biological …

Direct Comparisons Of Ice Cloud Macro- And Microphysical Properties Simulated By The Community Atmosphere Model Version 5 With Hippo Aircraft Observations, Chenglai Wu, Xiaohong Liu, Minghui Diao, Kai Zhang, Andrew Gettelman, Zheng Lu, Joyce Penner, Zhaohui Lin

Faculty Publications, Meteorology and Climate Science

In this study we evaluate cloud properties simulated by the Community Atmosphere Model version 5 (CAM5) using in situ measurements from the HIAPER Pole-to-Pole Observations (HIPPO) campaign for the period of 2009 to 2011. The modeled wind and temperature are nudged towards reanalysis. Model results collocated with HIPPO flight tracks are directly compared with the observations, and model sensitivities to the representations of ice nucleation and growth are also examined. Generally, CAM5 is able to capture specific cloud systems in terms of vertical configuration and horizontal extension. In total, the model reproduces 79.8 % of observed cloud occurrences inside model …

Oxidation Of Substituted Catechols At The Air-Water Interface: Production Of Carboxylic Acids, Quinones, And Polyphenols, Elizabeth A. Pillar, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic activities contribute benzene, toluene, and anisole to the environment, which in the atmosphere are converted into the respective phenols, cresols, and methoxyphenols by fast gas-phase reaction with hydroxyl radicals (HO(•)). Further processing of the latter species by HO(•) decreases their vapor pressure as a second hydroxyl group is incorporated to accelerate their oxidative aging at interfaces and in aqueous particles. This work shows how catechol, pyrogallol, 3-methylcatechol, 4-methylcatechol, and 3-methoxycatechol (all proxies for oxygenated aromatics derived from benzene, toluene, and anisole) react at the air-water interface with increasing O3(g) during τc ≈ 1 μs contact time and contrasts their …

Modeling Gross Primary Production Of Midwest Maize And Soybean Croplands With Satellite And Gridded Weather Data, Gunnar Malek-Madani

Department of Geography: Dissertations, Theses, and Student Research

The gross primary production (GPP) metric is useful in determining trends in the terrestrial carbon cycle. Models that determine GPP utilizing the light use efficiency (LUE) approach in conjunction with biophysical parameters that account for local weather conditions and crop specific factors are beneficial in that they combine the accuracy of the biophysical model with the versatility of the LUE model. One such model developed using in situ data was adapted to operate with remote sensing derived leaf area index (LAI) data and gridded weather datasets. The model, known as the Light Use Efficiency GPP Model (EGM), uses a four …

Droughtscape, Spring 2017, National Drought Mitigation Center

DroughtScape: Quarterly Newsletter of the National Drought Mitigation Center (2007–2023)

Contents

Drought center helps islands reduce drought vulnerability

2017 sees above-average precipitation, warmer temps

California pulls out of drought

After tech transfer, training Tunisia launches first drought map

Drought center releases 2016 annual report

Book chapter focuses on drought and health

U2U wraps up, brings useful tools to farmers

Survey finds drought info leads to better decisions

A Predictor Analysis Framework For Surface Radiation Budget Reprocessing Using Design Of Experiments, Patricia Allison Quigley

Engineering Management & Systems Engineering Theses & Dissertations

Earth’s Radiation Budget (ERB) is an accounting of all incoming energy from the sun and outgoing energy reflected and radiated to space by earth’s surface and atmosphere. The National Aeronautics and Space Administration (NASA)/Global Energy and Water Cycle Experiment (GEWEX) Surface Radiation Budget (SRB) project produces and archives long-term datasets representative of this energy exchange system on a global scale. The data are comprised of the longwave and shortwave radiative components of the system and is algorithmically derived from satellite and atmospheric assimilation products, and acquired atmospheric data. It is stored as 3-hourly, daily, monthly/3-hourly, and monthly averages of 1°x1° …

Reactivity Of Ketyl And Acetyl Radicals From Direct Solar Actinic Photolysis Of Aqueous Pyruvic Acid, Alexis J. Eugene, Marcelo I. Guzman

Chemistry Faculty Publications

The variable composition of secondary organic aerosols (SOA) contributes to the large uncertainty for predicting radiative forcing. A better understanding of the reaction mechanisms leading to aerosol formation such as for the photochemical reaction of aqueous pyruvic acid (PA) at λ ≥ 305 nm can contribute to constrain these uncertainties. Herein, the photochemistry of aqueous PA (5-300 mM) continuously sparged with air is re-examined in the laboratory under comparable irradiance at 38° N at noon on a summer day. Several analytical methods are employed to monitor the time series of the reaction, including (1) the derivatization of carbonyl (C═O) functional …

Latitudinal Position And Trends Of The Intertropical Convergence Zone (Itcz) And Its Relationship With Upwelling In The Southern Caribbean Sea And Global Climate Indices, Kaitlyn E. Colna

USF Tampa Graduate Theses and Dissertations

The Intertropical Convergence Zone (ITCZ) is a feature that results from the ocean-atmosphere interactions in the tropics around the world. The ITCZ is characterized by surface wind convergence, tall storm clouds, and it forms a belt of high time-averaged precipitation around the globe. The ITCZ undergoes seasonal migrations between 5°S and 15°N roughly following the subsolar point on Earth with the seasons, with a mean annual position located slightly above the Equator, between 2° and 5°N.

This study tested the hypothesis that there was a northward shift in the median position of the ITCZ in the first decade of the …

Simultaneous Upward And Downward Propagating Inertia-Gravity Waves In The Mlt Observed At Andes Lidar Observatory, Kai Ming Hung, Alan Z. Liu, Shao Dong Zhang, Fan Yi, Chun Ming Huang, Yun Gong, Quan Gan, Et Al.

Publications

Based on the temperature and zonal and meridional winds observed with an Na lidar at Andes Lidar Observatory (30.3°S, 70.7°W) on the night of 20–21 July 2015, we report simultaneous upward and downward propagating inertia-gravity waves (IGWs) in the mesosphere/lower stratosphere (MLT). The ground-based periods of the upward and downward IGWs are about 5.4 h and 4.8 h, respectively. The horizontal and vertical wavelengths are about 935 km and 10.9 km for the 5.4 h IGW and about 1248 km and 22 km for the 4.8 h IGW, respectively. Hodograph analyses indicate that the 5.4 h IGW propagates in the …

Data From: Optical Depth And Size Characteristics Of Small Coastal Florida Cumuli From Surface-Based Lidar And Radiometer Measurements, Rodrigo Delgadillo

Supplementary Data and Tools

Data in this collection is from micro-pulse lidar (MPL) and near field of view (NFOV) radiometer from 20 Dec 2014 to 1 March 2015. The instruments are co-located and zenith-aligned. Measurements were recorded at the CAROb site (http://carob.rsmas.miami.edu/) located in the University of Miami Rosenstiel School of Marine & Atmospheric Science. The data in this collection is categorized as MPL and zenith radiometer data.

P07. Characterizing The Purple Crow Lidar To Investigate Potential Sources Of Wet Bias, Jeffrey Vankerkhove, Robert J. Sica, Robin Wing, Steve Argall

Western Research Forum

The Purple Crow Lidar is a large aperture lidar, capable of retrieving water vapor profiles into the stratosphere. Water vapor in the upper Troposphere-Lower Stratosphere (UTLS) region is of particular importance in understanding Earth's radiative budget and atmospheric dynamics, making accurate UTLS measurements crucial. A comparison campaign with the NASA/GSFC ALVICE mobile lidar in the spring of 2012 showed PCL water vapor measurements were consistently larger than those of ALVICE in the lower stratosphere, prompting an investigation to characterize the system. The investigation looks into how changes to the data processing approach, as well as applying additional instrumental corrections, would …

P16. Ralmo Rotational Raman Temperature Retrieval: First Steps Towards The Application Of Optimal Estimation Method (Oem), Shayamila N. Mahagammulla Gamage, Robert Sica, Alexander Haefele

Western Research Forum

Background:

Temperature is an important atmospheric parameter that plays an extensive role in the fields of atmospheric dynamics, climatology, meteorology, and chemistry. Light detection and ranging (lidar), is a remote sensing technology that can be used for atmospheric temperature profiling. A lidar transmits short laser pulses into the atmosphere and the light scattered by the particles in the atmosphere is collected and measured using a telescope. The atmospheric temperatures can be retrieved by analysing the Pure Rotational Raman (PRR) scatter measurements from the nitrogen and oxygen molecules in the atmosphere.

Methods:

In this study use the Optimal Estimation Method (OEM) …

Umphlett Qci March 2017, Natalie Umphlett

High Plains Regional Climate Center: Staff Publications

Highlights for the Basin

Temperature and Precipitation Anomalies

Mountain Snowpack

Christmas Day Storm

Heavy Fuels Increase Fire Risk

Early Warmth Causes Concerns

3-Month Precipitation and Temperature Outlooks

NOAA Spring Flood Outlook

Assessment Of An Atmospheric Transport Model For Annual Inverse Estimates Of California Greenhouse Gas Emissions, Justin Bagley, Seongeun Jeong, Xinguang Cui, Sally Newman, Jingsong Zhang, Chad Priest, Mixtli Campos-Pineda, Arlyn Andrews, Laura Bianco, Matthew Lloyd, Neil Lareau, Craig Clements, Marc Fischer

Faculty Publications, Meteorology and Climate Science

Atmospheric inverse estimates of gas emissions depend on transport model predictions, hence driving a need to assess uncertainties in the transport model. In this study we assess the uncertainty in WRF-STILT (Weather Research and Forecasting and Stochastic Time-Inverted Lagrangian Transport) model predictions using a combination of meteorological and carbon monoxide (CO) measurements. WRF configurations were selected to minimize meteorological biases using meteorological measurements of winds and boundary layer depths from surface stations and radar wind profiler sites across California. We compare model predictions with CO measurements from four tower sites in California from June 2013 through May 2014 to assess …

Nitrate Radicals And Biogenic Volatile Organic Compounds: Oxidation, Mechanisms And Organic Aerosol, Nga Lee Ng, Steven S. Brown, Alexander T. Archibald, Elliot Atlas, Ronald C. Cohen, John N. Crowley, Douglas A. Day, Neil M. Donahue, Juliane L. Fry, Hendrik Fuchs, Robert J. Griffin, Marcelo I. Guzman, Hartmut Hermann, Alma Hodzic, Yoshiteru Iinuma, José L. Jimenez, Astrid Kiendler-Scharr, Ben H. Lee, Deborah J. Luecken, Jingqiu Mao, Robert Mclaren, Anke Mutzel, Hans D. Osthoff, Bin Ouyang, Benedicte Picquet-Varrault, Ulrich Platt, Havala O. T. Pye, Yinon Rudich, Rebecca H. Schwantes, Manabu Shiraiwa, Jochen Stutz, Joel A. Thornton, Andreas Tilgner, Brent J. Williams, Rahul A. Zaveri

Chemistry Faculty Publications

Oxidation of biogenic volatile organic compounds (BVOC) by the nitrate radical (NO₃) represents one of the important interactions between anthropogenic emissions related to combustion and natural emissions from the biosphere. This interaction has been recognized for more than 3 decades, during which time a large body of research has emerged from laboratory, field, and modeling studies. NO₃-BVOC reactions influence air quality, climate and visibility through regional and global budgets for reactive nitrogen (particularly organic nitrates), ozone, and organic aerosol. Despite its long history of research and the significance of this topic in atmospheric chemistry, a number …

Nonlinear Ionospheric Responses To Large-Amplitude Infrasonic-Acoustic Waves Generated By Undersea Earthquakes, M. D. Zettergren, J. B. Snively, A. Komjathy, O. P. Verkhoglyadova

Publications

Numerical models of ionospheric coupling with the neutral atmosphere are used to investigate perturbations of plasma density, vertically integrated total electron content (TEC), neutral velocity, and neutral temperature associated with large-amplitude acoustic waves generated by the initial ocean surface displacements from strong undersea earthquakes. A simplified source model for the 2011 Tohoku earthquake is constructed from estimates of initial ocean surface responses to approximate the vertical motions over realistic spatial and temporal scales. Resulting TEC perturbations from modeling case studies appear consistent with observational data, reproducing pronounced TEC depletions which are shown to be a consequence of the impacts of …

Contributions Of Wood Smoke And Vehicle Emissions To Ambient Concentrations Of Volatile Organic Compounds And Particulate Matter During The Yakima Wintertime Nitrate Study, Graham Vanderschelden, Benjamin De Foy, Courtney Herring, Susan D. Kaspari, Tim Vanreken, Bertram Jobson

All Faculty Scholarship for the College of the Sciences

A multiple linear regression (MLR) chemical mass balance model was applied to data collected during an air quality field experiment in Yakima, WA, during January 2013 to determine the relative contribution of residential wood combustion (RWC) and vehicle emissions to ambient pollutant levels. Acetonitrile was used as a chemical tracer for wood burning and nitrogen oxides (NOx) as a chemical tracer for mobile sources. RWC was found to be a substantial source of gas phase air toxics in wintertime. The MLR model found RWC primarily responsible for emissions of formaldehyde (73%), acetaldehyde (69%), and black carbon (55%) and mobile sources …