Geochemistry Commons^™

Lithostratigraphic And Geochemical Characterization Of The Upper Pennsylvanian ‘Wolfcamp D’ Shale, Midland Basin (Usa): Implications For Paleoenvironments And Unconventional Petroleum Reserviors, Patrick W. Baldwin

Theses and Dissertations--Earth and Environmental Sciences

An integrated stratigraphic analysis of a ~350 ft drill core from Upton County (Texas) has revealed pervasive variability of several key siliciclastic and carbonate lithofacies in vertical section, where organic-rich siliceous mudrock beds alternate with aluminum-rich mudrocks and calcareous gravity flow deposits. Sediment chemistry, especially major and trace elements derived from x-ray fluorescence, captures this variability with high sensitivity. The high frequency chemostratigraphic variability appears to be cyclic, and it is interpreted to represent the first example of deep-water Late Pennsylvanian cyclothems for the Midland Basin. Positive trace metal (Mo, Cr) correlations to total organic carbon and gamma ray response …

Spring Responses To Storms And Seasonal Variations In Recharge In The Middle Atlas Region Of Morocco, Brett Andrew Howell

Theses and Dissertations--Earth and Environmental Sciences

Springs in the Middle Atlas Mountains of Morocco are significant sources for public water supply. From March 2014 to May 2015, water temperatures were measured hourly at three springs (Ribaa, Sidi Rached, and Zerouka); water levels were measured hourly at Sidi Rached and Zerouka; and daily turbidity data were obtained from Ribaa. From March 2014 to March 2015, daily water samples were taken at Zerouka for analyses of the stable isotopes deuterium and oxygen-18. Hourly weather data (precipitation and air temperature) were available from March 2014 to May 2015 from Ifrane, near Zerouka. Temperature responses varied between the springs, showing …

Field, Geochronologic, And Geochemical Constraints On Late Precambrian To Early Paleozoic Terrane Accretion In The Southern Appalachian Blue Ridge Province, Emma A. Larkin

Theses and Dissertations--Earth and Environmental Sciences

Xenolith-bearing orthogneiss of Amazonian affinity discovered in the Dellwood quadrangle in the Blue Ridge basement complex represents the oldest crustal component of the southern Appalachians (1.33 – 1.37 Ga: Quinn, 2012). New U-Pb zircon ages for migmatitic paragneiss of the Cartoogechaye terrane exposed in the Dellwood quadrangle reveal two unique detrital zircon age signatures that indicate either a local eastern Laurentian margin source or an exotic source. Detailed mapping, whole rock geochemistry, and U-Pb zircon geochronology were conducted to determine whether this exotic crustal component extends farther south into the Hazelwood 7.5” quadrangle. Lithological similarities exist between paragneisses in the …

The Environmental Effects Of Coal Fires, Trent Garrison

Theses and Dissertations--Earth and Environmental Sciences

There are thousands of subterranean coal fires in the world that, because of incomplete combustion, emit a wide variety of volatile and semivolatile organic compounds to the atmosphere, water, and soil at concentrations that could pose health risks to humans and wildlife. The main goals of this study were to (1) review methods that are used to characterize physical and chemical characteristics of coal-fire sites, (2) determine relationships between gas emissions and physical and chemical characteristics of coal-fire sites, using a combination of regression and multivariate statistical methods, and (3) determine the concentrations of volatile and semivolatile organic compounds in …

Fluvial Responses To Growth Faulting In The West Pearl River, Louisiana, Stephen A. Prosser

Theses and Dissertations--Earth and Environmental Sciences

The Pearl River Delta (PRD) in southeastern Louisiana is an actively deforming deltaic complex displaying surface and near-surface evidence of growth faulting. Active growth faults in these environments are rarely identified at the surface, in part because the downthrown blocks often experience increased rates of sediment deposition leading to an obscured and low-relief, or entirely absent, surface expression. Faulting can be expressed in fluvial systems as changes in channel gradient, which often result in coincident changes in channel sinuosity, migration rates, planform deflections, and/or ponding features within the deformed zone. The study area is focused on a meander bend of …

Temporal And Spatial Characterization Of Macondo 252 Signatures In Gulf Of Mexico Shelf And Slope Sediments, Olivia P. Woodruff

Theses and Dissertations--Earth and Environmental Sciences

The long-term fate of hydrocarbons in the Gulf of Mexico (GOMx) following the 2010 Deepwater Horizon oil spill has yet to be fully characterized. Elemental (% C and % N), stable isotopes (δ¹³C_organic), and polycyclic aromatic hydrocarbon (PAH) molecular signatures were investigated in shelf and slope sediments collected in October 2010 and 2011 to gain insight into processes affecting the distribution and fate of spilled Macondo oil. Particulate organic carbon (POC) ranged between 1.55 and 2.22 wt. % in 2010 and 0.55 and 2.06 % in 2011 while the corresponding δ¹³C_organic ranges were …

Modeling Of Co2-Water-Rock Interactions In A Mississippian Sandstone Reservoir Of Kentucky, Anne M. Schumacher

Theses and Dissertations--Earth and Environmental Sciences

This study examined CO₂-water-rock interactions occurring during a carbon sequestration pilot test into a Mississippian oil reservoir in western Kentucky. New samples (n=62) and archived data, both collected from oil wells, were used to characterize the chemistry of formation waters from the Sugar Creek field in Hopkins County. In addition, core and cuttings samples (n=17) from the reservoir and overlying cap-rocks in, or near, the field were analyzed for bulk and clay mineralogy using X-ray diffraction. Electric logs were used to select sample intervals within the overlying cap-rocks and the center of the producing zones in the Jackson …

Distribution And Impacts Of Petroleum Hydrocarbons In Louisiana Tidal Marsh Sediments Following The Deepwater Horizon Oil Spill, Rachel S. Hatch

Theses and Dissertations--Earth and Environmental Sciences

Following the 2010 Deepwater Horizon (DWH) spill, sediment cores were analyzed from marshes at various levels of oiling to determine how deeply oil penetrated sediment in these marsh environments, and if at these sites it had quantifiably affected benthic ecosystems. Minimum mixing depths were determined from penetration of the lithogenic radionuclide ²³⁴Th, which ranged from 0.25 to 4.5 cm. Sediment accumulation rates were determined using ²¹⁰Pb, with verification from ¹³⁷Cs in selected cores. Lead-210 profiles revealed long-term (decadal) mixing. Bay Jimmy, Louisiana was significantly affected by the DWH oil spill, as indicated by total polycyclic aromatic hydrocarbon …

Abiotic Nitrate And Nitrite Reactivity With Iron Oxide Minerals, Prakash Dhakal

Theses and Dissertations--Plant and Soil Sciences

Under iron (Fe³⁺)-reducing conditions where aqueous Fe²⁺ and unreduced solid Fe³⁺-oxides commonly coexist, soil Fe²⁺ oxidation has been shown to be coupled with nitrate (NO₃^-) reduction. One possible secondary reaction is the involvement of NO₃^- and nitrite (NO₂^-) with Fe-oxide minerals found in many natural environments. Yet, spectroscopic measurements and kinetic data on reactivity of NO₃^- and NO₂^- with Fe-containing oxide minerals such as goethite (a-FeOOH), and magnetite (Fe₃O­₄) are not found in the literature. The reactivity of …

The Evolution Of Grenville Basement In The Eastern Great Smoky Mountains; Constraints From U-Pb Zircon Geochronology, Whole Rock Sm-Nd, And Feldspar Pb Geochemistry, Ryan Joel Quinn

Theses and Dissertations--Earth and Environmental Sciences

Identifying the crustal affinity of Grenville basement rocks in the Dellwood quadrangle, western NC, provides insight into the tectonic evolution of eastern Laurentia during Grenville orogenesis. U-Pb zircon geochronology of orthogneiss, augen gneiss, and mafic xenoliths in orthogneiss reveal magmatic pulses at 1130, 1180, and 1330 Ma and metamorphic episodes at 450 and 1040 Ma. Xenoliths in 1330 Ma orthogneiss are as old as 1382 Ma and represent the oldest component of Blue Ridge basement identified to-date. Feldspar Pb isotope values span a range between juvenile-Laurentian and southern-central Appalachian basement/Amazonia. Most Pb isotope data define an array consistent with crustal …

Petrologic, Geochemical, And Geochronologic Constraints On The Tectonic Evolution Of The Southern Appalachian Orogen, Blue Ridge Province Of Western North Carolina, Eric Douglas Anderson

University of Kentucky Doctoral Dissertations

The Blue Ridge Province of western North Carolina contains a wide variety of metamorphosed igneous and sedimentary rocks that record the tectonic effects of Precambrian and Paleozoic orogenic cycles. Tectonic interpretations of the events that led to the present configuration are varied and often conflicting. This investigation examines metamorphosed mafic rocks that are widely interpreted to have formed during the closure of ocean basins. Metabasites, and specifically eclogites, have a tendency to mark tectonic sutures and frequently preserve pressure (P), temperature (T), and age data (t) that can be gleaned from mineral equilibria and U-Pb isotopic compositions. As such, the …

Paleogene Mirelands Of The Upper Mississippi Embayment, Western Kentucky, Jennifer Marie Klein O'Keefe

University of Kentucky Doctoral Dissertations

Detailed petrography, geochemistry, and palynology together describe the depositional environments and paleoecology of an abandoned meander-fill system in western Kentucky. Oriented block petrography reveals alternating clay-rich and attrinite-rich zones of variable thickness. Woody tissues, where present, do not show dessication features and deflation layers could not be identified. Overall, petrography is indicative of a topogenous mire. Mire palyno-assemblages are less diverse than assemblages reported from clays in the region. Castanea-Cupuliferoidaepollenites assemblages dominate the entire system and other tree pollen are common; fungal spores are relatively uncommon. Weighted statistical analyses reveal ecological groupings beyond this dominance and define botanical succession within …

Compositional Variations In The Fire Clay Coal Bed Of Eastern Kentucky: Geochemistry, Petrography, Palynology, And Paleoecology, Cortland F. Eble, James C. Hower, William Morton Andrews Jr.

Report of Investigations--KGS

Bench samples of the Fire Clay coal bed, collected from 28 localities in a study area of eight 7.5-minute quadrangles in the Eastern Kentucky Coal Field, were analyzed geochemically, petrographically, and palynologically to determine any spatial or temporal trends among the studied parameters.

At most sample sites the Fire Clay is split by a flint-clay parting of probable volcanic origin. The upper bench of the Fire Clay coal generally is thick, laterally continuous, low in ash yield and sulfur content, has a moderate to high calorific value, and is high in total vitrinite content. In contrast, the lower bench generally …

Hydrogeology, Hydrogeochemistry, And Spoil Settlement At A Large Mine-Spoil Area In Eastern Kentucky: Star Fire Tract, David R. Wunsch, James S. Dinger, Page B. Taylor, Daniel I. Carey, C. Douglas R. Graham

Report of Investigations--KGS

An applied research program at the Star Fire surface mine in eastern Kentucky, owned and operated by Cypress-AMAX Coal Co., defined spoil characteristics to develop and monitor water resources, which will help identify a reliable water supply for future property development. Water stored in the mine spoil may provide a usable ground-water supply, and the spoil could also be engineered to provide base flow to surfacewater reservoirs.

Ground-water recharge enters the spoil by way of sinking streams, ground-water flow from bedrock in contact with the mine spoil, and a specially designed infiltration basin. Ground water discharges predominantly from springs and …

Considerations Of Variations In Ionospheric Field Effects In Mapping Equatorial Lithospheric Magsat Magnetic Anomalies, Dhananjay Ravat, W. J. Hinze

Earth and Environmental Sciences Faculty Publications

Longitudinal, seasonal, and altitude‐dependent variability of magnetic fields is investigated in equatorial latitudes to determine their effect on the isolation of lithospheric Magsat magnetic anomalies. An estimate of ‘ionospheric effect’ was compiled by averaging the total intensity Magsat anomalies as a function of dip latitudes (called ‘dip‐latitude averages’) from dawn and dusk data sets grouped according to longitudes, time (months), and altitudes. Unanticipated seasonal variations were observed in dusk Magsat data over the Indian sector that may contribute to an improved understanding of the equatorial electrojet. The amplitudes of the dawn dip‐latitude averages are small in comparison to the dusk …

Solution Geochemistry Of The Water Of Limestone Terrains, John Thrailkill, David B. Beiter, Michael T. Osolnik, Roger H. Postley, William T. Mitchell, Leonard N. Plummer, James R. Riddell, Richard C. Worley, Robert D. Zwicker

KWRRI Research Reports

Limestone groundwater flows mainly in openings it has solutionally enlarged, thus an understanding of the water's state of saturation relative to calcite (the principal mineral component of limestone) is fundamental to an understanding of the nature and evolution of the limestone aquifer. This study investigated the Mammoth Cave-Sinkhole Plain (MCSP) and Cave Hollow (CH) aquifers in Kentucky, both in Missippian limestones.

Both aquifers were always undersaturated with calcite. Except for completely ventilated vadose flows (usually) and some vadose seepage (occasionally), all recharges sampled (sinking streams, vadose flows, and vadose seepage) were also undersaturated. The lack of saturation in the MCSP …

Third Report Of The Geological Survey In Kentucky, Made During The Years 1856 And 1857, David Dale Owen

Administrative Report--KGS

Third report. Assisted by Robert Peter (geochemist), Sidney S. Lyon (topographer), Leo Lesquereux (paleontologist), and Edward T. Cox (paleontologist).