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Full-Text Articles in Analytical Chemistry

Tissue-Specific Heavy Metal Accumulation And Sediment–Mangrove Dynamics In Port Everglades, Florida, Dimitrios Giarikos, Amy Hirons, Jason Gershman, Sophie Welch May 2026

Tissue-Specific Heavy Metal Accumulation And Sediment–Mangrove Dynamics In Port Everglades, Florida, Dimitrios Giarikos, Amy Hirons, Jason Gershman, Sophie Welch

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Coastal wetlands near industrialized waterways face increasing heavy metal contamination, yet the role of mangroves as biogeochemical buffers remains poorly understood. This study quantified 16 heavy metals in sediments and red mangrove (Rhizophora mangle) tissues (roots, branches, and leaves) across four sites near Port Everglades, Florida, examining tissue-specific partitioning, contamination patterns, and sediment-to-plant transfer. The South Turning Basin (STB) was the principal contamination hotspot, with geometric mean (GM) concentrations of arsenic (As; 27.8 µg/g) and zinc (Zn; 203 µg/g) exceeding threshold effect levels, while Cu exceeded its probable effect level (PEL; 193 µg/g). Mercury (Hg) exceeded its PEL …


Peruvian Pinniped Teeth Trace Element Data-Tracking Ecosystem Variabilites Through Trace Element Record Found In Peruvian Pinniped Dentin, Dimitrios Giarikos, Amy Hirons, Ally E. Sheehan, Radleigh Santos Mar 2026

Peruvian Pinniped Teeth Trace Element Data-Tracking Ecosystem Variabilites Through Trace Element Record Found In Peruvian Pinniped Dentin, Dimitrios Giarikos, Amy Hirons, Ally E. Sheehan, Radleigh Santos

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The South American sea lion (Otaria byronia; SASL) and the Peruvian fur seal (Arctocephalus australis; PFS) are apex predators within the Humboldt Current ecosystem, where population dynamics respond to both natural variability and anthropogenic pressures, including El Niño–Southern Oscillation (ENSO) events and coastal mining. This study quantified 18 trace elements (TEs) in canine dentin from both species collected at Punta San Juan, Peru using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) to evaluate long-term environmental exposure. Because dentin is deposited incrementally, it preserves a chronological chemical archive reflecting ontogenetic shifts in diet and habitat use. Overall, TE concentrations were broadly similar …


Salmon As An Ecological Pathway Of Contaminants Into Alaskan Food Webs, Miranda Brohman, Gretchen Roffler, Dimitri G. Giarikos, David Kerstetter, Amy C. Hirons Mar 2025

Salmon As An Ecological Pathway Of Contaminants Into Alaskan Food Webs, Miranda Brohman, Gretchen Roffler, Dimitri G. Giarikos, David Kerstetter, Amy C. Hirons

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Salmon are important fish taxa for humans and animals in hemiboreal and subarctic ecosystems. Trace elements and their marine food web bioaccumulation raises biomagnification and potential human health risk concerns. Sixteen trace element concentrations and their health risk assessments were determined in seven different tissues of two Southeast Alaska salmon species (chum, Oncorhynchus keta and pink, Oncorhynchus gorbuscha). Chum tissues had overall higher trace element concentrations compared to pink, which may be attributed to a difference of diets, generally longer-lived and spending more time in the open ocean. All kidney and liver samples exceeded the tolerable daily intake for …


Northern Fur Ssal Vibrissae Organochlorine Contaminant Concentrations, Dimitri Giarikos, Amy Hirons, Courtney White Aug 2024

Northern Fur Ssal Vibrissae Organochlorine Contaminant Concentrations, Dimitri Giarikos, Amy Hirons, Courtney White

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The eastern Pacific stock of northern fur seals (Callorhinus ursinus) on the Pribilof Islands has experienced population declines since 1980. The decline may be due to anthropogenic persistent organic pollutants (POPs) which bioaccumulate, are toxic, and persistent. This study conducted a comparison of 21 organochlorine (OC) and 39 polybrominated diphenyl ether (PBDE) analyte concentrations utilizing archived vibrissae (whiskers) from individual fur seals sampled in 1993 (n=30) and 2013 (n=41). The PBDEs had values five times greater than the legacy status OCs. There were no significant mean concentration differences between 1993 and 2013 for total organochlorines (ΣOCs), or total …


Northern Fur Seal Vibrissae Polybrominateddiphenylether Concentrations, Dimitri Giarikos, Amy Hirons, Courtney White Aug 2024

Northern Fur Seal Vibrissae Polybrominateddiphenylether Concentrations, Dimitri Giarikos, Amy Hirons, Courtney White

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The eastern Pacific stock of northern fur seals (Callorhinus ursinus) on the Pribilof Islands has experienced population declines since 1980. The decline may be due to anthropogenic persistent organic pollutants (POPs) which bioaccumulate, are toxic, and persistent. This study conducted a comparison of 21 organochlorine (OC) and 39 polybrominated diphenyl ether (PBDE) analyte concentrations utilizing archived vibrissae (whiskers) from individual fur seals sampled in 1993 (n=30) and 2013 (n=41). The PBDEs had values five times greater than the legacy status OCs. There were no significant mean concentration differences between 1993 and 2013 for total organochlorines (ΣOCs), or total …


Heavy Metals Implications To Sediment Microbiome And Coral Response To Arsenic Dosing, Dimitrios G. Giarikos, Amy Hirons, Jose V. Lopez, Abigail Renegar, Jason Gershman Jun 2024

Heavy Metals Implications To Sediment Microbiome And Coral Response To Arsenic Dosing, Dimitrios G. Giarikos, Amy Hirons, Jose V. Lopez, Abigail Renegar, Jason Gershman

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No abstract provided.