Oceanography and Atmospheric Sciences and Meteorology Commons^™

Wave-Modified Mean Exothermic Heating In The Mesopause Region, Michael P. Hickey Ph.D., R. L. Walterscheid

Publications

We employ a model of wave-driven OH nightglow fluctuations to calculate the effects of gravity waves on the chemical exothermic heating due to reactions involving odd hydrogen and odd oxygen species in the mesopause region. Using a model based on time means and deviations from those means, it is demonstrated that gravity waves contribute to the time-average exothermic heating. The effect can be significant because the fractional fluctuations in minor species density can be substantially greater than the fractional fluctuation of the major gas density. Our calculations reveal that the waves mitigate the exothermic heating, demonstrating their potential importance in …

Simulations Of The Effects Of Water Vapor, Cloud Liquid Water, And Ice On Amsu Moisture Channel Brightness Temperatures, Bradley M. Muller, Henry E. Fuelberg, Xuwu Xiang

Publications

Radiative transfer simulations are performed to determine how water vapor and nonprecipitating cloud liquid water and ice particles within typical midlatitude atmospheres affect brightness temperatures T-B's of moisture sounding channels used in the Advanced Microwave Sounding Unit (AMSU) and AMSU-like instruments. The purpose is to promote a general understanding of passive top-of-atmosphere T-B's for window frequencies at 23.8, 89.0, and 157.0 GHz, and water vapor frequencies at 176.31, 180.31, and 182.31 GHz by documenting specific examples. This is accomplished through detailed analyses of T-B's for idealized atmospheres, mostly representing temperate conditions over land. Cloud effects are considered in terms of …

Soluble Acidic Species In Air And Snow At Summit, Greenland, Jack E. Dibb, R. Talbot, M H. Bergin

Earth Sciences

Simultaneous measurements of the concentrations of soluble acidic species in the gas, aerosol and snow phases at Summit, Greenland were made during summer 1993. Mean concentrations of gas phase HCOOH, CH₃COOH, and HNO₃ (49±28, 32±17 and 0.9±0.6 nmol m⁻³ STP, respectively) exceeded the concentrations of aerosol-associated HCOO⁻, CH₃COO⁻, and NO₃⁻by 1–3 orders of magnitude. On average, SO₂ concentrations (0.9±0.6 nmol m⁻³ STP) were approximately 1/3 those of aerosol SO₄⁼, but this ratio varied widely due largely to changes in the concentration of …

Ozone Heating And The Destabilization Of Traveling Waves During Summer, Terrence R. Nathan, Eugene Cordero, Long Li

Faculty Publications, Meteorology and Climate Science

The effects of ozone heating on the linear stability of lower stratospheric traveling waves of the summertime, extratropical circulation are examined. Based on coupled equations for the quasigeostrophic potential vorticity and ozone volume mixing ratio, it is shown that the diabatic heating arising from ozone advection can offset the damping due to Newtonian cooling, leading to wave amplification and significant changes in the structure and zonally rectified fluxes of the wave fields in both the lower stratosphere and troposphere. The vertical profile of the zonal mean wind plays a crucial role in determining whether the ozone heating destabilizes eastward and/or …

A Diffuse Reflectance Infrared Fourier Transform Spectroscopic Investigation Of The Oxidation Of Co On Platinum/Tin(Iv) Oxide-Based Catalysts, Julie Christi Stiltner Patrick

Chemistry & Biochemistry Theses & Dissertations

Platinum/tin(IV) oxide-based catalysts have been developed for the oxidation of carbon monoxide at 55 °C and 1 atmosphere pressure. A diffuse reflectance infrared fourier transform spectroscopic (DRIFTS) investigation of this oxidation has been performed. Four catalyst samples have been subjected to a 5% carbon monoxide pretreatment at 125 °C, helium exposure at 55 °C, bottled air (20% oxygen) exposure at 55 °c, and exposure to a 2:1 stoichiometric mixture of carbon monoxide and oxygen at 55 °C. During the course of these exposures, evidence for the development of two different surface carbon monoxide configurations has been found: one that is …

Estimation Of Stratospheric Input To The Arctic Troposphere: 7be And 10be In Aerosols At Alert, Canada, Jack E. Dibb, David Meeker, R C. Finkel, J Southon, Marc W. Caffee, Leonard A. Barrie

Earth Sciences

Concentrations of 7Be and 210Pb in 2 years of weekly high-volume aerosol samples collected at Alert, Northwest Territories, Canada, showed pronounced seasonal variations. We observed a broad winter peak in 210Pb concentration and a spring peak in 7Be. These peaks were similar in magnitude and duration to previously reported results for a number of stations in the Arctic Basin. Beryllium 10 concentrations (determined only during the first year of this study) were well correlated with those of 7Be; the atom ratio 10Be/7Be was nearly constant at 2.2 throughout the year. This relatively high value of 10Be/7Be indicates that the stratosphere …

New Sources For The Hot Oxygen Geocorona, P. G. Richards, Michael P. Hickey Ph.D., D. G. Torr

Publications

This paper investigates new sources of thermospheric non thermal (hot) oxygen due to exothermic reactions involving numerous minor (ion and neutral) and metastable species. Numerical calculations are performed for low latitude, daytime, winter conditions, with moderately high solar activity and low magnetic activity. Under these conditions we find that the quenching of metastable species are a significant source of hot oxygen, with kinetic energy production rates a factor of ten higher than those due to previously considered O2+ and NO+ dissociative recombination reactions. Some of the most significant new sources of hot oxygen are reactions involving quenching of O+(²D), O(¹D), …

Comparison Of Theories For Gravity Wave Induced Fluctuations In Airglow Emissions, R. L. Walterscheid, G. Schubert, Michael P. Hickey Ph.D.

Publications

A comparison is undertaken of theories for the gravity wave induced fluctuations in the intensity of airglow emissions and the associated temperature of the source region. The comparison is made in terms of Krassovsky's ratio ηE for a vertically extended emission region (ηE is the ratio of the vertically integrated normalized intensity perturbation to the vertically integrated normalized intensity-weighted temperature perturbation). It is shown that the formulas for ηE in the works by Tarasick and Hines (1990) and Schubert et al. (1991) are in agreement for the case of an inviscid atmosphere. The calculation of ηE using the theory of …

Sulfate And Msa In The Air And Snow On The Greenland Ice Sheet, J L. Jaffrezo, C Davidson, M Legrand, Jack E. Dibb

Earth Sciences

Sulfate and methanesulfonic acid (MSA) concentrations in aerosol, surface snow, and snowpit samples have been measured at two sites on the Greenland Ice Sheet. Seasonal variations of the concentrations observed for these chemical species in the atmosphere are reproduced in the surface snow and preserved in the snowpit sequence. The amplitude of the variations over a year are smaller in the snow than in the air, but the ratios of the concentrations are comparable. The seasonal variations for sulfate are different at the altitude of the Ice Sheet compared to those observed at sea level, with low concentrations in winter …

137cs Gamma-Ray Detection At Summit, Greenland, P. P. Dunphy, Jack E. Dibb

Earth Sciences

Global fall-out from atmospheric testing of thermonuclear weapons produced horizon markers corresponding to the initiation of testing in 1953 and the maximum fall-out in 1963. The radioactive isotope 137Cs associated with these events has a half-life of 30.2 years. Therefore, with the appropriate radiation detectors, this fall-out can be used as a long-term temporal indicator in glaciers and snowpack. A prototype γ-ray detector system was successfully tested and was used to make in-situ measurements of the 137Cs marker in a borehole at Summit, Greenland. The system consisted of a 7.6 cm by 7.6 cm NaI (Tl) scintillation crystal/photomultiplier detector, commercial …

An Ice-Core-Based Record Of Biomass Burning In The Arctic And Subarctic, 1750-1980, Sallie I. Whitlow, Paul A. Mayewski, Jack E. Dibb, Mark S. Twickler, G Holdsworth

Earth Sciences

No abstract provided.

Invariant Manifolds Of A Toy Climate Model, Michael Toner

Mathematics & Statistics Theses & Dissertations

According to astronomical theory, ice ages are caused by variations in the Earth's orbit. However, ice core data shows strong fluctuations in ice volume at a low frequency not significantly present in orbital variations. To understand how this might occur, the dynamics of a two dimensional nonlinear differential equation representing glacier/temperature interaction of an idealized climate was studied. Self sustained oscillation of the autonomous equation was used to model the internal mechanisms that could produce these fluctuations. Periodic parametric modulation of a damped internal oscillation was used to model periodic climate response at double the external modulation period. Both phenomena …

Periodic And Homoclinic Orbits In A Toy Climate Model, M. Toner, A. D. Kirwan Jr.

Mathematics & Statistics Faculty Publications

A two dimensional system of autonomous nonlinear ordinary differential equations models glacier growth and temperature changes on an idealized planet. We apply standard perturbative techniques from dynamical systems theory to study small amplitude periodic orbits about a constant equilibrium. The equations are put in cononical form and the local phase space topology is examined. Maximum and minimum periods of oscillation are obtained and related to the radius of the orbit. An adjacent equilibrium is shown to have saddle character and the inflowing and outflowing manifolds of this saddle are studied using numerical integration. The inflowing manifolds show the region of …

Air Pollution Transport Modeling, David M. Paal

Theses and Dissertations

This research effort addresses modeling of the transportation of air pollution in the atmosphere and the numerical analysis of the partial differential equations used in such modeling. Three Gaussian models are examined and compared using example problems. Several finite difference schemes are developed to solve the partial differential equations used in air pollution transport modeling. This study examines three Gaussian models SCREEN, AFTOX, and the program GAUSPLUM. The model GAUSPLUM is developed in this study and uses the Ada programming language and the analytic solution to the advection- diffusion equation. Numerical analysis of the partial differential equations PDE used in …

Shock Wave Interaction With L-Shaped Structures, Richard C. Miller

Theses and Dissertations

This study investigated the interaction of shock waves with L-shaped structures using the CTH hydrodynamics code developed by Sandia National Laboratories. Computer models of shock waves traveling through air were developed using techniques similar to shock tube experiments. Models of L-shaped buildings were used to determine overpressures achieved by the reflecting shock versus angle of incidence of the shock front. An L-shaped building model rotated 45 degrees to the planar shock front produced the highest reflected overpressure of 9.73 atmospheres in the corner joining the two wings, a value 9.5 times the incident overpressure of 1.02 atmospheres. The same L-shaped …

Performance Impacts For Actuator Misalignments And Failures In Large- Aperture Adaptive-Optic Telescopes, Timothy D. Hogan

Theses and Dissertations

Large-aperture telescopes require adaptive optics in order to compensate for atmospheric turbulence which would otherwise negate the resolution advantages of using large apertures. This investigation analyzes the impacts of misalignments and failures, in the deformable mirror actuators, upon the performance of such systems. A numerical simulation of a standard adaptive optics system is used to generate characteristic optical transfer function OTF and signal-to-noise ratio SNR performance metrics. The performance impacts of the misalignments are shown to be dependent upon the Fried parameter effective telescope diameter, the source object brightness, and the control system time delay. The degree of performance degradation …

A Comparison Of No And N20 Production By The Autophic Nitrifier Nitrosomonas Europaea And The Heterotrophic Nitrifier Alcaligenes Faecalis, Iris C. Anderson, Mark Poth, Julie Homstead, David J. Burdige

OES Faculty Publications

Soil microorganisms are important sources of the nitrogen trace gases NO and N₂O for the atmosphere. Present evidence suggests that autotrophic nitrifiers such as Nitrosomonas europaea are the primary producers of NO and N₂O in aerobic soils, whereas denitrifiers such as Pseudomonas spp. or Alcaligenes spp. are responsible for most of the NO and N₂O emissions from anaerobic soils. It has been shown that Alcaligenes faecalis, a bacterium common in both soil and water, is capable of concomitant heterotrophic nitrification and denitrification. This study was undertaken to determine whether heterotrophic nitrification might be …

Gravity Wave-Driven Fluctuations In The O2 Atmospheric (0-1) Nightglow From An Extended, Dissipative Emission Region, Michael P. Hickey Ph.D., G. Schubert, R. L. Walterscheid

Publications

The wave-driven fluctuations in the O2(0-1) atmospheric nightglow is modeled and the parameter (eta) is calculated using a model that accounts for either three-body recombination of atomic oxygen atoms alone to form the O2(b exp 1 Sigma(g)(+)) state directly, or by the further inclusion of the process that allows the formation of the O2(c exp 1 Sigma(u)(-)) intermediate state. The calculations are performed for a latitude of 18 deg N and for the months of March and June. The general results, which display how (eta) varies with wave period, horizontal wavelength, season, and chemical scheme, show that for given values …

An Alternative Representation Of The Ice Canopy For Calculating Microwave Brightness Temperatures Over A Thunderstorm, Bradley M. Muller, Henry E. Fuelberg, Eric A. Smith

Publications

Passive microwave brightness temperatures (T(B)'s) at 92 and 183 GHz from an aircraft thunderstorm overflight are compared with values calculated from radar-derived hydrometeor profiles and a modified proximity sounding. Two methods for modeling particles in the ice canopy are contrasted. The first is a ''traditional'' approach employing Marshall-Palmer ice spheres. The second, or ''alternative,'' method partitions 20% of the ice water content into a Marshall-Palmer component for graupel and hail, and 80% into a modified gamma spherical particle size distribution function representing ice crystals.

Results from the alternative approach are superior to those from the traditional method in the anvil …

Characterization Of Laboratory Generated Turbulence By Optical Phase Measurements, Eric P. Magee

Theses and Dissertations

The resolution achieved by an optical imaging system in the presence of the random effects of the atmosphere is severely degraded from the theoretical diffraction limit. Techniques exist for recovering near diffraction limited performance of an imaging system in the presence of atmospheric turbulence. As opposed to laboratory testing, testing image enhancement techniques in the Earth's atmosphere imposes many limitations. Unfavorable weather conditions could result in the loss of time and money invested in conducting the experiments. With a properly characterized turbulence generator, with statistics that match those of the atmosphere, experimental testing of image enhancement techniques can be conducted …

Heat Storage And Transport Processes In The Tropical Atlantic Ocean, Andras Kapolnai

OES Theses and Dissertations

Heat storage and transport processes of the tropical Atlantic play an important role in the climate of three continents. The exploration of how the warm water mass maintenance in the equatorial basin depends on various external factors is therefore an important task. This study examines the annual cycle of the warm water mass formation and its transport in the equatorial Atlantic through the interaction of the atmospheric and oceanic boundary layers. Key features of the model are the sea level wind field, equatorial upwelling rate and escape transport of the formed warm water out of the equatorial basin.

The model …

Global Snow Cover Monitoring: An Update, David A. Robinson, Kenneth F. Dewey, Richard R. Heim Jr.

United States Department of Commerce: Staff Publications

Accurate monitoring of the large-scale dimensions of global snow cover is essential for understanding details of climate dynamics and climate change. Presently, such information is gathered individually from ground station networks and satellite platforms. Efforts are in progress to consolidate and analyze long-term station records from a number of countries. To gain truly global coverage, however, satellite-based monitoring techniques must be employed. A 27-year record of Northern Hemisphere continental snow cover produced by the United States National Oceanic and Atmospheric Administration (NOAA) is the longest such environmental record available. Records of Southern Hemisphere continental cover and snow on top of …

A Comparison Of Gulf Stream Sea Surface Height Fields Derived From Geosat Altimeter Data And Those Derived From Sea Surface Temperature Data, Tal Ezer, George L. Mellor, Dong-Shan Ko, Ziv Sirkes

CCPO Publications

Two types of satellite data, Geosat altimeter data and sea surface temperature data (SST), are compared and evaluated for their usefulness in assimilation into a numerical model of the Gulf Stream region. Synoptic sea surface height (SSH) fields are derived from the SST data in the following way: first three-dimensional temperature and salinity analysis fields are obtained through the Optimum Thermal Interpolation System (OTIS), and then SSH fields are calculated using a primitive equation, free-surface, numerical model running in a diagnostic mode. The aforementioned SSH fields are compared with SSH fields obtained from the Geosat altimeter data. Use of Geosat …

Beryllium 7 And Lead 210 In The Western Hemisphere Arctic Atmosphere: Observations From Three Recent Aircraft-Based Sampling Programs, Jack E. Dibb, R. Talbot, G L. Gregory

Earth Sciences

Concentrations of the natural radionuclides ⁷Be and ²¹⁰Pb were determined in aerosol samples collected in the western hemisphere Arctic during the recent NOAA Arctic Gas and Aerosol Sampling Program (AGASP 3) and NASA Global Tropospheric Experiment/Arctic Boundary Layer Expeditions (GTE/ABLE 3A and ABLE 3B) missions. Beryllium 7 showed a free tropospheric concentration maximum between 4 and 5 km in the summer of 1990. Previous ⁷Be data obtained in the late 1950s and early 1960s also indicated a similar vertical distribution of ⁷Be near 70°N. Injection of stratospheric air through tropopause folds associated with the Arctic jet …

Seasonal And Latitudinal Variations Of Gravity Wave-Driven Fluctuations In Oh Nightglow, Michael P. Hickey Ph.D., R. L. Walterscheid, G. Schubert

Publications

The seasonal and latitudinal variations of the gravity wave-driven fluctuations in the OH nightglow are investigated theoretically using a model that accounts for emission from an extended OH layer and includes the effects of eddy diffusivities in the gravity wave dynamics. The mean (unperturbed) state is obtained from a two-dimensional, nighttime model so that mean-state number densities, temperatures and eddy diffusivities are all self-consistent. Seasonal and latitudinal variations in the background OH nightglow emission and in the propagation and dissipation characteristics of the gravity waves influence how the OH nightglow modulations due to gravity waves depend on season and latitude. …

The Accumulation Of 210pb At Summit, Greenland Since 1855, Jack E. Dibb

Earth Sciences

The decay corrected activity of 210Pb at the time of deposition shows considerable short term variability, but no clear seasonal or annual periodicity. 210Pb activity in surface snow at this site has averaged 0.7 pCi kg-1 since 1927, but the period 1915-1927 is characterized by a steady decline from higher levels. The average annual accumulation of 210Pb has markedly declined since at least 1870. Similar observation at Dye 3 suggest that 210Pb accumulation has decreased throughout this century over much of the Greenland Ice Sheet. If the records of 210Pb in the firn of the Greenland Ice Sheet are mainly …

¿Sirve El Ozono Para Combatir El Cólera?, Aldemaro Romero Jr.

Publications and Research

No abstract provided.

Gravity Wave-Driven Fluctuations In Oh Nightglow From An Extended, Dissipative Emission Region, G. Schubert, R. L. Walterscheid, Michael P. Hickey Ph.D.

Publications

The theory of gravity wave-driven fluctuations in the OH nightglow from an extended source region is generalized to account for effects of eddy kinematic viscosity ν and eddy thermal diffusivity κ. In the nondiffusive case, the amplitudes and phases of vertically integrated normalized intensity 〈δI〉/〈Ī〉 and temperature 〈δTI〉/〈ĪI〉perturbations and vertically integrated Krassovsky's ratio 〈η〉 as functions of period are influenced by the upper limit of vertical integration of the extended source, especially at long periods when vertical wavelengths λᵥ are small. The effects, which include oscillations in 〈δT〉/〈Ī〉 , and 〈η〉, particularly at long …

Analytical Modeling And Simulation For Investigation Of A Digital Gas Filter Correlation Radiometer, Catherine P. Mcgowan

Electrical & Computer Engineering Theses & Dissertations

This thesis investigates a digital gas filter correlation radiometer called the Tropospheric Radiometer for Atmospheric Chemistry and Environmental Research (TRACER), which will be used to remotely measure carbon monoxide at three levels in the troposphere. The nadir-viewing radiometer measures the differential absorption of radiation through the atmosphere at 4.67@m and 2.33pm wavelengths. This thesis develops an analytical model of the TRACER measurement process to evaluate the effect of varying certain system parameters on the measurement. The independent sampling criterion and the response of linear systems to random signals are explained. A parametric simulation model is also developed to evaluate the …

Modifications To Mcnp, Version 3b: Incorporating A Variable Density Atmosphere. Addendum, David L. Monti, Kirk A. Mathews

AFIT Documents

MCNP version 3B was modified to incorporate a continuously variable density atmosphere. This was accomplished by representing the variation of air density as a function of altitude with a series of continuous piecewise exponential curves up to a maximum altitude of 1000 km. User-written subroutines and functions were written which incorporated these piecewise functions. These subroutines and functions were subsequently incorporated into a production version of MCNP. Several MCNP subroutines and files were modified in support of these modifications. This report discusses detailed information regarding the theoretical development of the variable density model, the user written subroutines and functions, the …