Geochemistry Commons^™

Walker Lake Basin Data, Larry V. Benson, Steve P. Lund

United States Geological Survey: Datasets

Walker Lake Basin Data

Name Date modified Time modified Size MB Extension

Walker Lake Core 84-8 isotope and age data.xls 27.01.2018 15:25:52 0.03 xls

Walker Lake core WL002 PSV age and chemical data.xlsx 09.02.2018 20:04:50 0.03 xlsx

In the Walker Lake Basin folder:

Depth, ¹⁴C age (not corrected for reservoir effect), ¹⁸O, ¹³C data for core 84-8 are reported in:

Benson, L. V., 1988, Preliminary paleolimnologic data for the Walker Lake subbasin, California and Nevada: United States Geological Survey Water-Resources Investigations Report 87-4258, 50 p. Palaeogeography, Palaeoclimatology, Palaeoecology 240: 497-507.

Depth, PSV age, TIC , ¹⁸O, …

Pyramid Lake Core Data, Larry V. Benson

United States Geological Survey: Datasets

Pyramid Lake Core Data

14C and calibrated ages for core PLC08-1.xlsx 01.03.2014 19:45:30 0.01 xlsx

14C and calibrated ages for core PLC92B.xlsx 04.03.2014 16:41:30 0.01 xlsx

14C and calibrated ages for core PLC97-3.xlsx 01.03.2014 19:50:48 0.01 xlsx

CalKa Depth TOC TIC 18O 13C for PLC97-1.xlsx 09.11.2017 20:51:22 0.04 xlsx

Depth 14CAge Corrected 14C AGE CAL Age PLC98-4.xlsx 15.11.2017 18:26:12 0.01 xlsx

Depth 180 13C TOTC TOC TIC porosity CYBP Box Core PLB98-2.xlsx 01.03.2014 20:00:46 0.01 xlsx

Depth CalAge TIC TOTC TOC 13C 18O PLC98-4.xlsx 02.03.2014 00:32:20 0.05 xlsx

Depth Equivalent Depth in PLC08-1 PSV age 180 13C TIC TOC for …

Dam Removal In The Usa: Effects On River Water Quality, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Dam removal decisions should ideally be made after a thorough cost-benefit analysis. If dam obsolescence, structural safety, harm to fisheries, maintenance costs, and reservoir eutrophication are among the primary concerns, decommissioning would likely be favored. On the other hand, dams provide considerable benefits including water storage for agricultural and urban consumption, renewable electricity generation, support of navigational canal systems, flood control, and lakes for recreation. Because of these competing factors and interests, dam removal decision-making in the United States is often a slow process fraught with controversy, as in the case of the Klamath River.

Dams provided mechanical water power …

Using Strontium Isotopes In Conjunction With Major, And Trace Elements To Identify Water/Rock Interaction In The Upper Kittitas County, Washington, James Patterson, Carey Gazis

All Master's Theses

The complex bedrock lithologies in the Upper Kittitas County provide an ideal setting for developing isotopic methodology to identify groundwater sources and track flow paths through water-rock interaction. A wide range of 87Sr/86Sr (0.7040 to 0.7068) in surface waters, springs, and groundwater from wells was found, allowing for identification of the individual signatures of lithologic units. Rock leachates from different lithology were compared to water samples to determine a general 87Sr/86Sr signature of the water-rock interaction for that lithology. The signatures identified were systematically lower than their associated waters, but similar enough to identify the expected 87Sr/86Sr of water-rock interaction …

Proportions Of Convective And Stratiform Precipitation Revealed In Water Isotope Ratios, Pradeep K. Aggarwal, Ulrike Romatschke, Luis Araguas-Araguas, Dagnachew Belachew, Fred J. Longstaffe, Peter Berg, Courtney Schumacher, Aaron Funk

Earth Sciences Publications

Tropical and midlatitude precipitation is fundamentally of two types, spatially-limited and high-intensity convective or widespread and lower-intensity stratiform, owing to differences in vertical air motions and microphysical processes governing rain formation. These processes are difficult to observe or model and precipitation partitioning into rain types is critical for understanding how the water cycle responds to climate changes. Here, we combine two independent data sets – convective and stratiform precipitation fractions, derived from the Tropical Rainfall Measuring Mission satellite or synoptic cloud observations, and stable isotope and tritium compositions of surface precipitation, derived from a global network – to show that …

A Hydrochemical Assessment Of Groundwater Recharge And Flow In The Broome Sandstone Aquifer, La Grange Area, Western Australia, Glenn A. Harrington, Nikki M. Harrington

Natural resources commissioned reports

The Department of Agriculture and Food Western Australia has undertaken a four-year Royalties for Regions funded project in the La Grange Groundwater Area south of Broome. The purpose of the project was to provide improved knowledge and confidence about soil suitability and water availability for potential expansion of irrigated agriculture in the region. A range of complementary techniques have been used to assess the groundwater resources in the Broome Sandstone aquifer, including contemporary approaches such as drilling and aquifer pumping tests, and state-of-the-art approaches such as airborne geophysical surveys and hydrochemistry investigations.

This report presents a synthesis of all hydrochemistry …

Cone In Cone Concretions Of The Stanley Group In Southeastern Oklahoma, Kyle B. Ayres

Electronic Theses and Dissertations

Cone in cone concretions found in the Stanley Group of Southeastern Oklahoma have a variety of external and internal attributes which allow diagenetic and theoretical models of formation to be hypothesized. Stanley Group carbonate cone in cone concretions are initially formed in sulfur reducing horizons at shallow burial depths in a poorly circulated possibly deep trough containing siliceous sediments and organic matter. Collected concretions near the town of Smithville, Oklahoma displayed four different external morphologies and four variations of mineral constituents. All concretions contained microscopic cones which initiated diffusion and/or fluid patterns and is an early cementation process that directly …

An Investigation Of Hydrogeologic, Stratigraphic, And Structural Controls On Acer Grandidentatum Communities In A Karst Landscape, Owl Mountain Province, Fort Hood Military Installation, Texas, Melinda S. Faulkner

Electronic Theses and Dissertations

The Owl Mountain Province is located within the Fort Hood Military Installation, an approximately 880 km2 installation established in the 1940s in Bell and Coryell counties, Texas, which has undergone extensive land use changes associated with military training, maintaining much of the vegetation in early succession. This study investigates thelithologic, stratigraphic, and structural controls on the hydrologic, hydrogeologic, and geomorphologic evolution of the Owl Mountain Province as expressed by mesic vegetation communities, including Pleistocene relicts Acer grandidentatum, within karst terrains. These systems exhibit complexly overprinted speleogenetic evolutions within a dynamic groundwater regime resulting from regional climate shifts throughout the …

Evaluation Of Groundwater Quality In Paleozoic Aquifers Using Gis Techniques, Central Texas, Garrett R. Harris

Electronic Theses and Dissertations

Lab analyses of groundwater chemistry from monitoring wells completed in the Paleozoic Aquifers surrounding the Llano Uplift of Central Texas has been recorded and made available to the public through the Texas Water Development Board (TWDB). This study evaluated the results of these data dating back to the 1940s to determine changes over time, the dynamics of the hydrologic system, and the locations where hydraulic connectivity is most probable. The initial results established two distinct hydrologic systems that required the separation of the northern from the southern region. The northern sub-region (NSR) contains the largest expanse of continuity of both …

Using Naturally Occurring Radon 222 As A Tracer To Quantify Groundwater Fluxes To Streams, Mandy Machinal

Graduate Theses & Non-Theses

Naturally occurring radon in groundwater was used to test radon mixing models. Two different mixing models were used to quantify groundwater fluxes to streams; an analytical solution and a finite difference method. Two different bodies of waters were used in this study. The first location was Johnson Creek located in Grant-Kohrs Ranch in Deer Lodge, Montana. This is a small creek where lots of sampling points were taken. The stretch of Johnson Creek where radon samples were collected was about 0.34 km long with a flowrate between 0.01 m3/s and 0.017 m3/s. The second location was Merced River located in …

Natural Acid Rock Drainage And Ferricrete Deposit Chemistry Of The Judith Mountains, Montana, Sara Edinberg

Graduate Theses & Non-Theses

The Judith Mountains are a low-elevation “island” mountain range in east-central Montana composed of a series of laccoliths and stocks cut by coarse-grained alkali granite and tinguaite dikes. The geology of the Judith Mountains in the vicinity of Red Mountain and Judith Peak, two of the tallest mountains in the range, is conducive to the creation of headwater streams that are naturally acidic. Extensive limonite staining on Red Mountain attests to the widespread presence of disseminated pyrite in hydrothermally altered porphyry rock. However, no major historical mining operations are known to the area. The acidic streams undergo neutralization in pH …

Sea Lamprey Mating Pheromone Registered By U.S. Environmental Protection Agency As First Vertebrate Pheromone Biopesticide, Marc Gaden, Marisa Lubeck

United States Geological Survey: Publications

Ann Arbor, MI – The U.S. Environmental Protection Agency registered a sea lamprey mating pheromone, 3kPZS, as the first ever vertebrate pheromone biopesticide in late December, 2015. Like an alluring perfume, the mating pheromone is a scent released by male sea lampreys to lure females onto nesting sites. Research and development of the mating pheromone was funded by the Great Lakes Fishery Commission, with additional support from the Great Lakes Restoration Initiative, in collaboration with federal government, university, and private industry partners.

Spring Responses To Storms And Seasonal Variations In Recharge In The Middle Atlas Region Of Morocco, Brett Andrew Howell

Theses and Dissertations--Earth and Environmental Sciences

Springs in the Middle Atlas Mountains of Morocco are significant sources for public water supply. From March 2014 to May 2015, water temperatures were measured hourly at three springs (Ribaa, Sidi Rached, and Zerouka); water levels were measured hourly at Sidi Rached and Zerouka; and daily turbidity data were obtained from Ribaa. From March 2014 to March 2015, daily water samples were taken at Zerouka for analyses of the stable isotopes deuterium and oxygen-18. Hourly weather data (precipitation and air temperature) were available from March 2014 to May 2015 from Ifrane, near Zerouka. Temperature responses varied between the springs, showing …

Geochemical Processes And Controls Affecting Water Quality Of The Karst Area Of Big Creek Near Mt. Judea, Arkansas, V. Brahana, J. Nix, C. Kuyper, T. Turk, F. Usrey, S. Hodges, C. Bitting, K. Ficco, E. Pollock, R. Quick, B. Thompson, J. Murdoch

Journal of the Arkansas Academy of Science

Karst regions typically are considered to be vulnerable with respect to various land-use activities, owing to the intimate association of surface and groundwater and lack of contaminant attenuation provided by most karst aquifers. Inasmuch as the soluble rocks of the karst landscape can be dissolved to create large, rapid-flow zones that compete successfully with surface streams, groundwater and subsurface flow represent a much larger component of the hydrologic budget in karst regions than in areas where non-soluble rocks predominate. Karst areas typically are distinguished by being unique, but some general approaches can be applied to characterize the hydrology of the …

Seasonal Evolution Of Active Layer Formation In Subarctic Peat Plateaux And Implications For Dissolved Organic Matter Composition And Transfer, Jennifer L. Hickman

Theses and Dissertations (Comprehensive)

Peat-accumulating wetlands are ecosystems whose rate of photosynthetic production of organic matter is greater than that of its decomposition, resulting in a build up of soil organic matter that may take centuries to fully decompose. Carbon (C) stocks within these ecosystems are a function of inputs from photosynthesis, and losses from heterotrophic decomposition. Due to the short growing season and overall cold climate of boreal and tundra regions, C has been accumulating within these landscapes, mostly in soil organic matter, since the last glaciation. Climate change, predicted to result in rising temperatures and increased precipitation, has begun to degrade the …

An Investigation Of The Effects Of Chemical And Physical Weathering On Submerged Karst Surfaces, Bryan Charles Booth

USF Tampa Graduate Theses and Dissertations

Reports an investigation of the effects of chemical and physical weathering on submerged karst surfaces that pairs laboratory studies with computer modeling studies. The first study attempts to quantify the production of carbonate fines; soluble sediments produced by the incomplete dissolution of karst minerals during chemical weathering. Results show carbonate fine production in relation to dissolutional action; Chalk: 42.8%; Coquina: 2.6%; Dolomite: 3.1%; Gray Limestone: 4.8%; Ocala Limestone: 3.1%; Shell Limestone: 6.1%; Travertine: 8.6%. Due to the use of hydrochloric acid as opposed to carbonic acid these results may not be fully valid for application to natural speleogenic processes. The …

Exploring, Exploiting And Evolving Diversity Of Aquatic Ecosystem Models: A Community Perspective, Annette B.G. Janssen, George B. Arhonditsis, Arthur Beusen, Karsten Bolding, Louise Bruce, Jorn Bruggeman, Raoul-Marie Couture, Andrea S. Downing, J. Alex Elliott, Marieke A. Frassl, Gideon Gal, Daan J. Gerla, Matthew R. Hipsey, Fenjuan Hu, Stephen C. Ives, Jan H. Janse, Erik Jeppesen, Klaus D. Jöhnk, David Kneis, Xiangzhen Kong, Jan J. Kuiper, Moritz K. Lehmann, Carsten Lemmen, Deniz Özkundakci, Thomas Petzoldt, Karsten Rinke, Barbara J. Robson, René Sachse, Sebastiaan A. Schep, Martin Schmid, Huub Scholten, Sven Teurlincx, Dennis Trolle, Tineke A. Troost, Anne A. Van Dam, Luuk P.A. Van Gerven, Mariska Weijerman, Scott A. Wells, Wolf M. Mooij

Civil and Environmental Engineering Faculty Publications and Presentations

Here, we present a community perspective on how to explore, exploit and evolve the diversity in aquatic ecosystem models. These models play an important role in understanding the functioning of aquatic ecosystems, filling in observation gaps and developing effective strategies for water quality management. In this spirit, numerous models have been developed since the 1970s. We set off to explore model diversity by making an inventory among 42 aquatic ecosystem modellers, by categorizing the resulting set of models and by analysing them for diversity. We then focus on how to exploit model diversity by comparing and combining different aspects of …

Phosphorus Sorption Dynamics In Shallow Groundwater, Coastal Everglades, Florida, Usa, Hilary Flower

USF Tampa Graduate Theses and Dissertations

For this dissertation I studied phosphorus (P) sorption dynamics in the shallow groundwater of the southern Everglades. In particular, I examined how the ambient water type governs soluble reactive P (SRP) availability through adsorption/desorption reactions with the aquifer matrix. Chapter 2 investigated how P sorption dynamics of the mangrove root zone sediment are affected by high bicarbonate brackish groundwater compared to both fresh groundwater and saltwater. The results from chapter 2 show that the sediment exhibited exceptionally low sorption efficiency in the high bicarbonate brackish water, which would allow ambient water SRP concentration to be maintained at a higher level. …

Hydrochemical Characteristics And Formation Mechanism Of Groundwater In The Liulin Karst System, Min Yang, Feng'e Zhang, Sheng Zhang, Miying Yin, Guoqing Wu

Sinkhole Conference 2015

The Liulin karst system is typical of hydrogeological systems in northwestern China, with a group of springs as the dominant mechanism for regional groundwater discharge. To reveal the hydrochemical formation mechanism of the Liulin karst groundwater system, we studied the hydrogeochemical processes of karst groundwater in aquifers at the base of the hydrogeological investigation. Then starting from the chemical composition of karst groundwater together with the recharge-runoff - discharge process of groundwater systems, we analyzed the solutes origin and the dissolved mineral facies of the groundwater chemical composition. The results showed that the anionic and cationic compositions of karst water …

Determination Of The Relationship Of Nitrate To Discharge And Flow Systems In North Florida Springs, Sam B. Upchurch

Sinkhole Conference 2015

The Suwannee River Water Management District has collected quarterly discharge and water quality data from 30 1st and 2nd magnitude springs in the Suwannee River Basin since 1998. These data were collected quarterly well into the late 2000s and constitute a valuable database for characterizing spring discharge behavior. Trend and correlation analyses were used to compare the relationships of NO3- + NO2- (nitrate in this paper), specific conductance, and spring discharge. Trends were considered significant if alpha levels of the trend slopes were ≤ 0.05. Data from 50% of the springs show that nitrate concentrations increase as discharge from the …

Hydrologic And Geochemical Dynamics Of Vadose Zone Recharge In A Mantled Karst Aquifer: Results Of Monitoring Drip Waters In Mystery Cave, Minnesota, Daniel H. Doctor, E. Calvin Alexander Jr., Roy Jameson, Scott C. Alexander

Sinkhole Conference 2015

Caves provide direct access to flows through the vadose zone that recharge karst aquifers. Although many recent studies have documented the highly dynamic processes associated with vadose zone flows in karst settings, few have been conducted in mantled karst settings, such as that of southeastern Minnesota. Here we present some results of a long-term program of cave drip monitoring conducted within Mystery Cave, Minnesota. In this study, two perennial ceiling drip sites were monitored between 1997 and 2001. The sites were located about 90 m (300 ft) apart along the same cave passage approximately 18 m (60 ft) below the …

Tracer Studies Conducted Nearly Two Decades Apart Elucidate Groundwater Movement Through A Karst Aquifer In The Frederick Valley Of Maryland, Keith A. White, Michael K. Cobb, Thomas Aley, Ethan Weikel

Sinkhole Conference 2015

A pair of groundwater tracer studies at a single karst test site were completed 18 years apart. The results of these studies have provided evidence of both relatively rapid advective transport via conduits and an extreme capacity for dye storage and retardation. The tracer results, coupled with other subsurface investigation data, are used to develop a conceptual model for groundwater movement through this karst aquifer in the Frederick Valley of Maryland, as well as identify implications for remediation. Three fluorescent tracer dyes used in the initial study were detected in several background monitoring locations established for the second study conducted …

Using Bromide Tracer To Measure Uranium Diffusivity In Ground Water Sediments, Francis Michael Tee, Morris E. Jones, Megan K. Dustin, Sharon Bone, John Bargar

STAR Program Research Presentations

More than 129 million liters of groundwater are contaminated with uranium at Old Rifle, Colorado – a former uranium-processing site that operated until 1958. The original Department of Energy (DOE) strategy for remediation, involving natural flushing of U from the groundwater through mixing with surface water, has not proven successful. Thin pockets of silt-, clay-, and organic-rich sediments referred to as naturally reduced zones (NRZs) act both as sinks and sources of U to the aquifer, contribute to plume persistence, and appear to be diffusion limited controlled.

To better understand how the NRZs are diffusion limited controlled, a bromide tracer …

Preliminary Isotope Assessment, La Grange Groundwater Area, Glenn A. Harrington

Natural resources commissioned reports

The Department of Agriculture and Food, Western Australia (DAFWA) is currently undertaking a Royalties for Regions funded project in the La Grange Groundwater Area south of Broome. The focus is on providing improved confidence about soil suitability and water availability for potential expansion of irrigated agriculture in the region. Groundwater in the Broome Sandstone Aquifer (BSA) is the target water resource, however before the La Grange project commenced little was known about the physical and chemical attributes of the aquifer. This report provides the results of estimated groundwater recharge and residence times using environmental tracer techniques.

Sampling of 12 existing …

Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin

Graduate Theses and Dissertations

The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …

Quantitative Hermeneutics: Counting Forestructures On A Path From W.M. Davis To The Concept Of Multiple-Permeability Karst Aquifers, H. L. Vacher, Lee J. Florea

International Journal of Speleology

Hermeneutics is the theory of interpretation. One of its major components is recognizing prejudgments, or forestructures, that we bring to our objects of study. In this paper, we construct a historical narrative of the evolution of thinking about the role of caves in relation to groundwater flow in limestone, and we tabulate forestructures as they appear in the story. This account consists of three overlapping time periods: the before and after of an incident that repelled hydrogeologists and students of karst from each other in the middle of the 20^th century; a period, up to around the turn of …

Fluxes Of Dissolved Organic Carbon During Storm Events In The Neponset River Watershed, Keith Thomas Cialino

Graduate Doctoral Dissertations

The transport of dissolved organic carbon (DOC) and chromophoric dissolved organic matter (CDOM) from land to coastal environments strongly influences coastal ecosystems. The presence of first flush phenomena due to rainwater runoff traveling from land into waterways can greatly affect carbon fluxes to coastal areas. This research utilizes sensors, autosamplers, and standard watershed sampling in order to assess for the presence of first flush and its significance. A rainfall simulator was built in order to collect runoff on two land use types. Time series data suggest that first flush of dissolved organic carbon was present for all rainfall intensities simulated …

Stable Isotopes As A Tool To Characterize Carbon Cycling And Develop Hydrologic Budgets In Mantled Karst Settings, Katherine Knierim

Graduate Theses and Dissertations

Isotopes of water (δ2H/δ18O), carbon dioxide (δ13C-CO2), and dissolved inorganic carbon (δ13C-DIC) were used to explore water quality, trace carbon cycling, and quantify recharge sources through mantled karst and into Blowing Spring Cave (BSC). Of the possible sources of contamination in the BSC recharge area, septic-tank effluent was hypothesized to degrade water quality at the spring outlet of BSC because of the dominance of septic tanks for waste treatment, unsuitable topography and soil for septic-tank absorption fields, increased nitrate and chloride concentrations concomitant with increased urbanization, and increased Escherichia coli with discharge. Carbon cycling between the soil and BSC was …

Using Kriging, Cokriging, And Gis To Visualize Fe And Mn In Groundwater, Crystal Johnson

Electronic Theses and Dissertations

For aesthetic, economic, and health-related reasons, allowable concentrations of iron (Fe) and manganese (Mn) found present in drinking water are 0.3 mg/L and 0.05 mg/L, respectively. Water samples taken from private drinking wells in the rural communities within Buncombe County, North Carolina contain amounts of these metals in concentrations higher than the suggested limits. This study focused on bedrock geology, elevation, saprolite thickness, and well depth to determine factors affecting Fe and Mn. Using ArcGIS 10.2, spatial trends in Fe and Mn concentrations ranges were visualized, and estimates of the metal concentrations were interpolated to unmonitored areas. Results from this …

Influence Of Road Salt Deicers On Anaerobic Respiration And Metal Speciation In Soils, Danielle Dupuis

Honors Theses

Road salt deicers, especially NaCl and CaCl₂, are used throughout the world on paved areas during the winter. Previous studies suggest that road salt deicers can alter the biogeochemistry of sediment located near roadways and influence the mobility of heavy metals. The goal of this study is to investigate the influence of CaCl₂ on wetland soil biogeochemistry, especially trace metal speciation. Sediment cores were collected in the fall from a freshwater wetland near an urban kettle lake (Asylum Lake, Kalamazoo, MI) and incubated for 100 days in deionized water (control), 5 g/L of CaCl₂, or …