Geochemistry Commons^™

Pressure-Induced Phase Transition In 1,3,5-Triamino-2,4,6-Trinitrobenzene (Tatb), Brad A. Steele, Samantha M. Clarke, Matthew P. Kroonblawd, I-Feng W. Kuo, Philip F. Pagoria, Sergey N. Tkachev, Jesse S. Smith, Sorin Bastea, Laurence E. Fried, Joseph M. Zaug, Elissaios Stavrou, Oliver Tschauner

Geoscience Faculty Research

Determining the unreacted equation of state of 1,3, 5-triamino-2,4,6-trinitrobenzene (TATB) is challenging because it exhibits low crystal symmetry and low X-ray scattering strength. Here, we present the first high-pressure single-crystal X-ray diffraction (SXD) study of this material. Our SXD results reveal a previously unknown transition to a monoclinic phase above 4 GPa. No abrupt change of the volume occurs but the compressibility changes. Concomitant first principles evolutionary crystal structure prediction USPEX calculations confirm this transition and show that it involves a pressure-induced in-plane shift of the layers of TATB molecules with respect to the ambient-pressure phase.

Petrogenesis Of Unusual Occurrence Of Amphibole Asbestos In Mohave County, Arizona And Clark County, Nevada, Tomoyo Austin

UNLV Theses, Dissertations, Professional Papers, and Capstones

The term “asbestos” applies to six types of fibrous amphiboles or chrysotile with specific morphologies that are commercially mined and processed. Inhaling asbestos fibers is known to cause many negative health effects, including mesothelioma, several different cancers, various respiratory diseases and non-respiratory diseases, and fatalities. The recent years, several cases of non-occupational exposure to asbestos fibers raised an awareness of environmental exposure to naturally occurring asbestos (NOA) which refers to asbestiform minerals that fall out of the regulatory definition of asbestos.

There are two sources of NOA in the area, Wilson Ridge pluton, AZ, and Boulder City pluton, NV which …

Dissolution Rates Of Allophane, Fe-Allophane, And Hisingerite And Implications For Aqueous Alteration On Mars And In Potential Returned Martian Samples, S. J. Ralston

UNLV Theses, Dissertations, Professional Papers, and Capstones

Recent measurements from Mars document X-ray amorphous/nano-crystalline materials in multiple locations across the planet. However, despite their prevalence, little is known about these materials or what their presence implies for the history of Mars. The amorphous component of the martian soil in Gale Crater has an X-ray diffraction pattern that can be partially fit with allophane (approximately Al2O3•(SiO2)1.3-2•(H2O)2.5-3), as well as low-temperature water release consistent with allophane. The chemical data from Gale Crater suggest that other silicate phases similar to allophane, such as Fe-substituted allophane (here, approximately (Fe2O3)0.01(Al2O3)0.99(SiO2)2•3H2O) and hisingerite (approximately Fe3+2Si2O5(OH)4•(H2O)), may also be present. In order to investigate …

Shergottite Northwest Africa 6963: A Pyroxene‐Cumulate Martian Gabbro, Justin Filiberto, Juliane Gross, Arya Udry, Jarek Trela, Axel Wittmann, Kevin M. Cannon, Sarah Penniston-Dorland, Richard Ash, Victoria E. Hamilton, Andrea L. Meado, Paul Carpenter, Brad Jolliff, Eric C. Ferré

Geoscience Faculty Research

Northwest Africa (NWA) 6963 was found in Guelmim‐Es‐Semara, Morocco, and based on its bulk chemistry and oxygen isotopes, it was classified as a Martian meteorite. On the basis of a preliminary study of the textures and crystal sizes, it was resubclassified as a gabbroic shergottite because of the similarity with terrestrial and lunar gabbros. However, the previous work was not a quantitative investigation of NWA 6963; to supplement the original resubclassification and enable full comparison between this and other Martian samples; here we investigate the mineralogy, petrology, geochemistry, quantitative textural analyses, and spectral properties of gabbroic shergottite NWA 6963 to …

Petrology And Geochemistry Of The Enriched Poikilitic Shergottite Northwest Africa 10169: Insight Into The Martian Interior, Logan Matthew Combs

UNLV Theses, Dissertations, Professional Papers, and Capstones

The martian meteorite Northwest Africa (NWA) 10169 is classified as a new member of the geochemically enriched poikilitic shergottites, based on mineral composition, Lu-Hf isotope systematics, and rare earth element (REE) composition. Akin to other poikilitic shergottites, it shows a similar bimodal texture to other enriched and intermediate poikilitic shergottites. In addition, olivine and pyroxene in the poikilitic zone have higher Mg#’s (Mg/Mg+Fe) than those in the interstitial areas, suggesting that the poikilitic texture represents early-stage crystallization, opposed to late-stage non-poikilitic crystallization. Calculated fO2 values are reduced (FMQ -2.3 ± 0.23) within the poikilitic texture, and more oxidized (FMQ -1.07 …

U–Pb Dating Of Cave Spar: A New Shallow Crust Landscape Evolution Tool, D. D. Decker, V. J. Ployak, Y. Asmeron, Matthew Lachniet

Geoscience Faculty Research

In carbonate terranes, rocks types that provide apatite are not available to effectively use apatite fission track (AFT) or (U/Th)‐He chronometry (AHe). Here we suggest that calcite cave spar can be an effective chronometer and complimentary to AFT and AHe thermochronometers in carbonate regions such as our study area, the Guadalupe Mountains of southeastern New Mexico, and west Texas. Our measured depth of cave spar deposition is 500 ± 250 m beneath the regional water table, formed at temperatures of 40° to 80°C, indicating that these caves and their spar crystals form near the supercritical CO2‐subcritical CO2 boundary where we …

Phosphate Release: The Effect Of Prebiotic Organic Compounds On Dissolution Of Merrillite, Whitlockite, Chlorapatite, And Fluorapatite, Courtney Lea Bartlett

UNLV Theses, Dissertations, Professional Papers, and Capstones

Phosphate is an essential nutrient on Earth, used by life for ATP, DNA, RNA, and phospholipid membranes. Therefore, if life is or ever was present on Mars, phosphorus may have played an important role in determining the habitability of an environment. Phosphorus does not have a significant volatile phase; its release from minerals is consequently critical to phosphorus availability and prebiotic chemistry. Phosphate release from Mars-relevant minerals such as merrillite and chlorapatite has been previously found to differ significantly from phosphate release from fluorapatite, the dominant phosphate phase on Earth. However, the environments in which phosphate release would have been …

An Elemental Highway: Investigation Of A High Nickel Anomaly In Olivine From The Island Of Niihau, Hawaii, Alexander James Valentine

UNLV Theses, Dissertations, Professional Papers, and Capstones

The study of volcanic geochemistry is one of the main gateways for investigating the Earth’s mantle. One important topic in the field is that of nickel (Ni) in the mineral olivine. While Ni is a compatible element in olivine, its high concentration at a given MgO content is not well understood. A variety of hypotheses have been proposed, including attributing presence of Ni to pyroxenite source melting, contribution from the core, or variation in peridotite source melting. In addition to the other hypotheses, chemical diffusion may also be a mechanism for enriching olivine Ni concentration. Magnesium-iron (Mg-Fe) isotopic measurements have …

Characterizing Crystal Populations For The Petrogenesis Of The Post-Collapse Rhyolites In The Long Valley Caldera, California, William Joseph

UNLV Theses, Dissertations, Professional Papers, and Capstones

Post-collapse rhyolites of the Long Valley in eastern California are the product of remelting of crystal mush bodies via mafic rejuvenation following the eruption of the Bishop Tuff. This is supported by mineral textures and major element geochemistry from the Resurgent Dome rhyolite, the Moat rhyolite, the Hot Creek Flow, and the Deer Mountain rhyolite. New 40Ar/39Ar eruptive ages are reported for the Moat rhyolites (525 ka, 333 ka, 118 – 94 ka), Hot Creek Flow (312 – 295 ka), and the Deer Mountain rhyolite (65 ka). The initial post-collapse eruptions, resulting in the Resurgent Dome rhyolite, appear to be …

Characterizing The Earliest Stages Of Partial Melting: A Study Of The Pyrometamorphic Aureole Of Miocene Mt. Perkins Pluton, Northwest Arizona, Mathew Beshears

UNLV Theses, Dissertations, Professional Papers, and Capstones

Partial melting is an important process in the evolution of continental crust. Due to its progressive nature, evidence of the early stages of partial melting is often overprinted by later, advanced stages of partial melting. Experimental work has provided a model for the early stages of partial melting, but is limited to timescales of hours to weeks. Pyrometamorphic environments within the contact aureole of mafic intrusions provide natural laboratories for the study of the earliest stages of partial melt production on geologic time scales of 102 collected along two traverses of the tilted pyrometamorphic aureole of the Mt. Perkins pluton …

Characterization Of Gold And Related Mineralization At The North Bullion Carlin System, Railroad Project, A Nevada Carlin-~Type Gold Prospect, Melanie Nicole Newton

UNLV Theses, Dissertations, Professional Papers, and Capstones

A study of the North Bullion Carlin system, a Nevada Carlin-type gold prospect located on trend with the large Carlin-type gold deposits (CTGD) of the Carlin Trend, identified characteristics of ore and alteration mineralization, mineral paragenesis, and pyrite and whole rock geochemistry that are similar to characteristics that typify Carlin-type gold deposits. The North Bullion Carlin system is hosted in Devonian shelf carbonates and the Mississippian overlap assemblage, host rocks that are different from typical CTGD shelf-slope carbonate assemblage host rocks. The mineralogy and ore-stage gold-bearing pyrite rims at North Bullion are not as well developed as they are in …

Ediacaran Ocean Redox Evolution, Swapan Kumar Sahoo

UNLV Theses, Dissertations, Professional Papers, and Capstones

The relative role that environmental versus intrinsic biological factors played in

shaping the history of life on Earth is a fundamental but unanswered question in the

natural sciences. Most famously, it has been heavily debated if the emergence and

diversification of early animals during the Ediacaran Period (ca. 635–541 Ma) was tied to

a rise in atmospheric-oceanic oxygen levels. Temporally discontinuous geochemical data and patchy fossil record in literature are inadequate to chart the Ediacaran redox history and its causal relationship with the biotic evolution. My PhD study aims for a multiproxy geochemical record within a well-established stratigraphic framework of …

Dissolution Of Nontronite In Low Water Activity Brines And Implications For The Aqueous History Of Mars, Michael Henry Steiner

UNLV Theses, Dissertations, Professional Papers, and Capstones

Water is essential to life on Earth and is likely to play a role in determining the habitability of other planets. Pure liquid water is not stable on the surface of Mars but brines can temporarily remain liquid, and increasing evidence suggests the presence of recent liquid water, including brines, on Mars. Brines can host life at temperatures as low as -30 ºC and some organisms can live at activities of water as low as 0.61. Therefore, if brines have been present on Mars, they may act as habitable environments.

The Fe-rich smectite nontronite, (CaO0.5,Na)0.3 Fe3+2(Si,Al)4O10(OH)2·nH2O, has been detected on …

Predictive Modeling Of Terrestrial Radiation Exposure From Geologic Materials, Daniel A. Haber

UNLV Theses, Dissertations, Professional Papers, and Capstones

Aerial gamma ray surveys are an important tool for national security, scientific, and industrial interests in determining locations of both anthropogenic and natural sources of radioactivity. There is a relationship between radioactivity and geology and in the past this relationship has been used to predict geology from an aerial survey. The purpose of this project

is to develop a method to predict the radiologic exposure rate of the geologic materials in an area by creating a model using geologic data, images from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), geochemical data, and pre-existing low spatial resolution aerial surveys …

An Investigation Into Transitions In Clay Mineral Chemistry On Mars, Seth Gainey

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation is comprised of three studies investigating clay mineralogy on, or near the martian surface, with an introductory chapter, introducing and linking the three studies. Chapter two is on the subject of clay mineral synthesis, including Fe/Mg clay minerals which have been detected at multiple locations across the southern highlands. These Fe/Mg clay minerals have been previously interpreted as forming in anoxic/reducing environments, conducive to the preservation of organic matter. The results of this study suggest that the previous interpretation of Fe/Mg-rich clay as requiring anoxic/reducing conditions may not be accurate, as the minor presence of Mg (below what …

Modeling Background Radiation Using Geochemical Data, Kara Marsac

UNLV Theses, Dissertations, Professional Papers, and Capstones

Aerial gamma ray surveys have many applications in geology and science in general, such as locating mining prospects, defining radioactive plumes, and detecting nuclear weapons. Unfortunately there is currently no simple way to separate the natural gamma radiation of soil and rocks from that of contaminants such as radioactive plumes. This project used geochemical data (uranium, potassium and thorium concentrations) collected from national databases, private companies, and the NURE (National Uranium Resource Evaluation) Survey, to create forward models of exposure rates measured by aerial gamma ray surveys. We developed these techniques using an area in north central Arizona known as …

Carbon Isotope Variations Associated With A Middle Ordovician Karstic Unconformity, Patricia Suzanne Williams

UNLV Theses, Dissertations, Professional Papers, and Capstones

Large negative carbon isotope (δ¹³C) excursions have been documented from late Neoproterozoic-Paleozoic successions. These δ¹³C excursions have been widely used for regional and global stratigraphic correlation, particularly in strata with limited paleontological and radiometric age controls. Recent studies, however, argued that some negative δ¹³C excursions from stratigraphic record may have been resulted from meteoric/burial diagenesis, which commonly shifts both carbon and oxygen isotopes toward lower values. Testing the diagenetic origin of δ¹³C excursions in stratigraphic successions without independent stratigraphic framework has been difficult because it evolves into circular arguments about stratigraphic completeness …

Subalklaine Volcanism In The Eastern Basin And Range Province: Examples From The Miocene Mccullough Range Volcanic Field And The Pliocene To Holocene Black Rock Desert Volcanic Field, Racheal Leighann Johnsen

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation is composed of three papers that apply geologic mapping, whole rock geochemical and isotopic analysis, and mineral chemistry to describe two large, long-lived (~6 million years), and compositionally heterogeneous volcanic fields and posit sources of the rock types present in each. These fields are the McCullough Range in southern Nevada, which was a locus of volcanic activity from ~19 - 12 Ma and the Black Rock Desert volcanic field in west-central Utah, which began forming at ~6 Ma and is still active today, with the most recent eruption occurring ~720 years ago.

Chapter Two is composed of a …

New Early Miocene 40ar/39ar Ages For Nakwai, Northwest Kenya, Africa, And Paleontological Analysis Of Meroehyrax Kyongoi Dentition, Dawn Elena Reynoso

UNLV Theses, Dissertations, Professional Papers, and Capstones

Nakwai is a fossiliferous region in the Turkana Basin of northwestern Kenya. Until recently the only ages for the Nakwai formation were based on biostratigraphic correlation with Losodok; a late Oligocene site located to the north of Nakwai. The new 40Ar/39Ar ages in this study range from 23 Ma to 15 Ma and constrain the upper portions of the Nakwai section to the early Miocene. These ages make it the only securely dated fossil locality in the region that represents the earliest Miocene; all of the other early Miocene fossil localities date back to ~20 Ma or younger. The time …

Porphyry Copper Exploration Of The Hualapai Mountains, Mohave County, Arizona, Usa: A Multi-Faceted Approach, Patrick Kevin Meazell

UNLV Theses, Dissertations, Professional Papers, and Capstones

A variety of exploration methods including geologic mapping, trace- and major-level geochemical analyses, fluid inclusion petrography, remote sensing, and SWIR clay spectroscopy were used to investigate the potential for porphyry Cu-Mo mineralization at the Wikieup prospect, in the southern Hualapai Mountains of northwestern Arizona. Aspects of the Mineral Park mine were used as an analogue to guide exploration due to the proximity and similar geology of the area.

The Hualapai Mountains are a series of northwest-trending Precambrian gneisses, schists, granitoids and amphibolites that have been cut by younger intrusive rocks. Within the Wikieup study area, the intrusive rocks include aplite …

Mars-Relevant Phosphate Minerals And Implications For Martian Habitability, Christopher Adcock

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation is comprised of three studies focused on martian phosphate availability, with an introductory chapter introducing and linking the three studies. Chapter two is on the subject of merrillite synthesis. Merrillite is an extraterrestrial Ca-phosphate mineral similar to the mineral whitlockite and is found as a dominant primary phosphate mineral in martian meteorites. The chapter includes methods of whitlockite and merrillite synthesis as well as a detailed characterization of the produced minerals and a mechanism by which charge balance can be maintained when merrillite is synthesized through dehydrogenation of whitlockite.

Chapter three presents the results of kinetic and thermodynamic …

The Effect Of Single Crystal Elastic And Plastic Anisotropy On Stress And Strain Heterogeneity: Comparison Of Olivine To Other Common Minerals, Christopher Joseph Cline Ii

UNLV Theses, Dissertations, Professional Papers, and Capstones

In order to investigate the influence of single crystal elastic anisotropy on the heterogeneity of stress distributions during polycrystalline deformation multiple deformed crystalline materials were analyzed using electron backscatter diffraction (EBSD). Deformation experiments were conducted on samples of Solnhofen limestone using a modified Griggs piston cylinder apparatus at UNLV, and also on San Carlos olivine using the D-DIA multi-anvil press at the National Synchrotron Light Source beamline X17B2. Analysis of the mechanical twins in deformed calcite and kink bands in olivine help elucidate deviations in local stress directions away from that of the applied macroscopic stress. Combined calculated compression directions …

Modern To Late Pleistocene Stable Isotope Climatology Of Alaska, Alison Sloat

UNLV Theses, Dissertations, Professional Papers, and Capstones

Understanding modern controls on climate is necessary to interpret past climatic conditions. This project investigated the modern controls on δ18O and δD values in Alaskan surface waters to interpret the controls on Late Pleistocene climate variability. ArcGIS was used to develop an isoscape of modern δ18O and δD values of over 400 surface water samples collected across Alaska and the Yukon. It was found that winter temperature and precipitation have the greatest controls on δ18O and δD values in Alaska, resulting in high δ18O values along the coast of the Gulf of Alaska and low values inland toward Central Alaska. …

Connecting Aerial Gamma Ray Surveys And Geochemical Data, Kara Marsac, Pamela Burnley, Elisabeth Hausrath, Russell Malchow, Daniel Haber

NSTec UNLV Symposium

• Radiation in the Environment
• Aerial Gamma Ray Surveys
• Radiation and Geology
• Collecting Existing Geochemical Data
• Rock Unit Geochemistry
• Model Creation and Comparison

Predictive Modeling Of Radiological Background Using Geochemistry, Daniel Haber, Pamela C. Burnley, Kara Marsac, Russell Malchow, Elisabeth Hausrath, Christopher Adcock

NSTec UNLV Symposium

• Introduction & Background
• Methods
• Models
• Results and Discussion
• Future Work

Dissolution Rates Of Amorphous Al- And Fe-Phosphates And Their Relevance To Phosphate Mobility On Mars, Valerie Tu

UNLV Theses, Dissertations, Professional Papers, and Capstones

Phosphate is an essential element for life on Earth, and therefore if life exists or ever existed on Mars it may have required phosphate. Amorphous Al- and Fe-phosphates rapidly precipitate from acidic solutions and amorphous Al-phosphates likely control phosphate concentrations in some natural waters on Earth. Amorphous phases may be even more important on Mars than on Earth, and amorphous phosphates are therefore likely important in the phosphate cycle on Mars. Despite this importance, however, few dissolution rates exist for amorphous Al- and Fe- phosphates. In this study, dissolution rates of amorphous Al- and Fe-phosphates were measured in flow-through reactors …

Petrogenesis Of The East Fork Member Rhyolites, Valles Caldera, New Mexico, Usa, Carla Eichler

UNLV Theses, Dissertations, Professional Papers, and Capstones

The most recent volcanism in the Valles caldera is represented by the El Cajete Pyroclastic Beds (ECPB), Battleship Rock Ignimbrite (BRI), and Banco Bonito Flow (BBF) as well as the VC-1 rhyolite, which are collectively known as the East Fork Member (EFM) of the Valles Rhyolite. The EFM was erupted at approximately 55 ka and 40 ka after an approximate 460 ka lull in volcanism. Previous studies suggested a mafic intrusion at depth triggered the eruptions. This thesis represents the first detailed study of the EFM.

Crystal assemblages consist of plagioclase, biotite, clinopyroxene, orthopyroxene, amphibole, sanidine, quartz, and oxides. Electron …

Volcanic Evolution Of The Southern Quinn Canyon Range: Implications For Regional Correlation Of Volcanic Units, Christina Emery

UNLV Theses, Dissertations, Professional Papers, and Capstones

The southern Quinn Canyon Range lies in an area of the Great Basin subjected to large-volume Oligocene-Miocene silicic volcanism and smaller volume basaltic volcanism during the Pliocene. Three major ash-flow tuff units were correlated in the southern Quinn Canyon Range (the Pahranagat Tuff, Clifford Spring Tuff, and the Cow Canyon Tuff) with regional units by utilizing U/Pb and 40 Ar/ 39Ar geochronology, geochemical correlation, and field mapping. Isotopic analysis suggests that basalt in the southern Quinn Canyon Range is part of the Death Valley-Pancake Range Basalt Zone and is similar to Reveille Range Episode 1 and 2 basalts. Further comparison …

Evaluation Of Possible Source Rocks In Northern Nye County, Nevada: Implications For Hydrocarbon Exploration, Inessa Yurchenko

UNLV Theses, Dissertations, Professional Papers, and Capstones

The presence of oil outside of Railroad Valley, northern Nye County has sparked the interest of exploration companies in Nevada. The geology in this region is very complex and the level of petroleum exploration is low. In order to understand the distribution of oil, a complete petroleum systems analysis is required. Previous studies confirmed that the Mississippian Chainman Shale and Cretaceous to Paleocene Sheep Pass Formation, Member B are source rocks. However, a number of other possible source rocks exist in northern Nye County, but they are not confirmed because of incomplete datasets. The goal of this thesis project is …

Chemical Weathering Of The Mafic Minerals Serpentine And Olivine In Natural Environments, Julie Lynn Baumeister

UNLV Theses, Dissertations, Professional Papers, and Capstones

Chemical weathering is a critical process that plays a key role in controlling the chemistry of natural waters, the cycling of atmospheric carbon dioxide, and the formation of soil. The weathering of silicate minerals is important because the Earth's crust is composed of approximately 92 weight percent silicate minerals. Despite an extensive literature on mineral dissolution and kinetics, relatively few studies have examined weathering of the mafic minerals serpentine and olivine, especially in a natural environment. The first chapter of this thesis provides an introduction to the minerals serpentine and olivine. The second chapter of this thesis examines the important …