Sustainability Commons^™

Thermal And Mechanical Activation Of Estonian Oil Shale Cfbc And Hydrated Legacy Fly Ash As An Alternative Binder System For Opc Replacement, Peeter Paaver

World of Coal Ash Proceedings

This study investigates high volume of Ordinary Portland Cement (OPC) substitution with fly ash based calcium sulfoaluminate binder. The utilization of circulating fluidized bed combustion (CFBC) boilers imposes limitations on the recycling of fly ash due to its lower combustion temperature inhibiting the formation of reactive calcium silicate minerals resulting in diminished pozzolanic properties of the ash paste. Our previous research (Paaver et al., 2020, 2022) has demonstrated that the mechanical activation of sulfur and calcium-rich Estonian oil shale CFBC fly ash produces calcium sulfoaluminate (CSA) type active binder allowing high-volume OPC replacement of up to 50%, with a reduction …

Benefits Of Containerized Water Treatment Systems For Coal-Fired Power Plants, Andrew Vincent

World of Coal Ash Proceedings

Containerized systems deliver many of the same functional benefits as housing treatment equipment in permanent buildings, while significantly reducing engineering, construction, and installation costs. By containerizing a water treatment system, a substantial portion of fabrication, assembly, and testing can be completed in a controlled shop environment rather than in the field. This approach greatly reduces on-site labor requirements, mobilization duration, and overall installation complexity. Once delivered to site, containerized systems can be used as permanent installations. Alternatively, they offer the flexibility to be relocated within a plant or transferred between different sites as operational needs change. Multiple containerized systems can …

Rare Earth Element Distribution And Mineral Host In Coal Derived Ash From South African Power Stations, Sanki Biswas, Nicola Wagner, Oftense Moroeng

World of Coal Ash Proceedings

The global shift toward low-carbon energy systems, electric mobility, and digital technologies has sharply increased the demand for critical minerals, including rare earth elements (REY) vital for permanent magnets, batteries, wind turbines, photovoltaic cells, semiconductors, and modern defence applications. Coal by-products—particularly coal fly ash (CFA) and coal bottom ash (CBA)—are emerging as promising secondary sources of REY, but their economic viability depends on effective enrichment and extraction methods. South Africa’s coal-fired power plants generate nearly thirty million tonnes of coal-ash each year. This study investigates REY concentrations in CFA and CBA collected from five major power stations (PS-1 to PS-5) …

Lessons Learned From Managing Ash Pond Closure Waters, Danny Stephens, Tom Geeza, Phil Benson, Ashwin Ranna

World of Coal Ash Proceedings

The water management issues created by ash pond closure are complex and can create technology selection and operational management challenges. Ash dewatering activities produce highly variable effluents, depending on ash composition, aging, and dewatering and stormwater management techniques. Effluent limitations can also be highly variable, depending upon the size of the receiving body and the anticipated composition of the effluent stream. The user often faces competing risks: installing an unnecessarily complex and expensive treatment plant, being limited on closure activities by limitations in water treatment capabilities, or both. This paper presents several lessons learned from assessing ash closure water management …

Epri Ccp Beneficiation Research Update, Benjamin Gallagher, Patrick Webb

World of Coal Ash Proceedings

Coal combustion products (CCPs) are frequently utilized as supplementary materials in cement and concrete manufacturing. With an estimated 2 billion metric tons stored in repositories across the United States, interest in beneficial use has expanded beyond class F fly ash to include ponded and high-LOI ash. Beneficiation provides a critical pathway for managing CCP repositories, particularly under closure-by-removal strategies, and where ash sources have historically been difficult to process. Research conducted at EPRI’s Ash Beneficial Use Center (ABUC) examines the feasibility of processing these ash types into usable products and offers insights into repository variability and classification. Furthermore, the study …

Risk Evaluation Of Small Coal Combustion Residual Management Unit (Ccrmu) Fills, Andrew Bittner, John Kondziolka, Qian Zhang, Masoud Arshadi

World of Coal Ash Proceedings

US EPA expanded the scope of CCR regulations in 2024 to areas of historical CCR placement not regulated under the 2015 CCR rule, including CCR used as fill. US EPA presented new risk analyses specific to CCRMU fills and defined different regulations for CCRMU fills from 1 to 1,000 tons, noting uncertainty as to whether there was a size of CCRMU fill below which acceptable risks could be expected. This research fills US EPA's stated data gap by modeling and analyzing impacts from small CCRMU fills. Modeling was conducted using the same methods, models, and most of the same inputs …

Investigating The Performance Of Processed Stockpile Fly Ash For Low Carbon Concrete, Michael Mccarthy, Arfas Habeeb, Laszlo Csetenyi, Roderick Jones

World of Coal Ash Proceedings

Reducing embodied carbon in concrete has increasingly focused on clinker substitution through the use of supplementary cementitious materials (SCMs). However, the local availability of fly ash, a widely used SCM in the UK, offering benefits in this role, has reduced over the past decade, as coal-fired electricity generating plants have gradually been taken out of service. Attention has, therefore, increasingly focused on fly ash from stockpile and landfill sites to maintain supply, i.e., material not used following production and put into storage. Most UK fly ash originated from the burning of bituminous coal, producing low-lime siliceous material, which although undergoing …

Solar Solution For Closed Ccr Units And Adjacent Land, Chris Fairey

World of Coal Ash Proceedings

Solar Solution for Closed CCR Units and Adjacent Land Chris Fairey1, Kenny Hughes1 1Watershed Geo, 1125 Sanctuary Pkwy, Suite 180, Alpharetta, GA 30009 KEYWORDS: Solar, Racking, Brownfield, Greenfield, Slopes, PowerCap® ABSTRACT With the reduction in coal fired power generation, there is a consistent trend in the industry to supplement generation with solar power. The property located within and surrounding these decommissioned power plants offers a significant opportunity to create a renewable solar power asset. The PowerCap® Nail to Rail System, developed by Watershed Geo, is an advanced solar racking solution designed for sites that do not require environmental closure such …

Abundances Of Elements In Global Coals, Shifeng Dai

World of Coal Ash Proceedings

The abundance of elements in coal is important not only because it provides a solid scientific and practical foundation for various geochemical comparisons, but also because it helps address broader questions in Earth Sciences. In this study, data on major and trace elements in global coals comprising hundreds of thousands of coal samples were compiled from peer-reviewed journal articles, books, various databases, dissertations, and technical reports. These data formed the basis for estimating element abundances in global coals presented in this study. All collected data were rigorously screened for reliability, and any records with questionable quality were excluded from the …

Consolidation Modeling To Support Closure Planning Of An Upstream Raise Ccr Surface Impoundment Containing Fgd Material, Tanya Walkenbach, Craig Schuettpelz, Todd Stong, Shane Stockdill

World of Coal Ash Proceedings

Rainbow Energy Center’s (REC’s) Coal Creek Station has managed calcium sulfite flue gas desulfurization (FGD) material in composite-lined upstream raise surface impoundments since 2001. The upstream raise surface impoundment utilizes bottom ash (drainage zone) and fly ash (structural zone) produced at Coal Creek Station to contain the FGD placement. FGD material was hydraulically sluiced to the center of the 110-acre Upstream Raise 92 (UR92) coal combustion residual (CCR) unit between 2001 and 2021. The FGD was deposited to a maximum thickness of approximately 100 feet in the center of the unit. Significant consolidation of FGD material occurred with subsequent FGD …

Investigation Of A Historical Coal Combustion Residuals Management Unit (Ccrmu), Todd Stong, Shane Stockdill, Erin Hunter

World of Coal Ash Proceedings

Rainbow Energy Center’s (REC’s) Coal Creek Station has managed coal combustion residuals (CCR) in various engineered impoundments and landfills since plant operation began in 1978. Since then, waste containment methods have evolved resulting in significant changes to their CCR management practice. In the late 1980s and early 1990s REC closed several existing CCR units with natural soil liners and constructed several new CCR units with composite liner systems. One of the closed units was an area now referred to as North Section 16, an impoundment that received CCR including bottom ash, fly ash, and flue gas desulfurization material. North Section …

Transportation Logistics Panel, John Ward, Andrew Vollmer, Tracy Zea, Marci Jenks

World of Coal Ash Proceedings

As the industry shifts from freshly generated ash to harvested materials and advanced utilization, logistics is becoming one of the primary drivers of project success or failure. This moderated panel will explore how sourcing, transportation, and storage realities are changing — and what project teams most often underestimate when working with harvested coal ash. Panelists will discuss what breaks, what becomes more complex, and how logistics considerations are reshaping planning and development.

Optimization Of Remedial Strategies For Ccr Site Corrective Action Through Advanced Geochemical Modeling, Cole Mayer, Pj Nolan

World of Coal Ash Proceedings

The power industry is actively designing and implementing corrective measures for Coal Combustion Residuals (CCR). In many cases, these measures include active remedies such as pump and treat, in-situ injection, or reactive barriers, all of which demand a thorough understanding of the underlying geochemical system. Depending on the geochemical characteristics of an aquifer, different chemical reagents can achieve varying degrees of success or even be detrimental to the remediation of the site. Advanced geochemical modeling is an invaluable tool for developing a remedy that is optimized to the site-specific geological, hydrological, and geochemical environment. In the case study presented here, …

Application Of Stable Isotopes In An Alternative Source Demonstration, Alison O'Connor

World of Coal Ash Proceedings

Stable isotope analysis is commonly used in age dating, provenance studies and to differentiate between sources of groundwater. Multiple studies have shown that strontium and boron isotopic ratios can be successfully used in identifying CCR impacts to groundwater. This talk presents an applied case study using boron and strontium isotopes in conjunction with additional geochemical approaches in an alternative source demonstration. Boron and strontium isotopes were measured in both groundwater and CCR leachate over sampling events from 2019 to 2025. The data revealed that strontium and boron isotopic signatures in groundwater near the CCR unit differed significantly from both site-specific …

Distinguishing Ccp From Nuclear Impacts In Groundwater, Lea Millet

World of Coal Ash Proceedings

As the energy transition from fossil fuels to other generation technologies continues, many companies worldwide are evaluating the feasibility of constructing nuclear power plants at sites previously used for coal-powered generation. Thermal power plant sites offer advantages for siting nuclear generation such as proximity to cooling water and grid connections; however existing impacts to groundwater from coal combustion product (CCP) management units may confound monitoring programs designed to detect impacts from nuclear operations. For example, boron and lithium may be present in waters associated with CCP management and nuclear power plant operations, and potassium that often has concentrations above background …

Ccr Landfill Closure Challenges, Solutions And Innovation, Jay Mokotoff, Drew Browning, Steve Applegate

World of Coal Ash Proceedings

CCR landfills can present unique design and construction challenges for the industry when closing these units at the end of their life. In comparison to CCR surface impoundments, CCR landfills typically have greater flexibility under the CCR Rule for operations and beneficial use purposes and may not have defined closure dates which results in some of these closures extending further into the future. However, as coal burning plants continue to shudder, the closure of these landfills is rapidly approaching. This presentation will focus on the challenging site conditions, site specific considerations and potential solutions when designing and constructing the landfill …

Engineering Granulometry To Optimize Performance Of Reclaimed Ash, Russell Hill

World of Coal Ash Proceedings

As utility production of fresh fly ash declines, the concrete industry is turning to reclaimed and beneficiated materials to maintain reliable SCM supply. This transition creates an opportunity not only to secure volumes but to engineer improved performance. The ReCinis™ beneficiation process enables this by providing controls that tune particle-size distribution (PSD), sphericity, packing behavior, surface area, and surface activation. Processing trials show that blends combining fine ground fractions with spherical, broad-graded hydrocyclone overflow (OF) materials can balance high reactivity with favorable rheology. Mechanochemical activation during grinding appears to increase reactivity beyond what surface-area metrics alone predict, likely through removal …

Alternative Cover Permitting And The Ccr Rule, Evan Andrews, Victor Damasceno

World of Coal Ash Proceedings

Federal rules (40 CFR Parts 9, 257 and 261) that regulate coal combustion residuals (CCR) created a significant demand associated with closure of coal ash management and storage facilities using liner systems. Timelines associated with these facility closures combined with substantial project scale and potential for future mining /reuse has driven the need for closure systems that perform beyond the prescriptive soil / geomembrane caps outlined in the federal regulations. As outlined in section 257.102 (d)(3)(i) of the CCR Rule, the standard cover system must include an infiltration layer of at least 18 inches of earthen material and an erosion …

Sustainability And Waste Diversion At Tva Shawnee "Project Phoenix", Bryan Jacob, Shane Harris

World of Coal Ash Proceedings

An engineered turf closure system can serve as an ideal foundation for a solar energy system to be installed atop coal combustion residual (CCR) impoundments. This approach not only enables productive power generation during the post-closure period, it also preserves opportunities for recovery and beneficial use of CCR material in the future. “Project Phoenix” at TVA’s Shawnee Fossil Plant offers an illustrative example. This paper will cover the sustainability benefits of the companion ClosureTurf® and PowerCap® systems installed at that site as well as waste diversion activities undertaken during construction to recycle as much as practical and minimize waste destined …

Demystifying Large Language Models: How Ai Is Transforming Data, Compliance, And Decision-Making In Coal Ash And Environmental Management, Scott Pfeiffer

World of Coal Ash Proceedings

The environmental and coal combustion residuals (CCR) industries generate vast amounts of information—from groundwater monitoring reports and RCRA documentation to closure plans and analytical data. Managing, interpreting, and communicating this information is a growing challenge for utilities, regulators, and consultants alike. Large Language Models (LLMs), such as OpenAI’s GPT architecture, represent a breakthrough in how organizations can interact with their technical data. These models use deep neural networks trained on billions of words to understand, summarize, and generate language with human-like accuracy. When securely adapted for enterprise use, LLMs can automate routine reporting, extract data from technical documents, generate regulatory …

Expert Perspectives On The U.S. Coal Combustion Products Market – Now, Then, And The Future, Mark Rokoff, David Cox, Walter Lemaire, John Ward

World of Coal Ash Proceedings

This panel discussion will explore the continued evolution of the U.S. coal combustion products market, with a focus on the impacts of dynamic regulatory and market forces. Invited expert panelists will share perspectives on developments over the past several years (building on discussions from WOCA 2022 and WOCA 2024), current conditions, and expected future trends—particularly those likely to shape the market between 2026 and 2030. The discussion will address the interrelated markets for engineering, construction, and beneficiation of ash from both operating and inactive plants. Panelists will offer perspectives relevant to the full coal ash industry, from owner/operator organizations to …

Subsurface Delineation Of Coal Combustion Residuals Using Multiple Geophysical Methods, Eric Hageman, Adam Rak, Thomas Jordan, Kate Mckinley

World of Coal Ash Proceedings

Geophysical techniques provide alternative methods of Coal Combustion Residual (CCR) delineation and characterization to supplement more invasive boring programs used for beneficial reuse planning. A demonstration project was designed to characterize the electromagnetic and seismic stratigraphy of CCR material and test the effectiveness of three geophysical techniques: Electrical Resistivity Imaging (ERI), Transient Electromagnetic (TEM) induction, and Multi-channel Analysis of Surface Wave (MASW). The demonstration project was completed at a dry-stack CCR unit containing a variety of CCR ash, gypsum, and thin layers of drainage aggregate (limestone). During a single-day deployment, several geophysical survey tests were conducted in specific areas of …

Sustainability In The Fashion Industry: Environmental Effects & Analyzing Innovative Approaches To Reducing Environmental Impact While Maintaining Profitability And Effectiveness, Haley Castillo Rebollar

Senior Honors Theses

The fast-fashion business model has several severe environmental impacts, including resource overconsumption, chemical pollution, greenhouse gas emissions, and solid waste consumption. Hence, the sustainable fashion alternative is questioned as to whether it can be applied with recoverable economic value and limited consequential impact when considering novel approaches in business model innovation, supply chain transformation, and the adoption of digital technologies. Evidence suggests that sustainability and profitability need not be mutually exclusive when strategic intervening actions are effectively managed. The set of principles of the circular economy, sustainable enterprise architecture frameworks, green supply chain management, advanced systems of forecasting, and three-dimensional …

The Cobalt Curse: Cobalt’S Role And Risks, Marley Jackowitz

Student Theses 2015-Present

This paper examines the hidden environmental, geopolitical, economic, and social costs of the cobalt supply chain. Fueled by the demand for battery technology and electric vehicles, cobalt has become an essential element to the green energy transition. With the largest share of global cobalt deposits, the Democratic Republic of the Congo bears a disproportionate share of the industry’s harms. Cobalt mining in the DRC is marked by environmentally degrading practices and inhumane working conditions, compromising Congolese health, safety, and well-being. Chapter 1 discusses the environmental impacts of DRC cobalt mining and its adverse effects on public health. Environmentally degrading mining …

Environmental Sustainability Assessment Of Field Phosphate Monitoring Methods For Creeks, Quintino Medi

All Theses

Creeks serve as conduits for water, nutrients, and contaminants to larger water bodies such as rivers and lakes, and their health is a key indicator of overall watershed water quality condition. Unlike rivers, creeks are under-monitored due to their small size, hydrological variability, and limited accessibility. Many technologies exist for monitoring phosphorus in surface waters. Technologies may be classified into two general categories: i) proxy real-time sensors, which record generic water quality parameters, and ii) chemical reagent-based assays, which quantify soluble reactive phosphorus (SRP) in batch samples. There is a lack of studies that compare the features and benefits of …

At The Intersection Of Science And Sustainability: A Qualitative Study Of Food Scientists' Personal And Professional Perspectives, Srushti Parikh

Theses, Dissertations and Culminating Projects

Sustainable food systems require not only technological innovation but a more profound understanding of the professionals involved in the field. Even though the topic of sustainability is currently gaining importance throughout the food industry, the real expertise of food scientists is under-researched. PURPOSE: The purpose of this study is to explore food scientists' perspectives on sustainability, how these perceptions influence the way they pursue their careers, and how they view their impact in the larger sustainability agenda of the food industry. METHODS AND MATERIALS: This study captured detailed insights of 22 food scientists’ perspectives through qualitative methods. Food scientists in …

Evaluating The Rural/Urban Divide In Conservation: Methods Of Improvement In Conservation Programming Across Kentucky, Lauren Tackett

Honors College Theses

Kentucky’s lands and waterways have always defined the state. Our unique karst landscape, combined with the Appalachian Mountains and Ohio River, help characterize the state and its identity. However, across Kentucky conservation efforts within recent years have been under attack. Through legislation changes and policy challenges, various bills have sought to repeal Kentucky’s conservation efforts regarding water, soil, and land use. Furthermore, there has been a rise in environmental disasters within the state that cause long term issues for both rural and urban communities to contend with. The responsibility of land stewardship falls on a variety of entities but weighs …

Barriers To Climate Change And Sustainability Action: Nursing Education And Practice, Dawn Marie Smith

Dissertations

Climate change is one of the most pressing public health emergencies of our time and nurses can have a great impact in their current practice and in the education of future nurses (The Alliance of Nurses for Healthy Environments, n.d.; American Nurses Association, 2023; Health Care without Harm, 2025). Deaths due to rising temperatures, vector-borne illness, and food insecurity related to drought and extreme weather are on the rise (WHO, 2024). It has been estimated that globally over 250,000 additional deaths will be attributed to climate related effects between 2030 and 2050 (Watts et al., 2020; WHO, 2023).

A primary …

Resilience By Living With The Land And Community: A Case Study Of A Local Food Forest, Olivia Beck

Honors Theses

Imagine a public space where food, leisure, outdoor activity, and community engagement occur in one place, all in an urban forest ecosystem. For many, this is a hopeful vision of the future, and that is exactly what the idea of an urban food forest provides. In agroecology, a food forest or forest garden consists of planting diverse edible plants and mimicking the patterns of natural ecosystems. The intricate planning and design ensure the forest is self-sustaining, much like a natural forest, making it very resilient once established. However, they face many challenges and take time to grow and develop to …

Growing Change: A Gis Spatial Analysis To Plan Urban Gardens In Chattanooga, Carson A. Chalk

Honors Theses

Food insecurity and limited access to fresh nutritious food in Chattanooga is a prevalent issue, primarily among lower socioeconomic households, and can put strain on overall well-being. This study aimed to identify suitable vacant parcels in Chattanooga where urban gardens could be developed using a GIS-based spatial analysis. Spatial data involving vacant parcels, slope, zoning, and proximity to grocery stores was cross referenced with socioeconomic data focused on poverty rates, vehicle ownership, and mean household income to identify the most suitable sites in areas of greatest need. Sites identified as suitable through GIS were then visited to verify their suitability. …