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Articles 2641 - 2670 of 2720
Full-Text Articles in Chemistry
Synthesis And Characterisation Of Anhydrous Magnesium Phosphate Mg$_3$(Po$_4$)$_2$, A. Baykal, M. Kizilyalli, R. Kniep
Synthesis And Characterisation Of Anhydrous Magnesium Phosphate Mg$_3$(Po$_4$)$_2$, A. Baykal, M. Kizilyalli, R. Kniep
Turkish Journal of Chemistry
The synthesis and characterization of anhydorus Mg_3(PO$_4)_2 was investigated. Mg_3(PO$_4)_2 is reported to have similar structural arrangements with Co_3(PO_4)_2 and \gamma-Zn_3(PO_4)_2 compounds. The sample was prepared by a new technique which is the reaction of MgCl_2.6H_2O and Na_3PO_4.12H_2O solutions at pH=5.1, which was adjusted by adding concentrated H_3PO_4 to the reaction mixture and heating the precipitated product at 600^{\circ}C untill constant weight. The purity of the product was checked by X-ray powder diffraction, IR, density measurement, SEM and DTA analysis. The monoclinic unit cell dimensions of product are a=7.605 (2), b=8.233 (3), c=5.080 (1)A^{\circ} and \beta= 94.19^{\circ} (3), which was …
A Topological Approach To The Stabilities Of Isomeric Hückel And Mobius Type Cyclacenes, Lemi Türker
A Topological Approach To The Stabilities Of Isomeric Hückel And Mobius Type Cyclacenes, Lemi Türker
Turkish Journal of Chemistry
Within the constraints of Hückel molecular orbital theory, Hückel and Mobius type cyclacenes were investigated in terms of their angle of total \pi-electron energy, O_{\pi}, and cos O_{\pi} to find out how structural changes affect the stabilities. It has been theoretically deduced that as the number of benzenoid rings (R) increases the isomeric Hückel and Mbius type cyclacenes should have comparable stabilities, although for low values of R odd-Hückel type and even-Mobius type are predicted to be more stable.
Hydrolysis And Condensation Reactions Of Methacrylate-Modified Aluminum Alkoxides, Ertuğrul Arpaç, Efraim Avşar
Hydrolysis And Condensation Reactions Of Methacrylate-Modified Aluminum Alkoxides, Ertuğrul Arpaç, Efraim Avşar
Turkish Journal of Chemistry
The hydrolysis of aluminum tri-sec-butoxide and compounds obtained by substituting the larger functional groups for the present alkly groups in Al(O-sec-Bu)_3, and the reaction of these products with a polymerizable organic ligand, i.e. methacrylic acid, were studied together with the hydrolysis reactions of the final products. A good method of preparing high-tech materials and new composites uses organo-substituted silicon esters and/or alkoxides of various elements in a polycondensation process. Introducing a suitable organic network into the inorganic backbone gives desirable properties in new coating materials. The preparation of such materials is possible via the hydrolysis of metal alkoxides. Usually, different …
Crystal Structure Effect In Radiation-Induced Solid-State Polymerization Of Acrylamide, Ali Usanmaz
Crystal Structure Effect In Radiation-Induced Solid-State Polymerization Of Acrylamide, Ali Usanmaz
Turkish Journal of Chemistry
Crystal structure of arcylamide at -150^{\circ}C was studied to understand the role of the crystal structure on the reaction mechanism of radiation-induced polymerization in the solid-state. Acrylamide crystallizes in the monoclinic unit cell with the unit cell parameters as ; a=828.0(2) pm, b=578.0(4) pm, c=974.9(2) pm, \beta=119.62(4)^0, space group =P 2_1/c, Z=4 molecules/unit cell, d_x = 1.165 g/cm^3. From the results of the structural data a polymerization mechanism in the solid-state is suggested. The radiation damage in single crystal of acrylamide was also investigated in detail. The result showed the formation of the amorphous polymer, that phase separated from the …
A Study Of The Thermodynamical Interactions Of Bisphenol-A Polycarbonate With Some Solvents By Gas Chromatography, Özlem Cankurtaran, Ferdane Yilmaz
A Study Of The Thermodynamical Interactions Of Bisphenol-A Polycarbonate With Some Solvents By Gas Chromatography, Özlem Cankurtaran, Ferdane Yilmaz
Turkish Journal of Chemistry
Retentin diagrams of polycarbonate for n-nonane, ethyl acetate and n-butyl acetate were obtained using inverse gas chromatography in the temperature range 80-240^{\circ}C. The specific retention volumes, V^{\circ}_{g} the Flory-Huggins interaction parmeters, \chi^{\infty}_{12}, interaction parameters, \chi^{\ast}_{12}, and effective exchange-energy parameters \bar{X}_{12} of the equation-of-state theory of polycarbonate for n-octane, n-nonane, n-decane, ethyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate, tert-butyl acetate and isoamyl acetate were obtained in the temperature range 200-240^{\circ}C. The parameter \delta_2 was estimated to be 10.7 (cal/cm^3)^{1/2} at room temperature using the \chi^{\infty}_{12} extrapolated to room temperature. Keywords: Bisphenol-A polycarbonate, polymer-solvent interactions, inverse gas chromatography, solubility parameter.
Photoelectron Spectroscopy: A Tool In Sorption Studies, Şefik Süzer, Hasan N. Erten
Photoelectron Spectroscopy: A Tool In Sorption Studies, Şefik Süzer, Hasan N. Erten
Turkish Journal of Chemistry
Photoelectron spectroscopy using AlK\alpha (h\nu=1486.3 eV) has been applied to study the sorption of Cs^+, Sr^{2+}, Ba^{2+}, Zn^{2+} and Co^{2+} on magnesite kaolinite, smectite and chlorite. From the observed intensities of photoelectron peaks it was determined that in magnesite the sorption affinity of the above ions follow the order: Ba^{2+}>Co^{2+}\congSr^{2+}\congZn^{2+}>Cs^+. The order for the sorption of Ba^{2+} and Cs^+ are also determined as chlorite>magnesite>smectite>kaolinite and smectite>chlorite\congkaolinite>magnesite, respectively.
Kinetics Of Autoxidative Polymerization Of Sunflowerseed Oil, Hüseyin Topallar, Yüksel Bayrak, Mehmet İşcan
Kinetics Of Autoxidative Polymerization Of Sunflowerseed Oil, Hüseyin Topallar, Yüksel Bayrak, Mehmet İşcan
Turkish Journal of Chemistry
The rates of polymerization of unhydrogenated and hydrogenated sunflowerseed oils were measured under atmospheric conditions in the various containers (glass, PET and metal). Polymerization rates showed a strong dependence on the degree of unsaturation and the light transmittance of the containers. The average molecular weights of polymerized oils were determined by viscosity measurements.The relationship between viscosity and average molecular weight was determined. It is seen that unhydrogenated sunflowerseed oil has a higher polymerization rate than hydrogenated oil samples in a glass container and they has higher viscosity values.
Features Of Graft Copolymer Formation Through Reaction Of Functionalized Polyolefins With Poly-\Epsilon-Caprolactam, Elisa Passaglia, Francesco Picchioni, Mauro Aglietto, Giocomo Ruggeri, Francesco Ciardelli
Features Of Graft Copolymer Formation Through Reaction Of Functionalized Polyolefins With Poly-\Epsilon-Caprolactam, Elisa Passaglia, Francesco Picchioni, Mauro Aglietto, Giocomo Ruggeri, Francesco Ciardelli
Turkish Journal of Chemistry
The reaction in the melt of polyolefins containing 2-diethylsuccinate groups (DES) with poly-\epsilon-caprolactam (PA6) to give a graft copolymer was investigated under different conditions. Even using a large excess of DES groups over the PA6 terminal amino groups the graft copolymer yield resulted only partial thus suggesting a kinetic control of the reaction. The effect of various catalysts was then examined taking into account results obtained in a model reaction between a low molecular weight amine and diethylsuccinate. The results are discussed in terms of side reactions and miscibility of the pristine polymers.
Phase Transition Of Hydrolyzed Polyacrylamide Gels In Aqueous Solutions Of Poly(Ethylene Glycol), Nilhan Kayaman, Oğuz Okay, B. M. Baysal
Phase Transition Of Hydrolyzed Polyacrylamide Gels In Aqueous Solutions Of Poly(Ethylene Glycol), Nilhan Kayaman, Oğuz Okay, B. M. Baysal
Turkish Journal of Chemistry
Hydrolyzed polyacrylamide gels immersed in aqueous solutions of poly(ethylene glycol) (PEG) of molecular weight 300 exhibit a discontinuous volume change upon continuous increase of the PEG concentration in the external solution. As the duration of hydrolysis increases, that is, as the proportion of the ionic groups on the network chains increases, the critical concentration of PEG required for a discontinuous volume change rises and, also, the magnitude of the volume collapse becomes larger. Experimental results indicate that the gel collapse in PEG solution is due to the osmotic deswelling of the ionic gel rather than due to a complex formation …
Immobilization Of Glucose Oxidase And Urease In Hydrogel Matrices, İhsan Gürel, M.Yakup Arica, Vasıf Hasirci
Immobilization Of Glucose Oxidase And Urease In Hydrogel Matrices, İhsan Gürel, M.Yakup Arica, Vasıf Hasirci
Turkish Journal of Chemistry
Immobilization of glucose oxidase and urease in hydrogels of 2-hydroxyethyl methacrylae, and N-vinyl pyrrolidone (NVP) was achieved by irradiation (using UV kand \gamma- rays). The effect of radiation on entrapment efficiencies, retention of activities and swelling rates was obtained. To optimize the system, duration of exposure, reaction temperature, co-monomer concentrations, initiator and cross linker compositions were varied. The repeated reusability of the generated products was also tested. It was found that\gamma-irradiation at very low temperatures did not have a detrimental effect on the enzyme activity. Incorporation of more hydrophilic monomer (NVP), influenced matrix morphology and entrapment efficiencies and retained enzyme …
Potentiometric And Spectroscopic Determinaton Of Acid Dissociation Constants Of Some Phenols And Salicylic Acids, Rahmiye Aydin, Ulviye Özer, Naciye Türkel
Potentiometric And Spectroscopic Determinaton Of Acid Dissociation Constants Of Some Phenols And Salicylic Acids, Rahmiye Aydin, Ulviye Özer, Naciye Türkel
Turkish Journal of Chemistry
The dissociation constant of the catechol derivatives 4-nitrocatechol (NCAT), 2,3-dihydroxybenzoic acid (2,3-DHBA), 3,4-dihydroxybenzoic acid (3,4-DBHA), 3,4-dihydroxyhenylacetic acid (3,4-DPHA) and 3,4-dihydroxycinnamic acid (3,4-DHCA) were identified in 0.1M NaClO_4 ionic medium, at t=25^{\circ}C, by potentiometry. In addition, the first and second dissociation constants of the salicylic acid derivatives 5-nitrosalicylic acid (5-NSA), 4-hydroxysalicylic acid (4-HSA) 5-nitrosalicylic acid (5-HSA) were also determined by potentiometry. Furthermore, the second acid dissociation constants of these ligands were evaluated in I=0.1M NaClO_4 ionic medium, at a temperature of 25^{\circ}C by computer analysis of spectroscopic data.
Polymer Light Emitting Diodes, Frank E. Karasz, Bin Hu, Zhou Yang
Polymer Light Emitting Diodes, Frank E. Karasz, Bin Hu, Zhou Yang
Turkish Journal of Chemistry
Polyphenylene vinylene-based conjugated-nonconjugated alternating block copolymers form the active chromophores in a series of light emitting diodes (LEDs). The quantum efficiency and brightness of these devices can be improved by several orders of magnitude by incorporation of appropriate carrier transport layers and by rational choice of electrodes. Further improvements can be gained by blending of the active chromophores with high or low molecular weight species.
Carbon Monoxide Hydrogenation Over Ru-Mn-K/Al_2o_3 Catalysts, S. Tajammul Hussain, M. Ashraf Atta
Carbon Monoxide Hydrogenation Over Ru-Mn-K/Al_2o_3 Catalysts, S. Tajammul Hussain, M. Ashraf Atta
Turkish Journal of Chemistry
The catalytic behavior of a series Ru/Al_2O_3 catalysts promoted with various levels of Mn and K prepared by coimpregnation were investigated in the CO-hydrogenation reaction. Catalytic studies showed that the addition of Mn enhances the production of Fischer Tropsch products and K promotion in particular enhances the production of unsaturated hydrocarbons while inhibiting the methanation reaction. The influence of K and Mn on the Fischer Tropsch product selectivity in CO-hydrogenation studies is discussed in terms of ensemble and electronic effects, and the production of a new surface site Ru:Mn:K.
Ion Chromatographic Analysis Of Water-Soluble Anions In The Atmosphere In Amman, Jordan, Qasem M. Jaradat, Kamal A. Monami, Anwar G. Jiries
Ion Chromatographic Analysis Of Water-Soluble Anions In The Atmosphere In Amman, Jordan, Qasem M. Jaradat, Kamal A. Monami, Anwar G. Jiries
Turkish Journal of Chemistry
In the summer of 1995, samples of airborne particles were collected in the Amman area of Jordan. Ion chromatography (IC) was used for the determination of anions in these samples. Four anions were identified and quantified in the atmosphere of Amman. The concentration ranges of F^-, CL^-, NO_3^- and SO_4^= were 0.04 - 3.3, 2.25 - 15.7, 1.96 - 8.39 and 16.88 - 41.33 \mug/m^3, respectively. The study shows that Cl^-, NO_3^-, and SO_4^= are the major anions of air particulate, and the concentration of SO_4^= exceeds that of some other cities worldwide. The total suspended particles (TSP) value was …
Epr Spectroscopy Of Dog-Rose Polyphenoloxidase, Çiğdem Nuhoğlu, Fatih Ucun, Enise Ayyildiz, Y. Kemal Yoğurtçu, Halis Şaki̇roğlu, İrfan Küfrevi̇oğlu
Epr Spectroscopy Of Dog-Rose Polyphenoloxidase, Çiğdem Nuhoğlu, Fatih Ucun, Enise Ayyildiz, Y. Kemal Yoğurtçu, Halis Şaki̇roğlu, İrfan Küfrevi̇oğlu
Turkish Journal of Chemistry
Polyphenoloxidase(PPO) of dog-rose fruit was extracted and purified through (NH\4)\2SO\4 precipitation and dialysis. The optimum conditions for this purpose, i.e., pH and temperature, were determined with 4-methylcatechol optimum pH and temperature and found to be pH 8.5 and 20\ci, respectively. The inhibition effect of ascorbic acid was investigated and the I_{50} value was found to be 1.57\times10^{-4} M. The activity of dog-rose PPO was investigated by electron paramagnetic resonance (EPR) at different pH levels and temperatures. The optimum conditions obtained from both spectrophotometry and EPR were compared.
Catalytically Active Intermediates In Photochemical Metathesis, Çetin Bozkurt, Yavuz İmamoğlu
Catalytically Active Intermediates In Photochemical Metathesis, Çetin Bozkurt, Yavuz İmamoğlu
Turkish Journal of Chemistry
The nature of the active species in photocatalytic metathesis reaction was investigated. The formation of Wittig-type addition products with benzaldehyde indicates that catalytically active carbene is the product of olefin and tungsten hexacarbonyl under reaction conditions.
Synthesis Characterization And Miscibility Of Polyvinyl Butyrals Of Varying Vinyl Alcohol Contents, Z. M. Zhou, D. J. David, W. J. Macknight, F. E. Karasz
Synthesis Characterization And Miscibility Of Polyvinyl Butyrals Of Varying Vinyl Alcohol Contents, Z. M. Zhou, D. J. David, W. J. Macknight, F. E. Karasz
Turkish Journal of Chemistry
Polyvinyl butyrals (PVB) of systematically varying vinyl alcohol content have been synthesized and characterized using wet chemistry, IR, DSC, and TGA. The miscibility of PVB-PVB blends was studied by DSC as a function of vinyl alcohol content and vinyl alcohol content differences between the respective blend components. These data were use to construct an isothermal miscibility map of PVB and to calculate the intramolecular interaction parameter \chi_{VA,VB}. The \chi_{VA,VB} was a function of the absolute level of the vinyl alcohol (VA) and vinyl butyral (VB) contents of the polymers. In addition, the thermal stability of polyvinyl butyral was found to …
Network Characterization Of Energetic Poly(Glycidyl-Azide), Mehmet S. Eroğlu, Olgun Güven
Network Characterization Of Energetic Poly(Glycidyl-Azide), Mehmet S. Eroğlu, Olgun Güven
Turkish Journal of Chemistry
Energetic poly(glycidyl azide) (PGA) elastomers with different crosslink densities were prepared by varying the NCO/OH reactive-groups ratio from 0.8 to 1.0. In the preparation of the elastomers, PGA chains were end-liked with a mixture of hexamethylene diisocyanate (HMDI) and trimethylol propane (TMP) at a fixed TMP/PGA mole ratio. The number average molar mass between junction points of the network chains \overline{{\rm M}}_c was calculated using data obtained from swelling and uniaxial tensile tests and the results were compared. For the mechanical characterization of the networks, Mooney-Rivlin plots were prepared and the values of the constants 2C_1 and 2C_2 of PGA …
Electrical Conductivity Of Sodium Doped Poly(4-Vinylpyridine), Murat Özyalçin, Zuhal Küçükyavuz, Aref Jarvaherian, Savaş Küçükyavuz
Electrical Conductivity Of Sodium Doped Poly(4-Vinylpyridine), Murat Özyalçin, Zuhal Küçükyavuz, Aref Jarvaherian, Savaş Küçükyavuz
Turkish Journal of Chemistry
Poly(4-Vinylpyridine) was synthesized by free radicalic polymerization. Solution doping process with metallic sodium was carried out. A conductivity value around 10^{-6} S/cm was obtained. Relative change in the coductivity with dopant concentration, temperature dependence of conductivity, conductivity behavior in atmospheric conditions for the samples were analyzed. SEM and EDX techniques were also used for the characterization of the polymer.
Possible Roles Of Transition Metals In Cloudwater Relative To The Solar Short-Wave Radiation Absorption Anomaly, Xudong Huang, S. Sinan Keski̇n, Francis Pink, İlhan Ölmez
Possible Roles Of Transition Metals In Cloudwater Relative To The Solar Short-Wave Radiation Absorption Anomaly, Xudong Huang, S. Sinan Keski̇n, Francis Pink, İlhan Ölmez
Turkish Journal of Chemistry
Measurements of the absorption of solar short-wave radiation by clouds exceed those predicted by theoretical calculations. In order to understand the roles of minor and trace species in this absorption anomaly, cloudwater samples were collected from individual precipitating clouds and analyzed for trace metals and anionic species. Two generalized approaches were used to assess the direct impact of the absorption of solar short-wave radiation by transition metals and/or their anionic complexes. Additionally, it was suggested that iron and manganese may act as catalyts in the formation of sulfate aerosols which efficiently scatter solar radiation.
Synthesis And Characterization Of Complexes Of Co(Ii), Ni(Ii), Cd(Ii), Hg(Ii) And Pd(Ii) With Some N-Phenyl-N^{1}-2-[4-Phenyl-(Substituted) Thiazolyl]- Thioureas, B. Narayana, M. R. Gajendragad
Synthesis And Characterization Of Complexes Of Co(Ii), Ni(Ii), Cd(Ii), Hg(Ii) And Pd(Ii) With Some N-Phenyl-N^{1}-2-[4-Phenyl-(Substituted) Thiazolyl]- Thioureas, B. Narayana, M. R. Gajendragad
Turkish Journal of Chemistry
The Synthesis and characterization of the complexes of Co(II), Ni(II), Pd(II), Cd(II) and Hg(II) with N-phenyl-N^{1}-2(-4-phenylthiazoly)thiourea (PPT) and N-phenyl-N^{1}-2-(4-methylphenylthiazolyl)-thiourea (PMPT) and Co(II), Cd(II), and Hg(II) complexes of N-phenyl-N^{1}-2-(4-p- chlorophenylthiazolyl) thiourea (PCPT) are included in this paper. Based on analytical results, electronic and infrared spectral data and magnetic susceptibility measurements, plausible structures have been proposed.
Reduction Of Combustion Generated Pollution: Process Modifications And Energy Efficient Power Cycles, Janos M. Beer
Reduction Of Combustion Generated Pollution: Process Modifications And Energy Efficient Power Cycles, Janos M. Beer
Turkish Journal of Chemistry
Theoretical bases of combustion process modifications aimed at the reduction of pollutant emission are examined. It is shown, as an example, of how the minimization of emissions of nitrogen oxides leads to a design protocol that translates results of modeling and of bench scale experiments into guidelines for industrial design. The formation and emission of polycyclic aromatic compounds is also considered, because their formation is strongly favored in "low NO_x flames". In power generation the pollutant emission can be reduced effectively by the improvement of the ``heat rate,"i.e., the thermodynamic efficiency of the power cycle. Combined gas turbine-steam cycles which …
Examination Of Historical Textiles With Dyestuff Analyses By Tlc And Derivative Spectrophotometry, Recep Karadağ, Emre Dölen
Examination Of Historical Textiles With Dyestuff Analyses By Tlc And Derivative Spectrophotometry, Recep Karadağ, Emre Dölen
Turkish Journal of Chemistry
A group of historical textiles in the Topkapi Museum, i.e., silk brocades classified as 16th century pieces by art historians, were investigated by TLC and spectrophometric analyses of their dyestuffs for the purpose of dating these pieces. The dyestuffs contained intextile fibers were extracted with acid solutions of varying strength, and the acid extracts were analyzed by both TLC and spectrophotometry, either directly or after an organic solvent extraction step. The first derivative spectra proved to provide more information than the main spectra. In order to eliminate possible interferences in spectrophotometry arising from impurities in the fibers, e.g., compounds containing …
Investigation Of Hmo Spectra Of Hückel And Mobius Type Cyclacenes, Lemi Türker, Şakir Erkoç
Investigation Of Hmo Spectra Of Hückel And Mobius Type Cyclacenes, Lemi Türker, Şakir Erkoç
Turkish Journal of Chemistry
The Hückel molecular orbital spectra (HMO) of Hückel- and Mobius-type cyclacenes having 3-15 benzenoid rings were investigated and it was found that certain eigenvalues are topologically invariant, whereas others exhibit topological periodicity. For example, Hückel-type cyclacenes having 2r (r: 2,3,4,...) benzenoid rings which possess nonbonding molecular orbitals (NBMO) and are thus expected to be open shell structures.
Apocarbonic Anhydrase-Enzymatic Determination Of Zinc In Fruit Juices, Ayşe Karagölge, Nazan Demi̇r, Yaşar Demi̇r, İrfan Küfrevi̇oğlu
Apocarbonic Anhydrase-Enzymatic Determination Of Zinc In Fruit Juices, Ayşe Karagölge, Nazan Demi̇r, Yaşar Demi̇r, İrfan Küfrevi̇oğlu
Turkish Journal of Chemistry
In this study, a new enzymatic method for determining trace amount of zinc was employed on ten different fruit juices. The basis of the enzymatic method is that apocarbonic anhydrase regains its activity in proportion to the Zn^{2+} existing in a solution. Thus, the more activated the enzyme is in the medium, the higher the Zn^{2+} concentration in the solution will be. For this purpose, bovine carbonic anhydrase was purified from erythrocyte hemolisate by affinity chromatography. The Zn^{2+} bound to the enzyme was removed by of the purified enzyme against the solution of pyridine-2-6-dicarboxylic acid. Thus 100\% purified enzyme was …
Some Oxidation Reactions Of Isomeric Pyridinecarboxylic Acid Hydrazides, Rashid Iqbal, Samia Ebrahim, Muhammad Ziaulhaq
Some Oxidation Reactions Of Isomeric Pyridinecarboxylic Acid Hydrazides, Rashid Iqbal, Samia Ebrahim, Muhammad Ziaulhaq
Turkish Journal of Chemistry
The oxidation reactions of the three isomeric pyridinecarboxylic acid hydrazides were studied using sodium metaperidoate, silver(I) oxide and potassium ferricyanide separately. Potassium ferricyanide emerged as an excellent reagent for preparation of 2-pyridinecarboxaldehyde and 3-pyridinecarboxaldehyde from the respective isomeric pyridinecarboxylic acid hydrazides. Oxidation with silver(I) oxide in each case yielded the corresponding 1,2-dipyridoylhydrazine, while sodium metaperiodate furnished different products with each isomeric pyridinecarboxylic acid hyrazide.
^1h Nmr, Infrared And Mass Spectrometry Of Di- And Tri-Organotin Derivatives Of 1-Nitroso-2-Naphthol, Saqib Ali, Muhammad Mazhar, Moazzam Hussain Bhatti, Sohail Mahmood, Abida Kalsoom
^1h Nmr, Infrared And Mass Spectrometry Of Di- And Tri-Organotin Derivatives Of 1-Nitroso-2-Naphthol, Saqib Ali, Muhammad Mazhar, Moazzam Hussain Bhatti, Sohail Mahmood, Abida Kalsoom
Turkish Journal of Chemistry
The di- and tri-organotin derivatives R\2SnL\2 and R\3SnL where R = CH\3, n--C\4H\9, C\6H\5, C\6H_{11} and C\6H\5CH\2 and L = 1-nitroso-2-naphthoxy were synthesized. These derivatives were characterized by elemental analysis, infrared, ^1H NMR and mass spectrometry.
The Investigation Of Aluminum Sulfate-Potassium Chloride Solid Phase Reaction, İ. Ayhan Şengi̇l
The Investigation Of Aluminum Sulfate-Potassium Chloride Solid Phase Reaction, İ. Ayhan Şengi̇l
Turkish Journal of Chemistry
It was found that aluminum sulfate reacts with potassium chloride to produce K_{2}SO_{4}, Al_{2}O_{3}, and Cl_{2} in the solid phase at 700 ^{\circ}C. This reaction was investigated with thermal analysis under air and nitrogen atmosphere. By changing temperature and time parameters, the actual yield of conversion in question was examined analytically and the optimum temperature and time were found for the reaction. The rate expression of the solid phase reaction was also investigated and the rate equation was obtained.
Analysis Of Retention In Supercritical Fluid Chromatography And Its Relation To Solubility, Z. Şermin Gönenç, Uğur Akman, Aydın K. Sunol
Analysis Of Retention In Supercritical Fluid Chromatography And Its Relation To Solubility, Z. Şermin Gönenç, Uğur Akman, Aydın K. Sunol
Turkish Journal of Chemistry
The effects of temperature, pressure and supercritical fluid density on the solubility-retention relationship of solutes in supercritical fluid chromatography are investigated. New retention data for naphthalene, phenanthrene, benzoic acid and 2-methoxy-naphthalene is obtained as a function of pressure at different temperatures. The bulk of the data is taken near the critical region of the mobile gas where the anomalities are expected. This data is used to compare two approaches for thermodynamic modeling of pressure dependence of solute retention. In these approaches, mobile-phase partial molar volumes of the solutes are determined either from bulk solubility data or from infinite-dilution fugacity coefficients. …
Quantum-Chemical Investigations On The Functionalized 1h-Pyrimidines, İsmail Yildirim, Makbule Tezcan, Yahya Güzel, Emin Saripinar, Yunus Akçamur
Quantum-Chemical Investigations On The Functionalized 1h-Pyrimidines, İsmail Yildirim, Makbule Tezcan, Yahya Güzel, Emin Saripinar, Yunus Akçamur
Turkish Journal of Chemistry
Conformational analysis and quantum-chemical calculations were carried out by means of the methods MMP2 and SCF MO LCAO in the CNDO/2 and MNDO approximation for the series of compounds being functionalized 1H- pyrimidines. The analysis of the electron density distribution depending on the substituents' nature was done on the basis of the data obtained.