Oceanography and Atmospheric Sciences and Meteorology Commons^™

Procedures For Assessment Of The Marine Carbon System And Evaluation Of Access And Ocean Acidification Literacy In The Deaf Community, Loraine Martell-Bonet

USF Tampa Graduate Theses and Dissertations

One major goal of this dissertation addresses the need for improved laboratory procedures to measure chemical changes in seawater caused by the uptake of atmospheric CO2, especially in coastal environments. Due to the proximity of anthropogenic stressors in the coastal zone, the biogeochemical complexity of the CO2 system is more dynamic than the open ocean. My principal research objectives were addressed by developing methods for (1) improving the accuracy of pH measurements over a wide range of salinities and (2) investigating the acid-base properties of natural organics in the coastal ocean.

The accuracy of pH electrode calibrations is affected when …

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford

USF Tampa Graduate Theses and Dissertations

Nickel (Ni) is an important micronutrient for phytoplankton and bacteria that serves as a required co-factor in several metalloenzymes. Despite these known biological uses, total dissolved Ni concentrations remain elevated in global surface waters, in contrast to the surface depletion commonly observed for macronutrients and other nutrient-type trace elements. A prevailing hypothesis for the muted depletion of dissolved Ni concentrations in surface waters is that dissolved Ni in seawater is not in a bioavailable form. The chemical lability of Ni in seawater provides insight into Ni speciation and bioavailability, but few measurements have been made in the open ocean to …

Time-Series Analysis Of Coral Reef And Reef-Fish Biodiversity In The Florida Keys National Marine Sanctuary, Cara L. Estes

USF Tampa Graduate Theses and Dissertations

The general decline in coral-reef ecosystem health throughout the Caribbean between the 1970’s and late 1990’s seems to have slowed down or stopped, with only slight decreases in coral reef cover observed in the 2000’s through 2019. The earlier decline can be attributed to many different local and regional stressors that have acted together, and include naturally occurring (hurricanes, diseases) and anthropogenic pressures (increased sedimentation, fishing). These ecosystems provide a range of services to people, including food and protection from storms, with an annual benefit of billions of dollars. This has driven a desire to better understand these ecosystems. The …

Stable Isotope Analysis On Yellowfin And Blackfin Tuna Eye Lenses Reveals Life History Patterns In The Gulf Of Mexico, Kylee M. Rullo

USF Tampa Graduate Theses and Dissertations

Spatial geography, ontogenetic movement, and trophic patterns of mobile species are key elements of effective marine resource management. A number of methods are currently available for tracking movements of pelagic migratory species, including the use of conventional and electronic tags. However, tagging campaigns can take years to provide useful data, can be expensive, and only capture a portion of a fish’s lifetime. For this project, I used stable-isotopic ratios of nitrogen (δ15N) and carbon (δ13C) in metabolically inert, chronologically-layered fish-eye lenses to explore lifetime movement and trophic patterns of yellowfin tuna (Thunnus albacares) and blackfin tuna (Thunnus atlanticus) in the …

Meta-Analysis Of United States Seabird Populations Based On Ocean Biodiversity Information System (Obis) Records (1965–2018), Savannah Hartman

USF Tampa Graduate Theses and Dissertations

Understanding the distribution of organisms is an important priority for society as we live through ecosystem transformations that threaten the well-being of all organisms. I have approached the dynamic and complex issue of studying biodiversity by using open-access seabird data collected along the Americas since the 1960s. I explained how these data have changed over time and space, how certain species populations could have shifted over time, and possible correlations between this potential geographic change and select environmental variables.

In Chapter 2 I evaluated the suitability of the open-access data archive Ocean Biodiversity Information System (OBIS) for supporting detailed inquiry …

Exploring The Impact Of Eddies On Southern Ocean Biogeochemical Structure Using Bgc-Argo Float Observations, Nicola J. Guisewhite

USF Tampa Graduate Theses and Dissertations

The Southern Ocean plays a crucial role in global ocean circulation, and global heat and nutrient transport. However, this region is both distant and dangerous and is therefore largely under-sampled and understudied. Methods to fill in biogeochemical data-gaps include using limited in-situ data in models to output biogeochemical property estimates, but a number of recent studies have raised concerns about how most Southern Ocean models do not resolve eddies. Eddies are known to impact biogeochemistry around the globe but little is known about their impact in the Southern Ocean. This study examines temperature, salinity, oxygen, nitrate, and dissolved inorganic carbon …

Climate Of A Cave Laboratory Representative For Rock Art Caves In The Vézère Area (South-West France), Delphine Lacanette, Léna Bassel, Fabien Salmon, Jean-Christophe Portais, Bruno Bousquet, Rémy Chapoulie, Faten Ammari, Philippe Malaurent, Catherine Ferrier

International Journal of Speleology

Leye Cave (Dordogne, France) is a laboratory cave in the Vézère area, a region that contains some of the most famous rock art caves in the world such as Lascaux, Font-de-Gaume and Combarelles, and is listed as Human World Heritage by UNESCO. Leye Cave was selected because it is representative of painted caves, with respect to parameters such as its geological stage, the presence of water and carbon dioxide, the geological state of its walls, and the size of the cave. These wall states are studied to better understand the conditions of conservation of rock art caves without damaging them. …

Environmental Chemical Analysis Method Optimization And Application To Northwest Cuban Marine Sediment, Thea R. Bartlett

USF Tampa Graduate Theses and Dissertations

A method for gas chromatography tandem mass spectrometry (GC-MS/MS) in selected reaction monitoring (SRM) mode has been optimized to quantify 250 compounds of a variety of compound classes such as polycyclic aromatic hydrocarbons (PAHs), oxidized PAHs, organochlorinated pesticides, polychlorinated biphenyls, biomarkers (hopanes, steranes, tri-aromatic steroids, and fecal sterols), aliphatic hydrocarbons, and plastic additives. This method was validated based on available QA/QC standards using several environmental samples, both sediment and biota, and standard reference materials. This contaminant-focused method can be used as a forensic geochemistry tool to evaluate oil contamination and other contaminant histories in future research studies. When applied to …

Stable Isotope Analysis Of Doryteuthis (Amerigo) Pealeii Eye Lenses To Determine Migratory Patterns In The Eastern Gulf Of Mexico Using Statoliths For Age Determination, Hannah M. Schwaiger

USF Tampa Graduate Theses and Dissertations

Doryteuthis (Amerigo) pealeii is a common fisheries squid that occurs in the Gulf of Mexico (GoM) and along the east coast of the United States. These squid are an important link in the food web, linking higher and lower trophic positions (Madsen et al., 2007), and they are also used for human consumption. The migration patterns of D. pealeii populations in the northwestern North Atlantic have been thoroughly studied when compared to those in the GoM. This research aims to combine statolith aging and stable isotope analysis to enhance the understanding of D. pealeii migration patterns throughout their short, sub-annual …

Time Series Analysis Of Pseudo-Nitzschia Species Composition, Domoic Acid, And Environmental Conditions In The Gulf Of Maine From 2013-2020, Christina Chadwick

USF Tampa Graduate Theses and Dissertations

Phytoplankton are abundant in both fresh and marine waters and can form harmful algal blooms (HABs) by producing potent toxins that have devastating effects on human, wildlife, and economic health. The HAB-forming diatom genus, Pseudo-nitzschia, occurs globally and approximately half of the 59 currently identified species can produce the neurotoxin, domoic acid (DA). DA accumulates in shellfish and finfish and can cause Amnesic Shellfish Poisoning (ASP) in humans and DA Poisoning (DAP) in several species of wildlife, resulting in severe neurological dysfunction and mortality. Along with these health threats, DA toxicity is a major economic threat for shellfish and fish …

Airflow Dynamics In Wind Cave And Jewel Cave: How Do Barometric Caves Breathe?, Annika K. Gomell, Andreas Pflitsch

International Journal of Speleology

Recent research on air pressure propagation through barometric caves has revealed various speleoclimatological processes, which cause a more complex relationship between surface air pressure changes and resulting pressure gradients between cave and surface air than previously assumed. So far, however, studies on barometric cave airflow have only been based on surface air pressure measurements. Thus, this study investigates and compares airflow at the openings of Wind Cave and Jewel Cave – two major barometric cave systems in South Dakota, USA – as a response to surface air pressure changes and air pressure gradients. Based on high-resolution long-term air pressure measurements …

Inland Tropical Cyclone Intensity Decay In The Continental United States, Yijie Zhu

USF Tampa Graduate Theses and Dissertations

Tropical cyclone (TC) hazard preparation is mostly focused on coastal cities with less attention typically paid to inland regions. The impact of TCs that propagate far inland is often underestimated and can cause unexpected loss of life and economic loss. This dissertation aims to understand the decay process of TCs during the post-landfall stage by answering three main research questions: (1) What are the general patterns of inland tropical cyclones, including spatial variations, decay rates, and translation speeds? (2) Are there temporal changes in the intensity decay from inland moving hurricanes? (3) How is the hurricane post-landfall dissipation related to …

The Effects Of Temperature And Oxygen Availability On Aerobic Performance In Three Coastal Shark Species; Squalus Acanthias, Carcharhinus Limbatus, And Carcharhinus Leucas, Alyssa M. Andres

USF Tampa Graduate Theses and Dissertations

Anthropogenically driven climate changes are altering marine habitats globally. Rising sea surface temperatures and coastal eutrophication, arising from global warming and coastal nutrient loading, have resulted in progressive ocean deoxygenation. This may restrict available habitat of marine organisms as studies suggest that the balance between metabolic oxygen demand and environmental supply plays an important role in limiting viable habitat and species fitness. As ectothermic predators, with temperature-dependent metabolism and high metabolic demands, coastal shark species may be susceptible to shifts in ocean temperature and oxygen. Such environmental changes may alter metabolic performance and ultimately success and survival within shark habitat. …

Ocean Eddies And Frontal Zones In The Gulf Of Mexico And Straits Of Florida, Yingjun Zhang

USF Tampa Graduate Theses and Dissertations

Ocean eddies and fronts in the Gulf of Mexico (GoM) and the Straits of Florida (SoF) play important roles in ocean physics, biology, and ecology. These two ubiquitous physical features have been studied worldwide for decades, yet many questions remain unanswered or poorly studied for the GoM and SoF. This study aims to improve the understanding of ocean eddies and frontal zones in the GoM and SoF using satellite remote sensing, in situ observations and model outputs, as well as state-of-the-art algorithms, with the following objectives: 1) analyze the three-dimensional (3-D) statistical characteristics and thermohaline structure of mesoscale eddies in …

Zooplankton Biodiversity In The Northeast Gulf Of Mexico And On The West Florida Shelf From 2005 - 2014, Megan Ferguson

USF Tampa Graduate Theses and Dissertations

Zooplankton abundance and biodiversity was measured in the northeast Gulf of Mexico (NEGoM) and on the West Florida Shelf. Bongo net samples were collected between May 2005 to September 2009 through the SEAMAP program, and between July 2010 to August 2014 through the C-IMAGE program. Calanoid copepods were the most abundant zooplankton group in most of the samples collected, but ostracods, larvaceans, and chaetognaths were also abundant. Shannon and Inverse Simpson indices were calculated for all zooplankton samples and generally showed similar trends, but only Shannon indices were used for statistical analyses. In the winter and spring there were significant …

Elucidating The Sources Supplying Aerosol Iron, Zinc, And Cadmium To The Surface Of The North Pacific Ocean With Stable Isotopes, Zach B. Bunnell

USF Tampa Graduate Theses and Dissertations

Transition metals, such as iron (Fe), zinc (Zn) and cadmium (Cd), are found at just trace amounts within the global oceans yet are vital for many biological functions of phytoplankton. As a result, these metals influence the ocean’s efficacy for carbon sequestration. Atmospheric dust is the primary input of Fe to various surface waters and may also supply Zn and Cd to oligotrophic surface waters. Here, I present Fe, Zn, and Cd isotope data from the US North Pacific GEOTRACES Section GP15 (Alaska-Tahiti) from the low-dust season (Sept. – Nov. 2018). Using this data and aerosol enrichment factors, I show …

Chronological Accumulation Of Microplastics In The Gulf Of Mexico And Their Acute Effects On Coral Bleaching, Martina M. Plafcan

USF Tampa Graduate Theses and Dissertations

Microplastics have accumulated in the environment since plastic production began. They have spread to all areas of the globe from marine trenches to mountains and they can be harmful to organisms. However, research on microplastics has only recently begun so it is unclear how they have changed over time in many regions of the ocean and how current oceanic concentrations might affect marine life. Additionally, organisms such as corals are under stress and have been declining due to climate change, so it is not yet known if microplastics exacerbate these threats. My thesis addressed these gaps in the literature by …

Determinations Of Chemical Equilibria In Natural Waters Using Spectrophotometric Techniques, Katelyn M. Schockman

USF Tampa Graduate Theses and Dissertations

Accurate characterizations of chemical equilibria and thermodynamic processes in natural waters are key components for assessing the current state of our global climate and predicting future changes, especially for observations of small rates of change over long time scales. One of the most important chemical systems in natural waters is the system of inorganic carbon species comprised of carbon dioxide (CO2), bicarbonate, and carbonate. The bicarbonate dissociation constant, K2, describes the relationship between pH and the relative concentrations of bicarbonate and carbonate ions at thermodynamic equilibrium. The carbonate/bicarbonate equilibrium quotient is required in nearly all CO2 system calculations relevant to …

Modeling Air Pressure Propagation Through Wind Cave And Jewel Cave: How Can Air Pressure Signals Inside Barometric Caves Be Predicted From Surface Pressure Measurements?, Annika K. Gomell, Andreas Pflitsch

International Journal of Speleology

Recent speleoclimatological research has shed new light on air pressure dynamics inside barometric caves by identifying pressure-modifying processes and resulting systematic differences between cave and surface air pressure. Based on these new findings, a multi- step quantitative model is developed and explored to predict air pressure inside Wind Cave and Jewel Cave – two major barometric cave systems in the Black Hills of South Dakota, USA – from external surface measurements. Therefore, each identified speleoclimatological pressure process is translated into a mathematical operation. Model evaluation based on Pearson correlation and mean (absolute) deviation between model outputs and control measurements yields …

Empirical And Modeled Δ13c And Δ15n Isoscapes In The Gulf Of Mexico And Their Application To Fish Eye Lens Migration Studies, Brianna Michaud

USF Tampa Graduate Theses and Dissertations

Isoscapes are depictions of the spatial patterns of isotopic values in a given area. Isoscapes can be created using measurements form samples (empirical isoscapes) or using statistical models of spatial isotopic variation (modeled isoscapes). Isoscapes have a wide variety of potential applications though, in the realm of marine ecology, they are most often used infer ecological processes, food web linkages, the origin of samples, and the movements of marine organisms.

However, to use isoscapes for these applications, it is necessary to have isoscapes at spatial scales relevant to the application in question. It is also necessary to have isoscapes that …

A Physically Constrained Wavelet-Aided Statistical Model (Pcwasm) For Multidecadal Groundwater Dynamics Predictions And Climate Change Evaluation, Fatih Gordu

USF Tampa Graduate Theses and Dissertations

Long-term groundwater management relies on forecasts of decadal or longer groundwater levels driven by nested scales of variability in climate. Discerning the impacts of anthropogenic stressors on groundwater is also critical for establishing predevelopment benchmark groundwater conditions and developing climate change adaptation strategies to reduce risks and increase resiliency. This research demonstrates the development and successful applications of a new methodology to predict and assess multidecadal groundwater dynamics for understanding long-term effects of climate change and groundwater withdrawals.

A Physically Constrained Wavelet-Aided Statistical Model (PCWASM) is first introduced to analyze and predict monthly aquifer levels on multidecadal time scales. The …

Assessing Changes In Actual Air Quality And Public Perceptions Of Air Quality In Kathmandu Valley Nepal Pre And Post Covid-19 Lockdown, Robin Margherita Rives

USF Tampa Graduate Theses and Dissertations

Air pollution is a global concern. Cities around the world fail to meet air quality standards set by the World Health Organization Air Quality Guidelines, which has a significant impact on public health. As the capital city and largest metropolitan region of Nepal, Kathmandu is a hotspot for urban pollution in South Asia. Nepal faces emissions from both internal and external sources. External sources include emissions from Nepal’s neighboring countries of India and China and emissions resulting from tourism. Internal sources of pollution in the country include brick and cement factories, consumption of energy from traditional sources such as biomass, …

Quantitative Assessment Of The Trophic Ecology Of The Oceanic Ctenophore, Bolinopsis Infundibulum, In Monterey Bay, California, Victoria C. Scriven

USF Tampa Graduate Theses and Dissertations

Bolinopsis infundibulum is a wide-ranging, ubiquitous ctenophore whose fragile nature makes the collection of specimens and quantification of key predator-prey activities in controlled laboratory experiments, challenging. Thus, in situ methods often represent the best means for data collection. However, while present in surface waters, these animals can also be abundant at depths well beyond those attainable by divers. As a result, very little empirical data exist over the depth range of their natural habitats which limits our ability to assess key predator-prey interactions needed to assess their ecological role in midwater food webs. Working in Monterey Bay, California, remotely operated …

Anthropocene Fiction: Empathy, Kinship, And The Troubled Waters At The End Of The World, Megan Mandell Stowe

USF Tampa Graduate Theses and Dissertations

Anthropocene literature features characters and environments grappling with the devastation of climate change. Donna Haraway’s term Chthulucene narrows this category further by exposing the tentacular connections between overpopulation, dependence on material goods, species loss, and other facets of global warming—such as water as a resource. Three novels of the Chthulucene exhibit these connections, centering on the importance of water to both ecologies and personal identity. As seen in the novels, place attachment brings ecology and identity together by forging a stewardship between person and location, often resulting in efforts to defend and preserve a place. In Octavia Butler’s Parable of …

Anthropogenic Impacts On The Glowworm Cave, Waitomo, New Zealand: A Microclimate Management Approach, Chris Hendy, David J. Merritt, Shannon Corkill

International Journal of Speleology

Waitomo Glowworm Cave is a highly visited cave where the highlight is viewing the bioluminescence display of a large colony of glowworms. The visitation levels result in the build-up of anthropogenic CO₂, to the extent that it could cause corrosion of speleothems. The cave experiences chimney-effect ventilation with air flowing either upward or downward through the main cave chambers depending on air density differences between the cave and the outside environment. Lack of airflow leads to CO₂ build-up; however, unrestricted airflow can draw in cool, dry air which is harmful to the glowworms. Consequently, airflow is managed …

Low Impact Sampling Of Speleothems – Reconciling Scientific Study With Cave Conservation, Claire L.V. Macgregor, John C. Hellstrom, Jon D. Woodhead, Russell N. Drysdale, Rolan S. Eberhard

International Journal of Speleology

Speleothems are increasingly valued as important paleoclimate archives and yet the removal of samples from caves can come at a cost to natural heritage, impacting delicate environments with limited mechanisms for repair. Conservation of cave environments is a key responsibility for scientists and, with this in mind, we are working to develop and implement techniques that allow us to extract valuable scientific data, with minimal impact. In this study, we demonstrate the utility of low-impact reconnaissance dating surveys on caves in southern Tasmania and southwest Western Australia as a precursor to the removal of stalagmites for paleoclimate reconstruction. Small flakes …

Riverine And Estuarine Co2-System Studies On The West Coast Of Florida, Christopher S. Moore

USF Tampa Graduate Theses and Dissertations

Coastal and estuarine acidification impacts ecosystem health and economic resources and has both natural and anthropogenic components (Cai et al., 2021). Riverine input is one of several important factors that can influence acidification in coastal ecosystems. Rivers disgorging into coastal environments can create strong gradients, both spatial and temporal, that make accurate CO2-system characterization challenging. The work described in this thesis provides a baseline CO2-system study of four major rivers that flow into Tampa bay with an emphasis on seasonal change. As a second objective, this thesis examines the effects of HgII additions on CO2-system measurements in organic-rich estuarine waters. …

Continuous Color Model As A Tool To Improve Speleothem Age Model Development, Celia Campa-Bousoño, Ángel García-Pérez, Ana Moreno, Miguel Iglesias, Hai Cheng, R Lawrence Edwards, Heather Stoll

International Journal of Speleology

Because they can archive a variety of geochemical proxies and be precisely and accurately dated with the U-Th decay series chronometer, stalagmites are widely used for paleoclimate reconstructions. However, limitations in the use of this chronometer arise because U-Th dating is analytically time consuming, expensive, and requires a relatively large sample size. These limitations restrict the number of absolute dates usually obtained, which can result in significant uncertainties in the age model and inhibit the ability to archive high resolution records of environmental variability, particularly in those stalagmites where there are variations in growth rate not constrained by U-Th dates. …

Air Pressure Propagation Through Wind Cave And Jewel Cave: How Do Pressure Waves Travel Through Barometric Caves?, Annika K. Gomell, Daniel C. Austin, Marc J. Ohms, Andreas Pflitsch

International Journal of Speleology

In barometric caves, air pressure gradients between the outside atmosphere and the cave induce strong bidirectional compensating currents, which control almost all elements of speleoclimatology, including air temperature, humidity, and CO₂ dynamics. Therefore, this study set out to investigate air pressure propagation through Wind Cave and Jewel Cave – two major barometric cave systems in the Black Hills of South Dakota, USA. Based on high-resolution air pressure data from both the surface and several measurement sites inside the caves, four systematic changes of pressure waves during their journey through the caves and their related speleoclimatological processes were identified and …

From River To Sea: Improving Carbon System Measurement Methods For Use In Rivers, Estuaries, And Oceans, Ellie Hudson-Heck

USF Tampa Graduate Theses and Dissertations

Over the last 30 years, spectrophotometric methodologies have been developed, with increasing rigor, to accurately measure all four carbon system parameters: total alkalinity (A_T), total carbon (C_T), partial pressure of CO₂ (pCO₂), and pH. Spectrophotometric measurements of carbon system parameters rely on quantitative characterizations of the response of sulfonephthalein indicator dyes (e.g., meta-cresol purple (mCP), thymol blue (TB), and bromocresol purple (BCP)) to changing solution pH, as well the response of indicator physical-chemical characteristics to key environmental variables (salinity (S_P), temperature (T), and pressure). Until recently, the physical-chemical properties …