Geochemistry Commons^™

Dust Deposition To The Bermuda Region: A Comparison Of Estimates Using Seasonally-Resolved Measurements Of Aluminum In Water-Column, Aerosol, And Rain Samples, Tara Williams, Peter Sedwick, Bettina Sohst, Joe Resing, Kristen Buck, Salvatore Caprara, Rod Johnson, Dan Ohnemus, Ben Twining, Alessandro Tagliabue

College of Sciences Posters

Dust deposition is a major source of bioactive trace elements to the surface ocean, yet this flux remains difficult to constrain. Previously, time-averaged dust flux has been estimated using surface ocean dissolved aluminum (DAl) concentrations, assumed values for aerosol aluminum solubility (%Al_S), and the residence time of DAl in the surface mixed layer (SML). We apply this method to estimate dust deposition in the Bermuda Atlantic Time-series Study (BATS) region using water-column DAl data from cruises in 2019, which is compared with direct flux estimates from contemporaneous measurements of aluminum in aerosols and rain collected on Bermuda. Seasonal …

Shallow Water Coral Distribution And Its Response To Climate Change, Amaury De Jesus

Dissertations and Theses

Shallow water corals are one of the main reef-building organisms that secrete carbonates as their skeletons, and therefore, are one of the major sinks of CO2 in the ocean. These reef builders are also very crucial to marine environments and human society. As the global energy demand continues rising, fossil fuel burning increases at a faster pace despite the increase in energy supply using clean and renewable energy. The increase of CO2 in the atmosphere has been shown to exacerbate global warming and may cause ocean acidification, threatening the habitat of shallow-water corals. Many recent observations show alarming signs of …

Late Holocene Terrestrial Hydroclimate Reconstructions From Central And South American Sites, Brittany N. Price

Graduate Research Theses & Dissertations

Terrestrial records of hydroclimate variability from Central and South America were developed to better constrain previously unknown regional responses to a range of hydroclimate drivers in the recent past. Developing these late Holocene terrestrial hydroclimate records improves our understanding of past hydroclimate variability by increasing temporal resolution and allows us to further understand complexities in spatial dynamics of the climate system. From South-Central Chile, a geomorphic analysis of landforms emplaced in a glacial valley indicated a positive glacial mass balance in the recent past. A high-precision chlorine-36 chronology was developed from basaltic boulders, with additional minimum constraining ages from Araucaria …

Silting Dynamics And Metal Contaminants In The Georgetown Inner Harbor, Ezekiel Wil Meyers

Electronic Theses and Dissertations

The Georgetown inner harbor is an abandoned oxbow-like river loop and a vital historic site with a wealth of traditional businesses and heavy local industry located within Winyah Bay. Since the modification of the Sampit River in 1949, chronic rapid silting has plagued the inner harbor. With these substantial amounts of fine-grained material accumulating inside the inner harbor, business operations along the waterfront, navigational and maritime operations, and contamination within the harbor are of major concern. The goals of this study were to (a) understand the silting dynamics inside the inner harbor, (b) identify heavy metals which might be of …

Evaluating The Impact Of Submarine Groundwater Discharge On Nutrients And Trace Elements In Coastal Systems: The Examples Of The Tuckean Swamp (Australia) And The Mississippi Sound (Usa), Amy Moody

Dissertations

Submarine groundwater discharge (SGD) is the advective flow of both fresh terrestrial groundwater and recirculating seawater through aquifer sediments, which is released into the coastal ocean. In this dissertation, I evaluated the impact of SGD on the distributions and input of trace metals and nutrients. In the Tuckean Swamp, an estuary in Australia dominated by coastal acid sulfate soils, I determined the impact of groundwater on Ba and U during the flood season, when the local aquifer is flushed out after a rapid increase in water table elevation. For Ba and U, groundwater contributed up to 18 and 66 % …

Evaluation Of Carbon Isotopic Chemostratigraphy Of The Cedar Mountain Formation Of Utah, Clayton Forster

Graduate Theses and Dissertations

The Lower Cretaceous rocks of Utah preserve the origin of a multitude of dinosaur taxa, spread of angiosperms on the North American continent, and evolution of marsupial and eutherian mammals. However, the timing of deposition of these rocks is not well understood and must be determined to understand climatic controls on these biological events. Estimates of the age of the Cedar Mountain Formation and its constituent members range from Late Jurassic to early Late Cretaceous. Understanding the timing of deposition of the Cedar Mountain Formation is critical to dinosaurian and associated taxa studies as well as paleoclimate reconstructions from within …

Evaluating Alternative Ebullition Models For Predicting Peatland Methane Emission And Its Pathways Via Data–Model Fusion, Shuang Ma, Lifen Jiang, Rachel M. Wilson, Jeff P. Chanton, Scott Bridgham, Shuli Niu, Colleen M. Iversen, Avni Malhotra, Jiang Jiang, Xingjie Lu, Yuanyuan Huang, Jason Keller, Xiaofeng Xu, Daniel M. Ricciuto, Paul J. Hanson, Yiqi Luo

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Understanding the dynamics of peatland methane (CH4) emissions and quantifying sources of uncertainty in estimating peatland CH4 emissions are critical for mitigating climate change. The relative contributions of CH4 emission pathways through ebullition, plant-mediated transport, and diffusion, together with their different transport rates and vulnerability to oxidation, determine the quantity of CH4 to be oxidized before leaving the soil. Notwithstanding their importance, the relative contributions of the emission pathways are highly uncertain. In particular, the ebullition process is more uncertain and can lead to large uncertainties in modeled CH4 emissions. To improve model simulations of CH4 emission and its pathways, …

Empirical And Modeled Δ13c And Δ15n Isoscapes In The Gulf Of Mexico And Their Application To Fish Eye Lens Migration Studies, Brianna Michaud

USF Tampa Graduate Theses and Dissertations

Isoscapes are depictions of the spatial patterns of isotopic values in a given area. Isoscapes can be created using measurements form samples (empirical isoscapes) or using statistical models of spatial isotopic variation (modeled isoscapes). Isoscapes have a wide variety of potential applications though, in the realm of marine ecology, they are most often used infer ecological processes, food web linkages, the origin of samples, and the movements of marine organisms.

However, to use isoscapes for these applications, it is necessary to have isoscapes at spatial scales relevant to the application in question. It is also necessary to have isoscapes that …

Evaluating Holocene Precipitation Variability In The Baltic Region Using Oxygen Isotopes Of Lacustrine Carbonate From Estonia, Maxwell Gordon Boes

Graduate Research Theses & Dissertations

A high-resolution Holocene record of groundwater isotopic composition from eastern Europe enhances the current understanding of ocean atmosphere interactions and moisture transport dynamics. In the modern system, it has been established that the amount of regional winter precipitation is driven by the strength and direction of the sea level atmospheric pressure gradient over the Atlantic Ocean. This is defined by the North Atlantic Oscillation (NAO) index, that shows a positive correlation with precipitation amount during the cold season. This study aims to discover the link between atmospheric dynamics and the ratio of warm season to cold season precipitation through the …

Validation Of The Use Of Clathromorphum Compactum Growth And Skeletal Δ18o As A Proxy For Seawater Conditions, Teagan Mcmahon

Pitzer Senior Theses

Crustose coralline algae (CCA) are important organisms that create benthic habitat in the photic zone of oceans worldwide. CCAs mechanisms of photosynthesis and calcification may, in some cases, make them vulnerable to climate change and ocean acidification. Therefore, CCA are important not only for their ecological role within ecosystems but also for their ability to indicate the effects that ocean acidification and climate change may have on other marine calcifying organisms. Some species of CCA are known to be useful recorders of paleo oceanic conditions. These climate archives and reconstructions of past environmental conditions are important for understanding past changes …

The Influence Of Hydrogen Peroxide On The Enrichment Of Fe(Iii) Reducing Bacteria From Acid Mine Drainage, Susami Seth

Williams Honors College, Honors Research Projects

It is hypothesized that the ocean of Europa, a Jupiter moon, hosts bacteria on its oceanic floor. Understanding how Fe(III) reducing bacteria (FeRB) from AMD utilize organic materials within its surrounding environment outlines how FeRB could thrive and tolerate extreme conditions. FeRB are known to tolerate metals and highly reactive oxidants species (ROS), but in this experiment, H₂O₂ was the experimental factor to further test FeRB tolerance. H₂O₂ is a common ROS and is damaging to living material such as proteins, DNA, and RNA. A range of H₂O₂ concentrations were fed …

Analysis Of Titan's Fluvial Features Using Numerical Modeling, Jeshurun Horton

Mechanical Engineering Undergraduate Honors Theses

River channels have been observed near the Huygens probe landing site on the surface of Titan, along with evidence of rounded water ice boulders transported through fluid flow. Evidence near the landing site suggests active flow of liquid methane, which has motivated the study of the effects of sediment load and channel sizes on Titan’s fluvial features. A numerical model is used to determine the viscosity, flow velocity, and critical boulder transport diameter based on channel size, slope, and a range of sediment concentrations. This model achieves two ends: first, observed boulder diameters are used to determine the ideal channel …

Low Impact Sampling Of Speleothems – Reconciling Scientific Study With Cave Conservation, Claire L.V. Macgregor, John C. Hellstrom, Jon D. Woodhead, Russell N. Drysdale, Rolan S. Eberhard

International Journal of Speleology

Speleothems are increasingly valued as important paleoclimate archives and yet the removal of samples from caves can come at a cost to natural heritage, impacting delicate environments with limited mechanisms for repair. Conservation of cave environments is a key responsibility for scientists and, with this in mind, we are working to develop and implement techniques that allow us to extract valuable scientific data, with minimal impact. In this study, we demonstrate the utility of low-impact reconnaissance dating surveys on caves in southern Tasmania and southwest Western Australia as a precursor to the removal of stalagmites for paleoclimate reconstruction. Small flakes …

Hydrological Feedbacks On Peatland Ch4 Emission Under Warming And Elevated Co2: A Modeling Study, Fenghui Yuan, Yihui Wang, Daniel M. Ricciuto, Xiaoying Shi, Fengming Yuan, Thomas Brehme, Scott Bridgham, Jason Keller, Jeffrey M. Warren, Natalie A. Griffiths, Stephen D. Sebestyen, Paul J. Hanson, Peter E. Thornton, Xiaofeng Xu

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Peatland carbon cycling is critical for the land–atmosphere exchange of greenhouse gases, particularly under changing environments. Warming and elevated atmospheric carbon dioxide (eCO₂) concentrations directly enhance peatland methane (CH₄) emission, and indirectly affect CH₄ processes by altering hydrological conditions. An ecosystem model ELM-SPRUCE, the land model of the E3SM model, was used to understand the hydrological feedback mechanisms on CH₄ emission in a temperate peatland under a warming gradient and eCO₂ treatments. We found that the water table level was a critical regulator of hydrological feedbacks that affect peatland CH₄ dynamics; the …

Continuous Color Model As A Tool To Improve Speleothem Age Model Development, Celia Campa-Bousoño, Ángel García-Pérez, Ana Moreno, Miguel Iglesias, Hai Cheng, R Lawrence Edwards, Heather Stoll

International Journal of Speleology

Because they can archive a variety of geochemical proxies and be precisely and accurately dated with the U-Th decay series chronometer, stalagmites are widely used for paleoclimate reconstructions. However, limitations in the use of this chronometer arise because U-Th dating is analytically time consuming, expensive, and requires a relatively large sample size. These limitations restrict the number of absolute dates usually obtained, which can result in significant uncertainties in the age model and inhibit the ability to archive high resolution records of environmental variability, particularly in those stalagmites where there are variations in growth rate not constrained by U-Th dates. …

Archaeology And Seasonality Of Stock Island (8mo2), A Glades-Tradition Village On Key West, Ryan M. Harke

USF Tampa Graduate Theses and Dissertations

Later Glades-period cultures (ca. 500–1760 CE) of south Florida and the Florida Keys are understudied and thus poorly understood, especially those that pre-date the arrival of Spaniards to the New World. Recent archaeological models of their sociopolitical organization suggest that by the Glades I-II transition (750/800 CE), south Florida peoples were organized into what appear to be regional population centers (e.g., Pineland and Mound Key, Granada, Turner River) and smaller hinterland towns in the Everglades (e.g., Cane Patch, Bear Lake) and the Florida Keys (e.g., Stock Island, Clupper Site). Smaller towns are hypothesized to be sedentary, heterarchically-organized, simple chiefdoms from …

Past Ice-Ocean Interactions On The Sabrina Coast Shelf, East Antarctica: Deglacial To Recent Paleoenvironmental Insights From Marine Sediments, Kara J. Vadman

USF Tampa Graduate Theses and Dissertations

The East Antarctic Ice Sheet (EAIS) contains ~53 meters of sea level equivalent (SLE) ice, and observations suggest it is sensitive to ongoing and past climate change. The EAIS has traditionally been considered insensitive to climate perturbations because it is largely grounded above sea level. However, aerogeophysical surveys, oceanographic observations, and models indicate that large areas of the EAIS are grounded below sea level and contain 19.2 m SLE. Marine-based parts of the EAIS are thought to be located on inland-sloping beds that drain through marine terminating outlet glaciers, indicating large areas of the EAIS may be more sensitive to …

Changes In Tropospheric Ozone Associated With Strong Earthquakes And Possible Mechanism, Feng Jing, Ramesh P. Singh

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The index of ozone anomaly (IOA) has been proposed to detect changes in tropospheric ozone associated with strong earthquakes. The tropospheric ozone prior and after the 2008 Wenchuan earthquake has been analyzed using IOA. Atmospheric infrared sounder ozone volume mixing ratio (O3 VMR) at different pressure levels (600, 500, 400, 300, 200 hPa) for an 18-year period 2003–2020 has been considered to identify the unique behavior associated with the strong earthquakes. Our results show distinct enhancement in tropospheric ozone occurred 5 d (7 May 2008) prior to the main event and distributed along the Longmenshan fault zone. An enhancement in …

Diversity – Independent Factors Predict Elevated Extinction Rates, Dustin Perriguey, Corinne Myers, Jason Moore, Louis Scuderi

Earth and Planetary Sciences ETDs

Multiple linear regression was used to determine the relationships between diversity-independent factors (i.e., abiotic, climatic) 2, 5, and 10 Myrs-prior to the most elevated Phanerozoic extinctions. We constructed five abiotic variables from Phanerozoic proxy records1–5 to compare to extinction rates: mean temperature, temperature instability, carbon cycle instability, continental weathering rates, and habitat instability. All three models were statistically significant (P < 0.05) and explained > 70% of the variation in Alroy’s6 three-timer generic extinction rates. However, the 2 Myr-prior model explained the most variance in extinction rates and had the most predictive power, based on adjusted and predictive R2 (~ 72% and 41%, respectively). Carbon …

Characterization Of Uranium, Lead, And Rare Earth Element Pollution In Natural Soils And Sediments, Hope Rasmussen

Civil and Environmental Engineering Theses and Dissertations

Heavy metals in the environment add to the global burden of pollution, negatively impacting public health and ecosystem resilience. This study included projects regarding uranium (U), lead (Pb), and rare earth elements (REE) in natural samples, due to their known toxicity, ubiquity, and relevance in context to recent pollution trends. The first project focused on testing the potential of using a hydroxyapatite product as a remediation solution for U-contaminated groundwater and soil at an EPA Superfund site. The results showed that the U was sequestered in a highly crystalline mineral form within the solids, guiding the EPA to specify the …

Reconstructing Surface Water Carbonate Ion Concentration Changes In The Eastern Equatorial Pacific Across Glacial Transitions, Lenzie Gail Ward

OES Theses and Dissertations

Today, the eastern equatorial Pacific (EEP) plays a critical role in the global CO₂ budget as a major source of CO₂ to the atmosphere, but recent studies suggest the region may shift to a sink for atmospheric CO₂ under different climate states. Here, I focus on two transitional periods, the last deglaciation (25 kyr to present) and last glaciation (the Marine Isotope Stage (MIS) 5a-4 transition, 96 to 60 kyr), to investigate how the carbon system in the EEP responds to major climate changes. I measured B/Ca ratios in the planktic foraminifera Globigerina bulloides from core MV1014-17JC …

Investigating The Impact Of Meteoric Diagenesis On The Geochemistry Of Carbonate Eolianites, Eleuthera And Water Cay, The Bahamas, Graham S. Bonnot

LSU Master's Theses

The geochemical signatures imparted in major, minor, and trace elements, combined with light isotopes, suggest promising applications regarding the stabilization of meteorically altered limestone eolianites. Previous high-resolution studies have indicated that elements associated with carbonate diagenesis such as Mg and Sr can be valuable proxies for salinity and aragonite dissolution, respectively. In addition to testing these proxies, the analyses of several temperature-, diagenetic-, bioactive-, and redox-sensitive elements were evaluated using laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) to identify additional indicators during carbonate diagenesis. Two geochemical drivers of U were identified; (1) aragonite dissolution similar to Sr and (2) oxidation …

Coastal Watershed Monitoring And Management: Geomorphology, Geochemistry, And Hydrologic Modeling Of Los Peñasquitos Creek, Ca, Ravleen Khalsa-Basra

Theses

Rivers in semi-arid climates are directly influenced by local geographic and hydrologic conditions and impacted by modifications to hydrology via urbanization. Changes can influence erosion, morphology, habitat sustainability, and watershed health. In highly urbanized southern California coastal regions, these rare open spaces provide vital ecosystem services. Los Peñasquitos Creek in San Diego County is one such watershed. Using stream surveying and laboratory methods we quantified channel characteristics, grain size distribution, total metal concentration [M], organic carbon (%OC), and phosphate to longitudinally characterize the creek for improved management. Results identified three distinct reaches in the watershed (upper, middle, lower). Downstream, depth …

The 3H/3He Groundwater Age-Dating Method And Applications, Troy E. Gilmore, Mikaela L. Cherry, Didier Gastmans, Douglas Kip Solomon, Eric Christopher Humphrey

School of Natural Resources: Faculty Publications

Groundwater age-dating is an important tool for quantifying and managing water resources. Groundwater age is the elapsed time between recharge (at the land surface or water table) and the time when groundwater is sampled. If groundwater is sampled at the point of discharge from an aquifer, then the age represents the groundwater transit time. Groundwater that has recharged in recent decades is considered young groundwater. In many areas, the quality and quantity of young groundwater has been impacted by human activities and groundwater age-dating is useful for quantifying current and historical water and contaminant fluxes into and through aquifers. This …

Sodium-Calcium Ratios In The Planktic Foraminifera Trilobatus Sacculifer As A Proxy For Sea Surface Salinity, Colton Steele Watkins

OES Theses and Dissertations

Recent culture and field studies have found a significant positive correlation between seawater salinity and the incorporation of sodium into foraminiferal calcite, suggesting a potential new proxy for reconstructing past changes in sea surface salinity (SSS) (Mezger et al., 2016 and Bertlich et al., 2018). In order to test the applicability of this new proxy in an open-ocean setting, Na/Ca ratios in the planktic foraminifera Trilobatus sacculifer (T. sacculifer Na/Ca) were measured from a suite of sediment core tops spanning a natural salinity gradient from the North Atlantic subtropical gyre to the South Atlantic subtropical gyre. Initial results from …

Plio-Pleistocene Antarctic Ice-Ocean Interactions In The Ross Sea, Catherine Prunella

USF Tampa Graduate Theses and Dissertations

Warm, intermediate-depth Southern Ocean waters are implicated in recent Antarctic ice mass loss. Direct observations of Antarctic Ice Sheet (AIS) retreat are temporally limited, necessitating paleoceanographic records of ocean-ice interactions during past warm climate intervals. Deepsea and ice-proximal sediments record orbitally-paced glacial-interglacial fluctuations in AIS volume during the Plio-Pleistocene (last 5 million years; Ma), but the total contribution of the AIS and the role of ocean heat in these fluctuations remain unresolved. To address the response of Antarctica’s ice sheets to changing ocean temperatures during the Plio-Pleistocene, International Ocean Discovery Program (IODP) Expedition 374 recovered sediments from the Ross Sea …

Historical And Future Antarctic Precipitation Based On Cmip5 Models, Reanalysis Data And In Situ Measurements, Malcolm Tang Siong Yii

Student Works (2020-2029)

The study of precipitation in Antarctica is one of the most studied research topics today. The reliability and accuracy of climate models in simulating Antarctic precipitation, however, are still debatable. Measuring precipitation in Antarctica poses many distinctive challenges. This work attempts to establish a comprehensive study of precipitation in Antarctica. The first part of the study assesses a year-long measurements from five precipitation instruments with reanalysis datatsets and satellite data. The tipping bucket gauges (TBGs) were observed to be less sensitive compared to laser-based sensors (LBSs). Case studies of the daily precipitation and seasonal precipitation measurements showed VPF-730 to be …

Iron Speciation In Pm2.5 From Urban, Agriculture, And Mixed Environments In Colorado, Usa, Joseph R. Salazar, David J. Pfotenhauer, Frank Leresche, Fernando L. Rosario-Ortiz, Michael P. Hannigan, Sirine C. Fakra, Brian Majestic

Chemistry and Biochemistry: Faculty Scholarship

Atmospheric iron solubility varies depending on whether the particles are collected in rural or urban areas, with urban areas showing increased iron solubility. In this study, we investigate if the iron species present in different environments affects its ultimate solubility. Field data are presented from the Platte River Air Pollution and Photochemistry Experiment (PRAPPE), aimed at understanding the interactions between organic carbon and trace elements in atmospheric particulate matter (PM). 24-hr PM2.5 samples were collected during the summer and winter (2016–2017), at three different sites on the Eastern Colorado plains: an urban, agricultural, and a mixed site. Downtown Denver had …

Phosphorus Variability In The Area Of Influence Of The Mid-Barataria Sediment Diversion, Peter Mates

LSU Master's Theses

Man-made levees along the lower Mississippi River prevent delivery of sediment from building and maintaining Louisiana’s coastal wetlands. The Mid-Barataria sediment diversions is designed to reintroduce Mississippi River water, sediment, and nutrients into the sediment-starved Barataria Basin. Phosphorus (P) is an important macronutrient for regulating primary production in coastal marine ecosystems. Wetlands can serve as a sink or source for phosphorus to the overlying water column through various retention and release processes, dependent on concentration. Louisiana coastal systems can be phosphorus limited due to much higher concentrations of bioavailable Nitrogen in river water. The high soluble molar N:P ( >50:1) …

Investigating The Isotope Signatures Of Dissolved Iron In The Southern Atlantic Ocean, Brent A. Summers

USF Tampa Graduate Theses and Dissertations

Iron (Fe), used as a cofactor in nitrogen fixation and photosynthesis by oceanic microorganisms, has extremely low dissolved concentrations in the surface ocean, leading to widespread limitation of phytoplankton growth. Dissolved Fe isotope ratios (δ56Fe) have been shown to be useful in helping to quantify the sources and cycling of Fe in the oceans if Fe source signatures and fractionation processes are well understood. Here, this thesis presents data from GEOTRACES section GA10W, and investigate the isotopic signature of sediment-derived dissolved Fe from the South Atlantic margins. My results show that there are both shallow (δ56Fe of -0.2‰) and deep …