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Articles 271 - 300 of 1756
Full-Text Articles in Physical Chemistry
Preparation Of Pdcoir Tetrahedron Nanocatalysts And Its Performance Toward Ethanol Oxidation Reaction, Zhi-Yuan Yu, Rui Huang, Jie Liu, Guang Li, Qian-Tong Song, Shi-Gang Sun
Preparation Of Pdcoir Tetrahedron Nanocatalysts And Its Performance Toward Ethanol Oxidation Reaction, Zhi-Yuan Yu, Rui Huang, Jie Liu, Guang Li, Qian-Tong Song, Shi-Gang Sun
Journal of Electrochemistry
As a new energy conversion device, direct ethanol fuel cells (DEFCs) are widely concerned because of their remarkable advantages such as high theoretical energy density and wide fuel sources. However, the rapid development of DEFCs has been severely impeded due to the sluggish kinetic process and toxic intermediates especially in their anodic reactions. Palladium (Pd)-based materials are considered to be excellent anode catalysts for DEFCs, especially under alkaline conditions. And further improving their performance is an important direction to promote the development of DEFCs. Surface structure and composition are the key factors affecting the performance of catalysts which can be …
Research Progress On Transition State Of Organic Electrode Materials, Xue-Qian Zhang, Zhou-Guang Lu, Wei-Wei Huang
Research Progress On Transition State Of Organic Electrode Materials, Xue-Qian Zhang, Zhou-Guang Lu, Wei-Wei Huang
Journal of Electrochemistry
With the increasing requirements for high energy density, long lifetime, high safety, environmentally friendly fabrication, and sustainable development of large energy storage devices, the society calls for new electrode materials in rechargeable batteries beyond traditional inorganic materials which are limited by specific capacity. Organic electrode materials have been widely used in rechargeable batteries due to their advantages of large theoretical capacity, designable structures and environmentally friendly fabrications. In this review, the radical intermediates of organic electrode materials produced in the charging-discharging process (redox reaction) and their types are systematically reviewed. The stability of radical intermediates controlled by changing the structure …
Research Progress Of Sio2 Regrowth During Selective Etching Process In 3d Nand Manufacture Procedure, Zi-Han Zhou, Yun-Wen Wu, Ming Li, Su Wang
Research Progress Of Sio2 Regrowth During Selective Etching Process In 3d Nand Manufacture Procedure, Zi-Han Zhou, Yun-Wen Wu, Ming Li, Su Wang
Journal of Electrochemistry
As one of the most significant memory chips in semiconductor market, NAND has been developed from two-dimension (2D) to three-dimension (3D). Due to the three-dimensional memory structure of 3D NAND, the capacity density, read-write speed and reliability of memory chips have been greatly improved, as well as the reduction of power dissipation. It is by nitride-oxide selective etching process in the alternate stacked structure of 3D NAND that the inter-dielectric layers can be obtained. The more stack layers, the better performance of chips will be. Meanwhile, however, silicon dioxide (SiO2) would regrow on the corner of oxide layers, …
Preparation And Performance Investigation Of Li-Sgo Doped Semi-Ipns Porous Single Ion Conducting Polymer Electrolyte, Yun-Feng Zhang, Jia-Ming Dong, Chang Tan, Shi-Kang Huo, Jia-Ying Wang, Yang He, Ya-Ying Wang
Preparation And Performance Investigation Of Li-Sgo Doped Semi-Ipns Porous Single Ion Conducting Polymer Electrolyte, Yun-Feng Zhang, Jia-Ming Dong, Chang Tan, Shi-Kang Huo, Jia-Ying Wang, Yang He, Ya-Ying Wang
Journal of Electrochemistry
Herein, the lithiated sulfonated graphene oxide (Li-SGO) was successfully prepared via three steps by sulfonation of graphene oxide with 3-merraptnpropylt rimethnxysilane, oxidation of thiol into sulfonate with hydrogen peroxide and lithiation of sulfonate with aqueous lithium hydroxide. The as-prepared Li-SGO was then introduced into the semi-interpenetrating networks of single ion conducting polymer electrolyte (Li-SGO-FPAS) and poly vinylidenefluoride-hexafluoro propylene (PVDF-HFP) binder by in-situ polymerization to fabricate the porous single ion conducting polymer electrolyte membrane (Li-SGO-po-FPAS) generated from the poor compatibility between aromatic Li-SGO-FPAS and aliphatic PVDF-HFP binder. The key properties such as morphology, porosity, solvent uptake, mechanical …
Influence Of Resveratrol On Performance Of Long-Term Storage’S Lithium-Ion Battery Electrolyte, Lei Zhang, Xu-Ping Zhang, Si-Wei Zhang, Quan-Chao Zhuang
Influence Of Resveratrol On Performance Of Long-Term Storage’S Lithium-Ion Battery Electrolyte, Lei Zhang, Xu-Ping Zhang, Si-Wei Zhang, Quan-Chao Zhuang
Journal of Electrochemistry
Electrolyte of lithium-ion battery usually goes through processes of filling, transportation and storage from the completion of manufacture to the use. Understanding the influence of long-term storage process on performance of lithium-ion battery electrolyte is of theoretical significance for production of lithium-ion battery. Scanning electron microscope (SEM) images showed that the solid electrolyte interface (SEI) film formed on the surface of the graphite electrode was thicker in the base electrolyte after 6 months of storage. The charge/discharge test results showed that the reversible cycle capacity and cycle stability (capacity retention rate) of graphite electrode decreased significantly after 6 months of …
Research Progress In Electrodeposition Technology Of Titanium-Based Iridium Oxide Electrode, Dan-Dan Wu, Xu Wu
Research Progress In Electrodeposition Technology Of Titanium-Based Iridium Oxide Electrode, Dan-Dan Wu, Xu Wu
Journal of Electrochemistry
Titanium-based iridium oxide electrode has been widely used in various fields, such as electrocatalytic oxidation, biomedical applications, hydrometallurgical metal recovery, electro-osmotic dewatering, etc. At present, it is mainly prepared by traditional thermal decomposition method, however, which has high cost, cumbersome process, mainly relying on manual labor and cannot be mass-produced yet. It is, therefore, urgently necessary to explore new preparation technologies by focusing on electrodeposition technology, with technological characteristics such as eco-friendly and sustainable development. This article systematically discusses the research progress in iridium oxide electrodeposition preparation technology from the aspects of deposition solution formulation, base material selection and treatment, …
Preparations And Electrochemical Properties Of Bc/Coni2S4@Ppy Flexible Composites For Supercapacitors, Si-Yuan Peng, Shi-Run Yang, Jing-Hong Zhou, Zhi-Jun Sui, Tao Zhang, Yi Shi, Xing-Gui Zhou
Preparations And Electrochemical Properties Of Bc/Coni2S4@Ppy Flexible Composites For Supercapacitors, Si-Yuan Peng, Shi-Run Yang, Jing-Hong Zhou, Zhi-Jun Sui, Tao Zhang, Yi Shi, Xing-Gui Zhou
Journal of Electrochemistry
Flexible supercapacitor is one of the most promising energy storage devices for portable and wearable electronic products due to its advantages of high power density, fast charging and long cycle life. Therefore, self-supporting flexible electrode materials with high performance have attained more and more attention both in academia and in industry recently. In this work, using bacterial cellulose (BC) as a flexible substrate, the bacterial cellulose/nickel-cobalt sulfide@polypyrrole (BC/CoNi2S4@PPy) flexible composites with three-dimensional porous network and good conductivity were prepared by a combined solvothermal-in-situ polymerization-vacuum filtration method. The samples were characterized by X-ray diffraction, …
Syntheses Of Na3V2(Po4)2O2F As A Cathode For Sodium Ion Battery Application, Kai Wu
Syntheses Of Na3V2(Po4)2O2F As A Cathode For Sodium Ion Battery Application, Kai Wu
Journal of Electrochemistry
High-temperature solid-state method, hydro-thermal method and solvo-thermal method have been mainly employed to synthesize Na3V2(PO4)2O2F (NVPF) cathode materials. However, these methods are energy consuming and complicated, which is not applicable for a large scale industrial production. In this study, a rather low-temperature (70℃) co-precipitation strategy was proposed to synthesize NVPF cathode materials. The as-prepared NVPF cathode materials showed a spherical shape with a diameter of 400 ~ 500 nm, and exhibited a sodium storage of 105.6 mAh·g-1 and an efficiency of 90.06%. After a simple thermal process, the specific …
Core-Shell Structured Ru@Ptru Nanoflower Electrocatalysts Toward Alkaline Hydrogen Evolution Reaction, Xue-Liang Wang, Yuan-Yuan Cong, Chen-Xi Qiu, Sheng-Jie Wang, Jia-Qi Qin, Yu-Jiang Song
Core-Shell Structured Ru@Ptru Nanoflower Electrocatalysts Toward Alkaline Hydrogen Evolution Reaction, Xue-Liang Wang, Yuan-Yuan Cong, Chen-Xi Qiu, Sheng-Jie Wang, Jia-Qi Qin, Yu-Jiang Song
Journal of Electrochemistry
Water electrolysis for hydrogen production is beneficial for solving the problem of energy crisis and environmental issues. It is necessary to study highly active and cost-effective catalysts toward hydrogen evolution reaction (HER) to reduce the consumption of noble metals. Herein, we report the synthesis of core-shell structured Ru@Pt0.24Ru nanoflowers electrocatalyst by stepwise reduction of Ru and Pt precursors in the mixture of oleylamine and benzyl alcohol at 160 oC. The average diameter of the resultant Ru@Pt0.24Ru was 16.5±4.0 nm with a bulk atomic ratio between Pt and Ru of 0.24:1 and a surface ratio of …
Numerical Simulations Of Current And Temperature Distribution Of Symmetrical Double-Cathode Solid Oxide Fuel Cell Stacks Based On The Theory Of Electric-Chemical-Thermal Coupling, Cheng-Rong Yu, Jian-Guo Zhu, Cong-Ying Jiang, Yu-Chen Gu, Ye-Xin Zhou, Zhuo-Bin Li, Rong-Min Wu, Zheng Zhong, Wan-Bing Guan
Numerical Simulations Of Current And Temperature Distribution Of Symmetrical Double-Cathode Solid Oxide Fuel Cell Stacks Based On The Theory Of Electric-Chemical-Thermal Coupling, Cheng-Rong Yu, Jian-Guo Zhu, Cong-Ying Jiang, Yu-Chen Gu, Ye-Xin Zhou, Zhuo-Bin Li, Rong-Min Wu, Zheng Zhong, Wan-Bing Guan
Journal of Electrochemistry
Solid oxide fuel cell (SOFC) is a high-efficient clean conversion device for future energy management. Because of the low antioxidant reduction ability and complex thermal stress, the structure of traditional asymmetrical thin anode-supported planar SOFC is easily to be broken under stack operating conditions. To overcome these defects, a new complete symmetrical SOFC based on double-sided cathodes was developed. To study the influences of gas flow direction and current collection mode on the cell performance inside stack, a numerical model was established by finite element method based on the theory of electro-thermo-chemo multiphysical coupling. By applying this model, the molar …
Effect Of 18-Crown-6 Additive On Chromium Electrodeposition In Ionic Liquid, Yi-Jie Wang, Dong-Fang Niu, Xin-Sheng Zhang
Effect Of 18-Crown-6 Additive On Chromium Electrodeposition In Ionic Liquid, Yi-Jie Wang, Dong-Fang Niu, Xin-Sheng Zhang
Journal of Electrochemistry
Trivalent chromium ion (Cr3+) is used for electrodeposition due to its low toxicity. Electrodeposition in ionic liquids can greatly solve for hydrogen evolution problem. However,as a widely used Cr(III) precursor, chromium chloride hydrate (CrCl3·6H2O), still contains water. In the presence of water, Cr3+ will form a complex coordination structure with water molecules ([Cr(H2O)6]3+), which is a stable octahedral structure and is difficult to be directly reduced to chromium metal. Therefore, coordination agents should be added into the bath. In this work, the effect of 18-Crown-6 additive on …
Degradation And Thermal Characteristics Of Lini0.8Co0.15Al0.05O2/Graphite Lithium Ion Battery After Different State Of Charge Ranges Cycling, Cun Wang, Wei-Jiang Zhang, Teng-Fei He, Bo Lei, You-Jie Shi, Yao-Dong Zheng, Wei-Lin Luo, Fang-Ming Jiang
Degradation And Thermal Characteristics Of Lini0.8Co0.15Al0.05O2/Graphite Lithium Ion Battery After Different State Of Charge Ranges Cycling, Cun Wang, Wei-Jiang Zhang, Teng-Fei He, Bo Lei, You-Jie Shi, Yao-Dong Zheng, Wei-Lin Luo, Fang-Ming Jiang
Journal of Electrochemistry
The LiNi0.8Co0.15Al0.05O2 (NCA) cathode exhibits high energy density and large reversible capacity, which plays an essential role in the field of electric vehicles (EVs). However, low capacity retention and poor thermal stability limit its application. Few literatures are found for the capacity degradation mechanism of NCA/graphite batteries at home and abroad. The different state of charge (SOC) ranges cycle degradation behaviors of 18650-type NCA/graphite (2.4 Ah) battery were studied in this paper. The SOC ranges considered were 0% ~ 20% (low), 20% ~ 70% (medium), 70% ~ 100% (high), and 0% ~ 100% …
Effect Of Stereotaxically-Constructed Graphene On The Negative Electrode Performance Of Lead-Acid Batteries, Pin-Song Chen, Yi-Tao Hu, Xin-Yi Zhang, Pei-Kang Shen
Effect Of Stereotaxically-Constructed Graphene On The Negative Electrode Performance Of Lead-Acid Batteries, Pin-Song Chen, Yi-Tao Hu, Xin-Yi Zhang, Pei-Kang Shen
Journal of Electrochemistry
With the advantages of high ratio surface area, excellent conductivity and high stability, the stereotaxically-constructed graphene (SCG) material was added to the negative active material (NAM) of lead-acid battery for improving battery performance. XRD, SEM and cyclic voltammetry tests were carried out to analyze the influence of SCG on negative active material. It is found that the conversion efficiency of lead sulfate to lead in the negative active material added with SCG material was higher than that of control group, and the particle size of the lead sulfate obtained after the discharge reaction was smaller, which are favorable factors for …
Preparations And Photoelectrochemical Performances Of Rgo-Tio2 Nanotubes Arrays, Ze-Yang Zhang, Lan Sun, Chang-Jian Lin
Preparations And Photoelectrochemical Performances Of Rgo-Tio2 Nanotubes Arrays, Ze-Yang Zhang, Lan Sun, Chang-Jian Lin
Journal of Electrochemistry
Decorating TiO2 nanotube arrays with RGO to improve the photocatalytic activity of TiO2 nanotube arrays has been reported. For the reported RGO-TiO2 nanotube arrays, TiO2 nanotube arrays were prepared by anodizing the high-purity Ti foil in an organic electrolyte for multiple-step treatments, while RGO were deposited on TiO2 nanotube arrays by using cyclic voltammetry or other electrical reduction methods. To enhance the reduction degree and the coverage of RGO on the resultant RGO-TiO2 nanotube arrays, in this work, the one-step electrochemical anodization in hydrofluoric acid was used to fabricate TiO2 nanotube arrays with …
Effect Of Reaction Conditions On Cu⁃Catalyzed Co2 Electroreduction, Chang Zhu, Wei Chen, Yan-Fang Song, Xiao Dong, Gui-Hua Li, Wei Wei, Yu-Han Sun
Effect Of Reaction Conditions On Cu⁃Catalyzed Co2 Electroreduction, Chang Zhu, Wei Chen, Yan-Fang Song, Xiao Dong, Gui-Hua Li, Wei Wei, Yu-Han Sun
Journal of Electrochemistry
Electrochemical conversion of carbon dioxide (CO2) driven by renewable electricity that can meet both carbon emission reduction and renewable energy utilization has been rapidly developed in recent years. Copper (Cu) catalyst has long been a promising candidate for CO2 electroreduction applications because of its natural abundance and specific capability of producing a substantial amount of C2 products. However, various metallic Cu electrodes reported have been significantly influenced by the adsorption of certain cation/anion ions, resulting in wide-span catalytic activities and selectivity for various products. In addition, a recent report demonstrated that by virtue of gas-diffusion flow cell …
Preparation And Process Optimization Of Cathode Materials For Lithium-Sulfur Batteries, Kai Wu
Preparation And Process Optimization Of Cathode Materials For Lithium-Sulfur Batteries, Kai Wu
Journal of Electrochemistry
Lithium-sulfur (Li-S) batteries represent promising candidates for next-generation energy storage system due to their high energy density and low material cost. However, the industrial application of Li-S batteries remains challenges because of the shuttle effect from lithium polysulfides and the lack of facial routes for Li-S battery preparation. To solve these problems, a cathode consisting of different commercial carbon materials, namely, acetylene black (SP), Ketjen Black (KB) and carbon nanotube (CNT), with sulfur (S) is prepared separately for Li-S battery. After the process of 8-h ball milling for KB/S composite, together with the polyvinyl pyrrolidone (PVP) binder, the cathode could …
Synergistic Effect Of Dissolving O2 And Wavelength On The Photo-Assisted Anodic Deposition Of Ceo2 Thin Films, Tong-Zheng Jin, Yu-Meng Yang, Sheng-Hui Fan, Guo-Ying Wei, Zhao Zhang
Synergistic Effect Of Dissolving O2 And Wavelength On The Photo-Assisted Anodic Deposition Of Ceo2 Thin Films, Tong-Zheng Jin, Yu-Meng Yang, Sheng-Hui Fan, Guo-Ying Wei, Zhao Zhang
Journal of Electrochemistry
Cerium dioxide (CeO2) thin films have been applied as new material in many technical fields such as solid oxide fuel cells, catalysts, UV absorbents, pharmacology, and coatings for corrosion protection of many metals and alloys. Electrodeposition is widely considered to be one of the best preparation methods for CeO2 film. In this work, the CeO2 films were prepared by photo-assisted anodic deposition in the bath solutions containing 0.05 mol·L-1 cerium (III) nitrate, 0.1 mol·L-1 ammonia acetate and 70% (V/V) ethanol onto 316L stainless steel (SS) surface. The synergistic effects of …
Step-By-Step Modification Of Graphite Felt Electrode For Vanadium Redox Flow Battery, Jing-Yuan Lou, Dong-Jiang You, Xue-Jing Li
Step-By-Step Modification Of Graphite Felt Electrode For Vanadium Redox Flow Battery, Jing-Yuan Lou, Dong-Jiang You, Xue-Jing Li
Journal of Electrochemistry
As a well-known electrode material of the vanadium redox flow battery (VRFB),graphite felt electrode is the frequently-used electrode material in VRFB, and its low electrochemical activity is one of the key factors for the low power density of VRFB. In this work, we proposed a step-by-step modification method, which used KMnO4 to oxidize graphite felt first and then placed in an activation solution to excite its reactivity, to improve the electrochemical performance of the graphite felt electrode. According to the results from cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) characterizations …
Developments Of Machine Learning Potentials For Atomistic Simulations, Howard Yanxon
Developments Of Machine Learning Potentials For Atomistic Simulations, Howard Yanxon
UNLV Theses, Dissertations, Professional Papers, and Capstones
Atomistic modeling methods such as molecular dynamics play important roles in investigating time-dependent physical and chemical processes at the microscopic level. In the simulations, energy and forces, sometimes including stress tensor, need to be recalculated iteratively as the atomic configuration evolves. Consequently, atomistic simulations crucially depend on the accuracy of the underlying potential energy surface. Modern quantum mechanical modeling based on density functional theory can consistently generate an accurate description of the potential energy surface. In most cases, molecular dynamics simulations based on density functional theory suffer from highly demanding computational costs. On the other hand, atomistic simulations based on …
Adsorption And Reconfiguration Of Amphiphiles At Silica-Water Interfaces: Role Of Electrostatic Interactions, Van Der Waals Forces And Hydrogen Bonds, Yao Wu
LSU Doctoral Dissertations
The ability to explore and predict metastable structures of hybrid self-assemblies is of central importance for the next generation of advanced materials with novel properties. As compared to their thermodynamically stable forms, the kinetically stabilized materials show improved functionality potentially over their stable counterparts. The self-assembly processes usually originate from weak intermolecular interactions, involving a dynamic competition between attractive and repulsive interactions. These weak forces, including van der Waals (vdW), electrostatic interaction and the hydrogen bonding (H-bonding), can be tuned by external stimuli, e.g., confinement, temperature and ionization, and consequently driving hybrid materials into different configurations. It is challenging to …
Facile Synthesis Of Nitrogen-Doped Graphene-Like Active Carbon Materials For High Performance Lithium-Sulfur Battery, Quan-Hua Meng, Wen-Wen Deng, Chang-Ming Li
Facile Synthesis Of Nitrogen-Doped Graphene-Like Active Carbon Materials For High Performance Lithium-Sulfur Battery, Quan-Hua Meng, Wen-Wen Deng, Chang-Ming Li
Journal of Electrochemistry
Lithium-sulphur (Li-S) battery is regarded as a promising energy storage device because of its high theoretical capacity. However, the low S utilization and short cycling life limit the commercial applications. In this work, nitrogen-doped graphene-like carbon (NGC) materials were synthesized by simply pyrolyzing and carbonizing the mixture of melamine (C3H6N6) and L-cysteine (C3H7NO2S). The graphene-like structure in NGC effectively buffered the volume change of S during the discharge/charge process and improved the cycling stability. Meanwhile, nitrogen-containing functional groups in NGC facilitated the transportation of ions and suppressed the …
Highly Efficient Co2 Utilization Via Molten Salt Co2 Capture And Electrochemical Transformation Technology, Bo-Wen Deng, Hua-Yi Yin, Di-Hua Wang
Highly Efficient Co2 Utilization Via Molten Salt Co2 Capture And Electrochemical Transformation Technology, Bo-Wen Deng, Hua-Yi Yin, Di-Hua Wang
Journal of Electrochemistry
The molten electrolytes exhibit high CO2 absorption capacities, wide electrochemical windows and excellent reaction kinetics, which are promising electrolyte candidates for efficient capture and electrochemical conversion of high-flux CO2 driven by renewable and clean electricity sources. This short review introduces the recent advancements of CO2 electroreduction achieved by the authors using molten salt CO2 capture and electrochemical transformation (MSCC-ET) technology, involving CO2 absorption kinetics, cathodic kinetics, controllable synthesis of carbon products with unique nanostructures, development of inert oxygen evolution anodes and CO2 conversion efficiency as well as energy efficiency. The challenges and prospects are …
Electrochemical Engineering Of Carbon Nanodots, Lei Bao, Dai-Wen Pang
Electrochemical Engineering Of Carbon Nanodots, Lei Bao, Dai-Wen Pang
Journal of Electrochemistry
Aqueous batteries have been considered to be a competitive candidate for large-scale energy storage. However, most of aqueous batteries adopt inorganic electrode materials with metallic elements, which are based on the reversible insertion of metal ions, making their application being highly hindered by limited cycle life, environmental issue, high cost and low reserves. On the other hand, organic electrode materials offer the advantages of abundant reserves, tunable structures, renewability and environmental benignity. Furthermore, the wide internal space enables these organics to flexibly store various charge carriers. Organics have been investigated as the alternative to inorganic electrode materials. Herein, we review …
Research Progress Of Sulfur Cathode Catalytic Conversions For Lithium-Sulfur Batteries, Qin-Jun Shao, Jian Chen
Research Progress Of Sulfur Cathode Catalytic Conversions For Lithium-Sulfur Batteries, Qin-Jun Shao, Jian Chen
Journal of Electrochemistry
The electrochemical reduction of sulfur (S) takes place through multistep reactions when S is used as a cathode material. The complete discharge of S to form final product lithium sulfide (Li2S) is a two-electron reaction. The formation of low-order lithium polysulfides (LiPS) needs to overcome certain energy barriers. And the reduction of Li2S2 to Li2S is the rate-limited step. The reaction kinetic of sulfur cathode is the critical key to determine the electrochemical performance of Li-S batteries, such as specific energy, specific power and low temperature performance, etc. Accelerating the rate-limited step kinetics …
Liquid Metal Electrodes For Electrochemical Energy Storage Technologies, Hao-Miao Li, Hao Zhou, Kang-Li Wang, Kai Jiang
Liquid Metal Electrodes For Electrochemical Energy Storage Technologies, Hao-Miao Li, Hao Zhou, Kang-Li Wang, Kai Jiang
Journal of Electrochemistry
Electrochemical energy storage technologies (ESTs) with low cost, long lifespan and high safety are of great importance for efficient integration of renewable energy into the grid. Liquid metal electrodes (LMEs) possessing the merits of high electronic conductivity, easy manufacture and amorphous structure is of great application value in the field of energy storage batteries. During charge-discharge processing, the LMEs could avoid the issues of structural deformation and dendrite growth in solid metal electrodes, which could effectively extend the cycle life of the LME based batteries. Moreover, LME based batteries are easy to be scaled up and less expensive, which are …
A Model For The Anodic Carbonization Of Alkaline Polymer Electrolyte Fuel Cells, Qi-Hao Li, Ying-Ming Wang, Hua-Long Ma, Li Xiao, Gong-Wei Wang, Jun-Tao Lu, Lin Zhuang
A Model For The Anodic Carbonization Of Alkaline Polymer Electrolyte Fuel Cells, Qi-Hao Li, Ying-Ming Wang, Hua-Long Ma, Li Xiao, Gong-Wei Wang, Jun-Tao Lu, Lin Zhuang
Journal of Electrochemistry
The alkaline polymer electrolyte fuel cell (APEFC) has made appreciable progress in recent years but is still suffering performance loss during discharge with air as the oxidant. Several theories have been suggested to interpret the loss. However, efforts are still needed to reach a clear quantitative understanding. Based on the major experimental findings in combination with thermodynamics and kinetics of the reactions involved in the anode, this paper presents a model featuring layered carbonization in the anode and relevant grouped equations. The simulation results generated from the latter are compared with experiments, and possible principles to suppress the performance loss …
Porous-Electrode Theory Of Lithium Ion Battery: Old Paradigm And New Challenge, Xiao-Xiao Wang, Zi-Rui Zhou, Qiang Shan, Zeng-Ming Zhang, Jun Huang, Yu-Wen Liu, Sheng-Li Chen
Porous-Electrode Theory Of Lithium Ion Battery: Old Paradigm And New Challenge, Xiao-Xiao Wang, Zi-Rui Zhou, Qiang Shan, Zeng-Ming Zhang, Jun Huang, Yu-Wen Liu, Sheng-Li Chen
Journal of Electrochemistry
A critical review on the porous electrode theory developed by Newman and his colleagues is presented. We propose several ideas for further development of this theory by analyzing its limitations. The classical Newman theory does not consider ion steric effect in describing ion transport in electrolyte solutions, which can be amended by a newly developed ion-vacancy coupled charge transfer model for ion transport in concentrated solutions. Ion transport in solid particles of active materials is essentially an ion-electron coupled transport process, and its rationality is verified by comparing the calculated and experimental diffusion coefficients of Li + ion in intercalation …
Porous Electrodes In Electrochemical Energy Storage Systems, Wei-Xiao Ji, Gong-Wei Wang, Qiang Wang, Li-Jun Bai, De-Yang Qu
Porous Electrodes In Electrochemical Energy Storage Systems, Wei-Xiao Ji, Gong-Wei Wang, Qiang Wang, Li-Jun Bai, De-Yang Qu
Journal of Electrochemistry
Professor C.S. Cha was among the pioneers who have introduced modern electrochemistry to China. Under his leadership, the electrochemical research group in Wuhan University became one of the global powerhouses in fundamental and applied electrochemical researches. During the past many decades, Professor Cha and his colleagues in the university have educated and trained many students who have become part of the backbone of electrochemistry worldwide. In this review, we demonstrate the solid foundation laid by Professor Cha and his colleagues in Wuhan University, and the advancements made in the area of porous electrodes by the authors. All the authors in …
Progress And Prospects On Multifunctional Coating Separators For Lithium-Sulfur Battery, Zhuang-Zhuang Wei, Nan-Xiang Zhang, Feng Wu, Ren-Jie Chen
Progress And Prospects On Multifunctional Coating Separators For Lithium-Sulfur Battery, Zhuang-Zhuang Wei, Nan-Xiang Zhang, Feng Wu, Ren-Jie Chen
Journal of Electrochemistry
The development of advanced energy storage systems is crucial to meet the growing demand for electric vehicles, portable devices and renewable energy storage. Lithium-sulfur (Li-S) batteries, with their advantages of high specific energy, low cost of raw materials and environmental friendliness, are hotspots in the research field of new high performance batteries. However, there are still many problems which hinder the practical applications of lithium-sulfur batteries, such as the shuttle effect of soluble polysulfide intermediates, the growth of lithium dendrites, and the thermal stability and safety of lithium-sulfur batteries during use. The design of multifunctional coating separator is one of …
Licoo2 As Sulfur Host To Enhance Cathode Volumetric Capacity For Lithium-Sulfur Battery, Lu Wang, Xue-Ping Gao
Licoo2 As Sulfur Host To Enhance Cathode Volumetric Capacity For Lithium-Sulfur Battery, Lu Wang, Xue-Ping Gao
Journal of Electrochemistry
Lithium-sulfur battery is one of the most promising secondary battery systems due to its super high theoretical gravimetric and volumetric energy densities (2600 Wh·kg-1 and 2800 Wh·L-1, respectively). However, the practical volumetric capacity of sulfur cathode is still unsatisfied due to the overuse of low-density host materials, such as carbon nanomaterials. Herein, commercial LiCoO2 with the high tap density of 2.94 g·cm-3 was used as the host material to build high density sulfur-based composite and compact electrode for increasing the volumetric capacity. Obviously, the tap density of the as-prepared S/LiCoO2 composite was 1.90 g·cm …