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Full-Text Articles in Inorganic Chemistry
Improved Synthesis Of Pincer Ligand Precursor, And Synthesis And Structural Characterization Of Terphenyl Scaffolded S–C–S Palladium Pincer Complex., Paul Schroder, Thomas Spilker, Wilson Luu, James Updegraff, Man Lung Kwan, Paul Challen, John Protasiewicz
Improved Synthesis Of Pincer Ligand Precursor, And Synthesis And Structural Characterization Of Terphenyl Scaffolded S–C–S Palladium Pincer Complex., Paul Schroder, Thomas Spilker, Wilson Luu, James Updegraff, Man Lung Kwan, Paul Challen, John Protasiewicz
Man Lung Desmond Kwan
An easier and more expedient synthesis of 2,6-(BrCH2C6H4)2-4-I-C6H3 (2) is reported. This material allowed easy synthesis of the new pincer ligand precursor 2,6-(4-CH3C6H4SCH2C6H4)2-4-I-C6H3 (3) in 87% yield. Compound 3 reacts with Pd2(dba)3 to give the new palladium pincer complex 4. Compound 4 has been fully characterized, including structural characterization by single crystal X-ray diffraction methods. The results of the crystallographic work on 4 reveal a twisted type pincer complex not unlike related terphenyl pincer complexes.
Improved Synthesis Of Pincer Ligand Precursor, And Synthesis And Structural Characterization Of Terphenyl Scaffolded S–C–S Palladium Pincer Complex., Paul Schroder, Thomas Spilker, Wilson Luu, James Updegraff, Man Lung Kwan, Paul Challen, John Protasiewicz
Improved Synthesis Of Pincer Ligand Precursor, And Synthesis And Structural Characterization Of Terphenyl Scaffolded S–C–S Palladium Pincer Complex., Paul Schroder, Thomas Spilker, Wilson Luu, James Updegraff, Man Lung Kwan, Paul Challen, John Protasiewicz
Paul R. Challen
An easier and more expedient synthesis of 2,6-(BrCH2C6H4)2-4-I-C6H3 (2) is reported. This material allowed easy synthesis of the new pincer ligand precursor 2,6-(4-CH3C6H4SCH2C6H4)2-4-I-C6H3 (3) in 87% yield. Compound 3 reacts with Pd2(dba)3 to give the new palladium pincer complex 4. Compound 4 has been fully characterized, including structural characterization by single crystal X-ray diffraction methods. The results of the crystallographic work on 4 reveal a twisted type pincer complex not unlike related terphenyl pincer complexes.
The Spectroelectrochemical, Magnetic, And Structural Characterization Of Reduced Hexaazatriphenylenehexacarbonitrile, Hat(Cn)6., Joseph Gallegos, Anthony Francis, Nathan Ockwig, Paul Rasmussen, Raphael Raptis, Paul Challen, Issouf Ouedraogo
The Spectroelectrochemical, Magnetic, And Structural Characterization Of Reduced Hexaazatriphenylenehexacarbonitrile, Hat(Cn)6., Joseph Gallegos, Anthony Francis, Nathan Ockwig, Paul Rasmussen, Raphael Raptis, Paul Challen, Issouf Ouedraogo
Paul R. Challen
The cyanoazacarbon, hexaazatriphenylenehexacarbonitrile, or HAT(CN)6, is readily reduced and the spectroelectrochemical properties associated with the multiple reductions are described. The singly reduced radical monoanion forms stable salts and we report the crystal structure and magnetic properties for the tetrabutylammonium salt. [Tetra-n-butylammonium] [HAT(CN)6] behaves ferromagnetically below 3K and follows Curie Law behavior at higher temperatures after correction for Pauli-type susceptibility. The room temperature conductivity of the powdered salt is 3.8×10−8S/cm. The crystal structure shows closely bound pairs of radical anions with slip-stacking of these pairs to form a staircase, features that elucidate the observed properties. Thin films of HAT(CN)6 were found …
Highly Fluorous Complexes Of Ruthenium And Osmium And Their Solubility In Supercritical Carbon Dioxide, Brad Berven, George Koutsantonis, Brian Skelton, Robert Trengove, Allan White
Highly Fluorous Complexes Of Ruthenium And Osmium And Their Solubility In Supercritical Carbon Dioxide, Brad Berven, George Koutsantonis, Brian Skelton, Robert Trengove, Allan White
Brad Berven
A series of ruthenium and osmium complexes containing highly fluorous diphosphine ligands FPPF = (F13C6C6H4-p)2P(CH2)2P(p-C6H4C6F13)2 (dfppe) and (F13C6C6H4-p)2P(CH2)3P(p-C6H4C6F13)2 (dfppp) has been prepared. The fluorous diphosphine ligands incorporate four C6F13 “fluoro-ponytails”, and these have been effective in solubilizing the complexes in supercritical carbon dioxide (scCO2). Precise solubility measurements in scCO2 were performed for some of the complexes. The new complexes [MX2(FPPF)2] and [MX(FPPF)(η-C5H5)], M = Ru, Os, X = Cl, Br, have been characterized by a number of spectroscopic techniques and their electrochemical properties measured, three of the ruthenium complexes also being characterized by single-crystal X-ray studies. The noncovalent interactions observed …