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Articles 721 - 750 of 1277
Full-Text Articles in Physical Chemistry
Study On Direct Electro-Oxidation Of Anisaldehyde, Lin-Lin Wu, Ying-Hong Zhu, Shan-Shan Li, Hong-Yan Zeng, Chun-An Ma
Study On Direct Electro-Oxidation Of Anisaldehyde, Lin-Lin Wu, Ying-Hong Zhu, Shan-Shan Li, Hong-Yan Zeng, Chun-An Ma
Journal of Electrochemistry
The oxidation of anisole on Pt electrode was investigated by cyclic voltammery and constant potential electrolysis. The influence of scan rates, substrate concentration, supporting electrolytes and solvent were considered . The results show that the electro-oxidation process of anisole was irreversible. In this research the sulfuric acid was the best supporting electrolytes and acetone was the best solvent, and the process was controlled by diffusion . The product of constant potential electrolysis was charactered by GC-MS .The results show that the main products was anisaldehyde, and the selectivity was up to 66.5% when using acetone as solvent.
Dft Study Of Co2 Reduction To Hydrocarbons On Cu Surfaces, Li-Hui Ou, Sheng-Li Chen
Dft Study Of Co2 Reduction To Hydrocarbons On Cu Surfaces, Li-Hui Ou, Sheng-Li Chen
Journal of Electrochemistry
CO2 reduction on Cu(111) single crystal surfaces was studied using DFT calculations on the reaction energies and the minimum energy paths. The results indicated that the possible reaction paths for CO2 reduction on Cu(111) surface are CO2(g) + H* → COOH* → (CO +OH)*, (CO + H)* → CHO*, CHO + H → CH2O* → (CH2+O)*, CH2* + 2H* → CH4 or 2CH2* → C2H4. On Cu(111) surface, the reaction rate is controlled by steps of CH2O* → (CH2 …
Comparison Of Catalytic Performance On Different Materials Supported Pd Catalysts For Formic Acid Oxidation, Su-Dong Yang, Yan-Yu Liang, Zhu-Liang Wen, Qi-Jun Song, Xiao-Gang Zhang
Comparison Of Catalytic Performance On Different Materials Supported Pd Catalysts For Formic Acid Oxidation, Su-Dong Yang, Yan-Yu Liang, Zhu-Liang Wen, Qi-Jun Song, Xiao-Gang Zhang
Journal of Electrochemistry
Graphite oxide (GO) was prepared from by Hummers method. Then the graphene nanosheets supporting Pd catalysts were prepared by a single-step chemical reduction method. The electrocatalytic performance for formic acid oxidation of the prepared Pd/graphene composite was studied as an electrode material in comparison with the composite catalysts based on the other carbons (MWCNTs, SWCNTs, and Vulcan XC-72 carbon black). X-ray diffraction (XRD) and transmission electron microscopy (TEM) measurements indicated that the Pd nanoparticles were well dispersed on the surface of the graphene nanosheets with a small particle size. The electrocatalytic oxidation of formic acid was studied by electrochemically active …
Anode Electrodeposition Of Ti/Mno2 Electrode And Electrocatalytic Oxidization Properties Of Phenol Degradation, Ye Chen, Wen-Li Zhao, Qing Wen
Anode Electrodeposition Of Ti/Mno2 Electrode And Electrocatalytic Oxidization Properties Of Phenol Degradation, Ye Chen, Wen-Li Zhao, Qing Wen
Journal of Electrochemistry
Ti-base manganese dioxide (Ti/MnO2) electrode was prepared by anodically electrodeposition technology in this paper. The structure of the electrode, the microstructure of the electrode surface and the element composition of the electrode were analyzed by XRD, SEM and EDS. The preparation process parameters of the electrode were studied in detail with the help of the V~logi curve and phenol degradation curve. The Ti/MnO2 electrode was anodically electrodeposited at current density 4mA•cm-2, the Mn2 + ions concentration 0.5mol•L-1 and temperature70℃. The V~logi curve and phenol degradation curve were used to evaluate electrocatalytic oxidization properties …
Electrochemical Studies Of Zinc Injection Into The Structure Materials Of Nuclear Power Plants, Sheng-Han Zhang, Yu Tan, Ke-Xin Liang
Electrochemical Studies Of Zinc Injection Into The Structure Materials Of Nuclear Power Plants, Sheng-Han Zhang, Yu Tan, Ke-Xin Liang
Journal of Electrochemistry
The electrochemical and semiconductor characters of oxide films formed on 304L, 316L stainless steel and alloy 600 in high temperature water with zinc addition were studied. Stress corrosion cracking and occupational radiation can be retarded effectively by zinc injection to the primary circuit of pressurized water reactor (PWR). The semiconductor characters of the materials formed by zinc injection was analyzed by Mott-Schottky curves. The surface morphology and components of the corrosion oxide layer were examined and detected by scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). The result reveals that the smaller crystals and the complex Zn-Cr-Ni-Fe oxide were …
Electrochemical Capacitive Performance Of Mesoporous Carbon Based Co-Ni Oxides, Zhen-Sheng Yang, Ling-Bin Kong, Li Deng, Yong-Chun Luo, Long Kang
Electrochemical Capacitive Performance Of Mesoporous Carbon Based Co-Ni Oxides, Zhen-Sheng Yang, Ling-Bin Kong, Li Deng, Yong-Chun Luo, Long Kang
Journal of Electrochemistry
By using defects on the surface of CMK-3 served as nucleation center, Co0.25Ni0.75 oxide/C composite was successfully prepared through a simple chemical co-precipitation method. Characterization was carried by using X-ray diffraction, BET and scanning electron microscopy. Results showed that a perfect mesoporous network of interconnected nanoflakes was obtained for Co0.25Ni0.75 oxide/C composite and, this material has a less crystallization, interconnected nanoflakes network structure and a narrow mesoporous distribution at about 3~4 nm. The highly dispersed and loosely packed Co0.25Ni0.75 oxide/C composite possessed good electrochemical accessibility and fast diffusion rate of OH …
Synthesis Of Mesoporous Nickel Oxide For Supercapacitor Application, Xuan-Xuan Chen, Zhen-Zhen Zhao, Deng-Chao Wang, Zhong-Jie Huang, Wen-Bin Ni, Li Yu, Jian-Wei Zhao
Synthesis Of Mesoporous Nickel Oxide For Supercapacitor Application, Xuan-Xuan Chen, Zhen-Zhen Zhao, Deng-Chao Wang, Zhong-Jie Huang, Wen-Bin Ni, Li Yu, Jian-Wei Zhao
Journal of Electrochemistry
Mesoporous nickel oxide has been synthesized by calcining metal-organic coordination precursor.Transmission electron microscopy and BET test showed that the prepared NiO had a regular morphology and displayed a narrow size distribution.Electrochemical tests revealed that such mesoporous NiO had a specific capacity of 72 F·g-1 at the current of 2.0 A·g-1.Futhermore,the material showed excellent cycle-life stability.There was no degradation of capacitance after 1000 cycles.
A Titanium-Supported Nanoporous Pd Electrocatalyst For Methanol Oxidation, Feng-Juan Niu, Qing-Feng Yi
A Titanium-Supported Nanoporous Pd Electrocatalyst For Methanol Oxidation, Feng-Juan Niu, Qing-Feng Yi
Journal of Electrochemistry
Titanium-supported nanoporous palladium electrode(nanoPd /Ti) was prepared by a hydrothermal process in the presence of the ligand EDTA and using formaldehyde as reducing agent.SEM images showed that the size of Pd particles was about 60 nm and the Pd particles were connected with each other to form a three-dimensional network structure.Cyclic voltammetry(CV) and electrochemical impedance spectroscopy(EIS) were applied to evaluate the electrocatalytic activity of the nanoPd/Ti electrode towards methanol oxidation in alkaline solution.CV results showed that the nanoPd /Ti electrode presented high anodic peak densities and a low onset potential for methanol oxidation.Also nanoPd /Ti electrode showed excellent CO tolerance …
The Charge-Discharge Properties Of 40 Ah Aerospace Nickel Hydrogen Cell, Hai-Chang Zhang, Wen-Cheng Ming, Xue-Ying Ren, Hui-Juan Li, Hong-Min Fan, Li-Chao Li
The Charge-Discharge Properties Of 40 Ah Aerospace Nickel Hydrogen Cell, Hai-Chang Zhang, Wen-Cheng Ming, Xue-Ying Ren, Hui-Juan Li, Hong-Min Fan, Li-Chao Li
Journal of Electrochemistry
In present investigation,40 Ah nickel-hydrogen cell has been manufactured and its charge-discharge properties has been performed.The results indicate that the cell exhibited the best discharge capacity(50 Ah) when the test conditions were between 0~10 ℃,on the other hand,the cell accompanied with temperature being raised to 10 ℃ while the cell was subjected to discharge operating.The cell voltage decreased to -0.2 V and the cell temperature increased continuously during the over-discharge test.The cell voltage was first increased and then decreased,but the cell temperature was climbed rapidly while the cell was performed during the over-charge test.The 40 Ah nickel-hydrogen cell has excellent …
Novel Anion Exchange Membranes Base On Copolymer Of 2-(Diethylamino) Ethyl Methacrylate And Fluoro-Polyacrylate For Alkaline Direct Methanol Fuel Cells, Yan-Mei Zhang, Jun Fang, Ge Yan, Yong-Ze Zhuang
Novel Anion Exchange Membranes Base On Copolymer Of 2-(Diethylamino) Ethyl Methacrylate And Fluoro-Polyacrylate For Alkaline Direct Methanol Fuel Cells, Yan-Mei Zhang, Jun Fang, Ge Yan, Yong-Ze Zhuang
Journal of Electrochemistry
Anion exchange membrane fuel cells,which use anion exchange membranes as polyelectrolytes,have attracted more and more research interests recently.In this work,a series of hydroxyl-conducting anion-exchange membranes based on the copolymer of 2-(Diethylamino)ethyl methacrylate and fluoro-polyacrylate were prepared by radical polymerization,and their potential applications in alkaline fuel cells were assessed.It was shown that the ionic conductivity of the membranes reached 10-2 S·cm-1 at room temperature,while the methanol permeability was lower than 10-7 cm2·s-1.The maximum power density of fuel cell assembled with this membrane was achieved to be 43.2 mW·cm-2 at room temperature,indicating possible application …
Applications Of Raman Spectroscopy Technique In Lithium Ion Batteries, Liang Zhao, Yong-Sheng Hu, Hong Li, Zhao-Xiang Wang, Hong-Xing Xu, Xue-Jie Huang, Li-Quan Chen
Applications Of Raman Spectroscopy Technique In Lithium Ion Batteries, Liang Zhao, Yong-Sheng Hu, Hong Li, Zhao-Xiang Wang, Hong-Xing Xu, Xue-Jie Huang, Li-Quan Chen
Journal of Electrochemistry
The Raman spectroscopy has been widely used in the study of lithium ion batteries.In this short review,we gave some examples of the applications of Raman spectroscopy in the study of electrode materials including carbonaceous materials,spinel LiMxMn2-x O4,LiFePO4,as well as polymer electrolytes,room temperaturemolten salt electrolytes and the solid-electrolyte interphase layers.The advantages and disadvantages of the ex-situ and in-situ Raman spectrum techniques are discussed.Using new Raman techniques to investigate Li-ion batteries are suggested.
Electrooxidation Of Methanol On Multilayer Films Of Polypyrrole-Platinum Electrode, Ling Zhang, Long-Zhen Zheng
Electrooxidation Of Methanol On Multilayer Films Of Polypyrrole-Platinum Electrode, Ling Zhang, Long-Zhen Zheng
Journal of Electrochemistry
Multilayer films of polypyrrole-platinum electrode were fabricated by cyclic voltammetric technique.Electro-oxidation of methanol on this electrode was investigated with the aid of cyclic voltammetry and chronoamperometry.Results demonstrated that the multilayer of polypyrrole-platinum electrode behaved better electrocatalytic performance for electro-oxidaton of methanol and better poison resistant.Furthermore,with the increase of deposited platinum loadings,the rate controlling step on electro-oxidation reaction of methanol was changed from CO oxidation to sorption-desorption of hydrogen.
Preparation And Electrochemical Properties Of Sn Thin Film As Anode Materials For Lithium-Ion Batteries, Hong-Mei Bai, Zhan-Liang Tao, Fang-Yi Cheng, Jun Chen
Preparation And Electrochemical Properties Of Sn Thin Film As Anode Materials For Lithium-Ion Batteries, Hong-Mei Bai, Zhan-Liang Tao, Fang-Yi Cheng, Jun Chen
Journal of Electrochemistry
Sn thin films as the anode materials of Li-ion batteries were prepared by vacuum-evaporation method on the copper foam substrate. The phase structure,surface morphology and electrochemical property of the as-prepared films were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM), and galvanostatic cycling. The results showed that three-dimensional structure of copper foam substrate enhanced the adhesion strength between the active material and the substrate, under the same substrate temperature, the particles became bigger with the increasing of evaporation time, while their electrochemical property decreased, under the same evaporation time, the particles didn′t changed obviously with the increasing of substrate temperature,while their cycle …
Electrocatalytic Oxidation Of Hydrazine At Rutin Carbon Nanotubes Modified Electrode, Hong-Fang Zhang, Qing-Lin Sheng, Jian-Bin Zheng
Electrocatalytic Oxidation Of Hydrazine At Rutin Carbon Nanotubes Modified Electrode, Hong-Fang Zhang, Qing-Lin Sheng, Jian-Bin Zheng
Journal of Electrochemistry
The electrochemical behavior and electrocatalytic oxidation of hydrazine on rutin multiwall carbon nanotubes modified glassy carbon electrode were studied by cyclic voltammetry.The experimental results indicated that the electrode exhibits good electrocatalytic activity to hydrazine at a reduced oxidation potential of 262 mV.The amperometric response of the modified electrode showed linear increase after successive addition of hydrazine in the concentration range of 2.5×10-6~1.0×10-4 mol·L-1 with a detection limit of 5×10-7 mol·L-1.
Electrochemical Double-Layer Capacitors Using Phenolic Resin-Based Carbon Fibers, Rong Xue, Jing-Wang Yan, Ying Tian, Bao-Lian Yi
Electrochemical Double-Layer Capacitors Using Phenolic Resin-Based Carbon Fibers, Rong Xue, Jing-Wang Yan, Ying Tian, Bao-Lian Yi
Journal of Electrochemistry
Phenolic resin-based activated carbon fiber(ACF) was prepared by KOH activation.The electrochemical properties of pulverized phenolic resin-based carbon fiber(P-ACF) were examined in 6 mol·L-1 KOH compared with that of the original ACF.P-ACF exhibited a better capacitive behavior and showed a larger specific capacitance(200 F·g-1) as well as a lower capacitance decrease at high current densities.The pore resistance for ion migration(Rp) in P-ACF was lower(2.96 Ω) than that in ACF(4.65 Ω).Pulverization increased the exposure of the cross section,lowered the contact resistance between the carbon fibers and decreased the pore resistance for ion migration.
Low-Temperature Performance Of Li-Ion Battery With Fluoroethylene Carbonate Electrolyte, Chun-Wei Yang, Feng Wu, Bo-Rong Wu, Yong-Huan Ren, Jing-Wen Yao
Low-Temperature Performance Of Li-Ion Battery With Fluoroethylene Carbonate Electrolyte, Chun-Wei Yang, Feng Wu, Bo-Rong Wu, Yong-Huan Ren, Jing-Wen Yao
Journal of Electrochemistry
The low temperature performance of electrolytes containing FEC including FEC+EMC, EC and PC, as well as the compatibility of electrolytes with LiFePO4 anode and with MCMB cathode were investigated.The electrolyte exhibits a high value of ionic conductivity at low temperature.The stability of cathode was enhanced by the formation of SEI film at 1.6 V as a result of FEC reaction. The infrared spectra showed that FEC can suppress decomposition of other solvents during SEI formation, and lower the resistance of SEI on MCMB cathode. The electrochemistry test indicates that Li-ion batteries with FEC electrolyte display high capacity at low …
Electrochemical Deposition Of Zinc Oxide Crystal Whiskers, Peng-Zeng Lu, Su Li, Jin-Qian Jia, Zhen-Hai Liang
Electrochemical Deposition Of Zinc Oxide Crystal Whiskers, Peng-Zeng Lu, Su Li, Jin-Qian Jia, Zhen-Hai Liang
Journal of Electrochemistry
Pine needle ZnO crystal whiskers were electrodeposited by anodization of zinc foil.The crystal whiskers were characterized by scanning electron microscopy(SEM) and X-ray diffraction(XRD) spectroscopy.The results show that the lengths and diameters of ZnO crystal whiskers are 200~300 nm and 20~50 nm,respectively,with the ratio of the length to diameter ranging from 10~15.The whiskers belong to wurtzite ZnO(JCPDS 36-1451) with good crystallinity and high purity.The crystalization behavior of ZnO was studied by cyclic voltammetry.The effects of the surface oxide layer at the zinc substrates and the [Zn(OH)4]2-concentration of the aqueous electrolyte on the formation of zinc oxide whiskers …
The Sol-Gel Synthesis And Electrochemical Performance Of Li3V2(Po4)3/C Cathode Material For Lithium Ion Battery, Li-Ying Liu, Lian Chen, Hai-Yan Zhang, Yu-Chun Zhai
The Sol-Gel Synthesis And Electrochemical Performance Of Li3V2(Po4)3/C Cathode Material For Lithium Ion Battery, Li-Ying Liu, Lian Chen, Hai-Yan Zhang, Yu-Chun Zhai
Journal of Electrochemistry
Li3V2(PO4)3/C was synthesized by sol-gel method with citric acid as chelate and C sources. Physical and electrochemical performances of as-prepared materials were characterized through XRD, SEM and galvanostatic charge-discharge tests,etc. The results showed that products produced by calcining at 800 ℃ for 12 h had a single phase crystal structure and relatively small particle sizes with uniform distribution. At 0.1 C, 0.5 C and 1 C, the initial specific discharge capacities were 153.0, 143.1 and 130.6 mAh·g-1, respectively, and capacity efficiencies were 93.1%, 85.4% and 77.3% after 50 cycles, respectively. …
Photoelectrochemical Properties Of N, S, And Cl Modified Nano Tio2 Thin Films, Hong Yun, Chang-Jian Lin, Jing Li, Rong-Gui Du
Photoelectrochemical Properties Of N, S, And Cl Modified Nano Tio2 Thin Films, Hong Yun, Chang-Jian Lin, Jing Li, Rong-Gui Du
Journal of Electrochemistry
The nitrogen(N),sulfur(S) and chlorine(Cl) modified nano TiO2 thin films were prepared by adding Ti(O-n-Bu)4 as the precursor into concentrated HNO3,H2SO4 and HCl Solutions,respectively,on different substrates in a sol-gel process.The photoelectrochemical performances of N,S and Cl modified nano TiO2 thin films have been studied by UV-vis(DRS),photocurrent curves,EIS and OCP-time curves.N-modified TiO2 nano films show better surface structure,which helps to improve the quantum efficiency of nano TiO2 thin films.
Hydrothermal Reduction Synthesis Of Lifepo4 And Its Electrochemical Performance, Hong-Li Zou, Guang-Hui Zhang, Pei-Kang Shen
Hydrothermal Reduction Synthesis Of Lifepo4 And Its Electrochemical Performance, Hong-Li Zou, Guang-Hui Zhang, Pei-Kang Shen
Journal of Electrochemistry
The cathode materials of LiFePO4 were prepared via a hydrothermal reduction method using FeCl3 as Fe source and iron as a reducing agent.The results showed that ferric salt could be reduced to ferrous salt completely under the hydrothermal condition and pure-phase LiFePO4 was obtained based on the test results of XRD and FTIR.Carbon-coated LiFePO4 was synthesized by pyrolysisng glucose at high temperature.The morphologies of pure LiFePO4 displayed cluster-like while the LiFePO4/C displayed sphere-like particles.The electrochemical test showed that the LiFePO4/C had good rate performance,while LiFePO4 delivered much lower discharge capacity.
Effects Of Solvents And Electrolyte Salts On The Electrochemical Reduction Of Oxygen In Non-Aqueous Electrolytes, Yan-Yan Tian, Wei Wu, Jun Gao, Yong Yang
Effects Of Solvents And Electrolyte Salts On The Electrochemical Reduction Of Oxygen In Non-Aqueous Electrolytes, Yan-Yan Tian, Wei Wu, Jun Gao, Yong Yang
Journal of Electrochemistry
The electrochemical reduction processes of oxygen in different non-aqueous solvents such as acetonitrile(MeCN),propylene carbonate(PC) and their mixtures were investigated by cyclic voltammetry method.The results indicated a one electron reduction of oxygen to O2-occured in these systems as a first step reduction,no matter whether in tetrabutylammonium hexafluorophosphate(TBAPF6)/MeCN or TBAPF6/PC electrolyte.However,the CV curves in 0.1 mol·L-1 TBAPF6/MeCN showed a couple of reversible redox peaks,indicating that the reduction process of oxygen was irreversible in the 0.1 mol·L-1 TBAPF6/PC electrolyte.In the PC-based electrolyte,the reduction current peak reduced largely and the oxidation peak …
Electrodeposition Of Lead Dioxide From Dluoroborate Solutions, Chun-Mei Kong, Yong-Ming Tang, Wen-Zhong Yang, Xiao-Yuan Yang
Electrodeposition Of Lead Dioxide From Dluoroborate Solutions, Chun-Mei Kong, Yong-Ming Tang, Wen-Zhong Yang, Xiao-Yuan Yang
Journal of Electrochemistry
The PbO2 anodes were prepared on platinum from fluoroborate media and its doped solutions by electrodeposition technique.Elecchemical and pysicochemical properties of these PbO2 films were studied by cyclic voltammetry methods,XRD and SEM.The results showed that the presence of BF4-increased PbO2 electrodeposition rate;the prepared lead dioxide consisted of β-PbO2;the preferential orientation of crystals and surface morphology were affected a lot by doping F-and Fe3+.The FB/F-Fe-PbO2 electrode exhibited regular-shaped layers with compact morphology.Furthermore,increasing current density also change the preferential orientation of PbO2 crystals.
Research On Nafion/Sio2 Composite Membrane In All Vanadium Redox Flow Battery, Dong-Dong Liu, Mao-Cai Lin, Tao Guan, Qing-Chun Yu
Research On Nafion/Sio2 Composite Membrane In All Vanadium Redox Flow Battery, Dong-Dong Liu, Mao-Cai Lin, Tao Guan, Qing-Chun Yu
Journal of Electrochemistry
The Nafion117/SiO2 composite membrane was prepared by sol-gel method.The results showed that,during composite membrane preparation process,the ratio of MeOH and TEOS did not affect the penetration rate of VO2+ basically,however,the lowest permeability of 427×10-9cm2/s in the membrane was achieved while hydrolysis time was 10 min and natural drying for 24 h after hydrolysis,which reduced by 52 times than that in Nafion117 membrane.The SEM tests proved that SiO2 grains grew bigger in the composite membrane during the natural drying,and most of the holes in Nafion117 were filled.Single cell test showed the battery power efficiency was improved …
An In Situ Fourier Transform Infrared Spectroelectrochemical Study On Alcohols Electrocatalytic Oxidation At Pd Electrode In Acidic Solution, Hai-Ping Huang, Lian-Qin Wang, Pei-Kang Shen
An In Situ Fourier Transform Infrared Spectroelectrochemical Study On Alcohols Electrocatalytic Oxidation At Pd Electrode In Acidic Solution, Hai-Ping Huang, Lian-Qin Wang, Pei-Kang Shen
Journal of Electrochemistry
The methanol and ethylene glycol electrooxidation on palladium electrode in acidic solution has been investigated by cyclic voltammetry and in situ Fourier transform infrared spectroelectrochemistry. It shows that the oxidation of methanol and ethylene glycol at Pd electrode cannot proceed until over 1.5 V in acidic and neutral media. The overpotential decreases and the peak current density increases with the reduction in pH values. The formation of the oxygen-containing species significantly affects the alcohol oxidation on Pd electrode. The in situ FTIR spectroscopic measurements show that the oxidation products of ethylene glycol on Pd electrode are CO2 and oxalic …
Comparative Study Of Nanoporous Pt, Ptru And Ptruir Catalysts Using Electrochemical Ftir Spectroscopy, M. Amussen Robert, Holt-Hindle Peter, Nigro Samantha, Aicheng Chen
Comparative Study Of Nanoporous Pt, Ptru And Ptruir Catalysts Using Electrochemical Ftir Spectroscopy, M. Amussen Robert, Holt-Hindle Peter, Nigro Samantha, Aicheng Chen
Journal of Electrochemistry
In recent years much effort has been put towards developing efficient Pt-based electrocatalysts for applications in fuel cells. With the rising cost of precious metals such as Pt,the need to enhance the activity and to decrease the load of catalysts is prominent. Herein we report on the synthesis and comparative study of nanoporous Pt,PtRu and PtRuIr electrocatalysts. The nanoporous electrodes were fabricated using a hydrothermal method and characterized by scanning electron microscopy (SEM) ,energy dispersive spectroscopy (EDS) ,X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) . The electrocatalytic activity of the fabricated nanopo- rous materials was evaluated using both CO …
Electrooxidation Of Carbon Monoxide On Pd Thin Film-Coated Au Electrodes: Film Thickness Dependence, Yuqing Yang, Shouzhong Zou
Electrooxidation Of Carbon Monoxide On Pd Thin Film-Coated Au Electrodes: Film Thickness Dependence, Yuqing Yang, Shouzhong Zou
Journal of Electrochemistry
The adsorption and electrooxidation of CO on Pd-coated Au electrodes were studied by cyclic voltammetry and surface-enhanced Raman spectroscopy (SERS) . It is found that CO oxidation activity is film thickness dependent. Cyclic voltammograms (CVs) showed that CO oxidation peak potential shifted positively with the increase of the Pd thickness. SERS showed a redshift of the C—O stretching frequency with increasing Pd film thickness. These observations were explained by the dband theory. The strain effect strengthens CO adsorption and stabilizes adsorbed CO,while the ligand effect weakens CO adsorption and eases its oxidation. The ligand effect overpowers the strain effect.
In Situ Surface-Enhanced Raman Scattering Spectroscopic Study Of Sulfur Adsorption On Polycrystalline Platinum Electrode Surface, Bolian Xu, In-Su Park, Ying Li, De-Jun Chen, Yuye J. Tong
In Situ Surface-Enhanced Raman Scattering Spectroscopic Study Of Sulfur Adsorption On Polycrystalline Platinum Electrode Surface, Bolian Xu, In-Su Park, Ying Li, De-Jun Chen, Yuye J. Tong
Journal of Electrochemistry
The paper reports the first in situ surface enhanced Raman scattering (SERS) spectroelectrochemistry study of sulfur adsorption and electro-oxidation on highly roughened polycrystalline Pt surface in both acidic and basic supporting electrolytes. The SERS spectra were taken at a constant electrode potential after accumulative electro-oxidation CVs of the Pt electrode with pre-adsorbed sulfur species and at different electrode potentials that were varied stepwise of the Pt electrode immersed in sulfur-containing electrolytes without pre-adsorbed sulfur species. In both cases,a dominant vibrational band at 299 cm-1 in acidic electrolyte but at 310 cm-1 in basic electrolyte was observed,which was assigned …
Studies Of Oxidation Processes Of Adsorbed And Solution Co On Pt(110) Electrode By Cyclic Voltammetry And In Situ Ftirs, Li Tian, Jun-Tao Li, Jin-Yu Ye, Chun-Hua Zhen, Shi-Gang Sun
Studies Of Oxidation Processes Of Adsorbed And Solution Co On Pt(110) Electrode By Cyclic Voltammetry And In Situ Ftirs, Li Tian, Jun-Tao Li, Jin-Yu Ye, Chun-Hua Zhen, Shi-Gang Sun
Journal of Electrochemistry
The oxidation processes of adsorbed CO (COad) and solution phase CO (COsol) on Pt(110) electrode were investigated by cyclic voltammetry and in-situ FTIR spectroscopy. It has revealed that in comparison with COad on Pt(110) in a CO-free solution,the oxidation current peak of COsol in a CO-saturated solution is positively shifted ca. 168 mV,and the peak current density has been increased by 6. 70 times. Linear adsorbed CO (COL) is determined by in-situ FTIR spectroscopy as the main species,which is uniformly distributed on Pt (110) surface. In a CO-free solution,the onset potential of COL is measured by in-situ FTIRS ca. 0. …
Solid State Nmr Studies Of Lithium Manganese Silicate As Positive Electrode Materials For Li-Ion Batteries, Hu Cheng, Zi-Geng Liu, Yi-Xiao Li, Zhong Chen, Yong Yang
Solid State Nmr Studies Of Lithium Manganese Silicate As Positive Electrode Materials For Li-Ion Batteries, Hu Cheng, Zi-Geng Liu, Yi-Xiao Li, Zhong Chen, Yong Yang
Journal of Electrochemistry
The Li2MnSiO4 cathode material for lithium ion batteries was synthesized by sol-gel assisted hydrothermal method. XRD,FTIR and SS-NMR were used to study the phase,structure and morphology of obtained samples. Electrochemical performance of cathode material was tested. The results show that the main phase of sample prepared was Li2MnSiO4,whereas a small amount of impurities (Li2CO3) were existed. The Li2MnSiO4 cathode material gave an initial discharging capacity of about 190 mAh·g -1. But this capacity faded rapidly during the cycling process due to the decomposition of Li …
A High Performance Sulfur/Carbon Xerogel Composite In Lithium Sulfur Battery Application, Chong Wang, Jia-Jia Chen, Qiu-Jie She, Qian Zhang, Yi-Ning Shi, Ming-Sen Zheng, Quan-Feng Dong
A High Performance Sulfur/Carbon Xerogel Composite In Lithium Sulfur Battery Application, Chong Wang, Jia-Jia Chen, Qiu-Jie She, Qian Zhang, Yi-Ning Shi, Ming-Sen Zheng, Quan-Feng Dong
Journal of Electrochemistry
Sulfur/carbon composite was synthesized by the thermal method with the carbon xerogel as the conductive framework. The property of composite was characterd by XRD and SEM. It shown that the composite with the particle size below 10 μm had the same morphology as the carbon xerogel and the sulfur was absorbed in the pores in non-crystalline. The discharge capacity of the composites were 1311 mAh/g and 1107. 1 mAh/g at 0. 1C and 0. 2 C rates,respetively. And a retention capacity was about 800 mAh/g after 30 cylcyes.