Atmospheric Sciences Commons^™

The Influence Of Recurrent Modes Of Climate Variability On The Occurrence Of Winter And Summer Extreme Temperatures Over North America, Paul C. Loikith, Anthony J. Broccoli

Geography Faculty Publications and Presentations

The influence of the Pacific–North American (PNA) pattern, the northern annular mode (NAM), and the El Ni~no–Southern Oscillation (ENSO) on extreme temperature days and months over North America is examined. Associations between extreme temperature days and months are strongest with the PNA and NAM andweaker for ENSO. In general, the associationwith extremes tends to be stronger onmonthly than daily time scales and for winter as compared to summer. Extreme temperatures are associated with the PNAandNAMin the vicinity of the centers of action of these circulation patterns; however, many extremes also occur on days when the amplitude and polarity of these …

Identification And Characterization Of Fine Particulate Matter Hot Spots On An Urban Arterial Corridor Integrating Probe Vehicle, Traffic And Land Use Data, Katherine Eleanor Bell

Dissertations and Theses

The purpose of this study is to explore the use of integrated probe vehicle, traffic and land use data to identify and characterize fine particulate matter (PM[subscript 2.5]) hot spot locations on urban arterial corridors. In addition, a preliminary analysis is conducted to consider volatile organic compound (VOC) hot spot locations. A pollutant hot spot is defined as a location on a corridor in which the mean pollutant concentrations are consistently above the 85th percentile of pollutant concentrations when compared to all locations along the corridor. In order to collect data for this study, an electric vehicle was equipped with …

Methyl Halide Production By Calcareous Periphyton Mats From The Florida Everglades, Ann Eileen Raffel

Dissertations and Theses

Methyl halides are trace gases with both natural and anthropogenic origins. Once generated, these gases transport chlorine and bromine into the stratosphere, where they play an important role in ozone depleting catalytic cycles. The Florida Everglades is one location where methyl halide emissions have been proposed to be elevated due to high primary production and ionic halogens. This region also provides a unique study environment due to salt water intrusions, which occur during storm or low marsh water level-high tide events. The purpose of this research was twofold. First, quantification of methyl chloride (CH₃Cl) and methyl bromide (CH …

Effects Of Runoff Sensitivity And Catchment Characteristics On Regional Actual Evapotranspiration Trends In The Conterminous Us, Il-Won Jung, Heejun Chang, John Risley

Geography Faculty Publications and Presentations

An understanding of the role of hydro-climatic and geographic regimes on regional actual evapotranspiration (AET) change is essential to improving our knowledge on predicting water availability in a changing climate. This study investigates the relationship between AET change for a 60 year period (1951–2010) and the runoff sensitivity in 255 undisturbed catchments over the US. The runoff sensitivity to climate change is simply defined as the relative magnitude between runoff and precipitation changes with time. Runoff sensitivity can readily explain the conflicting directions of AET changes under similar precipitation change. Under increasing precipitation, AET decreases when runoff is increasing more …

Characterization Of Secondary Organic Aerosol Precursors Using Two-Dimensional Gas Chromatography With Time Of Flight Mass Spectrometry (Gc×Gc/Tofms), Melissa Jordan Roskamp

Dissertations and Theses

The oxidation of volatile organic compounds (VOCs) plays a role in both regional and global air quality through the formation of secondary organic aerosols (SOA). More than 1000TgC/yr of non-methane VOCs are emitted from biogenic sources (significantly greater than from anthropogenic sources). Despite this magnitude and potential importance for air quality, the body of knowledge around the identities, quantities and oxidation processes of these compounds is still incomplete (e.g., Goldstein & Galbally, 2007; Robinson et al., 2009). Two-dimensional gas chromatography paired with time-of-flight mass spectrometry (GC×GC/TOFMS) is a powerful analytical technique which is explored here for its role in better …

Incorporating Chemical Activity And Relative Humidity Effects In Regional Air Quality Modeling Of Organic Aerosol Formation, Marguerite Colasurdo Marks

Dissertations and Theses

Atmospheric particulate matter is known to have significant effects on human health, visibility, and global climate. The magnitudes of these effects, however, depend in complex ways on chemical composition, relative humidity, temperature, phase state, and other parameters. Current regional air quality models such as CMAQ (Community Multiscale Air Quality model) ignore many of these considerations, and consider that the formation of secondary organic aerosol (SOA) can be calculated by assuming thermodynamic ideality in the organic particulate matter (OPM) phase as well as negligible uptake of water into the OPM phase. Theoretical predictions and model simulations considering non-ideality and water uptake …

Classifying Reanalysis Surface Temperature Probability Density Functions (Pdfs) Over North America With Cluster Analysis, Paul C. Loikith, Benjamin R. Lintner, Jinwon Kim, Huikyo Lee

Geography Faculty Publications and Presentations

An important step in projecting future climate change impacts on extremes involves quantifying the underlying probability distribution functions (PDFs) of climate variables. However, doing so can prove challenging when multiple models and large domains are considered. Here an approach to PDF quantification using k-means clustering is considered. A standard clustering algorithm (with k = 5 clusters) is applied to 33 years of daily January surface temperature from two state-of-the-art reanalysis products, the North American Regional Reanalysis and the Modern Era Retrospective Analysis for Research and Applications. The resulting cluster assignments yield spatially coherent patterns that can be broadly related to …

Interspecific Variation In Leaf-Level Biogenic Emissions Of The Bambuseae, Andrea Natalie Melnychenko

Dissertations and Theses

Plants emit a diverse range of biogenic volatile organic compounds (BVOCs) into the atmosphere, of which isoprene is the most abundantly emitted. Isoprene significantly affects biological and atmospheric processes, but the range of isoprene and BVOCs present in bamboos has not been well characterized. In this thesis I explore the range of isoprene emission found in bamboos and relate it to plant morphological and physiological characteristics. In addition, I measure and relate the entire suite of BVOCs present in the bamboos to their fundamental isoprene emission rate.

Interspecific variation in isoprene emission documented in a comprehensive survey of bamboos. Two …

The Production Of Organic Nitrates In Portland Oregon And The Columbia River Gorge, Holly Ann Neill

Dissertations and Theses

This work studied the production of aerosol-phase organic nitrates in both Portland and the Columbia River Gorge (CRG). Ozone and NO_x species were investigated for correlation with organic nitrate aerosol, as they function as precursors to the production of organic nitrates. These ambient gas-phase measurements were collected in the same locations as high-volume (Hi-Vol) filters samples, in an urban and rural gorge setting to investigate correlations at the origin of the pollution plume and downwind. A novel Soxhlet extraction method for Hi-Vol filters was developed based on literature and EPA standard methods. Analysis for nitrate production was done by …

Effects Of Molecular Structure Of The Oxidation Products Of Reactive Atmospheric Hydrocarbons On The Formation Of Secondary Organic Particulate Matter, Including The Effects Of Water, Negar Niakan

Dissertations and Theses

Organic aerosols have significant effects on human health, air quality and climate. Secondary organic aerosols (SOA) are produced by the oxidation of primary-volatile organic compounds (VOC). For example, α-pinene reacts with oxidants such as hydroxyl radical (OH), ozone (O₃), and nitrate radical (NO₃), accounting for a significant portion of total organic aerosol in the atmosphere. Experimental studies have shown that the oxidation process between α-pinene and ozone has the most significant impact in the formation of SOA (Hoffmann et al., 1997). Most of the models used to predict SOA formation, however, are limited in that they …

Analyzing Experimental Data And Model Parameters: Implications For Predictions Of Soa Using Chemical Transport Models, Kelley Barsanti, Annmarie G. Carlton, Serena H. Chung

Civil and Environmental Engineering Faculty Publications and Presentations

Despite critical importance for air quality and climate predictions, accurate representation of secondary organic aerosol (SOA) formation remains elusive. An essential addition to the ongoing discussion of improving model predictions is an acknowledgement of the linkages between experimental conditions, parameter optimization and model output, as well as the linkage between empirically-derived partitioning parameters and the physicochemical properties of SOA they represent in models. In this work, a "best available" set of SOA modeling parameters is selected by comparing predicted SOA yields and mass concentrations with observed yields and mass concentrations from a comprehensive list of published smog chamber studies. Evaluated …

Community Earth System Model: Implementation, Validation, And Applications, William Christian Porter

Dissertations and Theses

The Community Earth System Model (CESM) is a coupling of five different models which are combined to simulate the dynamic interactions between and within the Earth's atmosphere, ocean, land, land-ice, and sea-ice. In this work, the installation and testing of CESM on Portland State University's Cluster for Climate Change and Aerosol Research (CsAR) is described and documented, and two research applications of the model are performed. First, the improved treatment of cloud microphysics within recent versions of CESM's atmospheric module is applied to an examination of changes in shortwave cloud forcing (SWCF) and results are compared to output from older …

Ensemble Methods For Dynamic Data Assimilation Of Chemical Observations In Atmospheric Models, Adrian Sandu, Emil Constantinescu, Gregory R. Carmichael, Tianfeng Chai, Dacian Daescu, John H. Seinfeld

Mathematics and Statistics Faculty Publications and Presentations

The task of providing an optimal analysis of the state of the atmosphere requires the development of dynamic data-driven systems (DDDAS) that efficiently integrate the observational data and the models. Data assimilation, the dynamic incorporation of additional data into an executing application, is an essential DDDAS concept with wide applicability. In this paper we discuss practical aspects of nonlinear ensemble Kalman data assimilation applied to atmospheric chemical transport models. We highlight the challenges encountered in this approach such as filter divergence and spurious corrections, and propose solutions to overcome them, such as background covariance inflation and filter localization. The predictability …

The Integrated Wrf/Urban Modeling System: Development, Evaluation, And Applications To Urban Environmental Problems, Fei Chen, Hiroyuki Kusaka, Robert Bornstein, Jason Ching, C.S.B. Grimmond, Susanne Grossman-Clarke, Thomas Loridan, Kevin W. Manning, Alberto Martilli, Shiguang Miao, David J. Sailor, Francisco P. Salamanca, Haider Taha, Mukul Tewari, Xuemei Wang, Andrzej A. Wyszogrodzki, Chaolin Zhang

Mechanical and Materials Engineering Faculty Publications and Presentations

To bridge the gaps between traditional mesoscale modeling and microscale modeling, the National Center for Atmospheric Research (NCAR), in collaboration with other agencies and research groups, has developed an integrated urban modeling system coupled to the Weather Research and Forecasting (WRF) model as a community tool to address urban environmental issues. The core of this WRF/urban modeling system consists of: 1) three methods with different degrees of freedom to parameterize urban surface processes, ranging from a simple bulk parameterization to a sophisticated multi-layer urban canopy model with an indoor outdoor exchange sub-model that directly interacts with the atmospheric boundary layer, …

Extensive Aerosol Optical Properties And Aerosol Mass Related Measurements During Tramp/Texaqs 2006 – Implications For Pm Compliance And Planning, Monica Elizabeth Wright, Dean B. Atkinson, Luke Ziemba, Robert Griffin, Naruki Hiranuma, Sarah D. Brooks, James Flynn, Ryan Perna, Bernhard Rappenglück, Winston Luke, Paul Kelley

Chemistry Faculty Publications and Presentations

Extensive aerosol optical properties, particle size distributions, and Aerodyne quadrupole aerosol mass spectrometer measurements collected during TRAMP/TexAQS 2006 were examined in light of collocated meteorological and chemical measurements. Much of the evident variability in the observed aerosol-related air quality is due to changing synoptic meteorological situations that direct emissions from various sources to the TRAMP site near the center of the Houston-Galveston-Brazoria (HGB) metropolitan area. In this study, five distinct long-term periods have been identified. During each of these periods, observed aerosol properties have implications that are of interest to environmental quality management agencies. During three of the periods, long …

Comparison Of In Situ And Columnar Aerosol Spectral Measurements During Texaqs-Gomaccs 2006: Testing Parameterizations For Estimating Aerosol Fine Mode Properties, Dean B. Atkinson, Paola Massoli, Norman T. O'Neill, Patricia K. Quinn, Sarah D. Brooks, Barry Lefer

Chemistry Faculty Publications and Presentations

During the 2006 Texas Air Quality Study and Gulf of Mexico Atmospheric Composition and Climate Study (TexAQS-GoMACCS 2006), the optical, chemical and microphysical properties of atmospheric aerosols were measured on multiple mobile platforms and at ground based stations. In situ measurements of the aerosol light extinction coefficient (σep) were performed by two multi-wavelength cavity ring-down (CRD) instruments, one located on board the NOAA R/V Ronald H. Brown (RHB) and the other located at the University of Houston, Moody Tower (UHMT). An AERONET sunphotometer was also located at the UHMT to measure the columnar aerosol optical depth (AOD). The σep data …

Application Of Tree-Structured Regression For Regional Precipitation Prediction Using General Circulation Model Output, Xiangshang Li, David J. Sailor

Mechanical and Materials Engineering Faculty Publications and Presentations

This study presents a tree-structured regression (TSR) method to relate daily precipitation with a variety of free-atmosphere variables. Historical data were used to identify distinct weather patterns associated with differing types of precipitation events. Models were developed using 67% of the data for training and the remaining data for model validation. Seasonal models were built for each of 2 US sites: San Francisco, California, and San Antonio, Texas. The average correlation between observed and simulated daily precipitation data series is 0.75 for the training set and 0.68 for the validation set. Relative humidity was found to be the dominant variable …

Adsorption Of Sulfur Dioxide On Douglas Fir Woodchips, Uen-Ping David Wang

Dissertations and Theses

In recent years, people have raised their alertness to the hazard of air pollution. Sulfur dioxide is one of the most dangerous chemical compounds among those air pollutants. A study on removing sulfur dioxide from an air stream by adsorption using wood chips as the adsorbent is presented in this thesis.

The reason for using wood as an adsorbent is that wood is a porous material and possesses a large surface of cell cavities which can hold a great amount of moisture. As sulfur dioxide gas is passed through the wood bed, it would be either condensed in the cell …