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Articles 4741 - 4770 of 59519

Full-Text Articles in Earth Sciences

Sedimentary Archives Of Late Quaternary Limnological, Ecological, And Environmental Change In The Eastern Sierra Nevada (California, Usa), Bailee Hodelka Jan 2025

Sedimentary Archives Of Late Quaternary Limnological, Ecological, And Environmental Change In The Eastern Sierra Nevada (California, Usa), Bailee Hodelka

Theses and Dissertations--Earth and Environmental Sciences

The Sierra Nevada essentially serve as the headwaters of California, providing crucial freshwater to the state through seasonal snowmelt. This water supply is threatened by climate change in complex ways that are not fully understood. Geological records provide a valuable source of information on how the hydrology, limnology, and ecology of the Sierra Nevada region has responded to climate changes of the past. This dissertation presents new sedimentary and paleoecological research from Mono Lake and Convict Lake (Mono County, California) and aims to shed light on environmental changes in the eastern Sierra Nevada from ~16 ka to present.

At Mono …


Bridging Prairie Restoration And Regenerative Agriculture With Compost Tea / The Rocket Incident: Post-Fire Soil Microbe Recovery On The Eastern Washington University Restoration Site, April Hersey Jan 2025

Bridging Prairie Restoration And Regenerative Agriculture With Compost Tea / The Rocket Incident: Post-Fire Soil Microbe Recovery On The Eastern Washington University Restoration Site, April Hersey

EWU Masters Thesis Collection

Inland Pacific Northwest prairie is an endangered ecosystem that has been reduced by conversion to agriculture. There is growing interest in the role of soil microorganisms in prairie ecosystems, which may be crucial for restoration of the plant community through interspecies interactions within the rhizosphere. One method for improving soil microorganism community composition is compost tea: enriched liquid compost extract. Compost tea is used in regenerative agriculture to improve crop yields and protect against pathogens. While research has supported compost tea application in regenerative agriculture, it has not been widely studied in the context of ecosystem restoration. After beginning a …


Fault Box Modeling Of Dip Slip Faults: A Framework For Fault Box Design And Future Studies, Hailey Pressnell Jan 2025

Fault Box Modeling Of Dip Slip Faults: A Framework For Fault Box Design And Future Studies, Hailey Pressnell

Master's Theses

The behavior of soils during surface fault rupture is a serious concern in the planning and design of infrastructure that may be located within or near a fault zone. Challenges associated with developing mitigation measures for surface fault rupture include the uncertainty of fault rupture and the variability of fault behavior. Current analytical procedures define surface fault rupture according to the type of fault movement (strike slip, normal or reverse), the amount of displacement on the fault, and the mechanics of the material overlying the fault. The purpose of this thesis is to reconfirm analytical solutions and gain a better …


Examining Short Term Drainage Impacts To Soil Health In Hydric And Non-Hydric Soils Of Waseca County, Minnesota, Ely Hartl Jan 2025

Examining Short Term Drainage Impacts To Soil Health In Hydric And Non-Hydric Soils Of Waseca County, Minnesota, Ely Hartl

All Graduate Theses, Dissertations, and Other Capstone Projects

Subsurface drainage is implemented throughout the Midwest United States to remove excess moisture from soil to enhance crop growth. Hydric soils are ubiquitous throughout Minnesota and are commonly drained due to their historically saturated conditions. Changing a soil's hydrology can impact its formation and properties. The alteration of physical, biological, and chemical soil properties can occur to both hydric and non-hydric soils, impacting overall soil health. The purpose of this study is to examine the short-term effects of tile drainage on the soil health of hydric and non-hydric soils in southern Minnesota. Research methods include: 1) collect soil-sediment cores to …


Yukon Dust From Source To Sink: Characterizing The St. Elias Mountains As A High-Latitude Dust Source, Audrey Y. Lemoine Jan 2025

Yukon Dust From Source To Sink: Characterizing The St. Elias Mountains As A High-Latitude Dust Source, Audrey Y. Lemoine

Honors Theses

High-latitude dust is an important, yet poorly understood, component of Earth’s climate system. It impacts weather and albedo by acting as cloud condensation nuclei, directly affects Earth’s radiative balance, and can enhance productivity by supplying nutrients to ecosystems. In order to better understand high-latitude dust dynamics and impacts, we sampled glacial meltwater, surface sediment, and Holocene loess in the Łhù’ààn Mân (Kluane Lake) region of the Yukon Territory, Canada. We found that suspended sediment concentration is correlated with average slope and glaciation within a catchment, and is influenced by river morphology. We present new εNd and 87Sr/86Sr …


Water Quality And Microplastic Contamination In An Urbanizing City Nakhon Pathom, Thailand, Boonyarak Chuanchit Jan 2025

Water Quality And Microplastic Contamination In An Urbanizing City Nakhon Pathom, Thailand, Boonyarak Chuanchit

Graduate Research Theses & Dissertations

Microplastics (MPs) are synthetic polymer particles less than 5 mm in size that originate from both primary manufacturing and the breakdown of larger plastics. Extensive studies have examined their occurrence in other environments, while little is known about their presence and behavior in groundwater, especially in urbanizing regions in Southeast Asia. This study investigates the occurrence and abundance of microplastics within groundwater systems of Nakhon Pathom, an urbanizing province in central Thailand.

Groundwater was collected representing shallow and deep aquifers between May 2023 and May 2025. The analyses included physical-chemical parameters, major ions, heavy metals, and microplastic abundance and composition. …


A Collaborative Assessment Of Coastal Ocean Acidification Monitoring In Maine & Standard Operating Procedures And Best Practices For The Collection Of Continuous Ph Data In Coastal Marine Environments, Christopher W. Hunt, Curtis Bohlen, Mike Doan, Jeremy Miller Jan 2025

A Collaborative Assessment Of Coastal Ocean Acidification Monitoring In Maine & Standard Operating Procedures And Best Practices For The Collection Of Continuous Ph Data In Coastal Marine Environments, Christopher W. Hunt, Curtis Bohlen, Mike Doan, Jeremy Miller

Faculty Publications

The ‘Sensor Squad’ of the Maine Ocean Climate Collaborative is the product of a 2023 Maine Coastal and Marine Climate Action Fund grant to conduct “A two-year pilot project designed to address and overcome technological barriers to ocean acidification data collection, develop protocols to elevate quality assurance and ensure comparable data, and meet regularly to discuss project results and data compilation”. The Squad consists of representatives from Friends of Casco Bay (FOCB), Wells National Estuarine Research Reserve (WNERR), and the University of New Hampshire (UNH). This report is a summary of their efforts to assess affordable, repeatable means of continuously …


Igc Oral Presentation Summary: Xxv Igc Congress, S. Ray Smith, Echo Elizabeth Gotsick, J. R. Weinert-Nelson, Alayna Jacobs, Christopher D. Teutsch, Will Fleming, D. R. Woodfield, James L. Klotz, Jeff Lehmkuhler, Greg S. Halich, Brittany Davis, Brittany Hendrix, Krista Lea Jan 2025

Igc Oral Presentation Summary: Xxv Igc Congress, S. Ray Smith, Echo Elizabeth Gotsick, J. R. Weinert-Nelson, Alayna Jacobs, Christopher D. Teutsch, Will Fleming, D. R. Woodfield, James L. Klotz, Jeff Lehmkuhler, Greg S. Halich, Brittany Davis, Brittany Hendrix, Krista Lea

IGC Proceedings (1977-2023)

This paper will give an overview of the XXV International Grassland Congress thematic, keynote, and plenary sessions. The theme of the XXV IGC Congress meeting was “Grasslands for Soil, Animal, and Human Health.” We had many people attending, presenting, and participating in all these sessions. Within a month after the conclusion of the Congress, the proceeding’s papers presented at the meeting will be available on the IGC app. By the end of 2023 all papers will be available for download through any search engine at internationalgrasslands.org.


Spatiotemporal Economic Impact Analysis Of The Taal Volcano Eruption Using Electricity Consumption And Nighttime Light Data, Ma Flordeliza P. Del Castillo, Toshio Fujimi, Hirokazu Tatano Jan 2025

Spatiotemporal Economic Impact Analysis Of The Taal Volcano Eruption Using Electricity Consumption And Nighttime Light Data, Ma Flordeliza P. Del Castillo, Toshio Fujimi, Hirokazu Tatano

SOSE Affiliate: Manila Observatory

Analyzing the spatiotemporal dimension of the economic impacts of disasters is critical for providing timely and proportionate support. However, traditional economic impact measures often lack spatiotemporal details. Hence, we estimated the daily electricity consumption (EC) loss using high-frequency EC data and analyzed temporal dimensions of the immediate impacts of Taal Volcano’s eruption on January 12, 2020. Subsequently, we computed the nighttime light (NTL) change using high-resolution NTL data to analyze the spatial distribution of these impacts. The temporal analysis revealed two EC loss peaks. The first peak coincided with the power outage and decreased energy demand, followed by a brief …


Topographic Forcing Of Submesoscale Instability In The Antarctic Circumpolar Current, Laur Ferris, Donglai Gong, John Klinck Jan 2025

Topographic Forcing Of Submesoscale Instability In The Antarctic Circumpolar Current, Laur Ferris, Donglai Gong, John Klinck

CCPO Publications

Subpolar frontal zones are characterized by energetic storms, intense seasonal cycles, and close connectivity with surrounding continental shelf topography. At the same time, predicting the ocean state depends on appropriate partition of resolved and parameterized dynamics, the latter of which requires understanding the dynamical processes generating diffusivity throughout the water column. While submesoscale frontal instabilities are shown to produce turbulent kinetic energy (TKE) and mixing in the surface boundary layer (SBL) of the global ocean, their development in complex dynamical regimes (e.g., elevated preexisting turbulence, large ageostrophic shear, or in proximity to topographic boundaries) is less understood. This study investigates …


Estimation Of Burned Severity Areas Using Landsat8 Data From 2016 To 2022 In Chiang Mai Province, Sarunya Karuna Jan 2025

Estimation Of Burned Severity Areas Using Landsat8 Data From 2016 To 2022 In Chiang Mai Province, Sarunya Karuna

Chulalongkorn University Theses and Dissertations (Chula ETD)

This study aims to evaluate the area and severity of wildfire damage in Chiang Mai Province using LANDSAT8 satellite data from 2016, 2018, 2020, and 2022, and to analyze the relationship between spatial factors, namely the Normalized Difference Vegetation Index (NDVI) and Land Surface Temperature (LST), with fire occurrence and severity. The study utilized hotspot data analysis in conjunction with the Differenced Normalized Burn Ratio (dNBR) index to assess the area and classify fire severity levels, while also analyzing pre-fire and post-fire NDVI and LST values to identify correlations. The results indicated that 2020 experienced the most severe fire situation, …


Heat Treatment Of Basaltic-Related Sapphire From Binh Thuan Deposit, Southern Vietnam, Yuparat Kwangsawat Jan 2025

Heat Treatment Of Basaltic-Related Sapphire From Binh Thuan Deposit, Southern Vietnam, Yuparat Kwangsawat

Chulalongkorn University Theses and Dissertations (Chula ETD)

Characteristics of basalt-related sapphires from Binh Thuan in Southern Vietnam were investigated before and after heat treatment. Samples were divided into four group, based on their color and hue including dark blue, blue, greenish blue, and bluish green. After being heated at 700-1000°C, sapphires' blue hue faded noticeably. Blue color turned to be intensified when heated at 1650°C. Subsequently, beryllium-assisted heating by a local professional gem treater was introduced to these sapphire samples which in turn yielded yellow to yellowish-blue hues. Color changes after heating are conclusively involved by trace compositions of sapphire and temperatures of heating. The appropriate treatment …


การศึกษารูปแบบความร่วมมือของภาครัฐและภาคเอกชนในการบริหารจัดการเหตุวิกฤติฉุกเฉินและนโยบายการรักษาความปลอดภัยย่านศูนย์กลางธุรกิจของกรุงเทพมหานคร, ปัญจรัตน์ เดชกุญชร Jan 2025

การศึกษารูปแบบความร่วมมือของภาครัฐและภาคเอกชนในการบริหารจัดการเหตุวิกฤติฉุกเฉินและนโยบายการรักษาความปลอดภัยย่านศูนย์กลางธุรกิจของกรุงเทพมหานคร, ปัญจรัตน์ เดชกุญชร

Chulalongkorn University Theses and Dissertations (Chula ETD)

ภัยพิบัติเป็นสิ่งที่ทั่วโลกเล็งเห็นความสำคัญและให้ความตระหนักในการบริหารจัดการ ด้วยการเปลี่ยนแปลงของโลกเป็นปัจจัยกระตุ้นให้เกิดเหตุขึ้นบ่อยครั้ง เป็นเหตุวิกฤติที่เกินการรับมือ การศึกษาเรื่อง รูปแบบความร่วมมือของภาครัฐและภาคเอกชนในการบริหารจัดการเหตุวิกฤติฉุกเฉินและนโยบายการรักษาความปลอดภัยย่านศูนย์กลางธุรกิจของกรุงเทพมหานคร เป็นการศึกษาในภาคการขับเคลื่อนนโยบายการบริหารระหว่างหน่วยงานภาครัฐและเครือข่ายภาคประชาชนในพื้นที่ย่านราชประสงค์ เขตปทุมวัน ภายใต้กรอบแนวคิดการร่วมมือทำงานกันระหว่างภาครัฐและภาคเอกชนแบบเครือข่าย Networking มีวัตถุประสงค์เพื่อทราบถึง 1) รูปแบบความร่วมมือเชิงนโยบายของภาครัฐและภาคเอกชนในการบริหารจัดการเหตุวิกฤติ 2) นโยบายการรักษาความปลอดภัยของภาครัฐและภาคเอกชนในพื้นที่ย่านราชประสงค์ 3) การออกแบบแผนการรับมือเหตุวิกฤติ และ 4) เพื่อดูแนวโน้มการเป็นต้นแบบนำร่องไปใช้ในพื้นที่ชุมชนเมืองอื่นในกรุงเทพมหานคร เป็นการวิจัยเชิงคุณภาพแบบกรณีศึกษา โดยการสัมภาษณ์ผู้บริหารกลุ่มภาคเอกชนกลุ่มผู้ประกอบวิสาหกิจในย่านราชประสงค์ จำนวน 10 องค์กร และหน่วยงานภาครัฐในพื้นที่อีก 2 องค์กร ใช้แบบสัมภาษณ์กึ่งโครงสร้าง วิเคราะห์ข้อมูลเชิงเนื้อหา พรรณนา พัฒนาแก่นสาระ ตรวจสอบด้วยวิธีเทคนิคสามเส้า ร่วมกับการศึกจากข้อมูลเอกสารและการลงพื้นที่เพื่อสังเกตการณ์ ผลการวิจัยพบว่า (1) รูปแบบความร่วมมือเชิงนโยบายของภาครัฐและภาคเอกชนในการบริหารจัดการเหตุวิกฤติฉุกเฉินในย่านราชประสงค์ ขับเคลื่อนด้วยแนวคิดการจัดการปกครองสาธารณะแนวใหม่แบบเครือข่าย ระหว่างภาครัฐกับเครือข่ายภาคเอกชน บวกกับ Disaster Management และ Crisis Management (2) นโยบายการรักษาความปลอดภัยใช้การร่วมออกแบบ ร่วมคิด และขับเคลื่อนกลไกเชิงนโยบายมีปฏิสัมพันธ์ในระดับองค์กร และระดับบุคคลต่อบุคคล (3) การออกแบบแผนการรับมือเหตุวิกฤติฉุกเฉินจากภัยพิบัติในย่านราชประสงค์ ใช้วิธีการเตรียมความพร้อม ตามหลักการของ Disaster Management ร่วมกับ Crisis Management (4) แนวโน้มการเป็นต้นแบบนำไปใช้ในพื้นที่ชุมชนเมืองอื่นในกรุงเทพมหานคร ต้องพิจารณาร่วมด้วยกับความเข้มแข็งของความร่วมมือของรัฐและเอกชนที่มีวิสัยทัศน์ แนวทางในการขับเคลื่อนไปในทิศทางเดียวกัน ระบบการเงินส่วนกลางที่น่าเชื่อถือ มีการจัดปรับการใช้รูปแบบให้เหมาะสมกับทรัพยากรที่มีอยู่ในพื้นที่ของตนเอง


Surface Currents In The Mid-Atlantic Bight: The Role Of The Gulf Stream Versus Wind, Tal Ezer Jan 2025

Surface Currents In The Mid-Atlantic Bight: The Role Of The Gulf Stream Versus Wind, Tal Ezer

CCPO Publications

Surface currents of the Mid-Atlantic Bight (MAB) were studied using high frequency radar (HFR) observations at 6 km resolution during a five-year period (2020-2024). The study's focus on the role of the Gulf Stream (GS) contrasts with most past studies that focused on the seasonal wind-driven currents. Empirical Orthogonal Function (EOF) analyses of the daily HFR currents were conducted with and without the GS, revealing modes of current variability linked to the seasonal wind pattern and storms versus modes linked to GS variability. The remote impact of the GS on coastal currents is complex, with different impacts seen on different …


Characterization And Leaching Feasibility Studies Of Copper Flue Dust For The Recovery Of Main And Trace Metals, Fardis Nakhaei, Marek Locmelis, Lana Alagha, Michael S. Moats, Carlos Eyzaguirre, Cory Smith Jan 2025

Characterization And Leaching Feasibility Studies Of Copper Flue Dust For The Recovery Of Main And Trace Metals, Fardis Nakhaei, Marek Locmelis, Lana Alagha, Michael S. Moats, Carlos Eyzaguirre, Cory Smith

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Although copper smelter dust (CSD) is classified as hazardous waste, it also serves as a valuable secondary resource, offering potential for the recovery of critical elements. In this study, CSD samples were collected from the waste heat boiler (WHB) and electrostatic precipitator (ESP) units connected to the flash smelting furnace at a copper smelter. The representative samples were extensively characterized by particle size, and chemical and mineralogical analyses. Following sample characterization, leaching experiments were performed to evaluate the potential extraction of Cu, Fe, As, Zn, Pb, In, Ga, and Ge from the flue dusts. Distilled water, H2SO4, and HCl were …


Distribution And Tooth Morphoguilds Of Mosasaurids (Squamata) Of The Campanian Western Interior Seaway With Implications For Controls On Mosasaur Paleobiogeography, Alec Zaborniak Jan 2025

Distribution And Tooth Morphoguilds Of Mosasaurids (Squamata) Of The Campanian Western Interior Seaway With Implications For Controls On Mosasaur Paleobiogeography, Alec Zaborniak

Master's Theses or Doctor of Nursing Practice

The Western Interior Seaway (WIS) of North America is well known for its mosasaurid squamate diversity, particularly during the Campanian of the Late Cretaceous. Mosasaurid diversity has historically been examined at a fine scale, with many studies investigating the faunal composition of specific assemblages; however, studies focusing on mosasaur communities within the Western Interior Seaway during specific Ages are currently lacking. Mosasaur tooth morphology has also been extensively studied, with tooth characteristics commonly being used as phylogenetic characters. However, many studies examining mosasaur communities and tooth morphology have been focused on broader spatiotemporal or phylogenetic scales. This study investigates the …


The Effects Of Return To Prairie In Barber County, Kansas: A Case Study Using Ndvi And Dendrochronology, Elijah O. Joy Jan 2025

The Effects Of Return To Prairie In Barber County, Kansas: A Case Study Using Ndvi And Dendrochronology, Elijah O. Joy

Master's Theses or Doctor of Nursing Practice

This study aims to evaluate the impact of prairie restoration efforts in Barber County, Kansas, with a focus on removal of Eastern Red Cedar. Restoration effectiveness was assessed using remote sensing of satellite scenes via NDVI, density analysis, and dendrochronological methods. The tree density analysis revealed a 66% reduction across the study area and a 99% reduction in the fully restored zones. NDVI analysis from 2010 to 2024 showed higher summer vegetation health and seasonal fluctuations influenced by climate variability and fire events. Dendrochronological data from tree cores reveals growth patterns and establishes a baseline for future dendrochronological chronologies. The …


Oil-Oil Correlation Across Sedimentary Basins In Kansas Using Molecular Geochemistry And Fourier Transform Infrared Spectroscopy, Oluwaseun V. Omoyemi Jan 2025

Oil-Oil Correlation Across Sedimentary Basins In Kansas Using Molecular Geochemistry And Fourier Transform Infrared Spectroscopy, Oluwaseun V. Omoyemi

Master's Theses or Doctor of Nursing Practice

Hydrocarbons are produced from different subbasins and stratigraphic intervals in Kansas. However, the geochemical characteristics and sources of these hydrocarbons are still poorly understood. While reservoir rocks, seals, and traps that are essential for petroleum systems are well defined within the state, the possible source rocks are often considered thermally immature, raising questions about their ability to generate the volume of hydrocarbons currently being produced. This research project tries to evaluate the geochemical characteristics of hydrocarbons produced in the state of Kansas and determine if the hydrocarbons from the different subbasins and stratigraphic units are genetically related. Thirty-seven crude oil …


A Histological Survey Of A Large, Sub-Adult Tylosaurus Nepaeolicus With Implications On The Validity Of Tylosaurus Kansasensis, Carson Cope Jan 2025

A Histological Survey Of A Large, Sub-Adult Tylosaurus Nepaeolicus With Implications On The Validity Of Tylosaurus Kansasensis, Carson Cope

Master's Theses or Doctor of Nursing Practice

Tylosaurus nepaeolicus is a basal, medium-sized tylosaurine mosasaur that lived during the late Coniacian and early Santonian in the Western Interior Seaway. Despite being a well-studied species, there is debate over whether Tylosaurus kansasensis represents the juvenile form of T. nepaeolicus, or if the two species are distinct. Osteohistology can determine organism age at time of death and can be used to help resolve this debate and provide a better understanding of the growth of T. nepaeolicus. Thin-sections were taken from a humerus, rib, and vertebra of a single individual (FHSM VP-2209). All thin-sections show primarily parallel-fibered cortical …


Applying Transfer Learning For Street-Scale Nuisance Flood Forecasting In Coastal-Urban Cities, Binata Roy, Jonathan L. Goodall, Diana Mcspadden, Chetan Kumar, Steven Goldenberg, Yidi Wang, Malachi Schram Jan 2025

Applying Transfer Learning For Street-Scale Nuisance Flood Forecasting In Coastal-Urban Cities, Binata Roy, Jonathan L. Goodall, Diana Mcspadden, Chetan Kumar, Steven Goldenberg, Yidi Wang, Malachi Schram

VMASC Publications

An important challenge with Machine Learning (ML) is its transferability; i.e., whether a ML model trained on one set of data can be applied to a second set of data without requiring full re-training of the model. Transfer Learning (TL) addresses this challenge by transferring knowledge learned in the source domain (the data it was trained on) to the target domain (a second set of data that is statistically different but related, which the model was not trained on). This study investigates the use of TL for street-scale nuisance flood forecasting by exploring whether a ML model trained for one …


Moderate Heating Renders 7.8-Million-Year-Old Sedimentary Organic Matter Bioavailable, Shuchai Gan, Verena B. Heuer, Frauke Schmidt, Lars Wormer, Faming Wang, Rishi R. Adhikari, Patrick Hatcher, Ann Pearson, Kai-Uwe Hinrichs Jan 2025

Moderate Heating Renders 7.8-Million-Year-Old Sedimentary Organic Matter Bioavailable, Shuchai Gan, Verena B. Heuer, Frauke Schmidt, Lars Wormer, Faming Wang, Rishi R. Adhikari, Patrick Hatcher, Ann Pearson, Kai-Uwe Hinrichs

Chemistry & Biochemistry Faculty Publications

Marine sediments are a large reservoir of recalcitrant organic matter and host microbes at subsurface depths exceeding 2.4 kilometers and temperatures up to 120°C, yet the mechanisms supplying bioavailable substrates remain unclear. Here, we investigated 7.8-million-year-old sediment from IODP Site C0012 off the Nankai Trough, Japan, through incubations at 20°, 35°, 55°, and 85°C to simulate burial temperatures. Using 3D fluorescence spectroscopy and ultrahigh-resolution mass spectrometry, we tracked changes in dissolved organic matter (DOM). At 35°C, humic-like DOM was released alongside metal ions, exhibiting low bioavailability. At 55°C, abiotic decomposition of humic compounds generated smaller, more bioavailable DOM, promoting fermentation. …


Molecular Characterization Of Humic And Fulvic Acids On Watterlogged And Well-Drained Amazonian Podzols, Amanda M. Tadini, Aleksandar I. Goranov, Stéphane Mounier, Débora M.B.P. Milori, Célia R. Montes, Patrick G. Hatcher Jan 2025

Molecular Characterization Of Humic And Fulvic Acids On Watterlogged And Well-Drained Amazonian Podzols, Amanda M. Tadini, Aleksandar I. Goranov, Stéphane Mounier, Débora M.B.P. Milori, Célia R. Montes, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

The Amazon rainforest is the largest tropical rainforest in the world. Amazonian Podzol soils, characteristic of this region, are known to store substantial amounts of organic carbon in both their surface and deep horizons. Despite decades of research, the molecular-level composition of these soils remains uncharacterized. This study addresses this knowledge gap by employing ultrahigh resolution mass spectrometry, namely, Fourier transform–ion cyclotron resonance–mass spectrometry (FT-ICR-MS), to determine the molecular composition of humic acid (HA) and fulvic acid (FA) fractions from two Amazonian Podzol profiles of varying levels of groundwater exposure (waterlogged vs well-drained). In the waterlogged soil compounds containing nitrogen, …


Deciphering The Chemistry Of Condensed Aromatic "Black" Carbon And Nitrogen In Amazonian Anthrosols, João Vitor Dos Santos, Aleksandar I. Goranov, Laís G. Fregolente, Marcia C. Bisinoti, Zhenhuan Sun, Klaus Schmidt-Rohr, Patrick G. Hatcher Jan 2025

Deciphering The Chemistry Of Condensed Aromatic "Black" Carbon And Nitrogen In Amazonian Anthrosols, João Vitor Dos Santos, Aleksandar I. Goranov, Laís G. Fregolente, Marcia C. Bisinoti, Zhenhuan Sun, Klaus Schmidt-Rohr, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Amazonian anthrosols are renowned for their high fertility and dark color, properties primarily attributed to the abundance of condensed aromatic carbon (ConAC) in the soil organic matter. ConAC, commonly referred to as black carbon, play a key role in the stability and nutrient retention of these soils. However, the processes governing the formation of ConAC and its transformation into oxygenated derivatives remain poorly understood. In this study, we used multiple analytical platforms to investigate the chemistry of ConAC-rich humic acids (HA) extracted from Terra Mulata de Indio, a type of Amazonian anthrosol. The results reveal that ConAC are predominantly …


Oxidation Camouflages Terrestrial Organic Matter To Appear Marine-Like, Aleksandar I. Goranov, Susan J. Carter, Ann Pearson, Patrick G. Hatcher Jan 2025

Oxidation Camouflages Terrestrial Organic Matter To Appear Marine-Like, Aleksandar I. Goranov, Susan J. Carter, Ann Pearson, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

The export of terrestrial organic matter (TOM) to the ocean has been traditionally viewed to be minimal or only of significance in near-coastal continental margins. The broadly accepted explanation for the widespread loss of terrestrial lignin biomarkers and apparent disappearance of the <-25‰ stable carbon isotopic signature (δ¹³C) of TOM is that TOM is almost fully degraded before reaching the open ocean. Oceanic carbon (δ¹³C value ≥ -22‰) is therefore thought to be derived primarily from algae. However, an alternative explanation for the different molecular and δ¹³C signatures in terrestrial and marine environments may be that oxidative processing transforms TOM to appear marine-like. To test this hypothesis, we subjected eight TOM samples to a strong oxidation gradient. At carbon losses typical of TOM degradation during transport and sedimentation (above 60%), the differentiators of provenance disappeared, leaving a residue that was marine-like both chemically (aliphatic- and nitrogen-rich) and isotopically (δ¹³C enrichment of 4 to 9‰). This challenges the validity of conventional two-endmember mixing models, suggesting that a much larger fraction than previously estimated of the organic matter found in the ocean may originate from terrestrial sources, impacting global models of carbon cycling and sequestration.


Restoring Rattlesnake Creek: Using Citizen Science To Assess The Ecological And Morphological Impacts Of Dam Removal In Western Montana, Bethany Blakey Jan 2025

Restoring Rattlesnake Creek: Using Citizen Science To Assess The Ecological And Morphological Impacts Of Dam Removal In Western Montana, Bethany Blakey

Undergraduate Theses, Professional Papers, and Capstone Artifacts

As dam removals increase in frequency across the U.S., most research has focused on the impact of larger dam removals, despite the removal of small dams being much more common. Given the hundreds of small dams in Montana, this research uses citizen science data collected over eight years spanning before and after a 2020 small dam removal in Rattlesnake Creek, Montana, to investigate impact on stream ecology and morphology. We analyzed pebble count grain size distributions and aquatic macroinvertebrate biotic indices from 2017 to 2024 to assess changes in sediment transport and macroinvertebrate population as well as evaluate the efficacy …


Geochemical And Sedimentological Signals Of Bottom Water Oxygen Dynamics From Lake Tanganyika (Zambia), Njahi Mwangala Jan 2025

Geochemical And Sedimentological Signals Of Bottom Water Oxygen Dynamics From Lake Tanganyika (Zambia), Njahi Mwangala

Theses and Dissertations--Earth and Environmental Sciences

Lake Tanganyika is a large, ancient freshwater body with exceptional biodiversity that is located in the East African Rift System. Lake Tanganyika’s size and longevity make its sedimentary record useful for understanding environmental changes that cross spatial and temporal boundaries. Lake Tanganyika is known to be susceptible to global warming given its tropical location. Over 12 million people living within Lake Tanganyika’s watershed rely on fishing for their income and nutrition. Changes to limnological function driven by climate could therefore have serious implications for human health and biodiversity conservation. This study focuses on using geochemical properties of modern lake bottom …


Late Holocene Paleolimnology Of Lake Tanganyika (East Africa), Leandro Domingos Luz Jan 2025

Late Holocene Paleolimnology Of Lake Tanganyika (East Africa), Leandro Domingos Luz

Theses and Dissertations--Earth and Environmental Sciences

Understanding the long-term responses of ecosystems to climate variability is crucial for predicting and mitigating future changes in the Afrotropics, a region where a significant portion of the population is highly vulnerable to extreme climatic events. Lake Tanganyika, the largest rift lake in East Africa, offers a unique sedimentary archive that can be used to investigate the limnological changes, hydroclimatic shifts, and vegetation dynamics across various timescales. A multi-proxy approach was employed to assess the landscape responses to hydroclimatic fluctuations in the Late Holocene, integrating paleoenvironmental records from radiocarbon-dated sediment cores. This approach involved sedimentology, mineralogy, geochemistry, phytolith analysis, and …


Applications Of Remote Sensing Data To Understanding Geohazards In Wyoming And Kentucky, Meredith Swallom Jan 2025

Applications Of Remote Sensing Data To Understanding Geohazards In Wyoming And Kentucky, Meredith Swallom

Theses and Dissertations--Earth and Environmental Sciences

Shallow geohazards such as earthquakes, landslides, and floods profoundly impact communities globally. Constraining susceptibility to these hazards is critical for effective hazard mitigation and building more resilient communities. This dissertation includes multiple studies that leverage remotely sensed datasets to address hazard susceptibility, including: (1) characterizing a potential northern extension of the Teton fault system, (2) deriving a vegetation-based metric to improve landslide susceptibility maps in eastern Kentucky, with potential global implications, and (3) combining numerical modeling, landscape models, and field constraints to understand how anthropogenic factors affect flood severity in southern Appalachian catchments.

In the first study, analysis of new …


Multi-Scale Analysis Of Karst Aquifer Vulnerability To Climate Change And Contamination Processes, Shishir Sarker Jan 2025

Multi-Scale Analysis Of Karst Aquifer Vulnerability To Climate Change And Contamination Processes, Shishir Sarker

Theses and Dissertations--Earth and Environmental Sciences

Karst aquifers represent some of the world’s most productive yet vulnerable groundwater systems, supplying freshwater to approximately 10% of the global population across 15% of Earth’s ice-free land surface. Their distinctive hydrological characteristics— including rapid recharge, preferential flow paths, and limited natural filtration— create unique vulnerabilities to both climate variability and contamination that pose significant challenges for sustainable water resource management. This dissertation presents a comprehensive multi-scale analysis of karst aquifer vulnerability through three interconnected studies that examine climate change impacts, microbial contamination dynamics, and contaminant transport processes across diverse geographic and hydrogeologic settings.

Chapter two investigates climate change impacts …


Monazite Ages In And Fertility Of Crystalline Basement Rocks Of The Eastern Inner Piedmont Province: Potential Source Of Detrital Ree Critical Mineral Resources In The Coastal Plain And Modern Fluvial Systems, Abagale K. Ramsey Jan 2025

Monazite Ages In And Fertility Of Crystalline Basement Rocks Of The Eastern Inner Piedmont Province: Potential Source Of Detrital Ree Critical Mineral Resources In The Coastal Plain And Modern Fluvial Systems, Abagale K. Ramsey

Theses and Dissertations--Earth and Environmental Sciences

The southeastern United States has been known for over a century as a potential resource for rare earth elements due to the abundance of monazite in sediments and crystalline basement rocks. However, sedimentary evolution of the monazite from bedrock to placer deposit and the provenance of the monazite remain untested. This study examined samples collected from the basement rocks of the Piedmont terrane in South Carolina and western North Carolina including peraluminous granites, metagranites, mica schists, and biotite gneisses, and heavy-mineral concentrates of first-order streams draining from these rocks, for age comparison and monazite abundance. Monazite grains were analyzed for …