Atmospheric Sciences Commons^™

Global Variations Of Hdo And Hdo/H2o Ratios In The Upper Troposphere And Lower Stratosphere Derived From Ace-Fts Satellite Measurements, William J. Randel, Elisabeth Moyer, Mijeong Park, Eric Jensen, Peter Bernath

Chemistry & Biochemistry Faculty Publications

High-quality satellite observations of water and deuterated water in the upper troposphere and lower stratosphere (UTLS) from the Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE-FTS) are used to map global climatological behavior. Spatial and temporal variability in these data suggest that convection plays a significant role in setting water vapor isotopic composition in these regions. In many instances, enhancements in HDO/H₂O (i.e., δD) are closely tied to patterns of climatological deep convection and uncorrelated with water vapor, although convection appears to have different isotopic effects in different locations. The ACE-FTS data reveal seasonal variations in the tropics …

Technical Note: A Trace Gas Climatology Derived From The Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts) Data Set, A. Jones, K. A. Walker, J. J. Jin, J. R. Taylor, C. D. Boone, P. F. Bernath, S. Brohede, G. L. Manney, S. Mcleod, R. Hughes, W. H. Daffer

Chemistry & Biochemistry Faculty Publications

The Atmospheric Chemistry Experiment-Fourier Transform Spectrometer (ACE-FTS) aboard the Canadian satellite SCISAT (launched in August 2003) was designed to investigate the composition of the upper troposphere, stratosphere, and mesosphere. ACE-FTS utilizes solar occultation to measure temperature and pressure as well as vertical profiles of over thirty chemical species including O₃, H₂O, CH₄, N₂O, CO, NO, NO₂, N₂O₅, HNO₃, HCl, ClONO₂, CCl₃F, CCl₂F₂, and HF. Global coverage for each species is obtained approximately over a three month …

Greenhouse Gas Measurements Over A 144 Km Open Path In The Canary Islands, J.S. A. Brooke, P. F. Bernath, G. Kirchengast, C. B. Thomas, J. G. Wang, K. A. Tereszchuk, G. González Abad, R. J. Hargreaves, C. A. Beale, J. J. Harrison

Chemistry & Biochemistry Faculty Publications

A new technique for the satellite remote sensing of greenhouse gases in the atmosphere via the absorption of short-wave infrared laser signals transmitted between counter-rotating satellites in low Earth orbit has recently been proposed; this would enable the acquisition of a long-term, stable, global set of altitude-resolved concentration measurements. We present the first ground-based experimental demonstration of this new infrared-laser occultation method, in which the atmospheric absorption of CO₂ near 2.1µm was measured over a ∼144km path length between two peaks in the Canary Islands (at an altitude of ∼2.4 km), using relatively low power diode lasers (∼4 to …

First Remote Sensing Observations Of Trifluoromethane (Hfc-23) In The Upper Troposphere And Lower Stratosphere, Jeremy J. Harrison, Christopher D. Boone, Alexander T. Brown, Nicholas D. C. Allen, Geoffrey C. Toon, Peter F. Bernath

Chemistry & Biochemistry Faculty Publications

This work reports the first remote sensing measurements of atmospheric HFC-23 (CHF₃) using solar occultation measurements made by the Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE-FTS) and the Jet Propulsion Laboratory Mark IV (MkIV) balloon interferometer. A total of 8809 ACE occultations measured between 2004 and 2010 have been processed, along with 24 MkIV occultations measured between 1989 and 2007. ACE data (yearly averages over the 10-25 km altitude range) in the tropics/subtropics (40°S-40°N) reveal a trend of 4.0 ± 1.6% per year in the growth of HFC-23 for 2004-2009 (or 3.9 ± 1.2% per year for 2004-2010), …

Analysis Of Iasi Tropospheric O₃ Data Over The Arctic During Polarcat Campaigns In 2008, M. Pommier, C. Clerbaux, K. S. Law, G. Ancellet, P. Bernath, P.-F. Coheur, J. Hadji-Lazaro, D. Hurtmans, P. Nédélec, J.-D. Paris, F. Ravetta, T. B. Ryerson, H. Schlager, A. J. Weinheimer

Chemistry & Biochemistry Faculty Publications

Ozone data retrieved in the Arctic region from infrared radiance spectra recorded by the Infrared Atmospheric Sounding Interferometer (IASI) on board the MetOp-A European satellite are presented. They are compared with in situ and lidar observations obtained during a series of aircraft measurement campaigns as part of the International Polar Year POLARCAT activities in spring and summer 2008. Different air masses were sampled during the campaigns including clean air, polluted plumes originating from anthropogenic sources, forest fire plumes from the three northern continents, and stratospheric-influenced air masses. The comparison between IASI O₃ [0–8 km], [0–12 km] partial columns and …

Rapid And Noncontaminating Sampling System For Trace Elements In Global Ocean Surveys, Gregory A. Cutter, Kenneth W. Bruland

OES Faculty Publications

A system for the rapid and noncontaminating sampling of trace elements with volumes of up to 36 L per depth and including the dissolved and particulate phases has been developed for ocean sections that are a crucial part of programs such as International GEOTRACES. The system uses commercially available components, including an aluminum Seabird Carousel with all titanium pressure housings for electronics and sensors to eliminate zinc sacrificial anodes and holding twenty-four 12 L GO-FLO bottles, and a 7500 m, 14 mm Vectran conducting cable (passing over an A-frame with nonmetallic sheave) spooled onto a traction winch. The GO-FLO bottles …

The Effect Of An Offshore Wind Turbine Array On Circulation In An Idealized Coastal Ocean, Mahmoud Kamel

OES Theses and Dissertations

The effect of arrays of wind turbines on circulation in the coastal ocean is analyzed with a coastal numerical model applied to a shallow coastal area like the Mid Atlantic Bight (MAB). A simplified model domain is specified with a linearly deepening shelf along a straight coastline. The initial density structure is a quasi-two layer situation with a sharp thermocline. Wind stress in most of the cases is either upwelling or downwelling favorable with constant amplitude continuing after a smooth start. There are two cases where oscillating wind forcing is used. Simulations consider wind arrays having different widths, different locations …

Design And Demonstration Of A Miniature Lidar System For Rover Applications, Benjamin Robinson

Electrical & Computer Engineering Theses & Dissertations

Public awareness of harmful human environmental effects such as global warming has increased greatly in recent years and researchers have increased their efforts in gaining more knowledge about the Earth's atmosphere. Natural and man-made processes pose threats lo the environment and human life, so knowledge of all atmospheric processes is necessary. Ozone and aerosols are important factors in many atmospheric processes and active remote sensing techniques provide a way lo analyze their quantity and distribution.

A compact ground-based lidar system for a robotic platform meant for atmospheric aerosol measurements was designed, tested, and evaluated. The system will eventually be deployed …

Improving Simulations Of The Upper Ocean By Inclusion Of Surface Waves In The Mellor-Yamada Turbulence Scheme, Chuan Jiang Huang, Fangli Qiao, Zhenya Song, Tal Ezer

CCPO Publications

The Mellor-Yamada turbulence closure scheme, used in many ocean circulation models, is often blamed for overly high simulated surface temperature and overly low simulated subsurface temperature in summer due to insufficient vertical mixing. Surface waves can enhance turbulence kinetic energy and mixing of the upper ocean via wave breaking and nonbreaking-wave-turbulence interaction. The influences of wave breaking and wave-turbulence interaction on the Mellor-Yamada scheme and upper ocean thermal structure are examined and compared with each other using one-dimensional and three-dimensional ocean circulation models. Model results show that the wave-turbulence interaction can effectively amend the problem of insufficient mixing in the …

Fossil And Contemporary Aerosol Particulate Organic Carbon In The Eastern United States: Implications For Deposition And Inputs To Watersheds, Andrew S. Wozniak, James E. Bauer, Rebecca M. Dickhut

Chemistry & Biochemistry Faculty Publications

Atmospheric particulate matter samples were collected from mid-Atlantic and northeastern U. S. (Virginia and New York, respectively) sites to assess the fossil versus contemporary sources contributing to aerosol organic carbon (OC) and the implications for its deposition to watersheds. Mean particulate matter total OC (TOC) deposition rates (wet + dry deposition) were calculated to be 1.6 and 2.4 mg C m^-2 d^-1 for the Virginia and New York sites, respectively. Wet deposition of particulate TOC was determined to be the dominant depositional mode, accounting for >65% (Virginia) and >80% (New York) of total aerosol TOC deposition. Isotopic mass …

Ace-Fts Measurements Of Trace Species In The Characterization Of Biomass Burning Plumes, K. A. Tereszchuk, G. González Abad, C. Clerbaux, D. Hurtmans, P.-F. Coheur, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

To further our understanding of the effects of biomass burning emissions on atmospheric composition, we report measurements of trace species in biomass burning plumes made by the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) instrument on the SCISAT-1 satellite. An extensive set of 15 molecules, C₂H₂, C₂H₆, CH₃OH, CH₄, CO, H₂CO, HCN, HCOOH, HNO₃, NO, NO₂, N₂O₅, O-3, OCS and SF₆ are used in our analysis. Even though most biomass burning smoke is typically confined to the …

Balloon Borne Mars Research Platforms, Sean Michael Hancock

Mechanical & Aerospace Engineering Theses & Dissertations

Aerial platforms can fill a measurement gap between orbiters and rovers, providing planetary scale high resolution in situ measurements, access to scientifically interesting terrain that is either inaccessible or hazardous to rovers, and serve as a planet-wide delivery platforms to deploy surface probes and rovers to areas inaccessible given existing entry, descent, and landing systems. A permanent robotic outpost on the Martian surface can utilize locally-derived hydrogen as a lifting gas for balloon systems deployed from Mars. That approach can simplify the inflation and launch of aerial vehicles while allowing for a long duration deployment campaign that is not constrained …

A Differential Absorption Model For Remote Sensing Of Atmospheric Pressure, Shivam J. Shah

Electrical & Computer Engineering Theses & Dissertations

The goal of the project is to develop and test a "model based" radar processing strategy that is compatible with the concept of a "cognitive radar". The basic approach will be to develop a cognitive radar algorithm (genetic algorithm) based on the capabilities of an existing commercially available Software Radio. While the focus of this effort is the development of a candidate approach for genetic algorithm, the longer term goal would be to implement the approach using this software radio technology to provide a low cost radar processor. The proposed technology would use differential absorption radar working at the 50-56 …

Mixing By Shear Instability At High Reynolds Number, W. R. Geyer, A. C. Lavery, M. E. Scully, J. H. Trowbridge

CCPO Publications

Shear instability is the dominant mechanism for converting fluid motion to mixing in the stratified ocean and atmosphere. The transition to turbulence has been well characterized in laboratory settings and numerical simulations at moderate Reynolds number-it involves "rolling up", i.e., overturning of the density structure within the cores of the instabilities. In contrast, measurements in an energetic estuarine shear zone reveal that the mixing induced by shear instability at high Reynolds number does not primarily occur by overturning in the cores; rather it results from secondary shear instabilities within the zones of intensified shear separating the cores. This regime is …

On The Fractional Solubillity Of Copper In Marine Aerosols: Toxicity Of Aeolian Copper Revisited, Edward R. Sholkovitz, Peter N. Sedwick, Thomas M. Church

OES Faculty Publications

Paytan et al. (2009) argue that the atmospheric deposition of aerosols lead to copper concentrations that are potentially toxic to marine phytoplankton in a large area of tropical and subtropical North Atlantic Ocean. A key assumption in their model is that all marine aerosols (mineral dust and anthropogenic particles) have a high (40%) fractional solubility of copper. Our data show that the fractional solubility of copper for Saharan dust over the Sargasso Sea and Bermuda is significantly lower (1-7%). In contrast, anthropogenic aerosols with non-Saharan sources have significantly higher values (10-100%). Hence, the potential Cu toxicity in the tropical and …

Effects Of Non-Equilibrium Plasma On Eukaryotic Cells (Final Report: Grant Fa9550-06-1-0004), Mounir Laroussi, Fred C. Dobbs, Old Dominion University

Electrical & Computer Engineering Faculty Publications

This document is our final report describing the research activities carried out under AFOSR Grant FA9550-06-1-0004. First, descriptions of our cold plasma generation systems are presented. Two systems, developed with past and present AFOSR support, are available in our laboratory. The first is a pulsed device capable of emitting a cold plasma plume in room air. The second is an air plasma generator the core of which is a dielectric barrier discharge excited by a high AC voltage. Following these brief descriptions we first present the effects of an atmospheric pressure air plasma on four different types of eukaryotic microalgae. …

A Compact Lidar For Aircraft Ozone Atmospheric Measurements, Joel A. Marcia

Electrical & Computer Engineering Theses & Dissertations

Researchers and the general public have expressed great concern over how human activities exacerbate pollution's deteriorating impact upon the environment. Effects such as global warming, air quality and ozone layer depletion are but a few examples that can have a dramatic effect on the quality of life worldwide.

A compact lidar system for the purpose of aircraft ozone atmospheric measurements was tested and evaluated. This system will eventually be deployed for aircraft-based, and possibly unpiloted atmospheric vehicle (UAV), ozone and aerosol measurements to improve our understanding of ozone production and transport. Each of the major subsystems was characterized and from …

Enso And Variability Of The Antarctic Peninsula Pelagic Marine Ecosystem, Valerie J. Loeb, Eileen E. Hofmann, John M. Klinck, Osmund Holm-Hansen, Warren B. White

CCPO Publications

The West Antarctic Peninsula region is an important source of Antarctic krill (Euphausia superba) in the Southern Ocean. From 1980-2004 abundance and concentration of phytoplankton and zooplankton, krill reproductive and recruitment success and seasonal sea ice extent here were significantly correlated with the atmospheric Southern Oscillation Index and exhibited three- to five-year frequencies characteristic of El Nino-Southern Oscillation (ENSO) variability. This linkage was associated with movements of the Southern Antarctic Circumpolar Current Front and Boundary, a changing influence of Antarctic Circumpolar Current and Weddell Sea waters, and eastward versus westward flow and mixing processes that are consistent with forcing by …

Cirene Air-Sea Interactions In The Seychelles-Chagos Thermocline Ridge Region, J. Vialard, J. P. Duvel, M. J. Mcphaden, P. Bouruet-Aubertot, B. Ward, E. Key, D. Bourras, R. Weller, P. Minnett, A. Weil

OES Faculty Publications

A field experiment in the southwestern Indian Ocean provides new insights into ocean-atmosphere interactions in a key climatic region.

Anthropogenic Osmium In Rain And Snow Reveals Global-Scale Atmospheric Contamination, Cynthia Chen, Peter N. Sedwick, Mukul Sharma

OES Faculty Publications

Osmium is one of the rarer elements in seawater, with typical concentration of ≈10 x 10^-15 g g^-1 ( 5.3 x 10^-14 mol kg^-1. The osmium isotope composition (¹⁸⁷Os/¹⁸⁸Os ratio) of deep oceans is 1.05, reflecting a balance between inputs from continental crust (≈ 1.3) and mantle/cosmic dust (≈ 0.13). Here, we show that the ¹⁸⁷Os/¹⁸⁸Os ratios measured in rain and snow collected around the world range from 0.16 to 0.48, much lower than expected (>1), but similar to the isotope composition of ores (approximate to 0.2) …

Technical Note: Molecular Characterization Of Aerosol-Derived Water Soluble Organic Carbon Using Ultrahigh Resolution Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, A. S. Wozniak, J. E. Bauer, R. L. Sleighter, R. M. Dickhut, Patrick Hatcher

Chemistry & Biochemistry Faculty Publications

Despite the acknowledged relevance of aerosol-derived water-soluble organic carbon (WSOC) to climate and biogeochemical cycling, characterization of aerosol WSOC has been limited. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) was utilized in this study to provide detailed molecular level characterization of the hi(,h molecular weight (HMW; m/z>223) component of aerosol-derived WSOC collected from rural sites in Virginia and New York, USA. More than 3000 peaks were detected by ESI FT-ICR MS within a m/z range of 223-600 for each sample. Approximately 86% (Virginia) and 78% (New York) of these peaks were assigned molecular formulas …

Sublethal And Killing Effects Of Atmospheric-Pressure, Nonthermal Plasma On Eukaryotic Microalgae In Aqueous Media, Ying Zhong Tang, Xin Pei Lu, Mounir Laroussi, Fred C. Dobbs

OES Faculty Publications

In-depth studies on the interaction of nonthermal plasmas with microorganisms usually focus on bacteria; only little attention has been given to their effects on more complex eukaryotic cells. We report here nonthermal plasma's effects on cell motility, viability staining, and morphology of eukaryotic microalgae, with three marine dinoflagellates and a marine diatom as major targets. The effects on motility and viability staining depended on the time of exposure to plasma and the species of microalgae. We observed a strong pH decrease in aqueous samples (marine and freshwater algal cultures, their culture media, and deionized water) after exposure to plasma, and …

Simulation Of The Recent Multidecadal Increase Of Atlantic Hurricane Activity Using An 18-Km-Grid Regional Model, Thomas R. Knutson, Joseph J. Sirutis, Stephen T. Garner, Isaac M. Held, Robert E. Tuleya

CCPO Publications

In this study, a new modeling framework for simulating Atlantic hurricane activity is introduced. The model is an 18-km-grid nonhydrostatic regional model, run over observed specified SSTs and nudged toward observed time-varying large-scale atmospheric conditions (Atlantic domain wavenumbers 0-2) derived from the National Centers for Environmental Prediction (NCEP) reanalyses. Using this "perfect large-scale model" approach for 27 recent August-October seasons (1980-2006), it is found that the model successfully reproduces the observed multidecadal increase in numbers of Atlantic hurricanes and several other tropical cyclone (TC) indices over this period. The correlation of simulated versus observed hurricane activity by year varies from …

Simulations Of Phytoplankton Species And Carbon Production In The Equatorial Pacific Ocean 1. Model Configuration And Ecosystem Dynamics, Baris Salihoglu, Eileen E. Hofmann

OES Faculty Publications

The primary objective of this research is to investigate phytoplankton community response to variations in physical forcing and biological processes in the Cold Tongue region of the equatorial Pacific Ocean at 0N, 140W. This research objective was addressed using a one-dimensional multicomponent lower trophic level ecosystem model that includes detailed algal physiology, such as spectrally-dependent photosynthetic processes and iron limitation on algal growth. The ecosystem model is forced by a one-year (1992) time series of spectrally-dependent light, temperature, and water column mixing obtained from a Tropical Atmosphere-Ocean (TAO) Array mooring. Autotrophic growth is represented by five algal groups, which have …

Iron In Ice Cores From Law Dome: A Record Of Atmospheric Iron Deposition For Maritime East Antarctica During The Holocene And Last Glacial Maximum, Ross Edwards, Peter N. Sedwick, Vin Morgan, Claude Boutron

OES Faculty Publications

Total dissolvable iron (TDFe) was measured in sections of ice cores recovered from Law Dome on the coast of Wilkes Land, East Antarctica. These samples include ice dating from the Last Glacial Maximum (LGM), the Last Deglaciation, and the early and mid Holocene as well as samples from the Anthropocene that have been dated with seasonal to annual resolution. Combining our TDFe concentration data with estimates of the ice accumulation rate, we estimate the atmospheric iron deposition for Law Dome and the adjacent Southern Ocean during these periods. Our results indicate that the atmospheric iron deposition flux to this region …

An Exercise In Forecasting Loop Current And Eddy Frontal Positions In The Gulf Of Mexico, Lie-Yauw Oey, Tal Ezer, George Forristall, C. Cooper, Steven Dimarco, S. Fan

CCPO Publications

As part of a model-evaluation exercise to forecast Loop Current and Loop Current eddy frontal positions in the Gulf of Mexico, the Princeton Regional Ocean Forecast System (PROFS) is tested to forecast 14 4-week periods Aug/25/99- Sep/20/00, during which a powerful eddy, Eddy Juggernaut (Eddy-J) separated from the Loop Current and propagated southwestward. To initialize each forecast, PROFS assimilates satellite sea surface height (SSH) anomaly and temperature (SST) by projecting them into subsurface density using a surface/subsurface correlation that is a function of the satellite SSH anomaly. The closest distances of the forecast fronts from seven fixed stations in the …

Flowers Of Ice- Beauty, Symmetry, And Complexity: A Review Of The Snowflake: Winter's Secret Beauty, John A. Adam

Mathematics & Statistics Faculty Publications

(First paragraph) Growing up as a child in southern England, my early memories of snow include trudging home from school with my father, gazing at the seemingly enormous snowdrifts that smoothed the hedgerows, fields and bushes, while listening to the soft “scrunch” of the snow under my Wellington boots. In the country, snow stretching as far as I could see was not a particularly uncommon sight. The quietness of the land under a foot of snow seemed eerie. I cannot remember the first time I looked at snowflakes per se; my interests as a small child were primarily in their …

Biophysical Mechanisms Of Larval Fish Ingress Into Chesapeake Bay, Jonathan A. Hare, Simon Thorrold, Harvey Walsh, Christian Reiss, Arnoldo Valle-Levinson, Cynthia Jones

OES Faculty Publications

Selective tidal stream transport is hypothesized as a dominant mechanism by which larvae of marine animals move through estuarine openings. For larvae moving from the shelf to estuarine habitats, selective tidal stream transport proposes that larvae are higher in the water column during flood tide and lower in the water column during ebb tide. Although a number of studies conclude that selective tidal stream transport is the mechanism responsible for larval ingress, few studies consider alternative mechanisms or consider passive explanations for tidal patterns in larval distributions. We examined the biophysical mechanisms responsible for larval ingress into Chesapeake Bay using …

Satellite Evidence Of Hurricane-Induced Phytoplankton Blooms In An Oceanic Desert, S. M. Babin, J. A. Carton, T. D. Dickey, J. D. Wiggert

CCPO Publications

The physical effects of hurricanes include deepening of the mixed layer and decreasing of the sea surface temperature in response to entrainment, curl-induced upwelling, and increased upper ocean cooling. However, the biological effects of hurricanes remain relatively unexplored. In this paper, we examine the passages of 13 hurricanes through the Sargasso Sea region of the North Atlantic during the years 1998 through 2001. Remotely sensed ocean color shows increased concentrations of surface chlorophyll within the cool wakes of the hurricanes, apparently in response to the injection of nutrients and/or biogenic pigments into the oligotrophic surface waters. This increase in post-storm …

Modeled And Observed Empirical Orthogonal Functions Of Currents In The Yucatan Channel, Gulf Of Mexico, Lie-Yauw Oey, Tal Ezer, Wilton Sturges

CCPO Publications

Candela et al. [2003] have reported empirical orthogonal function (EOF) analyses based on 23-month current-meter and acoustic Doppler current profiler measurements in the Yucatan Channel. Those authors noted the difference between EOFs obtained from observations and their z-level models and EOFs calculated by Ezer et al. [2003] from the results of a terrain-following model. Here a new analysis is reported that explains this difference, and that also suggests the importance of shelf-edge meander mode of the core Loop Current in the channel. We show that the terrain-following model gives EOFs with characteristics similar to those observed when data from the …