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Articles 1561 - 1590 of 2395
Full-Text Articles in Physical Chemistry
An Electrochemical Investigation Of Methanol Crossover In Dmfcs, Meng-Di You, Xuan Cheng, Lian Liu, Lu Zhang
An Electrochemical Investigation Of Methanol Crossover In Dmfcs, Meng-Di You, Xuan Cheng, Lian Liu, Lu Zhang
Journal of Electrochemistry
Methanol crossover and its effect on the open-circuit voltage(OCV) in DMFCs were studied usingcyclic voltammetry and chronoamperometry under stationary condition and at ambient temperature.An H-shapecell was constructed and a simulative DMFC test was carried out to investigate methanol crossover through Na-fion(117 from anode to cathode.The results revealed thatthe amountof methanol in the cathode side is depend-ent upon the time of penetration.As the concentration of methanol increased,the hydrogen adsorption-desorptionon the surface of electrode was suppressed and a shoulder peak appeared during the forward sweep for methanoloxidation.The simulative DMFC test also showed that the methanol crossover caused a sudden decline in theOCV.
Electrochemical Studies Of Iron-Doped Nickel Oxide Electrode For Oxygen Evolution Reaction, Jin-Zhao Huang, Zheng Xu, Hai-Ling Li, Guo-Hu Kang, Wen-Jing Wang
Electrochemical Studies Of Iron-Doped Nickel Oxide Electrode For Oxygen Evolution Reaction, Jin-Zhao Huang, Zheng Xu, Hai-Ling Li, Guo-Hu Kang, Wen-Jing Wang
Journal of Electrochemistry
In this paper,the iron-doped nickel oxide thin film as anode catalyst was prepared by RF reactivesputtering method.The oxygen evolution reaction(OER) on the iron-doped nickel oxide was investigated withcyclic voltammetry,liner sweep voltammetry,polarization curves and electrochemical impedance spectroscopy.Results showthat the iron acts as active site in the film which makes the overpotential lower,and changes therate-limiting from primary discharge of OH-ions to the recombination of oxygen atom.With the increasing of ox-ygen content in flu ratio during sputtering,the electrocatalytic activities of the film increase.Iron-doped nickeloxide thin film is promising material as OER electrocatalyst for hydrogen production than the nickel electrode.The oxygen overpotential on the …
Electrodeposition Of Three-Dimensional Porous Copper Films Using Hydrogen Bubbles As Template, Ya-Feng Sun, Zhen-Jiang Niu, Shu-Qiong Cen, Ze-Lin Li
Electrodeposition Of Three-Dimensional Porous Copper Films Using Hydrogen Bubbles As Template, Ya-Feng Sun, Zhen-Jiang Niu, Shu-Qiong Cen, Ze-Lin Li
Journal of Electrochemistry
Using cathodic hydrogen bubbles as a template,the three-dimensional(3-D) porous copper films have been successfully electrodeposited from a bath of 0.2 mol·dm-3 CuSO4 and 1.5 mol·dm-3 H2SO4,effects of deposition parameters including temperature,current density and additives(Na2SO4,HCl and Polyethylene glycol(PEG)) on the morphologies of the deposits have been systematically studied.SEM results showed that both the pore size and thickness of the pore walls decreased with cooling the electrolyte temperature or adding(Na2SO4) or PEG into the bath when the other deposition parameters were fixed.With addition small amounts of HCl …
Structure And Properties Of Electrodeposited Sn-Co Alloy Electrodes As Anode Material For Lithium-Ion Secondary Batteries, Hong-Hong Jiang, Ling Huang, Shun-Wei Zhou, Fu-Sheng Ke, Fang-Zu Yang, Xiao-Yong Fan, Shi-Gang Sun
Structure And Properties Of Electrodeposited Sn-Co Alloy Electrodes As Anode Material For Lithium-Ion Secondary Batteries, Hong-Hong Jiang, Ling Huang, Shun-Wei Zhou, Fu-Sheng Ke, Fang-Zu Yang, Xiao-Yong Fan, Shi-Gang Sun
Journal of Electrochemistry
The Sn-Co alloy deposits were prepared by electroplating.The structure and electrochemical performance of the electroplated Sn-Co alloys have been investigated in detail. Experimental results show that the porous Sn-Co alloy film exhibits hexagonal solid solution,with Sn as the solvent, Co as the solute. The texture of the Sn-Co alloy coating exhibits(110) preferred orientation. Electrochemical tests show that the porous Sn-Co alloy coating electrodes can deliver a discharge capacity of 643mAh/g in the first cycle. At the 20h cycle the charge was 461mAh/g. At initial charge curve the irreversible capacity is probably associated to a combination of processes, which may …
Preparation Of Spherical Ni(Oh)2 Coated With Coooh And Its Fast Charge Performance, Min-Jie Yang, Jun-Min Nan, Jian-Jun Xue, Yan Cui, Ming Cui
Preparation Of Spherical Ni(Oh)2 Coated With Coooh And Its Fast Charge Performance, Min-Jie Yang, Jun-Min Nan, Jian-Jun Xue, Yan Cui, Ming Cui
Journal of Electrochemistry
Spherical Ni(OH)2 was coated with CoOOH through chemical precipitation and electrolytic oxidation.The influences of CoOOH coating on fast charge performance ofMH/Ni battery were studied by preparing high capacity and fast charge AA size MH/Ni batteries.The sample coated with CoOOH was characterized by Infrared spectrum(IR) and scanning electron microscopy(SEM).The results showed that the internal resistance decreased 3.4 mΩ,the charge plateau lower and the cell temperrature was below 55 ℃ at the end of charging process when the cathode active material used Ni(OH)2 coated with CoOOH as compared with that doped by CoO.In addition,an initial discharge efficiency of 90.6% and …
Conductivity Of Comb Polyether Pure Solid Polymer Electrolyte, Lin Ye, Peng Gao, Zeng-Guo Feng, Feng Wu, Shi Chen, Guo-Qing Wang
Conductivity Of Comb Polyether Pure Solid Polymer Electrolyte, Lin Ye, Peng Gao, Zeng-Guo Feng, Feng Wu, Shi Chen, Guo-Qing Wang
Journal of Electrochemistry
A comb polymer was synthesized through cationic ring-opening polymerization starting from a monomer 3-hydroxymethyl-3-methyl-oxetane.The ion conductivity was measured by CHI660A electrochemical station under various lithium salt concentrations and various temperatures.The highest ion conductivity was recorded to be 10-4.43 S/cm at room temperature and 10-3.44 S/cm at 80 ℃.DSC results showed that the segment moves more difficultly with the increasing of lithium salts concentration.XPS found the existence of aggregating lithium ions in POE5 and POE10,and it suggested that POE20 had a suitable lithium concentration for polymer electrolyte.
Studies On Pva-Cmc-Koh-H2O Alkaline Polymer Electrolytes, An-Bao Yuan, Jun Zhao
Studies On Pva-Cmc-Koh-H2O Alkaline Polymer Electrolytes, An-Bao Yuan, Jun Zhao
Journal of Electrochemistry
A given amount of sodium carboxymethyl cellulose(CMC)was added to PVA complex and thus the PVA-CMC-KOH-H2O alkaline polymer electrolyte with this modification was prepared.The properties of the polymer electrolyte films were characterized by AC impedance,cyclic voltammetry,differential thermal analysis and infrared spectroscopic analysis methods.The polymer electrolyte exhibited a high ionic conductivity,typically 10-2S·cm-1 with an electrochemical stability window of about 1.6 V on stainless steel blocking electrodes.The influence of the film composition such as KOH,H2O and CMC on ion conductivity was investigated.In addition,a preliminary study was carried out on the polymer electrolyte for Ni/MH battery.It was …
Anodic Behaviors Of Pb-Ca-Sn-Re Alloy And Tradditional Pb-Ca-Sn Alloy In Sulfuric Acid Solutions, Dang-Guo Li, Gen-Shu Zhou, Liang Yao, Guan-Fa Lin, Mao-Sheng Zheng
Anodic Behaviors Of Pb-Ca-Sn-Re Alloy And Tradditional Pb-Ca-Sn Alloy In Sulfuric Acid Solutions, Dang-Guo Li, Gen-Shu Zhou, Liang Yao, Guan-Fa Lin, Mao-Sheng Zheng
Journal of Electrochemistry
The anodic behaviors of Pb-Ca-Sn-Re and Pb-Ca-Sn alloys were investigated at 1.28 V(vsHg/(H2SO4)) in 4.5 mol/L sulfuric acid solution by means of ac voltammetry,ac impedance and cyclic voltammetry.The results showed that the corrosion-resistance property of Pb-Ca-Sn-Re alloy is better than that of tradditional Pb-Ca-Sn alloy,the growth of Pb(Ⅱ) compounds was inhibited in the film of Pb-Ca-Sn-Re alloy,and the film impedance of Pb-Ca-Sn-Re alloy was decreased,indicating that the conductivity of the film was(increased),which is helpful to enhance the deep recycling property for lead acid battery.
Mechanism Of Self Discharge Performance Improvement In The Ni-Mh Batteries With Naoh Electrolyte, Xiao-Feng Li, Tong-Chi Xia, Hui-Chao Dong, Yan-Wei Wei
Mechanism Of Self Discharge Performance Improvement In The Ni-Mh Batteries With Naoh Electrolyte, Xiao-Feng Li, Tong-Chi Xia, Hui-Chao Dong, Yan-Wei Wei
Journal of Electrochemistry
The self-discharge performance and charge efficiency at 60 ℃ for Ni-MH battery can be markedly enhanced by using NaOH electrolyte instead of KOH electrolyte.Both the results of electrochemical impedance spectroscopy and cyclic voltammetry tests indicate that the separation of H2 from the negative electrode may be partly blocked in the former because of the change of the adsorption/desorption behavior of H on the surface of the negative electrode,thus results in an improvement of self-discharge performance of the battery.
2006 National Conference On Corrosion Electrochemistry And Measuring Methods, Editorial Office Of J.Electrochem.
2006 National Conference On Corrosion Electrochemistry And Measuring Methods, Editorial Office Of J.Electrochem.
Journal of Electrochemistry
No abstract provided.
Development On Hydriding/Dehydriding Kinetics Of Mg Nano-Materials For Hydrogen Storage, Wei Mo, Hong-Liang Sun, Hai-Chang Zhang, Hua-Bin Yang, Zuo-Xiang Zhou
Development On Hydriding/Dehydriding Kinetics Of Mg Nano-Materials For Hydrogen Storage, Wei Mo, Hong-Liang Sun, Hai-Chang Zhang, Hua-Bin Yang, Zuo-Xiang Zhou
Journal of Electrochemistry
The development of Mg nano-materials for hydrogen storage in the recent decade has been reviewed in this paper.It was shown the Mg nano-powders prepared by high-energy ball milling showed promising hydriding and dehydriding performance with the transition metal oxides and other types of hydrogen storage alloys(ABx)as the catalysts.
Electrocatalytic Oxidation Of Glucose On Nano Pt/C Electrode, Cui-Lian Chen, Xiao-Lan Wei, Pei Kang Shen
Electrocatalytic Oxidation Of Glucose On Nano Pt/C Electrode, Cui-Lian Chen, Xiao-Lan Wei, Pei Kang Shen
Journal of Electrochemistry
Nano Pt/C electrocatalysts were prepared by intermittent microwave heating method.The electrooxidation of glucose on smooth Pt and～Pt/C electrodes has been studied and compared.The results showed that the electrochemical properties on nano Pt/C were improved due to the reduction of the overpotential and the increase in the kinetic rate.The surface area would be significantly increased when the particle size of the catalyst was reduced to nano-scale,resulting in the increase in the activity.The enhancement in the resistance to poisoning could be explained that the oxygen-containing species are easier to react with poisoning species on nano Pt/C and re-active the electrode.
Effects Of Sulfide Ions On The Inhibiting Efficiency Of Eda As A Copper Corrosion Inhibitor In Dilute Hcl Solution, Wen-Juan Qu, Rong-Gui Du, Chang-Jian Lin
Effects Of Sulfide Ions On The Inhibiting Efficiency Of Eda As A Copper Corrosion Inhibitor In Dilute Hcl Solution, Wen-Juan Qu, Rong-Gui Du, Chang-Jian Lin
Journal of Electrochemistry
The anticorrosion action of EDA on copper in dilute HCl solution and the effect of sulfide ions on the inhibiting efficiency were studied by the Tafel plot method.The corrosion potential of Cu shifted to more positive value and the corrosion current density decreased after the addition of Na2S to the solution.The results indicated that sulphide ions could increase the inhibiting efficiency of EDA because of the synergistic inhibition effect between EDA and Na2S,resulting from the adsorption of HS- on the surface of Cu,facilitated the adsorption of EDA to form a highly protective adsorbed layer which …
The Complex Of Pasp And Tungstate As Inhibitors Of Cupronickel B10′S Corrosion In 3% Nacl Solution, Qun-Jie Xu, Guo-Ding Zhou, Hui-Feng Wang, Wen-Bin Cai
The Complex Of Pasp And Tungstate As Inhibitors Of Cupronickel B10′S Corrosion In 3% Nacl Solution, Qun-Jie Xu, Guo-Ding Zhou, Hui-Feng Wang, Wen-Bin Cai
Journal of Electrochemistry
AC impedance and polarization curve measurements were conducted to study the effects of environ-ment-friendly inhibitors PASP,Na2WO4 and their complexes on the corrosion of cupronickel B10 in 3%NaCl solution.The results indicate that PASP or Na2WO4 alone does inhibit the corrosion of B10,and most effectiveconcentrations are 40 mg/L and 60 mg/L for PASP and Na2WO4,respectively.With the total concentration of 40mg/L for the complex inhibitors,the optimum complex ratio of PASP to Na2WO4 was 3:1.The complex of such a combination showed a significantly synergetic inhibition effect on the corrosion of B10.
Effect Of Applied Potentials On The Formation Of Self-Assembled Monolayers Of Alkanethiol, Peng Diao, Xiao-Ning Wang, Qun-Chao Hou, Min Guo, Min Xiang, Qi Zhang
Effect Of Applied Potentials On The Formation Of Self-Assembled Monolayers Of Alkanethiol, Peng Diao, Xiao-Ning Wang, Qun-Chao Hou, Min Guo, Min Xiang, Qi Zhang
Journal of Electrochemistry
The self-assembled monolayers(SAMs)of n-dodecanethiol were prepared on gold substrates under electrochemical conditions using potential step technique.Electrochemical impedance spectroscopy was employed to characterize the SAMs prepared under different substrate potentials.It is found that the potential applied to gold substrate has great influence on the formation of SAMs.Within potential regime-0.8 V to 1.2 V,the increase of applied potential firstly leads to the formation of SAMs with higher packing density,better ordering and less defects.However,after reaching the maximum at 0.4 V,the packing density and the ordering of SAMs begin to deteriorate when the substrate potential is further increased.This work provides solid experimental basis for …
The Effect Of Solution Concentration On Properties Of Ru-Ti-Ir Oxide Anode Coatings, Ke Wang, Yan Han, Jun-Tao Wang, Xiao-Ling Zhang, Yu-Pu Sun
The Effect Of Solution Concentration On Properties Of Ru-Ti-Ir Oxide Anode Coatings, Ke Wang, Yan Han, Jun-Tao Wang, Xiao-Ling Zhang, Yu-Pu Sun
Journal of Electrochemistry
The anode coatings of Ru-Ti-Ir oxide with various solution concentrations were prepared by thermal decomposition.The scanning electron microscope(SEM),energy dispersive X-ray detector(EDX),X-ray diffraction(XRD),accelerated life,polarization curve,cyclic voltammetry and electrochemical impedance.spectroscopy(EIS)tests were carried out.The results showed that there was an obvious effect of solution concentrations on the morphology of the coatings,but little effect on polarization of chlorine evolution.Voltammetric charges and double layer capacitances of anode coatings had a tendency to fall down firstly then increase afterwards as the solution concentration increased.
Electrochemical Reduction Behavior Of Benzaldehyde In The Ionic Liquids, Ning Zhao, Wen-Ju Dong, Qi-Zeng Shi
Electrochemical Reduction Behavior Of Benzaldehyde In The Ionic Liquids, Ning Zhao, Wen-Ju Dong, Qi-Zeng Shi
Journal of Electrochemistry
In this paper, the electrochemical reduction of benzaldehyde was investigated in C4MIMBF4, C6MIMBF4 and C8MIMBF4 ionic liquids by cyclic linear sweep voltammetry,cyclic square-wave voltammetry and chronocoulometry.Benzaldehyde exhibits two successive one-electron irreversible reduction(EP1=-1.39 V, EP2=1.69 V) with GC electrode in C4MIMBF4, the voltammetric data for benzaldehyde give diffusion coefficients of 1.5*10-8cm2/s and 1.3*108cm2/s. There is one current peak in C6MIMBF4 and C8MIMBF4 ionic liquids due to their stronger alkalinity …
Oxygen Enrichment Effect Of Ceo2 To The Cathode Performance Of Proton Exchange Membrane Fuel Cell, Xiang-Li Hou, Hong-Feng Xu, Jian-Hua Dong, Xin Sun
Oxygen Enrichment Effect Of Ceo2 To The Cathode Performance Of Proton Exchange Membrane Fuel Cell, Xiang-Li Hou, Hong-Feng Xu, Jian-Hua Dong, Xin Sun
Journal of Electrochemistry
CeO2 was added to Pt/C catalyst in the cathode of PEMFC by both sol and impregnation methods.The samples were evaluated by TEM,cyclic voltammogram techniques and proton exchange membrane fuel cell performance test.The addition of CeO2 obviously improved the performance of PEMFC and represented a notable function of oxygen enrichment in the cathode side.But with the addition of CeO2,part of the catalyst surface was covered and led to the performance drop of the PEMFC.The best content of CeO2 is 1% when it is added by impregnation method and 3% when it is added by sol method.
In-Situ Detection Of The Effect Of Brighter In The Solution For Nickel And Phosphor Alloy, Jian Zheng, Ning Li, De-Yu Li, Guo-Feng Cui
In-Situ Detection Of The Effect Of Brighter In The Solution For Nickel And Phosphor Alloy, Jian Zheng, Ning Li, De-Yu Li, Guo-Feng Cui
Journal of Electrochemistry
In this work,the gold-plated mica was used for the substrate,the concentration of 5% of normal plating solution for the nickel was used as the mother solution,and the effect for the deposition by the brighter with ECSTM was in-situ detected.The solution for deposition without the brighter has no brightness,though the values of the roughness and the H_(A-V) have reduced in evidence after deposition;the solution for deposition with the complete brighter although has great brightness,the values of the roughness and the H_(A-V) have increased(after) deposition;the solution for deposition with the half brighter has a moderate effect on the H_(A-V) and (brightness).Hence,the brighter …
25th Ccs Congress (Notes Of The First Circular), Editorial Office Of J.Electrochem.
25th Ccs Congress (Notes Of The First Circular), Editorial Office Of J.Electrochem.
Journal of Electrochemistry
No abstract provided.
Special Photoelectrochemical Response Of Nano-Crystalline Tio2 Electrode, Bi-Bo Lan, Jian-Zhang Zhou, Yan-Yan Xi, Hong-Xiang Chen, Guang-Hua Yao, Zhong-Hua Lin
Special Photoelectrochemical Response Of Nano-Crystalline Tio2 Electrode, Bi-Bo Lan, Jian-Zhang Zhou, Yan-Yan Xi, Hong-Xiang Chen, Guang-Hua Yao, Zhong-Hua Lin
Journal of Electrochemistry
The nano-crystalline TiO2 electrodes were prepared by spread method,electrodeposition and sol-gel method.The experimental results show that the nano-crystalline TiO2 electrodes have special photoelectrochemical response-the photocrrent-potential curves appear peaks.The special photoelectrochemical behaviors of nano-(crystalline) TiO2 electrodes are ascribed to nano-structure as well as special light induced redox reaction mechanism of nano-crystalline semiconductor electrodes.
Potential Distributions On External Tank Bottom Under Cathodic Protection Of Deep Well Anode, Yan-Xia Du, Guo-Zhong Zhang, Gang Liu
Potential Distributions On External Tank Bottom Under Cathodic Protection Of Deep Well Anode, Yan-Xia Du, Guo-Zhong Zhang, Gang Liu
Journal of Electrochemistry
Potential distributions of deep well anodic electric field on external tank bottom were derived according to the basic law of electromagnetic field and the geometry characteristics of cathodic protection system.Making use of electric field superposition principle,considering the action of anodic and cathodic electric fields,the potential distributions on external tank bottom under the protection of deep well anode were studied.The calculated results were compared and agred well with the measured data.
Preparation Of Spinel Limn2O4 Cathode Materials For Li-Ion Batteries Based On Sol-Gel Process, Xiang-Ming He, Li Wang, Guo-Yun Zhang, Chang-Yin Jiang, Chun-Rong Wan
Preparation Of Spinel Limn2O4 Cathode Materials For Li-Ion Batteries Based On Sol-Gel Process, Xiang-Ming He, Li Wang, Guo-Yun Zhang, Chang-Yin Jiang, Chun-Rong Wan
Journal of Electrochemistry
Spinel LiMn2O4 was prepared from CH3COOLi·2H2O,Mn(CH3COO)2 and adipic acid based on sol-gel process.XRD analysis showed that when the sintering temperature increased,the crystallinity increased,and the capacity also increased.However,its cycleability reached a maximum value at 750 ℃.The sintering duration also influenced on the capacity.The optimized performance was obtained when the sintering was carried out at 750 ℃ for 20 h.Under these conditions,as-prepared spinel LiMn2O4 presented the initial discharge capacity of 130 mAh·g-1 and 125 mAh·g-1 at 15th cycle.
Degradation Of Aniline Wastewater By Electro-Heterogeneous Catalysis Reactor, Wei-Li Liu, Ai-Li Zhang, Ji-Ti Zhou, Bao-Jun Jia, Qun-Li Zhu
Degradation Of Aniline Wastewater By Electro-Heterogeneous Catalysis Reactor, Wei-Li Liu, Ai-Li Zhang, Ji-Ti Zhou, Bao-Jun Jia, Qun-Li Zhu
Journal of Electrochemistry
The treatment of aniline wastewater was investigated using novel electro-heterogeneous catalysis reactor.The effects of applied cell voltage,electrolysis lime,pH value and the electrolyte on electrolysis were investigated.The experimental results show that the reactor with a cell voltage of 30 V,an electrolysis time of 1 h,pH value of 7 and a salinity of 800 mg/L can achieve the best removal efficiency on aniline,which is more efficient than the sole electrochemical reactor.
Electrochemistry And Structures Of Silicon Surface, Gregory X.Zhang
Electrochemistry And Structures Of Silicon Surface, Gregory X.Zhang
Journal of Electrochemistry
Accurate control and fabrication of silicon surface structures from atomic scale to micrometer scale,which may be randomly associated with surface roughness or have well defined patterns,is critical for the per-formance and reliability of electronic devices.Electrochemical reactions of silicon in solutions involved in wetcleaning and etching of silicon wafer play an importantrole in determining the structures of silicon surface.Atre-mendous amount of researches have been done in the last several decades to understand and control a range ofcomplex electrochemical reactions at silicon/solution interface and their relations to the resulted surface struc-tures.The findings generated from these research efforts have been compiled and integrated …
Electroless Nickel Plating On Carbon Nanotube With Non-Palladium Activation Procedure, Guang-Hui Hu, Hui-Huang Wu, Fang-Zu Yang
Electroless Nickel Plating On Carbon Nanotube With Non-Palladium Activation Procedure, Guang-Hui Hu, Hui-Huang Wu, Fang-Zu Yang
Journal of Electrochemistry
A new procedure of surface activation without using palladium salt was proposed for electroless nickel plating on carbon nanotubes.In the procedure,carbon nanotubes were oxidized by nitric acid and then neutralized with NaOH to create carboxyl surface groups which were used to adsorb Ni2+ ions,thereafter the adsorbed Ni2+ ions were chemically reduced into Ni nano-particles as a catalytic center for electroless nickel deposition,all these were further confirmed by infrared absorption spectra and electron microscopic observations.The results indicate that the procedure is feasible to electroless nickel plating on carbon nanotubes.The different morphology of deposits obtained from electroless plating was also …
Electro-Generated Feo42- Using Modified Chitosan Cation Exchange Membrane, Huai-Zhen Zhong, Ri-Yao Chen, Xi Zheng, Zhen Chen
Electro-Generated Feo42- Using Modified Chitosan Cation Exchange Membrane, Huai-Zhen Zhong, Ri-Yao Chen, Xi Zheng, Zhen Chen
Journal of Electrochemistry
The chitosan cation membrane was prepared by crosslinked 2% and doped with 1% H2SO4.The products were marked as MCS.The physical properties and the ion exchange capacity of MCS were studied.Compared to the non-modified membrane,it was found that chemical modifications contributed to improving ion exchange capacity from 0.25 to 2.09 meq/g.Results was also suggested that the MCS can be used as a separator when producing sodium ferrate flocculent using electrochemical process.
Effects Of Srb Biofilm And Corrosion Product Films On Corrosion Behavior Of Carbon Steel, Jing Lin, Yong-Gui Yan, Guang-Zhang Chen, Guang-Zhou Liu, Qing-Fen Li
Effects Of Srb Biofilm And Corrosion Product Films On Corrosion Behavior Of Carbon Steel, Jing Lin, Yong-Gui Yan, Guang-Zhang Chen, Guang-Zhou Liu, Qing-Fen Li
Journal of Electrochemistry
Electrochemical techniques and surface analysis techniques were applied to study corrosion characteristic of A3 steel.The effects on corrosion behavior of A3 steel by sulfate-reducing bacteria(SRB)(biotic media)and corrosion product(abiotic media)were studied.The results showed that biofilms and corrosion product films play different role during different stages.Biofilms were easier flaky with increasing of its thickness.Non-uniform biofilms reduced pitting corrosion of the specimens.The corrosion product films formed under abiotic conditions were more adherently to the surface of the metal than those formed in biogenic media.
Solid Oxide Fuel Cells-Materials And Prospects, Molenda Janina, Marzec Jacek
Solid Oxide Fuel Cells-Materials And Prospects, Molenda Janina, Marzec Jacek
Journal of Electrochemistry
The paper summarizes and discusses the basic properties of solid oxide fuel cell (SOFC) components (electrode materials and electrolyte) from the point of view of their essential functional parameters suck as chemicalstability, transport, catalytic and thermomechanical properties under operational conditions in a SOFC. An interrela-tion between the defect structure of these materials related to oxygen nonstoichiometry and their electronic propertiesand catalytic activity was shown. Single-chamber fuel cell concept was also presented.
The Optimal Sulfonation Conditions Of Self-Doped Polyaniline Obtained By Using Experimental Strategies, Wen-Yar Li, Chi-Chang Hu
The Optimal Sulfonation Conditions Of Self-Doped Polyaniline Obtained By Using Experimental Strategies, Wen-Yar Li, Chi-Chang Hu
Journal of Electrochemistry
The optimal sulfonation condition of self-doped sulfonated polyaniline (prepared from leucoemeraldinebase; denoted as LEB-SPANI) with a high electronic conductivity was obtained by experimental strategies, includingthe fractional factorial design (FFD) and central composite design (CCD). From the FFD experiment, the self-doped LEB-SPANI prepared at a lowtemperature (4℃), a short reaction time (1 h), and a small volume of fumingsulfuric acid (10 mL) showed a better conductivity (ca.127 mS/cm). In the CCD study coupled with a confirmationtest, the highest conductivity (ca.141 mS/cm) of the LEB-SPANI film was obtained under a sulfonation temperatureof 4℃, a sulfonation time of 75 minutes, and a volume …