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Articles 1 - 24 of 24
Full-Text Articles in Inorganic Chemistry
Synthesis And Flammability Testing Of Epoxy Functionalized Phosphorous-Based Flame Retardants, Vladimir Benin, Xuemei Cui, Alexander Morgan, Karl Seiwert
Synthesis And Flammability Testing Of Epoxy Functionalized Phosphorous-Based Flame Retardants, Vladimir Benin, Xuemei Cui, Alexander Morgan, Karl Seiwert
Vladimir Benin
Several potential new phosphorus-containing flame retardant molecules were evaluated for heat release reduction potential by incorporation of the molecules into a polyurethane, generated from methylene diphenyl diisocyanate and 1,3-propane diol. The heat release reduction potential of these substances was evaluated using the pyrolysis combustion flow calorimeter (PCFC). The polyurethanes were prepared in the presence of the potential flame retardants via solvent mixing and copolymerization methods to qualitatively evaluate their potential reactivity into the polyurethane prior to heat release testing. The functionality of the flame retardants was epoxide based that would potentially react with the diol during polyurethane synthesis. Flammability testing …
Synthesis, Structural Studies And Desilylation Reactions Of Some N-2-(Trimethylsilyl)Ethyl-N-Nitrosocarbamates, Arpitha Thakkalapally, Vladimir Benin
Synthesis, Structural Studies And Desilylation Reactions Of Some N-2-(Trimethylsilyl)Ethyl-N-Nitrosocarbamates, Arpitha Thakkalapally, Vladimir Benin
Vladimir Benin
The present report describes the preparation and characterization of several N-2-(trimethylsilyl)ethyl-N-nitrosocarbamates, designed as precursors to thermally unstable secondary N-nitrosocarbamate anions via fluoride-assisted cleavage. X-ray structural studies demonstrate that the core N-nitrosocarbamate moiety has a nearly planar geometry, with an s-E orientation at the N–N bond. DFT calculations (B3LYP/6-31+G(d)) reproduce accurately the structural features of the title compounds and detailed conformational analysis at the same level of theory addresses the long-standing issue of preferred geometries for three classes of related structures: N-nitrosocarbamates, N-nitrosoureas and N-nitrosoamides. Desilylation studies demonstrate that both the …
Structure And Conformation Of The Medium-Sized Chlorophosphazene Rings, Bowers, David Bowers, Brian Wright, Vincenzo Scionti, Anthony Schultz, Matthew Panzner, Eric Twum, Lin-Lin Li, Bryan Katzenmeyer, Benjamin Thome, Peter Rinaldi, Chrys Wesdemiotis, Wiley Youngs, Claire Tessier
Structure And Conformation Of The Medium-Sized Chlorophosphazene Rings, Bowers, David Bowers, Brian Wright, Vincenzo Scionti, Anthony Schultz, Matthew Panzner, Eric Twum, Lin-Lin Li, Bryan Katzenmeyer, Benjamin Thome, Peter Rinaldi, Chrys Wesdemiotis, Wiley Youngs, Claire Tessier
Wiley J. Youngs
No abstract provided.
Structure And Conformation Of The Medium-Sized Chlorophosphazene Rings, Bowers, David Bowers, Brian Wright, Vincenzo Scionti, Anthony Schultz, Matthew Panzner, Eric Twum, Lin-Lin Li, Bryan Katzenmeyer, Benjamin Thome, Peter Rinaldi, Chrys Wesdemiotis, Wiley Youngs, Claire Tessier
Structure And Conformation Of The Medium-Sized Chlorophosphazene Rings, Bowers, David Bowers, Brian Wright, Vincenzo Scionti, Anthony Schultz, Matthew Panzner, Eric Twum, Lin-Lin Li, Bryan Katzenmeyer, Benjamin Thome, Peter Rinaldi, Chrys Wesdemiotis, Wiley Youngs, Claire Tessier
Claire A. Tessier
No abstract provided.
Come For The Content, Stay For The Community, Hilary Eppley
Come For The Content, Stay For The Community, Hilary Eppley
Hilary J. Eppley
No abstract provided.
Building An Online Teaching Community: An Evolving Tale Ofcommunication, Collaboration, Andchemistry, Barbara Reisner, Hilary Eppley, Margret Geselbracht, Elizabeth Jamieson, Adam Johnson, Sheila Smith, Joanne Stewart, Lori Watson, Scott Williams
Building An Online Teaching Community: An Evolving Tale Ofcommunication, Collaboration, Andchemistry, Barbara Reisner, Hilary Eppley, Margret Geselbracht, Elizabeth Jamieson, Adam Johnson, Sheila Smith, Joanne Stewart, Lori Watson, Scott Williams
Hilary J. Eppley
The Interactive Online Network of Inorganic Chemists (IONiC) has grown from a small group of faculty to a national and international network focused on improving inorganicChemistry learning. IONiC’s vision is to create a community of teachers and learners who make teaching visible using social networking tools to share, discuss, test, and assess their teaching methods. The features that have allowed the IONiC community to develop and grow and IONiC’s vision for the future are described. It is likely that the lessons learned apply to other groups seeking to develop professional communities through social networking.
Ionic: A Cyber-Enabled Community Of Practice For Improving Inorganic Chemicaleducation, Hilary Eppley, Adam Johnson, Ethan Benatan, Margret Geselbracht, Joanne Stewart, Barbara Reisner, Lori Watson, B. Williams
Ionic: A Cyber-Enabled Community Of Practice For Improving Inorganic Chemicaleducation, Hilary Eppley, Adam Johnson, Ethan Benatan, Margret Geselbracht, Joanne Stewart, Barbara Reisner, Lori Watson, B. Williams
Hilary J. Eppley
IONiC’s purpose is to enhance the inorganicChemistry classroom and laboratory experience for students and faculty members through the development of a vibrant virtual “community of practice”.
Jce Viper: An Inorganic Teaching And Learning Community, Ethan Benatan, Jezmynne Dene, Hilary Eppley, Margret Gesebracht, Elizabeth Jamieson, Adam Johnson, Barbara Reisner, Joanne Stewart, Lori Watson, B. Williams
Jce Viper: An Inorganic Teaching And Learning Community, Ethan Benatan, Jezmynne Dene, Hilary Eppley, Margret Gesebracht, Elizabeth Jamieson, Adam Johnson, Barbara Reisner, Joanne Stewart, Lori Watson, B. Williams
Hilary J. Eppley
To facilitate the effective sharing of teaching tools among faculty and the development of deep subject knowledge in support of teaching, a group of faculty from predominantly undergraduate institutions has established a virtual community of inorganic chemists, IONiC (Interactive Online Network of Inorganic Chemists). Our mission is to enhance the inorganicChemistry classroom and laboratory experience for students and faculty members through the development of a vibrant, collaborative, and open community. VIPEr, the Virtual Inorganic Pedagogical Electronic Resource, is a Web site that forms the online home for our community. VIPEr is an interactive Web resource that combines a repository of …
Isoquinoline-Derivatized Tris(2-Pyridylmethyl)Amines As Fluorescent Zinc Sensors With Strict Zn2+/Cd2+ Selectivity, Shawn Burdette, Yuji Mikata, Keiko Kawata, Saaya Takeuchi, Kaori Nakanishi, Hideo Konno, Saori Itami, Keiko Yasuda, Satoshi Tamotsu
Isoquinoline-Derivatized Tris(2-Pyridylmethyl)Amines As Fluorescent Zinc Sensors With Strict Zn2+/Cd2+ Selectivity, Shawn Burdette, Yuji Mikata, Keiko Kawata, Saaya Takeuchi, Kaori Nakanishi, Hideo Konno, Saori Itami, Keiko Yasuda, Satoshi Tamotsu
Shawn C. Burdette
Tris(2-pyridylmethyl)amine-based fluorescent ligands, N,N-bis(1-isoquinolylmethyl)-2-pyridylmethylamine (1-isoBQPA) and N,N-bis(7-methoxy-1-isoquinolylmethyl)-2-pyridylmethylamine (7-MeO-1-isoBQPA), have been prepared and the Zn2+-induced fluorescence enhancement has been investigated. Upon excitation at 324 nm, 1-isoBQPA exhibits a very weak emission (ϕ = [similar]0.010) in DMF–H2O (1 : 1). Upon Zn2+ addition, the 1-isoBQPA fluorescence increases (ϕZn = 0.055) at 357 nm and 464 nm. The fluorescence enhancement at longer wavelengths is Zn2+-specific, whereas Cd2+ induces a small emission increase at 464 nm (ICd/I0 = 1.1, ICd/IZn = 14%). The Zn2+/Cd2+ selectivity of the fluorescent response correlates with the Cd–Nisoquinoline and Zn–Nisoquinoline bond distances measured in the crystal structures. Introduction of …
Bis(2-Quinolylmethyl)Ethylenediaminediacetic Acids (Bqendas), Tqen–Edta Hybrid Molecules As Fluorescent Zinc Sensors, Shawn Burdette, Yju Mikata, Saaya Takeuchi, Hideo Konno, Satoshi Iwatsuki, Sakiko Akaji, Ikuko Hamagami, Masato Aoyama, Keiko Yasuda, Satoshi Tamotsu
Bis(2-Quinolylmethyl)Ethylenediaminediacetic Acids (Bqendas), Tqen–Edta Hybrid Molecules As Fluorescent Zinc Sensors, Shawn Burdette, Yju Mikata, Saaya Takeuchi, Hideo Konno, Satoshi Iwatsuki, Sakiko Akaji, Ikuko Hamagami, Masato Aoyama, Keiko Yasuda, Satoshi Tamotsu
Shawn C. Burdette
Molecular hybrids of TQEN (N,N,N′,N′-tetrakis(2-quinolylmethyl)ethylenediamine) and EDTA (ethylenediamine-N,N,N′,N′-tetraacetic acid) were examined as fluorescent Zn2+ sensors. Upon the addition of Zn2+, N,N-BQENDA (N,N-bis(2-quinolylmethyl)ethylenediamine-N′,N′-diacetic acid, 1a) exhibits a 30-fold emission enhancement at 456 nm (λex = 315 nm, ϕZn = 0.018) in buffer (HEPES, pH = 7.5, 100 mM KCl). The fluorescence enhancement is Zn2+-specific as Cd2+ induces much smaller increases (ICd/I0 = 5 and ICd/IZn = 16%). These spectroscopic properties, as well as the excellent water-solubility, represent a significant improvement compared to the parent TQEN sensor (ϕZn = 0.007, ICd/IZn = 64%). The isoquinoline analog N,N-1-isoBQENDA (N,N-bis(1-isoquinolylmethyl)ethylenediamine-N′,N′-diacetic acid, 1b) possesses a …
Improved Synthesis Of Pincer Ligand Precursor, And Synthesis And Structural Characterization Of Terphenyl Scaffolded S–C–S Palladium Pincer Complex., Paul Schroder, Thomas Spilker, Wilson Luu, James Updegraff, Man Lung Kwan, Paul Challen, John Protasiewicz
Improved Synthesis Of Pincer Ligand Precursor, And Synthesis And Structural Characterization Of Terphenyl Scaffolded S–C–S Palladium Pincer Complex., Paul Schroder, Thomas Spilker, Wilson Luu, James Updegraff, Man Lung Kwan, Paul Challen, John Protasiewicz
Man Lung Desmond Kwan
An easier and more expedient synthesis of 2,6-(BrCH2C6H4)2-4-I-C6H3 (2) is reported. This material allowed easy synthesis of the new pincer ligand precursor 2,6-(4-CH3C6H4SCH2C6H4)2-4-I-C6H3 (3) in 87% yield. Compound 3 reacts with Pd2(dba)3 to give the new palladium pincer complex 4. Compound 4 has been fully characterized, including structural characterization by single crystal X-ray diffraction methods. The results of the crystallographic work on 4 reveal a twisted type pincer complex not unlike related terphenyl pincer complexes.
Room-Temperature Vibrational Properties Of The Bimn2o5 Mullite, F Silva Júnior, C. Paschoal, R. Almeida, R. Moreira, W. Paraguassu, M. Castro Junior, A. Ayala, Z. Kann, Michael Lufaso
Room-Temperature Vibrational Properties Of The Bimn2o5 Mullite, F Silva Júnior, C. Paschoal, R. Almeida, R. Moreira, W. Paraguassu, M. Castro Junior, A. Ayala, Z. Kann, Michael Lufaso
Michael W. Lufaso
Raman and infrared spectroscopic measurements were performed and combined with lattice dynamics simulations in order to describe the room temperature vibrational properties of the BiMn2O5 mullite ceramic. A total of 13 Raman active modes and 19 infrared active modes were observed. The lattice dynamics simulation was used to assign the observed bands and to discuss the phonon behavior of this compound. The obtained dielectric constant and unloaded quality factor parameters for BMO ceramic obtained from the infrared data suggest the applicability of the BiMn2O5 as a possible candidate to microwave applications.
Efficient Oxidation Of Arylmethylene Compounds Using Nano-Mno2, Baskar Nammalwar, Chelsea Fortenberry, Richard Bunce, Sathish Lageshetty, Kevin Ausman
Efficient Oxidation Of Arylmethylene Compounds Using Nano-Mno2, Baskar Nammalwar, Chelsea Fortenberry, Richard Bunce, Sathish Lageshetty, Kevin Ausman
Kevin D. Ausman
Nano-MnO2 has been developed as an efficient and mild reagent for the high-yield oxidation of arylmethylene compounds to the corresponding aldehydes and ketones as well as benzylic ethers to esters. The reagent is conveniently prepared and shows reactivity superior to synthetic (Attenburrow) MnO2 and commercial MnO2 under both microwave and conventional conditions. Typical reactions are performed using 25 wt % of nano-MnO2 relative to the substrate, and the reagent can be recycled up to six times without significant loss of activity. The observed conversions correlate well with surface-water content in the different MnO2 samples, as determined by thermogravimetric analysis.
Quantifying Factors That Influence Metal Ion Release In Photocaged Complexes Using Zincast Derivatives, Shawn Burdette
Quantifying Factors That Influence Metal Ion Release In Photocaged Complexes Using Zincast Derivatives, Shawn Burdette
Shawn C. Burdette
Two generations of nitrobenzhydrol-based photocages for Zn2+ have been prepared and characterized. The first series includes the tridentate ZinCast-1 utilizes a bis-pyridin-2-ylmethyl-aniline ligand that forms a 5,5-chelate ring upon metal binding. The related photocages ZinCast-2 with a N-[2-(pyridine-2-yl)ethyl]-N-(pyridine-2-ylmethyl)aniline (5,6-chelate ring) and ZinCast-3 with a N,N-bis[2-(pyridine-2-yl)ethyl]aniline (6,6-chelate ring) were synthesized for comparative studies. The complexes formed by the ions Cu2+, Zn2+ and Cd2+ with three ZinCast and their photoproducts (ZinUnc) were interrogated by UV-Vis spectroscopy. The studies indicate that ZinCast-1 forms complexes of the highest stability and ZinCast-3 exhibits the most significant changes in metal affinity upon uncaging. These results suggest …
Improved Synthesis Of Pincer Ligand Precursor, And Synthesis And Structural Characterization Of Terphenyl Scaffolded S–C–S Palladium Pincer Complex., Paul Schroder, Thomas Spilker, Wilson Luu, James Updegraff, Man Lung Kwan, Paul Challen, John Protasiewicz
Improved Synthesis Of Pincer Ligand Precursor, And Synthesis And Structural Characterization Of Terphenyl Scaffolded S–C–S Palladium Pincer Complex., Paul Schroder, Thomas Spilker, Wilson Luu, James Updegraff, Man Lung Kwan, Paul Challen, John Protasiewicz
Paul R. Challen
An easier and more expedient synthesis of 2,6-(BrCH2C6H4)2-4-I-C6H3 (2) is reported. This material allowed easy synthesis of the new pincer ligand precursor 2,6-(4-CH3C6H4SCH2C6H4)2-4-I-C6H3 (3) in 87% yield. Compound 3 reacts with Pd2(dba)3 to give the new palladium pincer complex 4. Compound 4 has been fully characterized, including structural characterization by single crystal X-ray diffraction methods. The results of the crystallographic work on 4 reveal a twisted type pincer complex not unlike related terphenyl pincer complexes.
The Spectroelectrochemical, Magnetic, And Structural Characterization Of Reduced Hexaazatriphenylenehexacarbonitrile, Hat(Cn)6., Joseph Gallegos, Anthony Francis, Nathan Ockwig, Paul Rasmussen, Raphael Raptis, Paul Challen, Issouf Ouedraogo
The Spectroelectrochemical, Magnetic, And Structural Characterization Of Reduced Hexaazatriphenylenehexacarbonitrile, Hat(Cn)6., Joseph Gallegos, Anthony Francis, Nathan Ockwig, Paul Rasmussen, Raphael Raptis, Paul Challen, Issouf Ouedraogo
Paul R. Challen
The cyanoazacarbon, hexaazatriphenylenehexacarbonitrile, or HAT(CN)6, is readily reduced and the spectroelectrochemical properties associated with the multiple reductions are described. The singly reduced radical monoanion forms stable salts and we report the crystal structure and magnetic properties for the tetrabutylammonium salt. [Tetra-n-butylammonium] [HAT(CN)6] behaves ferromagnetically below 3K and follows Curie Law behavior at higher temperatures after correction for Pauli-type susceptibility. The room temperature conductivity of the powdered salt is 3.8×10−8S/cm. The crystal structure shows closely bound pairs of radical anions with slip-stacking of these pairs to form a staircase, features that elucidate the observed properties. Thin films of HAT(CN)6 were found …
Highly Fluorous Complexes Of Ruthenium And Osmium And Their Solubility In Supercritical Carbon Dioxide, Brad Berven, George Koutsantonis, Brian Skelton, Robert Trengove, Allan White
Highly Fluorous Complexes Of Ruthenium And Osmium And Their Solubility In Supercritical Carbon Dioxide, Brad Berven, George Koutsantonis, Brian Skelton, Robert Trengove, Allan White
Brad Berven
A series of ruthenium and osmium complexes containing highly fluorous diphosphine ligands FPPF = (F13C6C6H4-p)2P(CH2)2P(p-C6H4C6F13)2 (dfppe) and (F13C6C6H4-p)2P(CH2)3P(p-C6H4C6F13)2 (dfppp) has been prepared. The fluorous diphosphine ligands incorporate four C6F13 “fluoro-ponytails”, and these have been effective in solubilizing the complexes in supercritical carbon dioxide (scCO2). Precise solubility measurements in scCO2 were performed for some of the complexes. The new complexes [MX2(FPPF)2] and [MX(FPPF)(η-C5H5)], M = Ru, Os, X = Cl, Br, have been characterized by a number of spectroscopic techniques and their electrochemical properties measured, three of the ruthenium complexes also being characterized by single-crystal X-ray studies. The noncovalent interactions observed …
Highly Fluorous Bidentate Phosphines, Brad Berven, George Koutsantonis
Highly Fluorous Bidentate Phosphines, Brad Berven, George Koutsantonis
Brad Berven
The reaction of tetrachlorodiphosphines [Cl2P(CH2)nPCl2; n = 2-4] with fluorous aromatic precursors 4-bromo(perfluorohexyl)benzene and 4-(perfluorohexyl)phenol gave a series of fluorous-tagged diphosphines [(p-C6F13C6H4)2P(CH2)nP(C6H4C6F13-p)2; n = 2-4] and a new diphosphonite [(p-C6F13C6H4O)2P(CH2)3P(OC6H4C6F13-p)2]. The improved synthesis of 1,3-bis(dichlorophosphino)propane (dcpp), involved the facile chlorination of the corresponding primary phosphine with triphosgene. Fluorinated diimines RN=C(CH3)C(CH3)=NR, where R = p-C6H4C6F13 or p-C6H4C8F17 have also been prepared, and were found to be air-stable alternatives to the highly air-sensitive phosphorus-containing ligands. All compounds were characterised by a variety of techniques including NMR, IR, MS and microanalysis. The successful reduction of the phosphine-oxides [(p-C6F13C6H4)2P(O)(CH2)nP(O)(C6H4C6F13-p)2; n = 2,3] with phenylsilane …
Charge Density Wave Caused By Reducing Thse3 By One Electron. Superstructure And Short-Range Order In Ath2se6 (A = K, Rb) Studied By X-Ray Diffraction, Electron Diffraction, And Diffuse Scattering, Kyoung-Shin Choi, Rhonda Patschke, Simon Billinge, Mark Waner, Marcos Dantus, Mercouri Kanatzidis
Charge Density Wave Caused By Reducing Thse3 By One Electron. Superstructure And Short-Range Order In Ath2se6 (A = K, Rb) Studied By X-Ray Diffraction, Electron Diffraction, And Diffuse Scattering, Kyoung-Shin Choi, Rhonda Patschke, Simon Billinge, Mark Waner, Marcos Dantus, Mercouri Kanatzidis
Mark J. Waner
Charge Density Wave Caused by Reducing ThSe3 by One Electron. Superstructure and Short-Range Order in ATh2Se6 (A = K, Rb) Studied by X-ray Diffraction, Electron Diffraction, and Diffuse Scattering
A Niobium(V) Complex With Mixed O,S-Donor Ligands. Synthesis, Structure And Properties Of The Anion Tris(2-Mercapto-4-Methylphenolato)Niobate(V), Paul Challen, Diane Peapus, Karen Magnes
A Niobium(V) Complex With Mixed O,S-Donor Ligands. Synthesis, Structure And Properties Of The Anion Tris(2-Mercapto-4-Methylphenolato)Niobate(V), Paul Challen, Diane Peapus, Karen Magnes
Paul R. Challen
Reaction of Nb(OEt)5 with 2-mercapto-4-methylphenol (mmpH2) in the presence of triethylamine gave the mononuclear tris complex (Et3NH)[Nb(mmp)3] which was structurally characterized. The coordination geometry around the niobium is between octahedral and trigonal prismatic, with a twist angle of 41.5°. The mercaptophenolate ligands are arranged around the metal in a “propeller” fashion. (Et3NH)[Nb(mmp)3] was characterized by IR, 1H NMR and UV-vis spectroscopies, and cyclic voltammetry. A reversible reduction wave found at −1.03 V is for reduction to the NbIV complex.
Vanadium(Iv) Complexes With Mixed O,S Donor Ligands. Syntheses, Structures, And Properties Of The Anions Tris(2-Mercapto-4-Methylphenolato)Vanadate(Iv) And Bis(2-Mercaptophenolato)Oxovanadate(Iv), Paul Klich, Andrew Daniher, Paul Challen, David Mcconville, Wiley Youngs
Vanadium(Iv) Complexes With Mixed O,S Donor Ligands. Syntheses, Structures, And Properties Of The Anions Tris(2-Mercapto-4-Methylphenolato)Vanadate(Iv) And Bis(2-Mercaptophenolato)Oxovanadate(Iv), Paul Klich, Andrew Daniher, Paul Challen, David Mcconville, Wiley Youngs
Paul R. Challen
Reaction of VO(acac)2 with 2-mercaptophenol (mpH2) in the presence of triethylamine gives the mononuclear tris complex (Et3NH)2[V(mp)3] (1), in which the vanadyl oxygen has been displaced. An analogous reaction using 2-mercapto-4-methylphenol (mmpH2) afforded (Et3NH)(PNP)[V(mmp)3] (2), which was structurally characterized. 2 crystallizes in the orthorhombic space group Pna21 with unit cell parameters (at −163 °C) a = 23.974(7) Å, b = 9.569(4) Å, c = 25.101(6) Å, and Z = 4. The coordination geometry around the vanadium is between octahedral and trigonal prismatic. Reaction of VO(acac)2 with the sodium salt of 2-mercaptophenol produces the vanadyl(IV) complex Na(Ph4P)[VO(mp)2]·Et2O (3), which crystallizes in …
Nitrogenase Substrates As Intercluster Bridging Units Between The Molybdenum Atoms In Doubly Bridged, Double Cubanes. The Synthesis And Characterization Of The [Mofe3s4cl2(Cl4cat)]2(.Mu.2-S)(.Mu.2-L)]N- Anions (L = N2h4, N = 4; L = Cn-, N = 5), Paul Challen, Sang Koo, C. Kim, W. Dunham, D. Coucouvanis
Nitrogenase Substrates As Intercluster Bridging Units Between The Molybdenum Atoms In Doubly Bridged, Double Cubanes. The Synthesis And Characterization Of The [Mofe3s4cl2(Cl4cat)]2(.Mu.2-S)(.Mu.2-L)]N- Anions (L = N2h4, N = 4; L = Cn-, N = 5), Paul Challen, Sang Koo, C. Kim, W. Dunham, D. Coucouvanis
Paul R. Challen
No abstract provided.
New .Mu.2-S2--Coupled, Singly Bridged Double Cubane With The [(Fe4s4cl3)2s]4- Core. The Stepwise Synthesis And Structural Characterization Of (N-Bu4n)2(Ph4p)2[(Fe4s4cl3)2s], Paul Challen, Sang Koo, W. Dunham, D. Coucouvanis
New .Mu.2-S2--Coupled, Singly Bridged Double Cubane With The [(Fe4s4cl3)2s]4- Core. The Stepwise Synthesis And Structural Characterization Of (N-Bu4n)2(Ph4p)2[(Fe4s4cl3)2s], Paul Challen, Sang Koo, W. Dunham, D. Coucouvanis
Paul R. Challen
No abstract provided.
Stepwise Synthesis And Structural Characterization Of The Molybdenum-Iron-Sulfur {[Mofe3s4cl2(Cl4cat)]2(.Mu.2-S)2}6- And {[Mofe3s4cl2(Cl4cat)]2(.Mu.2-S)(.Mu.2-Oh}5- Doubly Bridged Double Cubanes Obtained By The Coupling Of [Mofe3s4] Clusters, Dimitri Coucouvanis, Paul Challen, Sang Koo, W. Davis, W. Butler, W. Dunham
Stepwise Synthesis And Structural Characterization Of The Molybdenum-Iron-Sulfur {[Mofe3s4cl2(Cl4cat)]2(.Mu.2-S)2}6- And {[Mofe3s4cl2(Cl4cat)]2(.Mu.2-S)(.Mu.2-Oh}5- Doubly Bridged Double Cubanes Obtained By The Coupling Of [Mofe3s4] Clusters, Dimitri Coucouvanis, Paul Challen, Sang Koo, W. Davis, W. Butler, W. Dunham
Paul R. Challen
No abstract provided.