Geochemistry Commons^™

Groundwater Contamination At Coal Ash Deposit Sites In Kentucky, Brandon Rose

Scholars Week

No abstract provided.

Spatial And Temporal Trends Of Mining-Related Lead-Zinc Sediment Contamination, Galena River Watershed, Sw Wisconsin-Nw Illinois, Dylan Alexander King

Graduate Theses/Dissertations

Alluvial sediments within the Galena River Watershed were severely contaminated with heavy metals by historical zinc (Zn) and lead (Pb) mining operations during the early 1800s until 1979. Since the mines closed, there have been efforts to remediate on-site mine waste. However, the effectiveness of these efforts to reduce metal concentrations in stream sediments is unknown. This study compares present-day (2017) contamination trends in the Galena River Watershed to trends reported 25 years ago. A total of 415 sediment/soil samples were collected and analyzed using X-ray florescence spectrometry to determine sediment metal concentrations. The highest concentrations of zinc measured were …

Extremely High Diversity Of Sulfate Minerals In Caves Of The Irazú Volcano (Costa Rica) Related To Crater Lake And Fumarolic Activity, Andrés Ulloa, Fernando Gázquez, Aurelio Sanz-Arranz, Jesús Medina, Fernando Rull, José María Calaforra, Guillermo E. Alvarado, María Martínez, Geoffroy Avard, J. Maarten De Moor, Jo De Waele

International Journal of Speleology

The caves of the Irazú volcano (Costa Rica), became accessible after the partial collapse of the NW sector of the Irazú volcano in 1994, offering the opportunity to investigate active minerogenetic processes in volcanic cave environments. We performed a detailed mineralogical and geochemical study of speleothems in the caves Cueva los Minerales and Cueva Los Mucolitos, both located in the northwest foothills of the main crater. Mineralogical analyses included X-ray diffraction (XRD) and Raman spectroscopy, while geochemical characterization used Energy Dispersive X-ray spectroscopy (EDX) coupled to Scanning Electron Microscopy (SEM). In addition, measurements of environmental parameters in the caves, …

Drip Water Measurements From Carlsbad Cavern: Implications Towards Paleoclimate Records Yielded From Evaporative-Zone Stalagmites, Victor J. Polyak, Jessica B.T. Rasmussen, Yemane Asmerom

International Journal of Speleology

Stalagmites can host numerous potential climate proxies (stable and radiogenic isotopes, trace elements, annual and non-annual banding, grayscale, growth hiatuses, mineral assemblage). Reproducibility and/or integration of proxy results between one or more stalagmites will become increasingly important, and ideally, climate records generated by multiple stalagmites from the same cave or cave room are expected to be near-identical. The reality is that stalagmites from the same cave room can yield differing results to some degree, especially in cave environment zones that are evaporative. Our drip water study in an evaporative shallow-depth cave environment in Carlsbad Cavern shows that adjacent drip sites …

Predicting Spatial Patterns In Precipitation Isotope (Δ2h And Δ18o) Seasonality Using Sinusoidal Isoscapes, Scott T. Allen, James W. Kirchner, Gregory R. Goldsmith

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Understanding how precipitation isotopes vary spatially and temporally is important for tracer applications. We tested how well month‐to‐month variations in precipitation δ18O and δ2H were captured by sinusoidal cycles, and how well spatial variations in these seasonal cycles could be predicted, across Switzerland. Sine functions representing seasonal cycles in precipitation isotopes explained between 47% and 94% of the variance in monthly δ18O and δ2H values at each monitoring site. A significant sinusoidal cycle was also observed in line‐conditioned excess. We interpolated the amplitudes, phases, and offsets of these sine functions across the landscape, using multiple linear …

Quantifying Factors That Influence Road Deicer Retention And Export In A Multi-Landuse Upstate New York Watershed, David Joseph Saba

Graduate Dissertations and Theses

Chloride contamination of streams and groundwater has become a prevalent issue throughout urbanizing areas in the last half century, particularly in northern latitudes where deicing salts are applied to roadways. This study determined how deicer impacted runoff disperses through sub-urban and urban areas on seasonal and multi-year scales. Chloride concentration changes were then modelled under varying pollutant loading scenarios through an integrated catchment model (INCA-Cl).

Six in-stream conductivity/stage/temperature sondes, recording at 15-minute intervals, were installed within the small (~9.6 km2) Fuler Hollow Creek multi-landuse watershed in Broome County NY and monitored over a 1-year period. Weekly grab samples were taken …

Chemical And Statistical Analysis Of Karst Groundwater Basin Signatures - Springfield, Mo, Benjamin E. Lockwood

Graduate Theses/Dissertations

Springfield, MO is located on the Springfield Plateau physiographic province. The Springfield plateau contains a number of Mississippian aged units and is mainly capped by the Burlington-Keokuk Formation. The Burlington-Keokuk is a highly fossiliferous limestone with nodular and interbedded chert. Beneath the Burlington-Keokuk lies the Elsey, Reeds Spring, and Pierson Formations respectively which comprise the Springfield Plateau aquifer hydrostratigraphic unit. Within the Springfield Plateau aquifer, a well-developed karst system includes springs, sinkholes, and caves. The Springfield Plateau aquifer is the predominant source for springs and seeps in the Springfield area. The purpose of this study was to understand the differences …

Geochemical Dynamics And Nitrous Oxide Release From The Hyporheic Zone Of Streams, Annika Marie Quick

Boise State University Theses and Dissertations

The hyporheic zones of streams and rivers, consisting of the sediments beneath and immediately adjacent to the stream channel, are an important site of geochemical processing. Due to the difficulty of measuring these geochemical processes in the hyporheic zone in situ with meaningful spatial and temporal resolution, we conducted multiple column and large-scale flume experiments to model 1D and 2D hyporheic flow paths and observed important geochemical reactions, including the production and consumption of nitrous oxide (N₂O). N₂O is a significant greenhouse gas, but the controls on its emissions from streams are poorly constrained. We describe …

Landscapes From The Waves—Marine Terraces Of California, Marjorie Schulz, Corey Lawrence, Daniel R. Muhs, Carol Prentice, Sam Flanagan

United States Geological Survey: Publications

M any coastlines around the world have stair-step landforms, known as marine terraces. Marine terraces make up a large part of coastal California’s landscape—from San Diego to Crescent City. Find out how these landscapes form, why marine terraces are of interest to scientists, and where you can explore these landscapes.

Marine terraces result from the interaction of two geologic processes: uplift of the land surface and the natural rise and fall of sea level over hundreds of thousands of years. As sea level rises, waves move underwater sediment—sand and gravel—back and forth against bedrock, acting like sandpaper to hone bedrock …

The Pothole Hydrology-Linked Systems Simulator (Phyliss)—Development And Application Of A Systems Model For Prairie-Pothole Wetlands, Owen P. Mckenna, David M. Mushet, Eric J. Scherff, Kyle I. Mclean, Christopher T. Mills

United States Geological Survey: Publications

The North American Prairie Pothole Region covers about 770,000 square kilometers of the United States and Canada (including parts of 5 States and 3 provinces: North Dakota, South Dakota, Montana, Minnesota, Iowa, Saskatchewan, Manitoba, and Alberta). The Laurentide Ice Sheet shaped the landscape of the region about 12,000 to 14,000 years ago. The retreat of the ice sheet left behind low-permeability glacial till and a landscape dotted with millions of depressions known today as prairie potholes. The wetlands that subsequently formed in these depressions, prairie-pothole wetlands, provide critical migratory-bird habitat and support dynamic aquatic communities. Extensive grasslands and productive agricultural …

Appendix 1. Testing The Influence Of Management Regime And Year On Vegetation Structure Variables On Two Grass Types On Federal Lands Managed Under An Adaptive-Management Framework By The U.S. Fish And Wildlife Service In North Dakota, South Dakota, Minnesota, And Montana, 2011–13, J.J Gannon, T.L. Shaffer, C.T. Moore

United States Geological Survey: Publications

Generalized linear mixed model (assuming a beta distribution with a logit link) testing the influence of management regime and year on mean bare-ground cover (percent) on two grass types on Federal lands managed under an adaptive-management framework by the U.S. Fish and Wildlife Service (Gannon and others, 2013) in North Dakota, South Dakota, Minnesota, and Montana, 2011–13.

Assessing The Impact Of The Conservation Reserve Program On Honey Bee Health, Otto, C.R.V., O'Dell, S., Bryant, R.B., Euliss, N.H., Bush

United States Geological Survey: Publications

Insect pollinators are critically important for maintaining U.S. food production and ecosystem health. The upper Midwest is home to more than 40 percent of all U.S. honey bee colonies and is considered by many beekeepers to be America’s last beekeeping refuge. Beekeepers come to this region because their honey bees require high-quality grassland and bee-friendly agricultural crops to make honey and to improve bee health. Agricultural grassland, such as those enrolled in the Conservation Reserve Program (CRP), support flowers that provide bees with the pollen and nectar they need. In 2014, the U.S. Department of Agriculture (USDA) and the U.S. …

Adaptive Management In Native Grasslands Managed By The U.S. Fish And Wildlife Service—Implications For Grassland Birds, Lawrence D. Igl, Welsey E. Newton, Todd A. Grant, Cami S. Dixon

United States Geological Survey: Publications

Burning and grazing are natural processes in native prairies that also serve as important tools in grassland management to conserve plant diversity, to limit encroachment of woody and invasive plants, and to maintain or improve prairies. Native prairies managed by the U.S. Fish and Wildlife Service (FWS) in the Prairie Pothole Region of the northern Great Plains have been extensively invaded by nonnative, cool-season species of grasses. These invasions were believed to reflect a common management history of long-term rest and little or no defoliation by natural processes (burning and grazing). To address the challenges associated with these invasive species, …

Using Multiple Environmental Tracers To Investigate The Relative Role Of Soil And Deep Groundwater In Stream Water Generation For A Snow-Dominated Headwater Catchment, Isabellah V. Von Trapp

Graduate Student Theses, Dissertations, & Professional Papers

In this study, seasonal fluctuation of environmental tracers in stream flow, soil water, and deep bedrock groundwater were used to constrain the role of deep bedrock groundwater in streamflow generation for a mountainous headwater catchment. Synoptic measurements of stream discharge, ²²²Rn, specific conductivity and major ion concentrations were measured throughout the water year over a 5 km reach of Cap Wallace Creek in the Lubrecht Experimental Forest, Montana, U.S.A. with the intention of understanding groundwater – surface water interactions across spatial and temporal scales. Stage measurements were continually recorded at seven stilling well locations along the reach. Discharge measurements …

Geophysical Delineation Of Megaporosity And Fluid Migration Pathways For Geohazard Characterization Within The Delaware Basin, Culberson County, Texas, Jonathan David Woodard

Electronic Theses and Dissertations

ABSTRACT

Differential dissolution of gypsum karst within the Delaware Basin poses a significant threat to infrastructure that society depends on. The study area is located in Culberson County, Texas and traverses a distance of approximately 54 kilometers along RM 652 within the Gypsum Plain which is situated on the northern margin of the Chihuahua Desert and includes outcrops of Castile and Rustler strata that host karst geohazards. Regions of karst geohazard potential have been physically surveyed proximal to the study area in evaporites throughout the Castile Formation outcrop; minimal hazards, in comparison to the Castile Formation, have been documented in …

Cave Monitoring In The Béke And Baradla Caves (Northeastern Hungary): Implications For The Conditions For The Formation Cave Carbonates, György Czuppon, Attila Demény, Szabolcs Leél-Őssy, Mihály Óvari, Mihály Molnár, József Stieber, Klaudia Kiss, Krisztina Kármán, Gergely Surányi, László Haszpra

International Journal of Speleology

In order to use speleothems in the reconstruction of past climate and environmental changes it is necessary to understand the environmental and hydrological processes that determine the physico-chemical conditions of carbonate precipitation and hence speleothem formation. Therefore, in this study an extended monitoring program was conducted in the Béke and Baradla caves located in the Aggtelek region (Northeastern Hungary). The studied caves are rich in speleothem and flowstone occurrences with great potential for paleoclimatology studies. The monitoring activity included measurements of atmospheric and cave temperatures, CO₂ concentration in cave air, as well as chemical and isotopic compositions of water …

Bonneville Basin Data, Larry V. Benson

United States Geological Survey: Datasets

In the Bonneville Basin folder, all data were reported in: Benson, L.V., Lund, S.P., Smoot, J.P., Rhode, D.E., Spencer, R.J., Verosub, K.L., Louderback, L.A., Johnson, C.A., Rye, R.O., Negrini, R., 2011. The rise and fall of Lake Bonneville between 45 and 10.5 ka. Quaternary International 235: 57-69.

http://digitalcommons.unl.edu/usgsstaffpub/726

General Comment: in most cases an age model based on ¹⁴C analyses is not included with the data sets although ones were created for the original publications. Given the general problems with ¹⁴C ages in the lakes of the Great Basin, age models based on paleomagnetic secular variation (PSV) are …

Groundwater And Subsurface Water In A Landscape With Shallow Bedrock: Implications For Agricultural Nutrient Export, Laura Kelley, Hunter R. Evans, Reid E. Buskirk, Jonathan M. Malzone, Walter S. Borowski

EKU Faculty and Staff Scholarship

Controls on nutrient export from agricultural landscapes include regional hydrological and geological conditions. In many central Kentucky basins shallow fractured bedrock produces focused groundwater discharge and flashy runoff events. Eastern Kentucky University’s Meadowbrook Farm is currently experimenting with nutrient sequestration techniques; however the effectiveness of these techniques given the local hydrogeology needs to be quantified. Our objective was to determine the potential pathways for nutrient export by mapping key hydrologic features and using a watershed approach. The key features mapped were springs, tile drains, runoff channels, land use and the underlying geology. We chose a 0.46 km² watershed to …

Diurnal And Seasonal Variation In Groundwater Nitrate -N Concentration In A Saturated Buffer Zone, Joseph Miller

Theses and Dissertations

Surface water pollution by nitrate (NO3-) is identified as a critical problem in agricultural land-use areas. Excess NO3- loading causes eutrophication and hypoxia in near-shore marine waters such as the Gulf of Mexico. Diversion of agricultural runoff into saturated buffer zones reduces NO3- loading. Although the mechanisms responsible for NO3- reduction in saturated buffer zones are well characterized, little is known about how NO3- concentrations vary temporally and what factors control those changes. The objective of this study is to understand NO3- concentration and environmental factor variability in a saturated buffer zone on a diurnal scale within and among the …

Sedimentary Characteristics And Nutrient Sequestration Of Embanked Floodplains Along The Lower Mississippi River, Mississippi And Louisiana, R M Malitha Rathnayake

Master's Theses

The Mississippi River Basin is the largest river basin in North America and the third largest river basin in the world. Most of the corn, soybeans, wheat, cattle, and hogs harvested in the United States come from the Mississippi River Basin and about 58% of the entire drainage basin is croplands. Runoff from these lands carries sediments and nutrients, and the Mississippi River transports these downstream and ultimately deposits them in the Gulf of Mexico. The northern Gulf of Mexico is one of largest human-caused hypoxic zones in the world. Hypoxia is the phenomena where the dissolved oxygen level decreases …

Trace Chemical Evaluation Of Cloud Seeding In The Payette Basin, James Mitchell Fisher

Boise State University Theses and Dissertations

Glaciogenic cloud seeding increases the fraction of super cooled liquid water precipitating from a given storm. Orographic clouds tend to be inefficient at higher cloud temperatures due to the lack of active natural ice nuclei. Adding artificial ice nuclei active at temperatures greater than -12^oC (where most natural ice nuclei are inactive) may result in an increase in snow precipitation, especially in orographic clouds. Silver iodide (AgI) is typically the artificial nucleating agent for winter orographic cloud seeding. Recent estimates suggest the addition of AgI to orographic storm clouds enhance precipitation by 3 - 15%. However, the National …

Tracking Potential Leakage Of Tailings-Lake Water Into Background Groundwater In Butte, Montana, Using Geochemical And Stable Isotope Tracers, Matthew Berzel

Graduate Theses & Non-Theses

This study was conducted to identify environmental tracers using water chemistry and stable isotopes in the Moulton Road area adjacent to the Yankee Doodle tailings impoundment north of Butte, Montana. The water level of the tailings lake is being raised as tailings slurry is pumped up to the impoundment, and numerous residential wells are located in close proximity. Although it has an alkaline pH (> 9), the water in the tailings lake is much higher in some chemical constituents than the wells and some of these constituents could be used as tracers to determine if lake water is migrating out …

Petrographical And Geochemical Changes In Bosnian Stalagmites And Their Palaeo-Environmental Significance, Veronica Chiarini, Isabelle Couchoud, Russell Drysdale, Petra Bajo, Simone Milanolo, Silvia Frisia, Alan Greig, John Hellstrom, Jo De Waele

International Journal of Speleology

Detailed petrographic observations have been coupled with trace element and δ¹³C - δ¹⁸O analyses in order to investigate their dynamics in two Holocene Bosnian speleothems. The potential of this multiproxy approach in providing a means to extract palaeo-environmental information from stalagmites whose stable isotope signals are noisy and without obvious trends has been tested. The studied stalagmites are mostly characterized by columnar microcrystalline fabric. At the sub-millimetre scale of lamination, different microcrystalline columnar sub-types (open and closed) have been detected and classified on the basis of the observed porosity and the crystallite size. The presence of …

Mono Lake Data, Larry V. Benson

United States Geological Survey: Datasets

Mono Lake Basin Data\ Depth CalAge TIC TOTC TOC 13C 18O

Mono Lake short cores.xlsx 03.03.2014 19:59:44 0.06 xlsx

Depth PSV age 18O 13C

TIC for Wilson Crk Fm.xlsx 02.03.2014 16:07:10 0.03 xlsx

Ostracode 18O and TE data Wilson Crk Fm.xlsx 10.11.2017 17:43:18 0.12 xlsx

Depth, calendar age, TIC, TOTC, TOC, ¹³C, and ¹⁸O of Mono Lake short cores were reported in:

Benson, L., Linsley, B., Smoot, J., Mensing, S., Lund, S., Stine, S., and Sarna-Wojcicki, A., 2003, Influence of the Pacific Decadal Oscillation on the climate of the Sierra Nevada, California and Nevada: Quaternary Research. Quaternary Research …

Summer Lake Basin Data, Larry V. Benson

United States Geological Survey: Datasets

Summer Lake Basin

Name Date modified Time modified Size MB Extension

Summer Lake Basin\

Depth PSV Age 13C 18O Summer Lake B&B core.xlsx 03.03.2014 16:51:12 0.03 xlsx

In the Summer Lake Basin folder:

Depth, PSV age, ¹⁸O, ¹³C data for Summer Lake core B&B are reported in:

Benson, L., Lund, S., Negrini, R., Linsley, B., and Zic, M. 2003. Response of North American Great Basin lakes to Dansgaard-Oeschger oscillations. Quaternary Science Reviews 22: 2,239-2,251.

General Comment: In most cases an age model based on ¹⁴C analyses is not included with the datasets although ones were created for …

Great Basin Surface Water And Precipitation Isotope Data, Larry V. Benson

United States Geological Survey: Datasets

In the Great Basin Surface Water and Precipitation Isotope Data folder:

Farad, Nixon, and Pyramid Lake 18O data were reported in:

Benson, L.V., 1994, Stable isotopes of oxygen and hydrogen in the Truckee River-Pyramid Lake surface-water system. 1. Data analysis and extraction of paleoclimatic information: Limnology and Oceanography, vol. 39, p. 344-355. https://digitalcommons.unl.edu/usgsstaffpub/1015

Spring chemistry around Pyramid Lake data were reported in:

Benson, L.V., 1994, Carbonate deposition, Pyramid Lake subbasin, Nevada: 1. Sequence of formation and elevational distribution of carbonate deposits (tufas): Palaeogeography, Palaeoclimatology, Palaeoecology, vol. 109, p. 55-87.

Benson, L.V., Kashgarian M., and Rubin, M., 1995, Carbonate deposition, …

Owens Lake Core Data, Larry V. Benson

United States Geological Survey: Datasets

In the Owens Lake core data folder:

¹⁴C ages for cores OL84 and OL90 were reported in:

Benson, L.V., Burdett, J.W., Kashgarian, M., Lund, S.P., Phillips, F.M., and Rye, R.O., 1996, Climatic and hydrologic Oscillations in the Owens Lake basin and adjacent Sierra Nevada, California: Science, vol. 274, p. 746-749.

Benson, L.V., 1999, Records of millennial-scale climate change from the Great Basin of the Western United States: In Clark, P., Webb, R., Keigwin, L., eds., Mechanisms of Global Climate Change at Millennial Time Scales, American Geophysical Union Monograph 112, p. 203-225.

Benson, L., 2003, Western Lakes: Chapter 9 in …

Paleomagnetic Secular Variation (Psv) Ages Of Wilson Crk, Plc08-1, Bl04-4, Ol90-1 And 2, Larry V. Benson

United States Geological Survey: Datasets

In the paleomagnetic secular variation (PSV) ages folder:

The data for OL90-1 and 2 have not been published

The data for PLC08-1 are reported in:

Benson, L.V., Smoot, J.P., Lund, S.P., Mensing, S.A., Rye, R.O., 2013. Insights from a synthesis of old and new climate-proxy data from the western Lahontan Basin for the period 48 to 11.5 ka. Quaternary International310, 62-82.

Lund, S., Benson, L., Negrini, R., Liddicoat, J., Mensing, S., 2016. A full-vector paleomagnetic secular variation record (PSV) from Pyramid Lake (Nevada) from 47-17 ka: Evidence for the successive Mono Lake and Laschamp Excursions. Earth and Planetary Sciences …

Pyramid And Winnemucca Lake Basin Carbonate Data, Larry V. Benson

United States Geological Survey: Datasets

In the Pyramid and Winnemucca lake basin carbonate data folder:

New unpublished and previously published ¹⁴C and calibrated ages for materials in the Winnemucca Caves are reported in the table and in the references listed below the table

¹⁴C and calibrated ages for Winnemucca Lake Basin carbonates are reported in:

Benson, L.V., Hattori, E.M., Southon, J., Aleck, B., 2013. Dating North America’s oldest petroglyphs, Winnemucca Lake subbasin, Nevada. Journal of Archaeological Science 40, 4466-4476.

Tufa ⁸⁷Sr, ¹⁸O, and ¹³C data are reported in:

Benson, L.V., Smoot, J.P., Lund, S.P., Mensing, S.A., Rye, R.O., 2013. Insights …

Reconstructed Discharge For Truckee River, Larry V. Benson

United States Geological Survey: Datasets

Reconstructed Discharge for Truckee River

Name Date modified Time modified Size MB Extension

Reconstructed Discharge Truckee R\ Reconstructed Discharge for Truckee River.xlsx 11.11.2017 22:40:52 0.02 xlsx

Reconstructed discharge of the Truckee River was made considering losses to evaporation in all upstream reservoirs and corrected for diversion from the Derby Dam to the Newlands area. These data were never previously published.

General Comment: In most cases an age model based on ¹⁴C analyses is not included with the datasets although ones were created for the original publications. Given the general problems with ¹⁴C ages in the lakes of the …