Atmospheric Sciences Commons^™

Comparison Of Combustion Efficiency To In-Situ Atmospheric Ammonia Measurements From A Miniature Chemical Ionization Mass Spectrometer In The La Basin, Taylor Krause, Barry L. Lefer, Timothy H. Betram, Steven R. Schill

Student Scholar Symposium Abstracts and Posters

Atmospheric ammonia (NH₃) has been shown to impact the environment and threaten both human and animal health, especially in heavily populated urban areas, yet to date there remains a paucity of direct measurements. Recent studies have suggested that ammonia may be generated as a byproduct of fossil fuel emissions due to highly active catalytic converters in light-duty gasoline vehicles. To investigate this relationship, an airborne miniature Chemical Ionization Mass Spectrometer (miniCIMS) was used to directly measure atmospheric ammonia and combustion reaction products in the Southern California LA Basin, during the 2015 NASA Student Airborne Research Program (SARP). The …

Techniques For Payload Stabilization For Improved Photography During Stratospheric Balloon Flights, James Flaten, Christopher Gosch, Joseph (Benjamin) Habeck

2017 Academic High Altitude Conference

Payload-box rotation and swing are perennial challenges to achieving high-quality photography (typically videography) during weather-balloon flights to “near-space” (AKA the stratosphere). Continuous camera motion can lead to blurred still photos, nearly-impossible-to-watch video footage, and precludes time-exposure photography required for most astronomical imaging even though altitudes are reached where the daytime sky appears black. Apparently-random payload rotation, persisting even at altitude, can often exceed servo rotation rates and frustrate attempts to do active camera pointing. Here we discuss mostly-passive payload stabilization strategies we, and our collaborators, have used to mitigate and dampen both swing and rotation of suspended payloads on high-altitude …

Dimethylsulfide Gas Transfer Coefficients From Algal Blooms In The Southern Ocean, T. G. Bell, Warren J. De Bruyn, Christa A. Marandino, S. D. Miller, C. S. Law, Eric S. Saltzman

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Air-sea dimethylsulfide (DMS) fluxes and bulk air-sea gradients were measured over the Southern Ocean in February-March 2012 during the Surface Ocean Aerosol Production (SOAP) study. The cruise encountered three distinct phytoplankton bloom regions, consisting of two blooms with moderate DMS levels, and a high biomass, dinoflagellate-dominated bloom with high seawater DMS levels (> 15 nM). Gas transfer coefficients were considerably scattered at wind speeds above 5 m s(-1). Bin averaging the data resulted in a linear relationship between wind speed and mean gas transfer velocity consistent with that previously observed. However, the wind-speed-binned gas transfer data distribution at all wind …

Long Term Ground Based Precipitation Data Analysis: Spatial And Temporal Variability, Luciano Rodriguez, Cyril S. Rakovski, Hesham El-Askary, Mohamed Allali

Student Scholar Symposium Abstracts and Posters

California is an area of diverse topography and has what many scientists call a Mediterranean climate. Various precipitation patterns exist due to El Niño Southern Oscillation (ENSO) which can cause abnormal precipitation or droughts. As temperature increases mainly due to the increase of CO2 in the atmosphere, it is rapidly changing the climate of not only California but the world. An increase in temperature is leading to droughts in certain areas as other areas are experiencing heavy rainfall/flooding. Droughts in return are providing a foundation for fires harming the ecosystem and nearby population. Various natural hazards can be induced due …

Aerosol Association With Severe Weather In The Great Plains, Gabriel A. Lojero

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Aerosols particles may serve as cloud condensation nuclei (CCN) and therefore play an important role in modulating cloud microphysics, to the point where convective storm intensity may be altered. The purpose of this study is to determine the impacts of biomass burning aerosols on convective storms over the Great Plains, especially the southern Great Plains, and to show synoptic regimes characterizing differing aerosol concentrations. A new technique to identify days with a high concentration of biomass burning aerosols was developed by using organic carbon, potassium, zinc, and bromine as the predominant tracers. An eleven-year climatology (2002-2012) for the biomass burning …

Data-Driven Diagnostics Of Terrestrial Carbon Dynamics Over North America, Jingfeng Xiao, Scott V. Ollinger, Steve Frolking, George Hurtt, David Y. Hollinger, Kenneth J. Davis, Yude Pan, Xiaoyang Zhang, Feng Deng, Jiquan Chen, Dennis D. Baldocchi, Beverly E. Law, M. Altaf Arain, Ankur R. Desai, Andrew D. Richardson, Ge Sun, Brian Amiro, Hank Margolis, Lianhong Gu, Russell L. Scott, Peter D. Blanken, Andrew E. Suyker

School of Natural Resources: Faculty Publications

The exchange of carbon dioxide is a key measure of ecosystem metabolism and a critical intersection between the terrestrial biosphere and the Earth’s climate. Despite the general agreement that the terrestrial ecosystems in North America provide a sizeable carbon sink, the size and distribution of the sink remain uncertain. We use a data-driven approach to upscale eddy covariance flux observations from towers to the continental scale by integrating flux observations, meteorology, stand age,aboveground biomass, and a proxy for canopy nitrogen concentrations from AmeriFlux and Fluxnet-Canada Research Network as well as a variety of satellite data streams from the MODIS sensors. …

Horizontal Divergence Of Typhoon-Generated Gravity Waves In The Upper Troposphere And Lower Stratosphere (Utls) And Its Influence On Typhoon Evolution, Seung Hee Kim, H.-Y. Chun, W. Jang

Mathematics, Physics, and Computer Science Faculty Articles and Research

The characteristics of horizontal divergence induced by typhoon-generated gravity waves (HDTGWs) and the influence of HDTGW on typhoon evolution are investigated based on the simulation results of Typhoon Saomai (2006) using the Weather Research and Forecasting (WRF) model. The power spectral density of HDTGW shows dominant powers at horizontal wavelengths of 20-30 km and at periods of less than 1 h. This is associated with gravity waves generated by vigorous convective clouds in an inner core region of the typhoon. However, the domain-averaged HDTGW in the upper troposphere and lower stratosphere had a spectral peak at 24 h, which is …

Air-Sea Dimethylsulfide (Dms) Gas Transfer In The North Atlantic: Evidence For Limited Interfacial Gas Exchange At High Wind Speed, T. G. Bell, Warren J. De Bruyn, S. D. Miller, B. Ward, K. Christensen, E. S. Saltzman

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Shipboard measurements of eddy covariance dimethylsulfide (DMS) air-sea fluxes and seawater concentration were carried out in the North Atlantic bloom region in June/July 2011. Gas transfer coefficients (k(660)) show a linear dependence on mean horizontal wind speed at wind speeds up to 11 m s(-1). At higher wind speeds the relationship between k(660) and wind speed weakens. At high winds, measured DMS fluxes were lower than predicted based on the linear relationship between wind speed and interfacial stress extrapolated from low to intermediate wind speeds. In contrast, the transfer coefficient for sensible heat did not exhibit this effect. The apparent …

Interannual And Spatial Impacts Of Phenological Transitions, Growing Season Length, And Spring And Autumn Temperatures On Carbon Sequestration: A North America Flux Data Synthesis, Chaoyang Wu, Alemu Gonsamo, Jing Ming Chen, Werner A. Kurz, David T. Price, Peter M. Lafleur, Rachhpal S. Jassal, Danilo Dragoni, Gil Bohrer, Christopher M. Gough, Shashi B. Verma, Andrew E. Suyker, J. William Munger

School of Natural Resources: Faculty Publications

Understanding feedbacks of ecosystem carbon sequestration to climate change is an urgent step in developing future ecosystem models. Using 187 site-years of flux data observed at 24 sites covering three plant functional types (i.e. evergreen forests (EF), deciduous forests (DF) and non-forest ecosystems (NF) (e.g., crop, grassland, wetland)) in North America, we present an analysis of both interannual and spatial relationships between annual net ecosystem production (NEP) and phenological indicators, including the flux-based carbon uptake period (CUP) and its transitions, degree-day-derived growing season length (GSL), and spring and autumn temperatures. Diverse responses were acquired between annul NEP and these indicators …

Assessing Delta Oxygen-18 In The Coral Genus Isopora For Reconstructing Indo-Pacific Regional And Seasonal Climate, Gavin Lemley

Legacy Theses & Dissertations (2009 - 2024)

Paleoclimate reconstructions often utilize coral reefs with very long time spans such as the genus Porites and Diploastrea, because of their potential to provide centuries of continuous climate records via geochemical signatures. Smaller corals, such as the genus Isopora, have been essentially unexplored as climate archives because their small skeletons (<1 m) and short lifespans (years to decades) do not provide such continuous geochemical records. There has not been a practical application for such corals until recently. In early 2010, the Integrated Ocean Drilling Program Leg 325 (IODP-325) cored drowned fossil reefs off the Great Barrier Reef (GBR) with the objectives of reconstructing sea level and surface ocean conditions since the Last Glacial Maximum. Out of 213 massive fossil corals that were recovered, most were massive Isoporan colonies. A 30-specimen subset of these fossils range in age from ~32,000 to ~11,500 years before present with even temporal spacing, based on preliminary U/Th dating of core catcher samples. This age distribution is excellent for meeting IODP-325 objectives, but the suitability of Isopora for paleoclimate analyses remains unknown.

Influence Of Anomalous Dry Conditions On Aerosols Over India: Transport, Distribution And Properties, Dimitris G. Kaskaoutis, Ritesh Gautam, Ramesh P. Singh, E. E. Housos, D. Goto, S. Singh, A. Bartzokas, P. G. Kosmopoulos, Manish Sharma, N. C. Hsu, B. N. Holben, T. Takemura

Mathematics, Physics, and Computer Science Faculty Articles and Research

A synergy of satellite and ground-based radiometric observations, along with chemical transport modeling, was used for the assessment of the influence of drought monsoon conditions of 2002 and prolonged dry pre-monsoon period of 2003 on aerosol properties over south Asia, with emphasis over northern India. Reanalysis data are also examined for studying the dry anomalous period from the climatological mean, that show prevalence of westerlies under anticyclonic circulation and subsidence favoring the accumulation of aerosols. TRMM observations over south Asia indicate significant rainfall deficit over northwestern India in July 2002 and May-June 2003. Subsequently, the anomalous and prolonged dry conditions …

Do Wind Turbines Affect Weather Conditions?: A Case Study In Indiana, Meghan F. Henschen, Brittany Herrholtz, Lacey Rhudy, Kathryn Demchak, Brian Doogs, Joshua Holland, Erik Larson, Johnny Martin, Matthew Rudkin

The Journal of Purdue Undergraduate Research

Wind turbines are becoming increasingly widespread in the United States as the world looks for cleaner sources of energy. Scientists, policymakers, and citizens have strong opinions regarding the positive and negative effects of wind energy projects, and there is a great deal of misinformation about wind energy circulating on the Web and other media sources. The purpose of this study is to gain a better understanding of how the rotation of hundreds of turbines can influence local weather conditions within a wind farm and in the surrounding areas. This experiment measures temperature, atmospheric pressure, wind speed, wind direction, relative humidity, …

Identifying Changes In Climatic Trends And The Fingerprints Of Landuse And Landcover Changes In The High Plains Of The Usa, Denis Mutiibwa

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Human activities such as conversion of natural ecosystem to croplands and urban-centers, deforestation and afforestation impact biophysical properties of land surface such as albedo, energy balance, and surface roughness. Alterations in these properties affect the heat and moisture exchanges between the land surface and atmospheric boundary layer. The objectives of this research were; (i) to quantitatively identify the High plains’ regional climate change in temperatures over the period 1895 to 2006, (ii) detect the signatures of anthropogenic forcing of LULC changes on the regional climate change of the High Plains, and (iii) examine the trends in evolving regional latent heat …

Spatial Patterns Of Drought Triggers And Indicators, Joseph P. Robine

Department of Environmental Studies: Undergraduate Student Theses

Drought is a reoccurring phenomenon with widespread economic, social, and environmental impacts. Unlike other disasters, a drought cannot be easily detected. In addition, droughts are widespread and develop slowly over time making it difficult to detect its onset and monitor its severity and impacts. To assist in monitoring the severity and spatial extent of droughts, drought managers frequently use indicators and triggers. Drought indicators are meteorological or hydrological variables or indices that quantify or describe the level of drought severity. A drought trigger is a value of an indicator that initiates management and response actions. Despite the clear importance of …

Trends Of Wind And Wind Power Over The Coterminous United States, Eric M. Holt

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

The trends of wind and wind power at a typical wind turbine hub height (80 m) are analyzed using the North American Regional Reanalysis (NARR) dataset for 1979-2009. Based upon the wind speeds at NARR’s vertical layers right above and below the 80 m level, the wind speeds at 80 m are estimated using two methods assuming the wind profile respectively as linear and power-law distribution with respect to the altitude in the lower boundary layer. Furthermore, we calculate the following variables at 80 m that are needed for the estimation and interpretation of wind power: the air density, zonal …

Measurement And Interpolation Of Sea Surface Temperature And Salinity In The Tropical Pacific: A 9,000 Nautical Mile Research Odyssey, Amber Brooks

Earth and Soil Sciences

The purpose of this project was to compare spline and inverse distance weighting interpolation tools on data collected in the tropical Pacific Ocean by ship and data from a global network of CTD floats, known as Argo floats (fig.1), to provide evidence that technological advancement and integration is aiding our understanding of the ocean-atmosphere system of planet Earth. Thirty-one sea surface temperature and salinity samples were manually taken across a 9,000 nautical mile trek of the Pacific Ocean for the months of April, May and June 2008. Argo ASCII globally gridded monthly averaged sea surface temperature and salinity data, from …

Effects Of Lightning And Other Meteorological Factors On Fire Activity In The North American Boreal Forest: Implications For Fire Weather Forecasting, David Peterson, Jun Wang, Charles Ichoku, Lorraine Remer

Department of Earth and Atmospheric Sciences: Faculty Publications

The effects of lightning and other meteorological factors on wildfire activity in the North American boreal forest are statistically analyzed during the fire seasons of 2000–2006 through an integration of the following data sets: the MODerate Resolution Imaging Spectroradiometer (MODIS) level 2 fire products, the 3-hourly 32-km gridded meteorological data from North American Regional Reanalysis (NARR), and the lightning data collected by the Canadian Lightning Detection Network (CLDN) and the Alaska Lightning Detection Network (ALDN). Positive anomalies of the 500 hPa geopotential height field, convective available potential energy (CAPE), number of cloud-to-ground lightning strikes, and the number of consecutive dry …

Impacts Of Meteorological Factors On Modis-Observed Fire Activity In The North American Boreal Forest: The Role Of Lightning, David A. Peterson

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

The meteorological impact on wildfire activity in the North American boreal forest during the fire seasons of 2000 – 2006 is statistically analyzed through an integration of the following data sets: the MODerate Resolution Imaging Spectroradiometer (MODIS) level 2 fire products, the 3-hourly 32-km gridded meteorological data from North American Regional Reanalysis (NARR), the instantaneous lightning data collected by the Canadian Lightning Detection Network (CLDN), and the Alaska Lightning Detection Network (ALDN). Positive anomalies of the 500 hpa geopotential height field, convective available potential energy (CAPE), number of cloud-to-ground lightning strikes, and the number of consecutive dry days are found …

Preserving Assets In At-Risk Municipalities: Financial Strategies For Climate Change Adaptation, New England Environmental Finance Center

Climate Change

A large share of America's population, businesses and economic activity now occurs in coastal areas. At the same time, during this century many coastal communities are likely to be severely impacted by sea level rise and increased storm surge and tidal flooding.

“What to do” about this vulnerability is the subject of this brief. It is intended to help municipalities identify courses of action and steps they might take toward increasing their resilience, especially regarding financial resources that will need to be allocated toward the various strategies identified.

Open Ocean Dms Air/Sea Fluxes Over The Eastern South Pacific Ocean, C. A. Marandino, Warren J. De Bruyn, S. D. Miller, E. S. Saltzman

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Air/sea fluxes of dimethylsulfide (DMS) were measured by eddy correlation over the Eastern South Pacific Ocean during January 2006. The cruise track extended from Manzanillo, Mexico, along 110 degrees W, to Punta Arenas, Chile. Bulk air and surface ocean DMS levels were also measured and gas transfer coefficients (k(DMS)) were computed. Air and seawater DMS measurements were made using chemical ionization mass spectrometry (API-CIMS) and a gas/liquid membrane equilibrator. Mean surface seawater DMS concentrations were 3.8 +/- 2.2 nM and atmospheric mixing ratios were 340 +/- 370 ppt. The air/sea flux of DMS was uniformly out of the ocean, with …

A Chemical Ionization Mass Spectrometer For Continuous Underway Shipboard Analysis Of Dimethylsulfide In Near-Surface Seawater, Eric S. Saltzman, Warren J. De Bruyn, M. J. Lawler, Christa Marandino, C. A. Mccormick

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

A compact, low-cost atmospheric pressure, chemical ionization mass spectrometer ('mini-CIMS') has been developed for continuous underway shipboard measurements of dimethylsulfide (DMS) in seawater. The instrument was used to analyze DMS in air equilibrated with flowing seawater across a porous Teflon membrane equilibrator. The equilibrated gas stream was diluted with air containing an isotopically-labeled internal standard. DMS is ionized at atmospheric pressure via proton transfer from water vapor, then declustered, mass filtered via quadrupole mass spectrometry, and detected with an electron multiplier. The instrument described here is based on a low-cost residual gas analyzer (Stanford Research Systems), which has been modified …

Dms Air/Sea Flux And Gas Transfer Coefficients From The North Atlantic Summertime Coccolithophore Bloom, Christa Marandino, Warren J. De Bruyn, Scott Miller, Eric S. Saltzman

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Dimethylsulfide (DMS) atmospheric and oceanic concentrations and eddy covariance air/sea fluxes were measured over the N. Atlantic Ocean during July 2007 from Iceland to Woods Hole, MA, USA. Seawater DMS levels north of 55 degrees N ranged from 3 to 17 nM, with variability related to the satellite-derived distributions of coccoliths and to a lesser extent, chlorophyll. For the most intense bloom region southwest of Iceland, DMS air/sea fluxes were as high as 300 mu mol m(-2) d(-1), larger than current model estimates. The observations imply that gas exchange coefficients in this region are significantly greater than those estimated using …

Eddy Correlation Measurements Of The Air/Sea Flux Of Dimethylsulfide Over The North Pacific Ocean, Christa A. Marandino, Warren J. De Bruyn, Scott D. Miller, Eric S. Saltzman

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Shipboard measurements of air/sea fluxes and sea surface concentrations of dimethylsulfide (DMS) were made over the tropical and midlatitude North Pacific Ocean. Atmospheric pressure chemical ionization mass spectrometry was used to measure DMS levels in ambient air and in air equilibrated with surface seawater drawn from a depth of 5 m. Air/sea fluxes were obtained using eddy covariance. Corrections and uncertainties involved in the calculation of fluxes from shipboard data are discussed. The surface ocean DMS concentrations measured during this study ranged from 1 to 10 nM, and atmospheric mixing ratios ranged from 20 to 1000 ppt. Air/sea fluxes ranged …

Oceanic Uptake And The Global Atmospheric Acetone Budget, Christa Marandino, Warren J. De Bruyn, Scott Miller, M. J. Prather, Eric S. Saltzman

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

In this study, direct measurements of the air/ sea flux of acetone were made over the North Pacific Ocean. The results demonstrate that the net flux of acetone is into, rather than out of the oceans. The extrapolated global ocean uptake of 48 Tg yr(-1) requires a major revision of the atmospheric acetone budget. This result is consistent with a recent reevaluation of acetone photodissociation quantum yields.

Extreme Rainfall In Texas: Patterns And Predictability, John W. Nielsen-Gammon, Fuqing Zhang, Andrew M. Odins, Boksoon Myoung

Mathematics, Physics, and Computer Science Faculty Articles and Research

Extreme rainfall, with storm total precipitation exceeding 500 mm, occurs several times per decade in Texas. According to a compositing analysis, the large-scale weather patterns associated with extreme rainfall events involve a northward deflection of the tropical trade winds into Texas, with deep southerly winds extending into the middle troposphere. One such event, the July 2002 South-Central Texas flood, is examined in detail. This particular event was associated with a stationary upper-level trough over central Texas and northern Mexico that established a steady influx of tropical moisture from the south. While the onset of the event was triggered by destabilization …

Atmospheric Variability Of Methyl Chloride During The Last 300 Years From An Antarctic Ice Core And Firn Air, M. Aydin, Eric S. Saltzman, Warren J. De Bruyn, S. A. Montzka, J. H. Butler, M. Battle

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Measurements of methyl chloride (CH3Cl) in Antarctic polar ice and firn air are used to describe the variability of atmospheric CH3Cl during the past 300 years. Firn air results from South Pole and Siple Dome suggest that the atmospheric abundance of CH3Cl increased by about 10% in the 50 years prior to 1990. Ice core measurements from Siple Dome provide evidence for a cyclic natural variability on the order of 10%, with a period of about 110 years in phase with the 20th century rise inferred from firn air. Thus, the CH3Cl increase measured in firn air may largely be …