Geochemistry Commons^™

Evaluating Recharge And Dynamics Of Flow In The Lower Virgin River Basin, Usa: Interpretation Of Hydrochemical And Stable Isotopic Data, Joseph Asante

UNLV Theses, Dissertations, Professional Papers, and Capstones

Because of the complex geologic setting of the Basin and Range province, groundwater flow systems of the Intermountain basins of the southwestern United States are complex and remain poorly understood. Understanding these flow systems is important for water budgeting on a regional and local scale, and development of robust numerical groundwater models for sustainable water use and protection of water-dependent ecosystems. Although for decades hydrochemistry and isotopes have been used to characterize and trace subsurface water and surface water, effectively interpreting these data are still challenging, which can be attributed to existing subjective grouping of these data and the lack …

Deciphering The Evolution Of Ore Fluids At The Batu Hijau Copper-~Gold Porphyry Deposit, Sumbawa, Indonesia, Jordan Thomas Armstrong

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fluid inclusions contained within quartz veins from the Batu Hijau Cu-Au porphyry deposit in Indonesia were analyzed to track the evolution of fluid temperature, pressure, and composition during the formation of the deposit to better understand the formation of this and other Cu-Au porphyry deposits in order aid future exploration. A combination of petrography, microthermometry, synchrotron x-ray fluorescence, and laser ablation-inductively coupled plasma-mass spectrometry were used to determine the temperature, pressure, and compositional aspects of the deposit.

Four types of fluid inclusions were recognized at Batu Hijau based on the volume percent of the vapor bubble; inclusions were classified as …

The Behavior Of Zircon During Partial Melting In Anatectic Migmatites: Insights To Metamorphism, Deformation And Tectonism In The Central Santa Fe Range, Northern New Mexico, Michelle Renee Stropky

UNLV Theses, Dissertations, Professional Papers, and Capstones

Three lithologic assemblages exposed in the central Santa Fe Range, northern New Mexico include (1) a septum of Proterozoic low temperature (~700oC, 5.5 kbars), semi-pelitic anatectic migmatites surrounded by (2) deformed megacrystic biotite granite that is intruded by (3) discrete plutons of largely undeformed hornblende biotite tonalite. Metamorphic fabrics in the migmatite record three deformation events (D1 - D3); a composite S1/S2 fabric (D1 and D2) that formed contemporaneous with anatexis and is folded about a southwest plunging map-scale (D3) antiform. The megacrystic granite exhibits a pervasive S1 subsolidus foliation that parallels the S1/S2 fabric in the migmatite and is …

Paired Positive Carbonate Carbon Isotope, Organic Carbon Isotope, And Oxygen Isotope Composition Study Across The Lower Mississippian Positive Carbon Isotope Excursion, Southeastern Nevada, Usa, Robert Alan Henry

UNLV Theses, Dissertations, Professional Papers, and Capstones

A prominent positive carbonate carbon isotope (delta13Ccarb) excursion of Early Mississippian age (ca 351 Ma) has been documented by previous studies from numerous sites globally. This delta13Ccarb excursion has been interpreted as resulting from enhanced organic carbon burial that removed 13C-depleted carbon from the ocean and atmosphere. Anticipated outcomes from enhanced organic carbon burial would include a similar positive excursion in organic carbon isotopes (delta13Corg) and a global cooling event resulting from reduced CO2 in the atmosphere and ocean. These predictions, however, were not tested sufficiently in previous studies. This research has tested these predictions through an integrated study of …

Magma Chamber Processes At Mutnovsky Volcano, Russia, Kelly L. Robertson

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation is composed of two manuscripts about the evolution of Mutnovsky Volcano in Kamchatka, Russia. Mutnovsky has been active for the past approximately 80,000 years, during which there was the formation and subsequent eruption of four major stratocones. These four eruptive centers, named Mutnovsky I, II, III, and IV from oldest to youngest, have a range of erupted product compositions from basalt to dacite. The first major goal of this project was to investigate the melt source for Mutnovsky. Whole rock trace element and Nd, Sr, and Pb isotopic data were used to determine that the melt source was …

Microstructural Characterization Of Kinked Germanate Olivine Grains, Alex Gregory Drue

UNLV Theses, Dissertations, Professional Papers, and Capstones

Olivine is the most common and the weakest mineral in the upper mantle. Thus the strength of olivine controls the rheology of the earth's upper mantle. The rheology of olivine in the upper mantle has important implications for mantle flow, mountain building, and rates of isostatic adjustment. Recent experimental measurements of the flow strength of deformed olivine polycrystals have assumed a homogeneous state of stress. X-ray synchrotron diffraction experiments have implied that this assumption is not always valid. Elastic Plastic Self Consistent (EPSC) modeling offers an approach to estimating the flow strength of olivine that does not assume a homogeneous …

Molecular Organic Geochemistry Of The Oil And Source Rocks In Railroad Valley, Eastern Great Basin, Nevada, United States, Laode Ahdyar

UNLV Theses, Dissertations, Professional Papers, and Capstones

A comprehensive geochemical study of oils from Railroad Valley, Nevada and two candidate source rock intervals from the nearby Egan Range, was conducted in order to establish oil-oil and oil-source rock correlations. Analyses consisted of total organic carbon, Rock-Eval pyrolysis, and vitrinite reflectance for source rock samples, as well as biomarker, diamondoids, and stable carbon isotope analyses on source rock extracts and oil samples.

Total organic carbon analyses showed high organic content in the Mississippian Chainman Shale. However, outcrop samples of the Paleogene Sheep Pass Formation Member B are organically lean. Strata in both of these units are immature to …

Pleistocene Climate In Alaska From Stable Isotopes In An Ice Wedge, Corinne Y. Griffing

UNLV Theses, Dissertations, Professional Papers, and Capstones

The CRREL permafrost tunnel offers a unique opportunity to sample ice wedges in a climate-controlled environment, penetrating frozen silts which host massive ground ice that may record Dansgaard-Oeschger (D-O) and Heinrich Events. Ice wedges in the tunnel have been dated to approximately 36-22 ka (Hamilton et al., 1988), allowing the paleoclimate of the region to be reconstructed during MIS 3, when D-O and Heinrich events were documented in various other records. These climate cycles are rapid climate oscillations that have been recognized in records from the Arctic and subarctic, and suggest that climate can rapidly shift by 10°C over millennial …

Melt Inclusions In Volcanic Rocks, Kirellos Sefein, Kelly L. Robertson, Adam Simon

Festival of Communities: UG Symposium (Posters)

We studied melt inclusions from Mutnovsky Volcano, Kamchatka, Russia as part of a larger project designed to contrain the eruptive history of Mutnovsky. Transmitted and reflected light petrographic microscopy was used to characterize melt inclusions in grain mounts of mineral separates, standard 30 micron thin sections, and 200 micron thick sections of the samples from the Mutnovsky. The inclusions were further divided into three main categories: recrystallized, partially recrystallized, and glassy inclusions. After all the melt inclusions have been categorized, they will be analyzed by using LA-ICP-MS to determine their major, minor and trace element compositions.

Age And Petrogenesis Of The Roaring Mountain Rhyolites, Yellowstone Volcanic Field, Wyoming, Kathleen Marie Wooton

UNLV Theses, Dissertations, Professional Papers, and Capstones

Extracaldera rhyolites in the Norris-Mammoth Corridor of the Yellowstone Volcanic Field (YVF) appear to be unrelated to intracaldera volcanism, resulting instead from a new crustal magma source derived from northeastward propagation of the Yellowstone “melting anomaly.” The youngest extracaldera rhyolite unit, the Roaring Mountain Member (RM), is chemically distinct from the previous extracaldera lavas, reverting to more primitive compositions.

This study suggests that the majority of the RM rhyolites erupted from the same large-scale silicic magma system. Based on geochemistry and 40Ar/39Ar geochronology, the Crystal Spring mingled rhyolite and Obsidian Cliff rhyolite erupted concurrently at 59.1 ± 2.0 ka. The …

Sequence And Chemostratigraphy Of The Middle Cambrian Succession In Nevada And Utah, Robyn A. Howley

UNLV Theses, Dissertations, Professional Papers, and Capstones

The House Range Embayment of western Utah and eastern Nevada was a prominent topographic feature on the passive margin of western North America during the middle and late Cambrian. In this study, detailed documentation of sequence boundaries, and their intervening sequences across a platform-to-basin transect of the House Range Embayment was used to establish a sequence-stratigraphic framework from which the depositional history of the embayment was deciphered. This framework was then used to test the hypothesis that the House Range Embayment formed by tectonic subsidence. In addition, the chemostratigraphic (δ13Ccarb) record across the embayment was analyzed within this framework to …

Carbon Isotopic Fractionation Across A Late Cambrian Carbonate Platform: A Regional Response To The Spice Event As Recorded In The Great Basin, Jonathan Lloyd Baker

UNLV Theses, Dissertations, Professional Papers, and Capstones

Geochemical models have suggested that the late Cambrian was characterized by a greenhouse climate with high pCO2. Furthermore, stableisotope analyses within the Great Basin have documented a large carbonate isotope (δ13Ccarb) excursion, known as the Steptoean Positive Carbon Isotope Excursion (SPICE). This event has been documented globally, and is interpreted as having resulted from enhanced organic carbon burial. Unless the size of carbon reservoirs in the Cambrian ocean was significantly different from those of the Cenozoic, this forcing should have resulted in a comparable carbon-isotope excursion in organic matter (δ13Corg). It is also predicted that increased organic carbon burial would …

Geochemistry Of Pyrite And Whole Rock Samples From The Getchell Carlin–Type Gold Deposit, Humboldt County, Nevada, Tim A. Howell, Jean S. Cline

Undergraduate Research Opportunities Program (UROP)

Carlin-type gold deposits were not recognized as a new major type of gold deposit until the 1960’s. The Getchell deposit, which is now known to be a Carlin-type gold deposit, was discovered in 1934 (Joralemon, 1951). This deposit is located in north central Nevada (Fig. 1). Much is known about the physical characteristics of Carlin-type gold deposits (Cline et al., 2005). An unusual characteristic of these deposits is that free gold is generally not present. Instead, gold occurs as sub-micrometer particles in the mineral pyrite or marcasite. The marcasite and pyrite that are gold bearing commonly occur as rims on …

Identification Of Geochemical Facies Through Major Ion Data And Additional Parameters From Shallow Groundwater Utilizing A Comparison Of Geomathematics And Traditional Methods In Las Vegas Valley, Nevada, Eric Dano

UNLV Theses, Dissertations, Professional Papers, and Capstones

There has been little exploration to identify geochemical facies in shallow groundwater in the Las Vegas Valley in Clark County, Nevada. Identification of hydrochemical facies in Las Vegas Valley is important for assessing the extent and nature of a potential groundwater resource. The identification of facies could be complicated by the possibility that secondary recharge constitutes a hydrochemical facies of its own. To identify geochemical facies, groundwater samples for major ions, stable isotopes and some municipal tracers were collected from 35 wells in an established network of monitor wells. Wells were purged with a bailer or 12V pump and EC, …

An Experimental Investigation Of Chemical Mass Transfer Processes In Crystallizing, Hydrous Silicate Magmas: The Genesis Of Ore Deposits And Metasomatic Fluids, Aaron S. Bell

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation is comprised of three broadly related experimental petrology projects on phase equilibria and noble metal solubility in hydrous silicate melts. Chapters two and three combine experimental petrology with high precision laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis of experimental run products in order to quantitatively constrain the behavior of the investigated metals. Chapter four presents experimental evidence detailing a novel oxidation mechanism for degassing silicate liquids as well as exploring the geochemical consequences of the proposed mechanism.

Chapter two presents the results of an experimental study on Au, Pt, and Pd behavior in coexisting silicate melt-sulfide-oxide …

Petrogenesis Of The Greenwater Range: Comparison To The Crater Flat Volcanic Field And Implications For Hazard Assessment, Ashley Kaye Tibbetts

UNLV Theses, Dissertations, Professional Papers, and Capstones

Pliocene basalts of the Greenwater Range, California erupted from 24 volcanic vents now represented by volcanic plugs, craters and scoria mounds. Basaltic magmas originated in the asthenospheric mantle, but show evidence of a lithospheric component. Depths and temperatures of melting calculated using a silica activity geobarometer are 54.3–89.6 km and 1367-1435oC, placing melting in the asthenosphere. The preferred petrogenetic model involves melting of lithospheric mantle thermally and mechanically, but not chemically, converted to asthenospheric mantle. Melting depths correspond to low velocity zones in the mantle as revealed in seismic profiles. Chemical and lithologic similarities between basalt in the Greenwater Range …

Using Fluid Inclusions To Trace Formative Fluid Evolution At The Verde And Pancho Porphyry Au Deposits Of The Refugio District, Chile, Brian Joshua Aillaud

UNLV Theses, Dissertations, Professional Papers, and Capstones

Evolution of magmatically-derived formative fluids, and the processes that control the ratio of ore metals in porphyry and high-sulfidation epithermal deposits remain enigmatic. The Refugio district in the Maricunga Belt of Northern Chile hosts the temporally and spatially related Pancho and Verde porphyry gold deposits. Vein types at Pancho include A-veins, transitional veins, banded veins, D-veins and quartz-alunite ledges that formed by replacement. Verde East and West lack A-veins, and show an earliest vein type with transitional characteristics of A- to banded veins, banded veins and D-veins. Fluid inclusions and quartz textures were characterized by using optical microscopy and cathodoluminesence …

Researching Nitrite Oxidation At High Temperatures, Dolores A. Huang, Jeremy A. Dodsworth, Brian P. Hedlund

Undergraduate Research Opportunities Program (UROP)

15N-nitrate (NO3 -) pool dilution experiments show that ammonia (NH3) is oxidized to nitrate in geothermal springs up to at least 85C; however, nitrite (NO2 -)- oxidizing microorganisms are only known to grow up to 66°C. We hypothesize that thermophilic microorganisms oxidize nitrite to nitrate at high temperatures. Alternatively, it is possible that nitrite is oxidized abiotically. We propose to test these hypotheses by setting up microbial enrichments designed to grow thermophilic nitrite oxidizing bacteria by varying incubation temperature (50, 65, 80°C), oxygen concentration (20% and 5%), and cultivation media. A negative control consisting of filtered spring water (0.1 μm) …

Sequence And Chemostratigraphic Study Across The Basal Eureka Quartzite Unconformity In The Great Basin, Nevada: Implications For The Origin Of The Late Ordovician Carbon Isotope Excursion, Apostolos Paul Kosmidis

UNLV Theses, Dissertations, Professional Papers, and Capstones

The positive carbon isotope (δ 13 C) excursion from the late Middle Ordovician Copenhagen Formation that underlies the Eureka Quartzite in central Nevada has been hypothesized to record a global cooling event ∼10 Myr prior to the well-recognized Late Ordovician Hirnantian glaciation (∼443 Ma). However, direct evidence for pre-Hirnantian continental glaciation remains scarce, raising uncertainties in the relationship between the inferred eustatic sea-level fall and the origin of the positive δ 13 C excursion. Additionally, previous stratigraphic studies from southern Nevada and California suggest relative sea-level fall in excess of ∼ 150 meters, which exceeds estimates for younger glacial periods …

In Situ Element Quantification In The Hydrothermal Diamond Anvil Cell Using Synchrotron X-Ray Fluorescence With Applications Toward Subduction Zone Processes, Steven Joseph Maglio

UNLV Theses, Dissertations, Professional Papers, and Capstones

Yttrium is used in geochemical investigations of arc volcanics and metamorphic geothermometers. The ability to use Y as a geochemical tool is predicated on an understanding of the mobility of Y during fluid-saturated conditions attending metamorphic and igneous processes. The goal of this work was to use the hydrothermal diamond anvil cell (HDAC) and synchrotron radiation X-ray fluorescence to quantify, in situ, the concentration of Y in aqueous fluids at 2-5 GPa and 650 - 800 °C; conditions likely at the oceanic lithosphere - mantle wedge interface in subduction zones. Previous studies have used modified diamond anvils which limits their …

Mineralogy And Micromorphology Of An Atacama Desert Soil, Chile: A Model For Hyperarid Pedogenesis, Michael S. Howell

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Atacama Desert is the oldest and driest desert on Earth. Hyperarid soils in this desert are dominated by rare (or exclusive) salt minerals and assemblages. Previous research details salt origins and abundance, however pedogenic processes involved in salt distribution are not adequately explained. Therefore, the main goal of this investigation was to identify and document evidence for hyperarid pedogenesis (via salt mineralogy and soil micromorphology) at a field site, Oficina Ercilla, located ~80 km northeast of Antofagasta, Chile within the Central Depression and hyperarid core of the Atacama Desert. This study presents an interpretational model for hyperarid pedogenesis, which …

A Study Of Nife(X)Cr(2-X)O4 By Laser Micro-Raman Spectroscopy, Lucas Wilson, Markus Vasquez, John Farley, Allen L. Johnson, Brian D. Hosterman

Undergraduate Research Opportunities Program (UROP)

Standards of spinels, composed of two metals and oxygen with the formula AB2O4, are being created with known composition to identify spinels in samples of unknown composition by comparison with the spectra obtained from the standards. Laser micro-Raman spectroscopy allows the identification of chemical species based on their unique vibrational modes. The degree to which spinels of varying composition can be identified will be determined. This will aid in the study of the corrosion of steel by liquid metal. Spinels are a likely component of the oxide layer. Understanding the composition of the products of corrosion leads to an understanding …

Direct Analysis Of Solid Corrosion Products By Laser Ablation Icp-Ms: Method Development And The Interaction Of Aqueous Uranium, Gadolinium And Neodymium With Iron Shot And Iron (Iii) Oxide, James Cizdziel, Klaus J. Stetzenbach, Amy J. Smiecinski

Publications (YM)

The purpose of this report is to summarize the work and present conclusions of Project Activity Task ORD-RF-03 conducted under cooperative agreement number DE-FC28-04RW12237 between the U.S. Department of Energy and the Nevada System of Higher Education (NSHE). The work was conducted in the Harry Reid Center for Environmental Studies of the University of Nevada Las Vegas from October 1, 2004 to September 30, 2006. The purpose of the study was to develop a method using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) for the direct analysis of iron corrosion products, to evaluate its capabilities, advantages, and limitations, and …

Geochemical Modeling Of Solubility And Speciation Of Uranium, Neptunium, And Plutonium, Zhongbo Yu, Yuyu Lin, Karen Johannesson, Amy J. Smiecinski, Klaus J. Stetzenbach

Publications (YM)

The purpose of this study is to model the solubility, speciation, and transport of three actinides: uranium (U), neptunium (Np), and plutonium (Pu) by a geochemical modeling tool under possible repository environmental conditions upon waste package failure. The dissolution concentration of three actinides in the waste package, their aqueous speciation after dissolving in the unsaturated zone (UZ), and transport processes in the saturated zone (SZ) along the groundwater flow path at Yucca Mountain (YM) are simulated by geochemical modeling calculations using PHREEQC. This model report was prepared in fulfillment of Groundwater Characterization at Yucca Mountain, Task II: Surface Complexation and …

Results Of Chemical Analyses For Alcove 8/ Niche 3 Tracer Studies, Jeanette Daniels, Amy J. Smiecinski

Publications (YM)

This is the final report detailing the analyses performed under ORD-FY04-011 "Chemical Analyses for Alcove 8/Niche 3 Tracer Studies," The work was performed under The University and Community College System of Nevada (UCCSN) and the Department of Energy (DOE) Cooperative Agreement DE-FC28-04RW12232, This task provided method development and analytical support for the Alcove 8/Niche 3 Tracer Studies in the Exploratory Studies Facility (ESF). Concentrations of tracers as well as major anions and cations were reported for samples provided by Lawrence Berkeley National Laboratory (LBNL) and the US Geological Survey (USGS). Samples were analyzed using High Performance Liquid Chromatography (HPLC) and …

2005- 2008 Unlv Mcnair Journal, Valerie Avery, Shana Bachus, Karmen K. Boehlke, Andrea Flores, Alden Kelly, Erick Lopez, Carol Preussler, Heather Shay, Ava Bookatz, Shaun Elsasser, Veronica Hicks, Shaida A. Jetha, Anthony Quinn, Thurithabhani Seneviratne, Teddy Boado Sim Jr., Liza Ward, Amris Henry-Rodgers, Jacquelynn Kaaa-Logan, Jason Orozco, Juan C. Plata, Bonnie Bartlett, Kathleen Bell, Vacheral M. Carter, Nydia Diaz, Kimberly Hackstock, Julio A. Luna, Charles Mao, Sandra Ramos, Precious Rideout, Benjamin Lee Watrous, Chet R. Whitley

McNair Journal

Journal articles based on research conducted by undergraduate students in the McNair Scholars Program

Table of Contents

Biography of Dr. Ronald E. McNair

Statements:

Dr. Neal J. Smatresk, UNLV President

Dr. Juanita P. Fain, Vice President of Student Affairs

Dr. William W. Sullivan, Associate Vice President for Retention and Outreach

Mr. Keith Rogers, Deputy Executive Director of the Center for Academic Enrichment and Outreach

McNair Scholars Institute Staff

Support For The Nye County Early Warning Drilling Program, Irene Farnham, Klaus J. Stetzenbach, Amy J. Smiecinski

Publications (YM)

This final report details the activities completed for Task 8 of the University and Community College System of Nevada (UCCSN) Cooperative Agreement with the US Department of Energy (DOE). Task 8, titled "Support for the Nye County Early Warning Drilling Program" provided for a variety of hydrochemical analyses. The requirements of the University and Community College System of Nevada (UCCSN) Quality Assurance (QA) Program were followed for all work performed on this task. The primary activity performed by the Harry Reid Center for Environmental Studies (HRC) for Task 8 was to provide hydrochemical analyses of the groundwater samples collected from …

Preliminary Geochemical Evaluation Of Groundwaters From Wells Of The Nye County Early Warning Drilling Program, Irene Farnham, Klaus J. Stetzenbach, Amy J. Smiecinski

Publications (YM)

As part of the Yucca Mountain Oversight program, the Nye County Nuclear Waste Repository Project Office (NWRPO) has established a groundwater monitoring program to protect groundwater resources for the residents of Nye County in Amargosa and Pahrump Valleys. This groundwater monitoring program, referred to as the Nye County Early Warning Drilling Program (NCEWDP), involves drilling a series of wells down-gradient from Yucca Mountain for long term groundwater monitoring and also to provide much needed geologic and hydrologic information in this area. A comprehensive database of aquifer parameters in the alluvial, volcanic, and carbonate aquifers down-gradient hydrogeologically of Yucca Mountain is …

Support For Infiltration And Seepage Studies In Exploratory Studies Facility Niches And Alcoves, Irene Farnham, Klaus J. Stetzenbach, Amy J. Smiecinski

Publications (YM)

This report details the analyses performed under Task 9 of the University and Community College System of Nevada (UCCSN) Cooperative Agreement with the US Department of Energy (DOE). This task, titled "Analysis of Chemical Tracers in Conjunction with the Vadose Zone Infiltration and Seepage Studies", provided for the development of analytical procedures and the analysis of samples from a tracer test currently in progress at Alcove 8 /Niche 3 in the Exploratory Studies Facility (ESF). The concentration of two tracers (bromide andpentafluorobenzoic acid) were quantified in the initial injectate solution and also the seepage samples collected from Niche 3. Samples …

Thermochronological Evolution Of Calcite Formation At The Proposed Yucca Mountain Repository Site, Nevada: Part 1, Secondary Mineral Paragenesis And Geochemistry, Jean S. Cline, Amy J. Smiecinski, Robert Bodnar

Publications (YM)

In the near future a decision will be made as to whether or not Yucca Mountain, 90 miles northwest of Las Vegas, Nevada is a suitable site for a permanent, underground, high level nuclear waste repository. A major factor in determining the suitability of Yucca Mountain as a repository is the potential for the site to be flooded by water during the regulatory lifetime. The current study was undertaken to examine the past fluid history at the site, to gain a better understanding of the possibility of flooding in the near geologic future. To estimate the past fluid flux into …