Geochemistry Commons^™

Identification And Quantitation Of Volatile Amines In Marine Sediments, Chuen Mei Huang

Chemistry & Biochemistry Theses & Dissertations

Pore waters which were taken from sediments of the Chesapeake Bay were analyzed to determine the presence of volatile amines. A purge-and-trap technique was used to concentrate the amines. Then, following derivatization with heptaflourobutyric anhydride, the HFBA-amines were analyzed by gas chromatography with electron capture detection and with mass spectrometric detection. One secondary amine, diethylamine with a concentration of 0.3-0.6 uM, was found in a total of three pore water samples from cores collected on two different dates. A primary amine, sec-butylamine with a concentration of O. 05 AIM, was also found in one of these same samples. Another primary …

Sulfide In Shelf/Slope Waters Of The Western Atlantic, Christian F. Krahforst

OES Theses and Dissertations

Sulfide in the surface ocean has been recently considered as a source of hydrogen sulfide gas in the marine boundary layer. This "oxic" sulfide may also be important as a ligand in trace metal complexation. In the absence of actual data, the existence of sulfide in the ocean mixed layer remains speculative. The purpose of this study was to develop a sensitive technique (having picomolar detection limits) for the determination of sulfide in seawater, and to investigate the distribution of sulfide in the surface ocean.

In order to assess the abundance and distribution of sulfide in surface waters, samples were …

Discrimination Of Subparallel Beach Ridges Using Detrital Ilmenite Composition And Fourier Shape Analysis, Allen E. Evans Jr.

OES Theses and Dissertations

Elemental composition (Fe, Ti, Mn, Mg, V, Cu, Ni, Zn, and Cr) and Fourier shape analysis of magnetically separated detrital ilmenite from seven Pleistocene and modern beach sand deposits of the Southeastern Virginia Coastal Plain were used to distinguish each deposit. Geomorphic expression, crosscutting relationships and proximity to the present shoreline differentiates the relative age of the seven sampled beach deposits. Analysis of ilmenite elemental composition, independent of geomorphic expression, distinguished beach sands of

different age and was successful in determining that each beach contained ilmenite similar in composition. Of the seven beach ridges tested, subtle yet significant differences in …

On The Linear Relation Between Mb And Ms For Discrimination Between Explosions And Earthquakes, Ali A. Nowroozi

OES Faculty Publications

Summary. The statistical capability of the m_b :M_s, discriminant for the discrimination of earthquake and explosion populations is examined by application of discriminant functions to a group of 83 explosions and 72 earthquakes in Eurasia. Equations are derived for the probability that an event is an earthquake or an explosion. The positive sign of DIS in the decision index equation,

DIS, = 34.3383 - 11.9569 mb_i, + 7.1 161 M_si,

indicates that the event i is an earthquake. Its negative sign indicates that event i is an explosion. The probability of …

Leachate Monitoring In Naturally Saline Groundwater Chesapeake Landfill Chesapeake Virginia, T. Britt Mcmillan

OES Theses and Dissertations

Groundwater chemistry around the Chesapeake municipal landfill was monitored over a one year period. Ten sample sites as well as two surface water sites were used to monitor water quality. Two wells, one at 3 m and the other at 10 m were located at each site. Surface water samples were taken from the Elizabeth River, north of the landfill, and a tidal channel, west of the landfill. Seven groundwater sites were downgradient of the landfill and three sites were upgradient (control sites).

The landfill overlies a tidal marsh, approximately 100 m south of the intracoastal waterway (Elizabeth River). Dredge …

The Use Of Ilmenite Element Composition For The Determination Of Provenance, Yu W. Tsang

OES Theses and Dissertations

Fifty three samples were taken from three major rivers and their tributaries in Virginia: the James, Roanoke. and Potomac-Shenandoah Rivers. Samples were obtained from the Valley and Ridge. Blue Ridge and Piedmont provinces. The possible source rock types for these samples were determined by comparison of tributary ilmenite composition with drainage basin rock types. Ilmenite element concentration varied with different rock types. Ti was usually high for the ilmenite derived from non-mafic igneous rocks. Mg and Cr were high for the ilmenite from mafic igneous rocks. Zn was low for metamorphic ilmenite. The ilmenite from sedimentary rocks tended to have …

Fault Movements And Tectonics Of Eastern Iran: Boundaries Of The Lut Plate, Ali A. Nowroozi, A. Mohajer-Ashjai

OES Faculty Publications

Summary. From 1977 March 21 to 1981 July 28, about 15 earthquakes with M_s ≥6.0 and many earthquakes with M_s≥4.5 have occurred in Iran. The upsurge of seismic activity started following the Khorqu earthquake of 1977 March 21, M,=7.0, south-east of the Fars folded series of Zagros. This shock had a thrust focal mechanism solution indicating the general northward movement of the Arabian plate with respect to the Iranian landmass. It was followed by six major damaging earthquakes in eastern Iran. The earthquakes are associated with extensive faulting which surrounds the Lut plate. (1) The Zarand earthquake …

The Aquatic Geochemistry Of The Particle-Reactive Radionuclides Po-210, Pb-210, And Be-7, James Forrest Todd

OES Theses and Dissertations

Integrated monthly wet-only and bulk precipitation samples for Be-7 and Pb-210 analysis were collected from November 1982 through October 1983 at two sites in lower Chesapeake Bay. Atmospheric deposition fluxes for Be-7 in wet-only and bulk precipitation averaged 0.013 and 0.014 pCi/cm²/d, respectively, and for Pb-210 averaged 0.36 and 0.40 pCi/cm²/yr, respectively, suggesting that dry deposition makes only a minor contribution to the total fluxes.

A seasonal trend was observed in the depositional flux of Be-7, with a pronounced maximum in the Spring. Approximately 40 percent of the annual Be-7 deposition occurred between February and April, …

A Method For Determining Creosote Contamination Of Sediment From The Elizabeth River, Norfolk, Va, Elizabeth G. Merrill

OES Theses and Dissertations

Hydrocarbon input sources to the Elizabeth River were investigated. Carbonized coal products (creosote, coal tar, and roof tar), petroleum products (Kuwait Crude Oil, No. 2 Fuel Oil, and a fuel oil spill sample) and soot (woodstove and diesel engine) have unique hydrocarbon distributions. Elizabeth River sediment hydrocarbon distributions indicate that they are contaminated with both carbonized coal and petroleum products. Using a simple two member mixing model, greater than 65 percent of Elizabeth River sediments' resolved aromatic compounds were determined to originate from carbonized coal products. These aromatic hydrocarbons include the EPA priority pollutant polynuclear aromatic hydrocarbons which are known …

Trace-Elements In Ilmenite - A Way To Discriminate Provenance Or Age In Coastal Sands, Dennis A. Darby

OES Faculty Publications

Trace elements and Ti percentage in ilmenite grains magnetically separated from modern and late Pleistocene coastal sands of southeastern Virginia and northwestern North Carolina were used to distinguish different deposits. Multivariate analysis of ilmenite composition (Ti, Mn, Mg, Cr, V, Ni, and Cu) from coastal deposits and potential source rivers enabled the identification of dominant source rivers. Using the trace element content of one mineral instead of heavy-mineral suites eliminated most of the hydraulic sorting, selective weathering, and intrastratal solution problems that often obscure heavy-mineral provenance determinations. Most ilmenite grains lacked exsolution or twinning, which are common to ilmenite; however, …

The Effect Of Polynuclear Aromatic Hydrocarbons On The Fecundity Of Acartia Tonsa (Calanoid Copepoda), Juanita Y. Grabarczyk

OES Theses and Dissertations

The concentrations of polynuclear aromatic hydrocarbons (PNAHs) were determined for several stations in the Elizabeth River. Thirteen PNAHs of the sixteen EPA priority pollutant PNAHs were present in the particulate fraction. The concentrations ranged from 10.0 ng/1 to 1000 ng/1. Ten of the sixteen EPA priority pollutant PNAH were present in the dissolved phase. Concentrations ranged from 2.0 ng/1 to 100 ng/1.

The environmental PNAHs concentrations were used to determine test concentrations. Bioassays were conducted to determine the effects of indigenous concentrations of seven predominant PNAHs (0.01 mg/1 to 2.4 mg/1 concentrations) on the fecundity of Acartia tonsa (calanoid Copepoda). …

Input And Distribution Of Sewage Derived Sedimentary Material Adjacent To Chesapeake-Elizabeth Sewage Outfall, Virginia Beach, Virginia, Robert Carroll Brown

OES Theses and Dissertations

The concentrations of coprostanol and hydrocarbons were measured in the effluent from the Chesapeake-Elizabeth sewage treatment plant and surface sediments from the area surrounding the effluent discharge site. Most of the coprostanol (>84%) and hydrocarbons (>91%) were associated with particulates in the effluent. Some of these particles were incorporated into the sedimentary column within the study area, while some may have escaped from the area.

The study area is found to be a dynamic area where changes in the percentage and distribution of fine-grained sediments occur over periods of months. The movement of fine-grained sediments is an important …

Some Effects Of The Polychaete Nereis Succinea Frey And Leukart 1847 On The Distribution Of Copper Cadmium And Zinc In Sediments And Water, Gabriela Kitzig August

OES Theses and Dissertations

Two laboratory experiments, each lasting 216 hours, were conducted in order to determine the effects of a burrowing polychaete, Nereis succinea Frey and Leukart, 1847, on the distribution of copper, cadmium, and zinc in sediments and water in environmentally controlled microcosms. Dissolved metal concentrations in microcosms containing worms (experimental) decreased more rapidly than in microcosms without worms (controls). From 72 hours to 216 hours, suspended metal concentrations in experimental microcosms increased while concentrations in controls remained relatively constant. Sediment cadmium concentrations in experimental microcosms increased more over time than in controls. Polychaetes accumulated significant amounts of all three metals. These …

The Distribution Of Cesium-137, Copper, Lead And Zinc In Various Sedimentary Environments Of The James River Estuary, Virginia, Colin Stevenson Moy

OES Theses and Dissertations

Ten grab samples and eight cores were obtained within a short stretch of the James River estuary. The distribution of CU, Pb, Zn, Cs-137, organic carbon (TOC) and fine-grained sediments in various depositional environments were examined. Within the past quarter of a century, these measured parameters have been accumulating preferentially in the low energy environment (Burwell Bay). The inventory of Cs-137 in the cores was linearly related to the inventory of heavy metals and TOC. The concentrations of Cs-137 in the surface sediments vary linearly to those of the other parameters suggesting that Cs-137 may be used as a tracer …

The Effects Of Elevated Calcium Chloride And Magnesium Chloride Levels On Larval Growth And Survival Of Macrobrachium Rosenbergii (De Man) (Decapoda Palaemonidae) Reared In The Laboratory, James Thomas Michaels Ii

OES Theses and Dissertations

The effects of elevated CaCl₂ , MgCl₂ , combination CaCl₂ and MgCl₂ concentrations and their associated ionic strengths on larval growth and survival of the freshwater prawn, Macrobrachium rosenbergii were investigated in the laboratory. Larvae were reared in diluted seawater of 15 parts per thousand salinity with elevated calcium concentrations of 330 parts per million and elevated magnesium concentrations of 1275 parts per million. Control larvae were also reared with elevated NaCl concentrations to duplicate the ionic strength increases of the combination CaCl₂ - MgCl₂ test solution which had the highest ionic strength. A …

Alkalinity And Ph In The Southern Chesapeake Bay And The James River Estuary, George T. F. Wong

OES Faculty Publications

The ranges of alkalinity and pH in the southern Chesapeake Bay and the James River estuary were 2.25 meq·liter⁻¹ at 32‰ to

The Distribution Of Several Metals And Cation Exchange Capacity In Sediment Fractions From An Artificial And Natural Marsh, James River, Virginia, William Nivens

OES Theses and Dissertations

In order to examine the mechanisms by which Fe, Mn, Ca, Zn, Cu, Ni and Pb are bound in sediments, a sequential selective extraction procedure was employed on sediment samples collected at an experimental dredge disposal marsh and a neighboring natural marsh located near Windmill Point, James River, Va. The metal concentrations were determined in six phases, interstitial water, exchangeable, easily reducible (oxides of Mn), organic, moderately, reducible (oxides of Fe), and residual fractions. In addition, the cation exchange capacity (CEC) of the sediments was determined as well as the actual role of organics and colloidal iron coatings as they …

Sediment Interstitial Dissolved Mercury And Carbon Relationships In An Artificial And Natural Marsh, James River, Virginia, Apostolos Katsaounis

OES Theses and Dissertations

Thirty six sediment cores were collected during August, 1976 and January, 1977 in order to examine the relationships between dissolved organic carbon and total dissolved mercury in the interstitial water of two marshes located near Windmill Point, James River, 16 km downstream from Hopewell, Virginia. The Windmill Point marsh development site is a dredged material disposal island in the James River. The reference marsh which does not contain dredged material, is located 2.3 km upstream at Ducking Stool Point.

The concentrations of dissolved organic carbon and total dissolved mercury showed no significant difference between the two marshes. Trends in the …

Processes Controlling The Distribution Of Methane In The Cariaco Tranch, Venezuela, Denis A. Wiesenburg

OES Theses and Dissertations

Abstract unavailable.

The Analysis Of Volatile Organic Compounds In The Southern Chesapeake Bay, Virginia By Gas Chromatography/Mass Spectrometry, James D. Haluska

OES Theses and Dissertations

Sea-water samples from the Norfolk, Virginia area were analyzed for trace volatile organic compounds by helium sparging. Contents of the trap were injected into a gas chromatograph/mass spectrometer. Analysis of the trap contents indicated the presence of aliphatic and olef1nic hydrocarbons containing up to six carbon atoms and eight halogenated compounds of up to two carbon atoms in length. The halogenated compounds which were identified were dichlorofluoromethane, trichlorotrifluoroethane, carbon tetrachloride, chloroform, trichloroethane (2 isomers) bromodichloromethane, and chlorotrifluoroethylene. The

relative concentrations of volatile organic compounds generally tended to increase in samples collected from water prone to urban environmental pressures. All eight …

Determination Of Nutrient Levels And Proposed Predictive Models For Phosphate In The Lafayette River, Norfolk, Virginia, John R. Montgomery

OES Theses and Dissertations

The Lafayette River, an Urban, well-mixed estuarine embayment, was sampled from October, 1970 to January, 1972 for phosphate, nitrate, nitrite, oxygen, water temperature and salinity. The mean values found for these samples were: oxygen saturation from 69% to 106% nitrate from 0 to 4 microgram-atoms per liter, and salinity from 13 ‰ to 24 ‰. The mouth of the Elizabeth River to Hampton Roads as also sampled from May, 1971 to August, 1971. The Lafayette and Elizabeth Rivers were also sampled over a 24 hour period in the summer of 1971 and the Lafayette River again in the winter of …

An Evaluation Of A Stable Isotope Of Dysprosium For Labeling And Tracing Sedimentary Particles, Charles Glenn Boone

OES Theses and Dissertations

An evaluation of the application of dysprosium oxide as a tracer coating to surface label sedimentary particles is made. Physical and chemical properties of the labeled sand are studied. Effective diameters and settling properties of the tracer sand are compared with unlabeled sand. A total of 8.51 kg of labeled sand was placed on the beach at Camp Pendleton. Dispersal patterns obtained 1 and 4 hours after tracer injection indicate a general down current mean tracer migration rate of 0.21 cm/sec (0.42ft/sec). An absolute detection limit of 4 or 5 parts per 100,000 and a real detection limit, after field …