Polymer Chemistry Commons^™

Soybean Oil-Derived Acrylate/Methacrylate Ether For High Resolution Additive Manufacturing (3d Printing) Technology, Tanuj Patel

Electronic Theses & Dissertations

Additive Manufacturing is one of the rapidly developing techniques, as industries continue to explore new ways to create prototypes and end-use parts, one of the significant challenges that remains is the reliance on petroleum-based plastics for 3D printing, especially in the production of photocurable resins. that may be used to prototype complex structures and sophisticated geometries that are typically challenging to produce with conventional methods. Thus, replacing petroleum-based plastics with renewable resources is increasingly important for additive manufacturing (3D printing) of photocurable resins. The use of bio-based renewable resources in AM is a feasible alternative to traditional petroleum-based plastics. Henceforth, …

Castor Oil Polyol-Based Adhesives With Additional Crosslinker For Improvement In Mechanical And Thermal Properties., Yash Desai

Electronic Theses & Dissertations

Polyurethanes (PU) have been promising polymeric materials with many applications, including adhesives. Projecting an estimated revenue from 42.8 billion $ in 2021 to 61.5 billion $ by 2026. However, a large number of PU adhesives are sourced from petroleum products. Therefore, to lower the dependence on non-renewable resources and provide sustainable and affordable alternatives. In this work will synthesize bio-based adhesives of polyurethane from modified castor oil-based polyol. Generally, polyurethane reaction depends on the properties of polyol and isocyanates. The most important aspect of these reactions is the OH number of the polyol, which is responsible for the crosslinking and …

Sunflower Oil-Based Wood Adhesive With High Mechanical Strength And Enhanced Bonding By Introducing Fillers, Arjun Chaudhari

Electronic Theses & Dissertations

Petroleum-based compounds are generally utilized in industries for getting higher mechanical strength for wood application, where the process of synthesis releases toxins into the environment and causes health issues.

Because of this, scientists are trying to make biobased compounds and products. In this research, sunflower polyol was used to make polyurethane (PU) resin. For the formation of polyol, an epoxidation reaction followed by a ring-opening reaction was performed. The presence of hydroxyl groups was confirmed using Fourier transform infrared spectroscopy (FT-IR) and hydroxyl value determination test to confirm the polyol formation. After that, hydroxyl groups of polyol were reacted with …

Bio-Based Uv-Curable Films And The Effect Of Bio-Content On The Properties Of The Films, Sahilkumar Chaudhary

Electronic Theses & Dissertations

The use of renewable resources in film formation has become a new focal point for industry because it is abundantly available and has less carbon emission during production than traditional ones. This has drawn researchers to investigate the functionality of bio-based raw materials and their end-usage. By modifying their chemical structures, the properties of these films like thermal resistance, impact resistance, and chemical resistance can be increased. In this research, limonene was used as a partial replacement for petroleum-based chemicals in film formation. A two-step chemical process was carried out to modify the limonene and the final product was used …

Soymeal Based Bio-Based Adhesive For Wood Application, Prashant Kote

Electronic Theses & Dissertations

Introducing bio-based materials as an alternative to petroleum-based products has been the greatest challenge for the industry which may reduce environmental problems. Currently, most of the wood adhesive is prepared using formaldehyde which is a non-renewable source as well as toxic. In this research, soybean meal was used as a renewable bio-based source for wood adhesive which has a potential to replace formaldehyde-based adhesives. In this study, soymeal was chemically modified, characterized, and evaluated for its adhesion performance, flow behavior, service life, and thermal stability.

In the first, soymeal was modified using acid (HCl), alkali (NaOH), and salt (CaCl_{2 …}

One-Step Synthesis Of Corn Oil-Based Polyol For Highly Flame-Retardant Rigid Polyurethane Foams, Tenzin Ingsel

Electronic Theses & Dissertations

Rigid polyurethane foams (RPUF), heavily utilized in construction, refrigeration, and the automotive industries, are a significant class of polyurethanes. They can substantially enhance energy efficiency by improving thermal insulation. However, the application of petrochemical sources in polyurethane has raised environmental concerns.

Such concerns call for the development and application of new bio-based polyurethanes to potentially reduce humanity's over-reliance on nonrenewable sources.

In this work, corn oil-based polyol was synthesized via popularized thiol-ene reaction. The obtained polyol was characterized by wet chemistry methods, spectroscopic evaluations, and chromatography. Non-halogenated flame retardants of cost-effective and environmentally friendly nature were incorporated into the polyurethane …

Environment-Friendly Flame Retardants For Bio-Based Polyurethanes, Felipe Martins De Souza

Electronic Theses & Dissertations

Finding alternative ways to decrease the large consumption of non-renewable resources has been one of the greatest challenges faced by the industry and academia. The trend of using bio-renewable-based materials is an interesting alternative to tackle environmental issues as well as provide economically viable materials. In this work, carvone, an essential oil, was used to synthesize a bio-based polyol through a thiol-ene reaction. The chemical functions were analyzed through Fourier transformed infrared spectrum (FTIR), gel permeation chromatography (GPC), viscosity, and hydroxyl number, which confirmed the synthesis of carvone-based polyol. The latter was then physically blended with three different flame-retardants separately: …

Bio-Crosslinking Of Starch Films With Oxidized Sucrose, Hazal Canisag

Department of Textiles, Merchandising and Fashion Design: Dissertations, Theses, and Student Research

In this work, corn starch films were crosslinked with a novel bio-based agent; oxidized sucrose and their strength and stability were improved. Although starch is an inexpensive, biodegradable and abundant source, industrial applications of starch films are limited due to their poor mechanical properties. Crosslinking is one of the most common methods to enhance the mechanical properties of starch films. However, most of the available crosslinkers, such as gluteraldehyde, phosphorus oxychloride, sodium trimetaphosphate, and epichlorohydrin, are either toxic, expensive or with low crosslinking efficiencies. Oxidized sucrose, which is derived by periodate cleavage, has aldehyde groups in the structure and this …