Inorganic Chemistry Commons^™

Stable Isotope Compositions Of Sedimentary Organic Matter Off Zanzibar Town, Ann Muzuka

Tanzania Journal of Science

Stable isotope compositions of sedimentary organic carbon for sediments collected off the Zanzibar Town averaged -17.9%. Low isotope values of organic carbon, which were associated with high C/N ratios, were observed within Zanzibar harbour suggesting a significant contribution of terrestrial organic matter to the harbour. Sediments collected outside the Zanzibar harbour were richer in ¹³C than those collected within the harbour area. This 13 enrichment in ¹³C can be attributed to a decrease in the influence of terrestrial organic matter (0M) and high contribution of' sea grasses. A decrease in the influence of terrestrial OM is further supported …

Bis(4-Carboxylato-5-Methyl-Oxazolidine) Nickel(Ii)Dihydrate, Its Preparation And Crystal Structure, Me Kamwaya

Tanzania Journal of Science

An aqueous solution of nickel (Il) acetate tetrahydrate was added to warm solution of L-threonine and sodium bicarbonate. The mixture was subsequently treated with aqueous solution of formaldehyde and stirred until the blue solution turned green. The reaction consists in a base catalysed condensation of formaldehyde with L-threonine-nickel (Il) – complex followed by formation of an oxazolidine ring. A single crystal X-ray investigation was carried out at 120(1) ^oC. The X-ray structure analysis showed an octahedral nickel comp/ex containing two water molecules. The oxazolidine rings were connected to the Ni by nitrogen and one of the carboxylato oxygen atoms. …

Synthesis Of Bis-(3-Carbethoxy-6-Methoxy-4-Methyl-2-Quinolyl) Selenide, Rr Malisa, G L. Mhehe, Sjm Mdachi

Tanzania Journal of Science

In the execution of a synthetic strategy aiming at 3-acetyl-2,4-dichloro-6-methoxyquinoline, a precursor to a 4-methoyselenolo[2,3-b]quinolone, we have instead obtained 2-chloro-3-carbethoxy-6-methoxy-4-methylquinoline. These results strongly suggest that the compound claimed to be 3-acetyl-2,4-dihydroxy-6-methoxyquinoline in the literature and a precursor to 3-actyl-2,4-dichloro-6-methoxyquinoline, is 3-carbethoxy-2-hydroxy-6-methoxy-4-methylquinoline, a precursor to 2-chlo-3-carbethoy-6-methoxy-4-methylquinoline. The reaction of the latter compound with sodium hydrogen selenide in ethanol yielded bis-(3-carbethoxy-6-methoxy-4-methyl-2-quinolyl) selenide.

Cu(Ii) Potentiation Of Alzheimer A Neurotoxicity, Xudong Huang, Math P. Cuajungco, Craig S. Atwood, Mariana A. Hartshorn, Joel D. A. Tyndall, Graeme R. Hanson, Karen C. Stokes, Michael C. Leopold, Et Al.

Chemistry Faculty Publications

Oxidative stress markers as well as high concentrations of copper are found in the vicinity of Aβ amyloid deposits in Alzheimer's disease. The neurotoxicity of Aβ in cell culture has been linked to H2O2generation by an unknown mechanism. We now report that Cu(II) markedly potentiates the neurotoxicity exhibited by Aβ in cell culture. The potentiation of toxicity is greatest for Aβ1–42 > Aβ1–40 ≫ mouse/rat Aβ1–40, corresponding to their relative capacities to reduce Cu(II) to Cu(I), form H2O2 in cell-free assays and to exhibit amyloid pathology. The copper complex of Aβ1–42 has a highly positive formal reduction potential (≈+500–550 mV versus …

Validity Of The Independent-Particle Approximation In X-Ray Photoemission: The Exception, Not The Rule, D. Hansen, Oliver Hemmers, H. Wang, Dennis W. Lindle, P. Focke, I. A. Sellin, Clemens Heske, H. S. Chakraborty, P. C. Deshmukh, S. T. Manson

Environmental Studies Faculty Publications

A combined experimental and theoretical study of argon valence photoionization illustrates the discovery of the broad lack of validity of the independent-particle approximation (IPA) for x-ray photoemission. In addition to previously known breakdowns of the IPA, which are limited to high photon energies and regions very near threshold, the observed breakdown in photoionization at intermediate energies demonstrates generally that the IPA is valid only in very restricted domains. These restrictions are expected to be relevant throughout the periodic table, with consequences for a wide variety of applications.

Zinc Speculation And Ligand Fluxes In Chesapeake Bay And Elizabeth River Pore Waters, Duncan Glover Byers

Chemistry & Biochemistry Theses & Dissertations

Presented here are the first data on the vertical concentrations, complexation, speciation, and fluxes of total dissolved zinc and zinc complexing ligands, and zinc speciation in sediment pore waters in the Chesapeake Bay and Elizabeth River, Virginia.

Sediment pore waters were collected in mid and southern Chesapeake Bay in November 1997 and in the Elizabeth River (Pinner's Point) in March, April, and July 1998. Flux experiments were conducted in Elizabeth River sediment cores in April and July 1998. [TDZn] and zinc complexation were determined using differential pulse anodic stripping voltammetry at a hanging mercury drop electrode (DPASV-HMDE).

[TDZn] in the …

Photochemistry And Pinhole Photography: An Interdisciplinary Experiment, Angeliki A. Rigos, Kevin Salemme

Visual & Performing Arts Faculty Publications

This interdisciplinary activity combines chemistry and art through the construction and use of a pinhole camera. We focused on the chemistry of the black and white photographic process as the science component of this activity. The reactions involved are good examples of photochemistry and multiphase chemical reactions, since the light sensitive materials (silver halides) are in the form of a gelatin emulsion of microscopic crystals.

Investigation Of Iron-Removing Agents, Melanie Wolfe

Theses, Dissertations and Capstones

Benign chemical agents for removing iron from people with iron-overload diseases are lacking; thus the purpose of this investigation is to evaluate the toxicity of acetaminophen in iron-overloaded mice compared to normal mice and to evaluate the iron-mobilizing ability of this agent in an iron-overloaded mouse model. Female Hilltop (ICR) CVF mice, ranging between six months to one year of age, were used in these experiments. Mice were given intraperionteal(ip) injections of 300 mg/kg ferric hydroxide-dextran complex for a total of five, eight, or thirteen injections to achieve an iron-overloaded state. Iron-overloaded mice were given ip injections of either 350,200, …