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Articles 1 - 5 of 5
Full-Text Articles in Inorganic Chemistry
29si Nmr And Saxs Investigation Of The Hybrid Organic-Inorganic Glasses Obtained By Consolidation Of The Melting Gels, Andrei Jitianu, Sylvian Cadars, Fan Zhang, Gabriela Rodriguez, Quentin Picard, Mario Aparicio, Jadra Mosa, Lisa C. Klein
29si Nmr And Saxs Investigation Of The Hybrid Organic-Inorganic Glasses Obtained By Consolidation Of The Melting Gels, Andrei Jitianu, Sylvian Cadars, Fan Zhang, Gabriela Rodriguez, Quentin Picard, Mario Aparicio, Jadra Mosa, Lisa C. Klein
Publications and Research
This study is focused on structural characterization of hybrid glasses obtained by consolidation of melting gels. The melting gels were prepared in molar ratios of methyltriethoxysilane (MTES) and dimethyldiethoxysilane (DMDES) of 75%MTES-25%DMDES and 65%MTES-35%DMDES. Following consolidation, the hybrid glasses were characterized using Raman, 29Si and 13C Nuclear Magnetic Resonance (NMR) spectroscopies, synchrotron Small Angle X-Ray Scattering (SAXS) and scanning electron microscopy (SEM). Raman spectroscopy revealed the presence of Si–C bonds in the hybrid glasses and 8-membered ring structures in the Si–O–Si network. Qualitative NMR spectroscopy identified the main molecular species, while quantitative NMR data showed that the ratio …
Thickness-Properties Synergy In Organic–Inorganic Consolidated Melting-Gel Coatings For Protection Of 304 Stainless Steel In Nacl Solutions, Mario Amapricio, Andrei Jitianu, Gabriela Rodriguez, Kutaiba Al-Marzoki, Mihaela Jitianu, Jadra Mosa, Lisa C. Klein
Thickness-Properties Synergy In Organic–Inorganic Consolidated Melting-Gel Coatings For Protection Of 304 Stainless Steel In Nacl Solutions, Mario Amapricio, Andrei Jitianu, Gabriela Rodriguez, Kutaiba Al-Marzoki, Mihaela Jitianu, Jadra Mosa, Lisa C. Klein
Publications and Research
Homogeneous and crack-free methyl-substituted organic–inorganic hybrid glass coatings (thickness up to 10 μm) were deposited on AISI 304 stainless steel. Different hybrid glasses obtained fromconsolidation of the diluted melting gels with various methyltriethoxysilane (MTES)/dimethyldiethoxysilane (DMDES) ratios were evaluated considering chemical structure, coating adhesion and corrosion protection. The 70MTES/30DMDES (molar%) melting-gel coating provided improved corrosion protection for this steel due to the synergy of different properties: a highly cross-linked inorganic structure, a coating plasticity based on the hybrid network, and a good adhesion to the substrate through hydroxyl groups. Electrochemical results showa good barrier film with a passive range of 500 …
Sol-Gel Assembly Of Metal Nanostructures Into Metallic Gel Frameworks And Their Applications, Xiaonan Gao
Sol-Gel Assembly Of Metal Nanostructures Into Metallic Gel Frameworks And Their Applications, Xiaonan Gao
Theses and Dissertations
The advent of nanoscience and nanotechnology has sparked many research forefronts in the creation of materials with control over size, shape, composition, and surface properties.1,2 However, for most of the applications, nanoscale materials need to be assembled into functional nanostructures that exhibit useful and controllable physical properties. Therefore, numerous efforts on the assembly of nanoparticles (NPs) using organic ligands, polymers and polyelectrolytes have been reported.3,4 However, the interactions between NPs are mediated by intervening ligands, which are detrimental to charge transport and limit the thermal stability. Hence, developing a new method to produce solid …
Fabrication Of Multifunctional Nanostructured Porous Materials, Ahmed A. Farghaly
Fabrication Of Multifunctional Nanostructured Porous Materials, Ahmed A. Farghaly
Theses and Dissertations
Nanostructured porous materials generally, and nanoporous noble metals specifically, have received considerable attention due to their superior chemical and physical properties over nanoparticles and bulk counterparts. This dissertation work aims to develop well-established strategies for the preparation of multifunctional nanostructured porous materials based on the combination of inorganic-chemistry, organic-chemistry and electrochemistry. The preparation strategies involved one or more of the following processes: sol-gel synthesis, co-electrodeposition, metal ions reduction, electropolymerization and dealloying or chemical etching. The study did not stop at the preparation limits but extended to investigate the reaction mechanism behind the formation of these multifunctional nanoporous structures in order …
Novel Microwave Assisted Synthesis Of Zns Nanomaterials, Suresh Pillai, Michael Seery, Damian Synnott, John Colreavy, Stephen Hinder
Novel Microwave Assisted Synthesis Of Zns Nanomaterials, Suresh Pillai, Michael Seery, Damian Synnott, John Colreavy, Stephen Hinder
Articles
A novel ambient pressure microwave-assisted technique is developed in which silver and indium modified ZnS is synthesised. The as prepared ZnS is characterised by X-ray diffraction, UV-Vis spectroscopy, X-ray photoelectron spectroscopy and luminescence spectroscopy. This procedure produced crystalline materials with particle sizes below 10 nm. The synthesis technique leads to defects in the crystal which induce mid energy levels in the band gap and lead to indoor light photocatalytic activity. Increasing the amount of silver causes a phase transition from cubic blende to hexagonal phase ZnS. In a comparative study, when the ZnS cubic blende is heated in a conventional …