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Chinese Chemical Society | Xiamen University

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Full-Text Articles in Physical Chemistry

Studies On The Inclusion Complexes Of Rhein With Cds By Oscilloscope Polarography, Xiang-Jun Li, Jun Lian, Yong Zhang, Jing-Hao Pan Aug 1999

Studies On The Inclusion Complexes Of Rhein With Cds By Oscilloscope Polarography, Xiang-Jun Li, Jun Lian, Yong Zhang, Jing-Hao Pan

Journal of Electrochemistry

Inclusion action of rhein with CDs was studied by linear sweep oscilloscope polarography. The molar ratio of inclusion complexes of rhein with CDs are 1:1, the inclusion constants in different temperature have been determined and the thermodynamics parameter of some inclusion complexes have also been obtained. It indicates that in normal temperature, the inclusion procedure go on spontaneously, improving temperature is unfavorable to the formation of inclusion complexes.

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Preparation And Ionic Conductivity Of Nanometer-Sized Li2+XGdXSi1+XO3 By The Sol-Gel Method, Ru-Fen Chen, Xiu-Qin Song, Hua-Ting Liu Aug 1999

Preparation And Ionic Conductivity Of Nanometer-Sized Li2+XGdXSi1+XO3 By The Sol-Gel Method, Ru-Fen Chen, Xiu-Qin Song, Hua-Ting Liu

Journal of Electrochemistry

Li2+xGdxSi1-xO3(x =0～0.15) samples have been prepared by the Sol-Gel method. The power samples were characterized by DTA-TG, XRD and TEM. Ionic conductivity of the sinter was determined by means of A-C impedance measurements. The experimental results showed that the range of solid-solution was 0 < x ≤ 0.09, while the conductivity of samples raised with increasing amount of Gd2O3 added, and average grain size of samples was 80 nm. In comparing with the samples by the conventional solid state reaction, the samples prepared by Sol-Gel method required lower temperature and presented higher ionic conductivity.

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A Study Self-Passivation Of Passivie Film Of Stainless Steel In Vinylon Aldehyde Solution, Si-Fu Hu, Chuan-Bi Xu, Zhu-Qiu Cheng Aug 1999

A Study Self-Passivation Of Passivie Film Of Stainless Steel In Vinylon Aldehyde Solution, Si-Fu Hu, Chuan-Bi Xu, Zhu-Qiu Cheng

Journal of Electrochemistry

Properties of self-passivation for the anodic passive film of 1Cr18Ni9Ti and the firsthand passive film of SUS 36 stainless steel in vinylon aldehyde solution(H2SO4(240 g/L)+Na2SO4(70 g/L)+HCHO(25 g/L)+[Fe3+](35.4 mg/L)+[Cl-](240 mg/L) at 70 ℃ were studied by galvanostatic and potentiostatic polarization mesurements. The effects of compponents of vinylon aldehyde solution, i.e. Fe3+ and Cl-, on the passivation behaviours of stainless steel have also been investigated. The experimental results showed there is a conversion zone of the active/passive state if the area ratio of active/passive state on these …

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Effects Of The Surfactant And Ph On Linear Potential Scan Of Aqueous Na2S Solution, Qing-Feng Yi, Qi-Yuan Chen, Ping-Min Zhang Aug 1999

Effects Of The Surfactant And Ph On Linear Potential Scan Of Aqueous Na2S Solution, Qing-Feng Yi, Qi-Yuan Chen, Ping-Min Zhang

Journal of Electrochemistry

In presence of a cationic surfactant HTAB,linear potential scans for Na2S at graphite anode in both saturated sodium tetra-borate solution and 1 mol·L-1 NaOH solution, have been investigated. Results show that anodic current density increases and peak potentials shift to more negative with the increase of HTAB concentrations. The anodic current densities increased by addition of HTAB are larger in 1 mol·L-1 NaOH than those in saturated sodium tetra-borate solution, resulting from different acting forces of HTAB with various charged electro-active species. Both oxidation and reduction peaks in cyclic voltammograms for Na2S containing solution …

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The Influence Of Heat On The Measurement Of Photocurrent At The Anodic Film Of Nickel Electrode, Hang Chen, Zhi-Yu Jiang May 1999

The Influence Of Heat On The Measurement Of Photocurrent At The Anodic Film Of Nickel Electrode, Hang Chen, Zhi-Yu Jiang

Journal of Electrochemistry

The influence of heat on the measurement of photocurrent for nickel electrode in 1 mol/L NaOH solution was investigated by using the photocurrent, photothermal and thermal current methods. It was found that the appearance of photocurrent in potential region of -0.75~0.20 V (vs. Hg/HgO electrode) was due to the p-type semiconductor properties of Ni(OH)2 film in which is agree with the previous report. In the Ni(OH)2/NiOOH redox potential region, the increase of temperature at the surface of working electrode during irradiation significantly promoted the electrochemical reaction strongly. The photocurrent observed in potential region 0.20~0.57 V is mainly …

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The Influential Factors On The Triboelectrochemical Behaviors Of The Passive Alloys, Dong-Bai Sun, Tao Li, Hong-Ying Yu, De-Jun Yang May 1999

The Influential Factors On The Triboelectrochemical Behaviors Of The Passive Alloys, Dong-Bai Sun, Tao Li, Hong-Ying Yu, De-Jun Yang

Journal of Electrochemistry

The tribocorrosion process of Fe-Cr alloys with different Cr content in H2SO4 solution was investigated. The influence of applied load, friction velocity, Cr content and concentration of H2SO4 in solution on the triboelectrochemical behaviors of the alloys was analyzed. It is shown that applied load and friction velocity have singnificant influence on the tribocurrent density in passive region when friction process occurs on part of the surface of alloy. Increasing the corrosion resistance of alloys or decreasing the aggressive of the solution can reduce the alloy removal velocity.

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A Study On The Cathode Protection Potential Against Pitting Corrosion, Chun-Chun Xu, You-Ping Liu, Xiao-Bo Zhang, Xu-Hui Zhao May 1999

A Study On The Cathode Protection Potential Against Pitting Corrosion, Chun-Chun Xu, You-Ping Liu, Xiao-Bo Zhang, Xu-Hui Zhao

Journal of Electrochemistry

The methods have been developed to determine the protection potential against pitting corrosion. They are based on the theory that the pitting protection potential (Ep) is actually the transition potential of the direction of current between the occluded cell and the external surface (ET). ET lasts from -220 mV to -440 mV (SCE), the lowest of which can be considered as cathode protection potential. The Ep values determined with cyclic potentiodynamic polarization method is included in the ET with above methods.

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Zro2 And Zro2-Y2O3 Coatings Deposited By High Energy Pulse, Wei-Ping Yu, Ye-Dong He, Li-Na Zhang, De-Ren Wang May 1999

Zro2 And Zro2-Y2O3 Coatings Deposited By High Energy Pulse, Wei-Ping Yu, Ye-Dong He, Li-Na Zhang, De-Ren Wang

Journal of Electrochemistry

The basic rule and influence factors on deposition of ZrO2 and ZrO2-Y2O3 coatings by high energy pulse were studied. After the oxidizing experiment in air at 1 000 for 100 h, it was shown that the oxidation resistance of 18-8 stainless steel was marketly enhanced by depositing ZrO2 and ZrO2-Y2O3 coatings. The oxidation resistance was increased about 20 times and the oxide scale spallation resistance was increased about 100 times.

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Electrochemical Behavior Of Riboflavin On Glassy Carbon Electrode, Hong Li, Lin-Cai Jiang, Liang-Nian Ji May 1999

Electrochemical Behavior Of Riboflavin On Glassy Carbon Electrode, Hong Li, Lin-Cai Jiang, Liang-Nian Ji

Journal of Electrochemistry

The electrochemical behavior of riboflavin(RF) on glassy carbon has been investigated by using potential sweep, rotating ring-disc electrode and the measurement of differential capacitance. It is shown that a single well-behaved oxidation-reduction wave corresponding to a reversible two-electrons reaction apears in medium of pH<6, and the adsorption of RFH2 formed by electro-reduction is weak and hence its solubility is good. In medium of pH>6, there are two separating but overlapping partly oxidation-reduction waves corresponding to two-step one-electron reaction. The adsorptions of RFH and RFH2 produced by reduction reactions in medium of 6

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Study On The Microband Array Electrode-Based Glucose Microsensor, Neng-Qin Jia, Chui-Jue Sun, Lin Gao, Zong-Rang Zhang, Jian-Zhong Zhu, Guo-Xiong Zhang May 1999

Study On The Microband Array Electrode-Based Glucose Microsensor, Neng-Qin Jia, Chui-Jue Sun, Lin Gao, Zong-Rang Zhang, Jian-Zhong Zhu, Guo-Xiong Zhang

Journal of Electrochemistry

The microband array electrode (MAE) consisting of 11 Pt microband of 5 m in wide, 2000 m long and 85 m gap was fabricated with a thin film techology. The MAE was characterized by means of cyclic voltammetry in a solution of K3Fe(CN)6 and H2O2. The results showed higher current density on MAE than on conventional Pt eletrode due to the strong edge effect of the former. A glucose microsensor was constructed with the substrate electrode of microband array. Microband array electrode was modified by Nafion followed by the immobilization of ferrocene onto …

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Oxidation And Adsorption Of Deoxyribonucleic Acid At Highly Ordered Pyrolytic Graphite And Glass Carbon Electrode, Jian-Zhang Zhou, Ling-Ling Wu, Jin Luo, Zhong-Hua Lin May 1999

Oxidation And Adsorption Of Deoxyribonucleic Acid At Highly Ordered Pyrolytic Graphite And Glass Carbon Electrode, Jian-Zhang Zhou, Ling-Ling Wu, Jin Luo, Zhong-Hua Lin

Journal of Electrochemistry

It is shown that calf thymus DNA (CT DNA) can be adsorbed at highly ordered pyrolytic graphite (HOPG) electrode and detected by differential pulse voltammetry (DPV) and electrochemical atomic force microscopy (ECAFM). It is found that controlled potential pre-polarization influences largely the adsorption of dsDNA while it has little influence on ssDNA. It is demonstrated that ECAFM is useful to exploit adsorption of DNA at HOPGE. The pattern of adsorption of DNA at HOPG electrode that fits best with the experimental data is proposed. The results aslo shows that UV/Vis reflection spectroscopy, which has not been used in studying electrochemical …

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Study On The Hydrogen Permeation Through Zinc Electrodeposit, Jiang-Li Cao, Ji-Xun Wu, Yan-Ping Lu, Jie Shi May 1999

Study On The Hydrogen Permeation Through Zinc Electrodeposit, Jiang-Li Cao, Ji-Xun Wu, Yan-Ping Lu, Jie Shi

Journal of Electrochemistry

The electrochemical hydrogen-permeation technique was used to study hydrogen permeation through zinc electrodeposit with bilayer specimens of Fe substrate/zinc electrodeposit. The effect of coating thickness on hydrogen diffusion coefficient and hydrogen steady-state flux was studied. The results showed that hydrogen diffusion coefficient was approximately in the range of 10-11 cm2·s-1 rank and zinc coating could retard hydrogen permeation. Accordingly, hydrogen steady-state flux and effective diffusion coefficient declined while the coating thickness increased.

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In Situ Ftir Spectroelectrochemical Study Of Palladium Hexacyanoferrate Thin Film Deposited On Glassy Carbon Electrode, Ai-Li Bo, Xiang-Qin Lin May 1999

In Situ Ftir Spectroelectrochemical Study Of Palladium Hexacyanoferrate Thin Film Deposited On Glassy Carbon Electrode, Ai-Li Bo, Xiang-Qin Lin

Journal of Electrochemistry

The electrochemically deposited Palladium hexacyanoferrate thin film on Glassy Carbon electrode (PdHCF|GC) has been studied in HCl, KCl and NaCl solutions by in-situ external reflection FTIR spectroelectrochemical technique. It is found that the behavior of the electroactive PdHCF film can be understood in terms of two states: Pd2Fe(II)(CN)6 formed in the inner layer and (M+)2Fe(II)(CN)6 (M+: electrolyte cation) formed in the outer layer. The inner layer is oxidized at Em=0.87 V in 1 mol/L KCl, while for the outer layer Em=0.77 V(vs. Ag/AgCl). In 1 mol/L NaCl or HCl solutions, …

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Xyz-2 High-Performance Electrochemical Suppressor For Ion Chromatography, Wei-Ling Hu, Hua-Shui Lin May 1999

Xyz-2 High-Performance Electrochemical Suppressor For Ion Chromatography, Wei-Ling Hu, Hua-Shui Lin

Journal of Electrochemistry

The packings of electrochemical suppressor on ion chromatography were studied. It was found that the best packing is the appropriately sulfonate globular resins uniform in size.Using these resins, suppression efficiency was improved to 99.98%,and sensitivity improves about 10%, the reproducibilities of both the height of ion peaks and retention time are very good (c.v<2).

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Influence Of Ptfe And Nafion On The Utilization Efficiency Of Pt/C Catalyst In Pemfc, Xiao-Liang Cheng, Bao-Lian Yi, Jing-Xin Zhang, Ming Han, Ya-Guang Qiao May 1999

Influence Of Ptfe And Nafion On The Utilization Efficiency Of Pt/C Catalyst In Pemfc, Xiao-Liang Cheng, Bao-Lian Yi, Jing-Xin Zhang, Ming Han, Ya-Guang Qiao

Journal of Electrochemistry

With cycling voltammetry curve(C-V), TEM and SEM photographs, the influence of PTFE and Nafion on the platinum utilization in catalyst layer of PEMFC was investigated. The results show that in gas diffusion electrode, the blocking effect of PTFE in the platinum utilization is not pronunced. In the thin-film catalyst layer, the electron conduct of the catalyst was blocked by the nafion solid and this caused the decrease of platinum utilization. With the increase of the nafion content in the catalyst layer, both platinum utilization and the electron conductivity decreased in the catalyst layer. Because the molecule size of nafion is …

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Preparation And Application Of Gold-Film On The Surface Of Bacterial-Modified Carbon Paste Electrode, Rong-Zong Hu, Yan-Ping Ruan, Hao Xu, Jin-Kun Fu, Wei-De Zhang, Wen-Yun Hu May 1999

Preparation And Application Of Gold-Film On The Surface Of Bacterial-Modified Carbon Paste Electrode, Rong-Zong Hu, Yan-Ping Ruan, Hao Xu, Jin-Kun Fu, Wei-De Zhang, Wen-Yun Hu

Journal of Electrochemistry

A novel method for preparation of gold-film composed of ultra-fine gold particles was reported in this paper. The gold-film was prepared by electrochemical method on the surface of the paste electrode modified with the strain Bacillus sp. D01 which has strong ability to absorb and reduce Au3+. In addition, this paper reported an experimental method of determining trace amount of Cu2+ in water solution using cathodic stripping analysis to estimate the performances of the obtained gold-film. The experimental results indicated that this new method for preparation of gold-film is simple. The obtained gold-film electrode is stable and …

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Electochemical Measuments Of Defective Coatingson Buried Steel Substrates, Shi-Zhe Song, Shi-Jiu Jin, Xiao-Ping Song, Yun-Hai Xu, Jian Li, Yu-Ping Liao, Guang-Sen Lai, Ling-Li Liu May 1999

Electochemical Measuments Of Defective Coatingson Buried Steel Substrates, Shi-Zhe Song, Shi-Jiu Jin, Xiao-Ping Song, Yun-Hai Xu, Jian Li, Yu-Ping Liao, Guang-Sen Lai, Ling-Li Liu

Journal of Electrochemistry

An electrochemical technique to detect the defects and detachments of the protective coating on the steel structures with electrochemical impedance spectroscopy (EIS) was offered. A new parameter K, which was defined as the ratio of the electrode resistance amplitude at a certain frequency to that at minimal frequency was obtained in present paper. The results indicated that the change of K at a certain range of frequency reflected the condition of protective coating. The technique was found to be very useful in estimating the different conditions of protective coating after being applied to the carbon steel samples covered with tar …

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The Adsorption Stability Of Interface Corrosion Inhibitor, Fu-Xing Gan, Di-Hua Wang, Jin-Yun Zou May 1999

The Adsorption Stability Of Interface Corrosion Inhibitor, Fu-Xing Gan, Di-Hua Wang, Jin-Yun Zou

Journal of Electrochemistry

Some new results on the adsorption stability of interface corrosion inhibitor are presented. The concept of adsorption stability and the factors influencing the adsorption stability were discussed. It is shown that the anodic desorption potential can be employed to evaluate the adsorption stability of the inhibitor as an empirical character in some conditions. Electrochemical oscillations phenomena were observed for the first time on a rotating iron electrode in H2SO4 solution containing organic inhibitor in the active potential region. These potentiostatic current oscillations can occur under cathodic polarization, as well as under anodic plarization. The oscillation period, amplitude, …

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Effects Of Nickel Content And Simulated Heat Affected Zone Of 2205 Duplex Stainless Steel On Pitting Corrosion, Horng-Yih Liou, Ju-Tung Lee, Wen-Ta Tsai, Rong-Iuan Hsieh, Yeongtsuen Pan May 1999

Effects Of Nickel Content And Simulated Heat Affected Zone Of 2205 Duplex Stainless Steel On Pitting Corrosion, Horng-Yih Liou, Ju-Tung Lee, Wen-Ta Tsai, Rong-Iuan Hsieh, Yeongtsuen Pan

Journal of Electrochemistry

The effects of nickel content and Gleeble simulated heat affected zone (HAZ) of 2205 stainless steel on pitting corrosion were investigated in this paper. The results showed that nickel content, ranging from 4.5 wt% to 6.5 wt% in base metal, had only a minor effect on the electrochemical polarization curves, with all Enp's and Epp's falling in the rang of 1100~1200 mV. Comparing with the base metal, the simulated HAZ microstructure caused an increase in the anodic current density, a distinct decrease in both Enp and Epp , and a reduction in the passive …

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Investigation Of Solution Chemistry In Crevice Of Carbon Steel And Its Anodic Polarization Behavior, Zhuo Chen, Cui-Wei Du, Bei Cao, Yin-Shun Wu, Hai Yang, Zheng-Rong Zhang May 1999

Investigation Of Solution Chemistry In Crevice Of Carbon Steel And Its Anodic Polarization Behavior, Zhuo Chen, Cui-Wei Du, Bei Cao, Yin-Shun Wu, Hai Yang, Zheng-Rong Zhang

Journal of Electrochemistry

A self-made wedge-shaped simulated crevice apparatus was designed to investigate the solution chemistry in crevice of carbon steel and its anodic polarization behavior. For carbon steel with 3.5%(wt) NaCl, the change and the distribution of electrode potential, concentration of Cl- and pH value of solution in the crevice, and the current density of metal in the crevice were measured respectively under various conditions of anodic polarization. The results showed that without polarization the metal about 2 cm away from the opening of the crevice was attacked preferentially because of its lowest free corrosion potential. The anodic polarization promoted the …

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Some Electrochemical Studies On The Bionic Nereistoxin Pesticide-(Ch3)2Nhch(Ch2S2O3)2Na⋅H2O, Chang-Geng Zhang May 1999

Some Electrochemical Studies On The Bionic Nereistoxin Pesticide-(Ch3)2Nhch(Ch2S2O3)2Na⋅H2O, Chang-Geng Zhang

Journal of Electrochemistry

A study of cyclic voltammetric behavior of the nereistoxin pesticide known as Shachongdan is reported. The effects of scan rate, electrolyte pH, and concentration are discussed.The study shows that this electrode process is an irreversible electrode reaction. The saturate adsorption of dihydronereistoxin on the electrode is also discussed with the saturate adsorption amount of 8.23×10-10 mol/cm2.

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The Behaviors Of Capacity Loss Of Limn2O4 Cathodeat Elevated Temperatures, Xiao-Hong Hu, Han-Xi Yang, Xin-Ping Ai, Sheng-Xian Li, Xin-Lin Hong May 1999

The Behaviors Of Capacity Loss Of Limn2O4 Cathodeat Elevated Temperatures, Xiao-Hong Hu, Han-Xi Yang, Xin-Ping Ai, Sheng-Xian Li, Xin-Lin Hong

Journal of Electrochemistry

The capacity loss of spinel LiMn2O4 cathode at elevated temperatures was evaluated by constant current charge-discharge methods and it was found that serious capacity loss and cycleability decrease occured at above 50, especially for the charged cells. The mechanisms for this phenomena were examined by atomic emission and infrared spectrometry of the electrolyte, XRD measurment of the cycled elecrode and microelectrode voltammetry of LiMn2O4 at room and elevated temperatures. The results showed that with increasing temperature, Mn and Li ions tended to redistribute partly in the spinel framework due to the disproportion of Mn …

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Effect Of Inhibitor On Electrochemical Behavior Of 1cr18 Stainless Steel In Acidic Solution Under Friction, Jin-Ping Xiong May 1999

Effect Of Inhibitor On Electrochemical Behavior Of 1cr18 Stainless Steel In Acidic Solution Under Friction, Jin-Ping Xiong

Journal of Electrochemistry

The electrochemical behavior of 1Cr18 stainless steel had been studied using a reciprocating triboelectrochemical equipment under friction in 0.2 mol/L H2SO4 solution with and without addition of thiourea, the frictionized surface of 1Cr18 stainless steel had been examined by the SEM, XPS and IR. The results showed that the loss rate of 1Cr18 stainless steel in the solution could be reduced by addition of thiourea. The adsorption of thiourea on the surface of 1Cr18 stainless steel prohibited the oxidization of Cr3+ to form Cr(Ⅵ) and formation of passive film consisting of CrO42- or/and Cr(Ⅵ), …

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Study Of Localized Corrosion Of Metals By Using The Electrochemical Techniques With Spatial Resolution, Chang-Jian Lin, Xiang-Dong Zhuo, Zu-De Feng, Rong-Gui Du, Zhao-Wu Tian Feb 1999

Study Of Localized Corrosion Of Metals By Using The Electrochemical Techniques With Spatial Resolution, Chang-Jian Lin, Xiang-Dong Zhuo, Zu-De Feng, Rong-Gui Du, Zhao-Wu Tian

Journal of Electrochemistry

The electrochemical inhomogeneities at interface of metal/solution play an important and often controlling role in localized corrosion of metals. The traditional electrochemical techniques involving potential, current density or ac impedance measurements over bulk specimens can only provide average and general information of the interface. Thus, the development of in situ imaging techniques is essential for further characterizing electrochemical inhomogeneities at the metal/solution interface of localized corrosion system. The electrochemical techniques with spatial resolution,including scanning single micro electrode, scanning double micro electrodse and scanning micro chemical probes are reviewed. The effects of electrochemical inhomogeneities on the corrosion behavior, and the mechanism …

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Electrochemical Surface Characterization Of Titanium Alloy(Ti-6al-4v), Jian-Zhong Chen, Qing-Liang Gao, Zhong-Yi Wang, Wen-Jing Xue Feb 1999

Electrochemical Surface Characterization Of Titanium Alloy(Ti-6al-4v), Jian-Zhong Chen, Qing-Liang Gao, Zhong-Yi Wang, Wen-Jing Xue

Journal of Electrochemistry

With its low density and high strength ratio, titanium alloy(Ti6Al4V) has become one of the most important materials both in the fields of aerospace and biomedical assays. Recently, titanium alloy was used as the implantation materials in human body because of its biocompatibility. The elecrochemical impedance techniques were then used to investigate the corrosion behavior of this material in hydrochloride and sulfuric acid solutions. A comparison between impedance spectra and anodic polarization over the correlated range of applied voltage confirms that AC impedance data can be used as a powerful tool for surface characterization of titanium …

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Some Effects Of Co On The Electrochromic Properties Of NioXHY Film, Xiao-Yan Cao, Wen-Hu Zhang, Hua-Tang Yuan, Wan-Lin Zhang, Yin-Nong Lin, Zuoxiang Zhou, Yunshi Zhang Feb 1999

Some Effects Of Co On The Electrochromic Properties Of NioXHY Film, Xiao-Yan Cao, Wen-Hu Zhang, Hua-Tang Yuan, Wan-Lin Zhang, Yin-Nong Lin, Zuoxiang Zhou, Yunshi Zhang

Journal of Electrochemistry

Some effects of Co addition upon the electrochromic characteristics of a nic-kel hydroxide film were studied. The films were electrodeposited on both polished Ni plate and conductive ITO glass. The electrochemical behaviors were investigated using the film on Ni plate by linear potential sweep, a.c. impedance, and anodic polarization curves for OER(oxygen evolution reaction). It was found that Co can lower the working voltage and raise the oxygen overpotential, but has little effect on the reaction kinetics. It was also found that the Co can improve the optical properties of the electrochromic film.

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Study On The Mechanism Of Ni/Zro2 Composite Electrodeposition, Qun-Jia Peng, Dao-Bin Mu, Ju-Sheng Ma, Xiang-Yun Tang Feb 1999

Study On The Mechanism Of Ni/Zro2 Composite Electrodeposition, Qun-Jia Peng, Dao-Bin Mu, Ju-Sheng Ma, Xiang-Yun Tang

Journal of Electrochemistry

The effects of cathodic current density and amount of particle dispersion in solution on the codeposition of Ni/ZrO2 composite in Watts bath were studied, and the machanism of the composite electrodeposition was investigated. The study shows that the composite electrodeposition is controlled by the transfer of particles to the cathode when the dispersion amount is small, causing the decrease of the codeposition with the increase of current density. With large amount dispersion, the composite electrodeposition is first controlled by the strong adsorption of particles on the cathode at low current density, resulting in the increase of the codeposition with …

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Kinetic Study Of Electrooxidation Of Benzene, Xin-Sheng Zhang, Ping Ding, Ying-Chun Dai, Wei-Kang Yuan Feb 1999

Kinetic Study Of Electrooxidation Of Benzene, Xin-Sheng Zhang, Ping Ding, Ying-Chun Dai, Wei-Kang Yuan

Journal of Electrochemistry

A reaction kinetic study for electrochemical oxidation of benzene was performed on a PbO2 rotating disk electrode in 1 mol/L H2SO4 aqueous solution. The reaction orders, the activation energies and transfer coefficient were measured, and the kinetic expression was obtained.

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Pitting Corrosion Of Ni-Based Alloy In Thiosulfate-Ion Containing Chloride Solutions, Yung-Fa Lee, Ting-Yu Wang, Wen-Ta Tsai Feb 1999

Pitting Corrosion Of Ni-Based Alloy In Thiosulfate-Ion Containing Chloride Solutions, Yung-Fa Lee, Ting-Yu Wang, Wen-Ta Tsai

Journal of Electrochemistry

The effect of thiosulfate ion on the pitting corrosion behavior of Ni-Based Alloy 690 in chloride solution was investigated. In plain sodium thiosulfate solution, Alloy 690 was immune to pitting corrosion. However, the addition of low concentration of sodium thiosulfate can enhance the initiation of pitting corrosion of Alloy 690. Nevertheless, inhibition of pitting corrosion was observed at high concentration of addition.

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Synthesis And Application Of Polymeric Corrosion Inhibitor For Reinforced Concrete, Wei-Wei Lin, Sheng-Xian Wang, Jian-Qing Zhang, Jun Yuan, Zhen-Guo Ji Feb 1999

Synthesis And Application Of Polymeric Corrosion Inhibitor For Reinforced Concrete, Wei-Wei Lin, Sheng-Xian Wang, Jian-Qing Zhang, Jun Yuan, Zhen-Guo Ji

Journal of Electrochemistry

A new polymer E-T was synthesized and used as a corrosion inhibitor for reinforced concrete. The inhibitive behavior and mechanism were studied with linear polarization, Tafel polarization, EIS and XPS method in simulated pore solution system with concrete samples. The result showed that the polymer was a mixing type inhibitor. A 1% dosage was sufficient to imhibit the corrosion of steel in simulated pore solution system. The salt endurance was enhanced from 0.02 mol/L to 0.10 mol/L. The result also showed the good synergetic effect of NaNO2, especially in low NaNO2 concentration. The EIS showed that E-T …

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