Sustainability Commons^™

Beyond Emergency: Charting Pathways To Sustainable Development In Fragile And Conflict-Affected Settings: A Case Study Of Yemen, Sharif Abdurabu Salem Farid Alsahbool

Theses and Dissertations

For nearly a decade, Yemen's eastern governorates of Hadramawt, Shabwah, and Al‑Mahrah have been relatively stable, yet the international aid system has kept delivering short‑term humanitarian relief like food baskets and water trucking instead of shifting to sustainable development that could rebuild people's lives, create jobs, fix infrastructure, and strengthen local government. This thesis investigates why this transition has taken so long. Based on 21 interviews with government officials, international NGO staff, and local NGO managers in these three governorates, the study develops a new way of understanding the problem. It introduces three ideas: the 'emergency mentality', which is a …

Metal-Free Nitrogen-Enriched Graphitic Carbon Nitride Architectures For Advanced Supercapacitor Energy Storage: Design, Synthesis, And Electrochemical Performance Optimization, Loujain Gamal Mohamed

Theses and Dissertations

Abstract

This thesis addresses the urgent global requirement for efficient energy storage materials by developing and characterizing advanced graphitic carbon nitride (g-C3N4)-based electrode materials for supercapacitors. A facile, low-cost thermal polymerization method produces 2D nitrogen-rich GCN nanosheets exhibiting excellent electrochemical stability and wide voltage windows, enabling symmetric devices with 19.33 Wh/kg energy density and remarkable cycling stability over 21,000 cycles. To overcome intrinsic limitations of pristine GCN, a 3D/2D metal free composite with bio-derived carbon (Bio-Cx) is synthesized, delivering high capacitance, wide potential windows, and ultrahigh energy density of 53.72 Wh/kg in asymmetric configurations paired with mesoporous nitrogen-doped carbon (MPNDC). …

Multifunctional Green Wall Systems For Greywater Treatment And Hygrothermal Regulation In Egypt, Laila Ossama Mohamed Elhusseiny Abdelsalam

Theses and Dissertations

Increasing environmental concerns regarding climate change and the intensifying challenge of water scarcity in Egypt necessitate the development of innovative, sustainable, and resource-efficient strategies for wastewater reuse. In the built environment, greywater constitutes a significant, relatively low-contaminant wastewater stream that, if treated to comply with Egyptian Codes and relevant international standards, can be safely reused for non-potable applications such as irrigation, landscaping, and building services. This research investigates the efficacy of an integrated green wall panel system, installed on building façades, for decentralized greywater treatment under Egypt’s climatic and environmental conditions, while simultaneously enhancing hygrothermal performance to reduce building energy …

De Novo Protein Binding To Zinc Oxide Through Biomineralization Pathways, Jean-Mark A. Francis

Theses and Dissertations

De novo proteins are structurally distinct from proteins found in nature and thus capable of having their amino acid sequence modified to accomplish tasks such as increasing protein-nanoparticle binding without unfolding or decomposing. Zinc Oxide nanoparticles are functionally distinct from their bulk counterparts and are widely used as semiconductors in a variety of fields such as medicine and agriculture. With demand for these nanoparticles increasing, environmentally sustainable methods of Zinc Oxide nanoparticle synthesis are being investigated as an eco-friendly alternative to currently utilized but environmentally hazardous chemical and physical techniques. This research investigates the binding characteristics between Zinc Oxide nanoparticles …

Determining The Toxic Threshold And Other Use Characteristics For Industrial Hemp Seed Oil Used For Wood Product Protection, Daylan M. Barnes

Theses and Dissertations

Plant-based wood treatments have been utilized for many years, with varying success. Oils such as those extracted from linseed (flax), tung, and hemp plants have been used for thousands of years as finishes on wood. These are all drying oils, which dry to a film when exposed to air. Hemp seed oil has a high fatty acid content and can take a long time to dry on wood products but is valued in woodworking for being easy to use, food-safe, and having little to no odor. In this study, cold-pressed hemp seed oil, blended with a soybean carrier oil, is …

Cover Crop-Induced Improvements To Soil Hydraulic Properties And The Role Of Termination Time In Mitigating Negative Soil Moisture Impacts, Fabrizio Javier Pilco

Theses and Dissertations

In the Lower Rio Grande Valley of South Texas, water scarcity and drought pose ongoing challenges for farmers. Although cover crops are promoted for improving soil health and moisture, their effects on soil hydraulic properties in this region remain understudied. This thesis addresses both long-term (Chapter 2) and short-term (Chapter 3) impacts of cover crops on soil hydraulic properties and soil moisture. Long-term effects were evaluated through a three-year participatory field trial across four farms using a BACI design, while short terms were evaluated using a complete randomized block design. Soil hydraulic properties (residual water content θr, saturated water content …

Sustainability Transformation For Healthcare Facilities Following Net Zero Model, Esraa Elmitainy

Theses and Dissertations

The healthcare industry is a field undergoing huge development. Focused on SDG 3 “Good Health and Well-being”, the healthcare industry, as the main health service provider, was marked by experts as a sector that should lead sustainable development by example. The current work aims to formulate a sustainability rating system for new and existing healthcare facilities to encourage the Egyptian healthcare industry to move towards sustainability according to net zero concepts. Additionally, the transition to net zero waste is investigated though experimental work to test the possibility of utilizing sterilized medical waste in cement-based bricks.

The rating system starts with …

The Influence Of The Un Watercourses Convention On The Development Of A Policy Design In The Nile River Basin, Zienab Ali Abdelhady

Theses and Dissertations

The adoption in 1997 of the United Nations Convention on the Law of the Non-navigational Uses of International Watercourses (UN Watercourses Convention or UNWC) marked a milestone in the codification and progressive development of international water law. Similarly, the signature in 2010 by the majority of the Nile Basin states of the Nile River Basin Cooperative Framework Agreement (CFA) was a major step towards a permanent legal and institutional framework as well as a significant shift from the currently applicable legal regime in the basin. The research concludes that the principles enshrined in the UNWC can assist future regional treaty …

Into Thick Air: Adapting Cultural Practices Into Solutions For Modern Wicked Problems, Syed Muhammad Erzum Naqvi

Theses and Dissertations

Into Thick Air argues that cultural practices can inspire solutions

to challenging modern problems. This project employs the Basant

festival as a case study to critically reimagine kite flying as a

collective practice with the potential to contribute to the reduction

of air pollution in Lahore, a city consistently ranked among those

with the poorest air quality globally. By building kites from fabric

treated with nanoparticle coatings, Into Thick Air transforms a

traditional community activity into an accessible, citizen-driven

method for removing pollutants from the air. The treated kites

empower Lahoris to take charge of their environment while

encouraging collective …

Structure Modifications And Alternative Monitoring Designs Of Wildlife Road Mitigation Structures, Madison T. Nadler

Theses and Dissertations

Wildlife mitigation structures are designed to keep animals off roadways while providing them safe passage to the other side and not impeding traffic flow. Camera traps are commonly used to assess the success of these mitigation structures, but there are downfalls to both the methods and structures. Alternative mitigation structure designs are needed to better prevent wildlife from accessing roadways in areas where they should be deterred. Additionally, traditional camera trapping methods do not accurately capture the full wildlife communities that may be utilizing these structures and other survey methods are needed, specifically aimed at small mammals, amphibians, and reptiles. …

Guiding Wildlife: Evaluating Wildlife Exit Designs And Sensor Lights For Safer Highways In South Texas, Rupesh Maharjan

Theses and Dissertations

Roadside exclusionary fencing is more prevalent on highways to prevent wildlife-vehicle collisions. Although it can mitigate wildlife road mortality by limiting their access to the road, it can also create a barrier for wildlife stranded within the right-of-way. In State Highway 100 of Texas, the Texas Department of Transportation installed ten wildlife exits to allow wildlife to escape the fenced roadway, and a pair of sensor lights on 13 wildlife guards (WGs) to scare off target species (bobcats and coyotes) from crossing the guards and accessing the roadway. In this study, the effectiveness of three wildlife exit (WE) designs were …

Mapping Urban Tree Canopy Using Publicly Available Satellite Data, Rosemary Mcguinness

Theses and Dissertations

This project addresses the need for accessible, cost-effective tools for quantifying spatial and temporal changes in tree canopy cover in urban areas. Urban tree canopy provides a wide range of ecosystem services, including lowering air temperatures, reducing pollution, and mitigating stormwater runoff. Cities around the world have placed the expansion of their urban forests at the center of their sustainability goals. Consistent and timely data on urban tree canopy is essential for urban greening initiatives to succeed. Existing methods of accessing information about urban tree canopy are highly technical, costly, and labor-intensive, while the freely available source of tree canopy …

Utilizing Unmanned Aerial Systems (Uas) And Computer Software To Assess Effects Of Cover Crops On Cash Crop Volumetric Mass And Plant Height, Carlos Andres Garcia Patlan

Theses and Dissertations

Sustainability in agriculture starts with the health of soil-- from its productivity and fertility, to its ability to retain water during droughts and allow for drainage during rain. One approach of improving soil health is the use of cover crops, a practice associated with improved nutrient availability in soils, the promotion of soil biodiversity and organic matter to improve density and structure, effective weed management, and ultimately improved yields of subsequent cash crops. Assessing the cumulative impacts of cover crops is difficult, with various metrics and indicators. Crop dry weight may be a way to predict the effects cover crops …

Feasibility Of Oil Palm Agroforestry System: Evaluating The Application Of Oil Palm Ash For Enhancing Cherry Tomato (Solanum Lycopersicum. Var. Nancy Rz) Production Using Brackish Water., Ime Joseph Bassey

Theses and Dissertations

Monoculture systems of oil palm production are ravaging the world’s tropical forests, causing deforestation and biodiversity loss, which contribute to climate change at an uncontrollable pace. Oil palm agroforestry systems (AFSs), one of the strategies of regenerative agriculture, have proven to reverse the unfavorable effects of the oil palm monoculture systems. A sustainable means of soil fertilization and irrigation must be explored to improve the feasibility of oil palm AFSs. This study evaluates the impact of the application of oil palm ash and brackish irrigation on cherry tomato production. The experiment was conducted in a hydroponic system using a 2*4 …

Developing A Precision Agriculture Framework To Assess Financial Viability Of Decisions In Farming And Conservation, Jennifer Sublett

Theses and Dissertations

Agricultural producers are invested in managing the impacts of crop damage on their yields and profit. When damage occurs early enough in an agricultural growing season, farmers have the option to replant their corn stand in an effort to recoup some of the lost profits. In this thesis two different types of naturally occurring damage, wildlife depredation and persistent weed or insect patches, were simulated on two representative regions of Mississippi. These data were then used to assess the financial viability of a range of damage mitigation methods, including partial replanting, enrollment into a government conservation buffer, and no action. …

Optimizing Edge-Of-Field Water Quality Monitoring Methods To Determine The Effects Of Best Management Practices On Nutrient And Sediment Runoff, Mark Hill

Theses and Dissertations

This study investigates the impact on water quality of combined agricultural best management practices cover crop and minimum tillage, alongside an examination of techniques used to collect those samples. Edge-of-field (EOF) water quality samples were collected from 11 working farms during a two-year paired field experiment. Results showed significant reductions in nutrient concentrations, increased discharge, and mixed findings regarding nutrient mass transport post-treatment. A suite of EOF collection techniques were compared using in-situ automated water sampling systems sampling the same runoff events. Sampling protocols influenced nutrient concentrations in composite samples, but unexpected variance in velocity sensors affected measured discharge, making …

Nutrient Optimization For Vegetable Production Under Decoupled Aquaponics Using Brackish Water, Salma Walid Hany Ahmed Abdelfattah

Theses and Dissertations

As the world moves to more sustainable agriculture methods in the agribusiness industry, decoupled aquaponics is recognized as one of the newest techniques currently being utilized to achieve more local food security. As the topic is still freshly new within the industry, a finite number of publications and studies have been made that address the topic hands-on with its many variables. Subsequently, in this paper, an experiment was conducted to assess the most optimized production conditions of both lacinato kale (Brassica oleracea var.palmifolia) and Swiss chard Bright Light (Beta vulgaris ssp. Cicla var. flavescens) plants through the utilization of a …

Development And Evaluation Of An Automated Tactical Tillage Tool To Control Weeds In Row-Crop Production Systems, Grace Mccormick Friday

Theses and Dissertations

Weed control is an integral part of a successful overall production strategy in row- cropping systems and has the potential to reduce or eliminate yield losses that negatively affect profitability. Timely and correctly selected herbicide applications are the major keys for effective weed control in a majority of instances. However, there are negative factors that contribute to ineffectiveness and weed escape issues that currently lack viable options for management. Sparsely populated late-season weeds that emerge after lay-by herbicide applications and weeds that have become tolerant and resistant to traditional herbicide chemistries are of greatest concern. Historically, these weeds would have …

Synthesis And Application Of Redox-Active Covalent Organic Frameworks In Rechargeable Batteries, Mohammad K. Shehab

Theses and Dissertations

Synthesis and Application of Redox-Active Covalent Organic Frameworks in Rechargeable Batteries

Mohammad K. Shehab

Department of Chemistry, Virginia Commonwealth University, Richmond, Virginia 23284, United States

Abstract

In recent years, lithium-ion batteries (LIBs) have been considered the dominant energy storage devices for portable electronics and electric vehicles due to their high energy density, low self-discharge rate, and long cycle life. In LIBs, the traditional positive electrodes employed are mainly derived from metal-containing inorganic compounds composed of cobalt, iron, nickel, or manganese (LiCoO₂, LiMn₂O₄, and LiFePO₄) coupled with graphite as the negative electrode. Despite …

Photocatalytic Degradation Of Organic Contaminants By Titania Particles Produced By Flame Spray Pyrolysis, Noah Babik

Theses and Dissertations

Advanced oxidation of organic pollutants with TiO2 photocatalysts is limited due to the wide bandgap of TiO2, 3.2 eV, which requires ultraviolet (UV) radiation. When nanosized TiO2 is modified by carbon doping, charge recombination is inhibited and the bandgap is narrowed, allowing for efficient photodegradation under visible light. Here, we propose a flame spray pyrolysis (FSP) technique to create TiO2. The facile process of FSP has been successful in preparing highly crystalline TiO2 nanoparticles. Using the same procedure to deposit TiO2 onto biochar, the photocatalyst was doped by the carbonaceous material. The morphology, crystalline and electronic structure of the FSP …

Evaluating Soil Health Changes Following Cover Crop And No-Till Integration Into A Soybean (Glycine Max) Cropping System In The Mississippi Alluvial Valley, Alexandra Gwin Firth

Theses and Dissertations

The transition of natural landscapes to intensive agricultural uses has resulted in severe loss of soil organic carbon (SOC), increased CO₂ emissions, river depletion, and groundwater overdraft. Despite negative documented effects of agricultural land use (i.e., soil erosion, nutrient runoff) on critical natural resources (i.e., water, soil), food production must increase to meet the demands of a rising human population. Given the environmental and agricultural productivity concerns of intensely managed soils, it is critical to implement conservation practices that mitigate the negative effects of crop production and enhance environmental integrity. In the Mississippi Alluvial Valley (MAV) region of Mississippi, USA, …

Design And Fabrication Of Nanostructured Electrodes For Complementary Electrochemical And Photoelectrochemical Water Splitting, Kholoud El Sayed Abousalem

Theses and Dissertations

Designing highly active, durable, and nonprecious electrodes for overall water splitting is of urgent scientific importance to realize sustainable hydrogen production. Accordingly, the need to search efficient energy production systems is of crucial necessity. In this thesis, two various systems for sustainable hydrogen production have been reported using electrochemical and photoelectrochemical pathways. In the first part of the thesis, electrochemical water splitting involving both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) has been established. To this end, an innovative approach is demonstrated to synthesize flower-like 3D homogenous trimetallic Mn, Ni, Co phosphide catalysts directly on nickel foam via …

Atomistic Simulation Of Na+ And Cl- Ions Binding Mechanisms To Tobermorite 14Å As A Model For Alkali Activated Cements, Ahmed Abdelkawy

Theses and Dissertations

The production of ordinary Portland cement (OPC) is responsible for ~8% of all man-made CO2 emissions. Unfortunately, due to the continuous increase in the number of construction projects, and since virtually all projects depend on hardened cement from the hydration of OPC as the main binding material, the production of OPC is not expected to decrease. Alkali-activated cement produced from the alkaline activation of byproducts of industries, such as iron and coal industries, or processed clays represents a potential substitute for OPC. However, the interaction of the reaction products of AAC with corrosive ions from the environment, such as Cl-, …

Beyond The Green Iron Cage: Exploring The Macro And Micro-Level Influences On Executive Decisions About Sustainability Investments In Small And Medium Size Firms, Igor Estraykh

Theses and Dissertations

Although research on corporate environmental sustainability has shed light on different aspects of organizational and individual level factors that influence corporate decisions, it does not fully account for how individual executives within firms react to these forces and make decisions, specifically within small to medium size enterprises (SMEs). This study used a grounded theory approach to interview 19 SME executives from 13 different industries to explore how organizational and individual level factors influence their ability to evaluate and make decisions related to sustainability initiatives. The study found that SME executives faced isomorphic pressures for sustainability, individual agency pressures, significant resource …

Evaluating Long-Range Transportation Plans For Mainstreaming Of Climate Adaptation Among Virginia Mpos, Sebastian L. Shetty

Theses and Dissertations

Despite the strides made towards addressing climate change through greenhouse gas (GHG) emissions reduction strategies, it has become increasingly apparent that attempting to mitigate the crisis in such a manner alone is insufficient. This thesis joins a growing body of research on how our societies must adapt to a changing climate, contributing more evidence on common barriers to adaptation and how they might be overcome. Through an attempt to evaluate the progress made towards mainstreaming, or integrating, climate change concerns into five Virginia MPOs’ long-range transportation plans (LRTPs), this study provides support for prior hypotheses around the potential for MPOs …

Engineered Nanostructured Nitrogen-Doped Carbon Network (Ndc) Electrodes With Unprecedented Cycling Stability For Water Capacitive Deionization In Harsh Conditions, Soha Essam Anwar

Theses and Dissertations

Capacitive deionization (CDI) is a feasible low-cost desalination technique for low-to-medium (brackish) salinity water. However, cycling stability and regeneration of the CDI electrodes are the bottlenecks hindering the practical application of the technology on large scale. Oxidation of the electrodes during the sequential adsorption-desorption processes is one of the most challenging problems hindering their long-term cycling performance. Herein, we demonstrated the ability to design and fabricate exceptionally stable CDI electrodes via a one-pot pyrolysis protocol. The optimized pyrolysis of nitrogen-carbon precursors at different temperatures enabled the fabrication of carbon materials with a controlled amount nitrogen dopant (NDCs) with exceptional cycling …

Can The Circular Economy Concretize Sustainability? A Construal Level Approach To Encourage Sustainable Consumption., Jolie Gutentag

Theses and Dissertations

Despite a growing awareness and understanding of the impact our lifestyles have on the environment, most people have not adequately changed their consumption patterns. One possibility for the disconnect is the perceived abstractness of sustainability. Drawing on construal level theory, this research proposes that framing environmental sustainability as circularity, using the principles of the circular economy, reduces the perceived abstractness of sustainability. Four studies investigate the effects of circular framing on sustainable consumption behavior, including the moderating role of consumers’ chronic level of construal, an innate mindset reflecting a tendency to view information more concretely or abstractly. Findings provide initial …

Optimizing The Environmental And Economic Sustainability Of Contingency Base Infrastructure, Jamie E. Filer

Theses and Dissertations

Contingency bases are often located in remote areas with limited access to established infrastructure grids. This isolation leads to standalone systems comprised of inefficient, resource-dependent infrastructure, which yields a significant logistical burden, creates negative environmental impacts, and increases costs. Planners can mitigate these negative impacts by selecting sustainable technologies. However, such alternatives often come at a higher procurement cost and mobilization requirement. Accordingly, this study aims to develop and implement a novel infrastructure sustainability assessment model capable of optimizing the tradeoffs between environmental and economic performance of infrastructure alternatives.

Fielding Sustainability: The Potential For Compost Extract As An Amendment On Athletic Turfgrass, Lacy M. Adams

Theses and Dissertations

Sustainability and green initiatives are being pushed across the country and the globe, but athletics are not seeing the same pressures as intensely. Golf courses are largely the only athletic arena that have received pressure and are beginning to implement more sustainable management practices. Agriculture is also making strides to use less chemicals through organic farming and improve soil health with cover crops. Meanwhile, the rest of the athletic world continues to contribute to soil compaction, chemical maintenance, and runoff all of which affect the quality of the local environment. The strides to improve athletics’ sustainability record can be seen …

Transportation And Sanitation Drivers Of Land Use/Land Cover Change: Loss Of The Jamaica Bay Wetlands, Margaret Joy Cytryn

Theses and Dissertations

This thesis presents an analysis (1830-2014) of the historical events of land use/land cover change in the Jamaica Bay estuary, identification of the agents of change, and a perspective on the potential drivers of transportation and sanitation in land use/land cover change.