Chemistry Commons^™

Synergistic Extraction Of Silver From Nitric Acid Medium With Dithizone In The Presence Of A Secondary Amine- Amberlite La-2 Using 110mag-Radioisotope, Madhusudan Mandal Ph.D.

Karbala International Journal of Modern Science

Synergistic extraction of silver has been investigated in the presence of two different kinds of extractants, one of which is a chelating ligand, dithizone and the other is a long-chain secondary amine amberlite LA-2 at pH 3.0 using a radiotracer technique. The apparent formation constant, overall equilibrium constant and adduct formation constants were calculated from distribution coefficients. Interestingly, it was observed that the adduct formation constant is too high when the ligand concentration is increased by keeping the amine concentration fixed at 0.044 M compared to that obtained when the ligand concentration is kept fixed at 8.74×10^-4 M.

Editorial Board

Karbala International Journal of Modern Science

No abstract provided.

Evaluation Of Wind Data Reliability By Using Logarithmic And Power Laws: A Case Study In Southern Iraq, Ahmed B. Khamees, Saif F. Yaseen, Khalid S. Heni, Mudar Ahmed Abdulsattar

Karbala International Journal of Modern Science

In this study, two sites were investigated in the southern region of Iraq: Ali AL-Gharbi and AL-Salman in Mesan and AL-Muthana provinces, respectively. A theoretical extrapolation between wind speed and height was carried out for both locations each month using the Logarithmic Law. Power Law was also applied to achieve calculations of wind shear coefficient (α) by using the actual data collected from the meteorological mast installed in each site at three levels of 10 m, 30 m, and 50 m, at an interval of ten minutes. To compare the effects of each law, two laws are employed.

Polystyrene Molecular Weight Determination Of Submicron Particles Shell, Airat Z. Sakhabutdinov, Safaa.M.R.H. Hussein, Alsu R. Ibragimova Ph.D., Vladimir Kuklin Ph.D., Maxim Petrovich Danilaev, L.Y. Zaharova

Karbala International Journal of Modern Science

The method of determination of the molecular weight of the polystyrene, which is formed as the shell on the surfaces of submicron aluminum oxide particles is considered in the paper. This method is based on the sedimentation of submicron particles, covered by polymer molecules, in a solvent for polystyrene. It is shown that the average polystyrene molecular weight is 39500±11250 amu, when the polymer shells on the surfaces of submicron particles (Al2O3) are formed by the vapor-phase method.

Adaptive Reconstruction Of The Heterogeneous Scan Line Etm+ Correction Technique, Heba Kh. Abbas, Salema S. Salman, Rash Awad Abtan, Anwar H. Al-Saleh, Ali A. Al-Zuky

Karbala International Journal of Modern Science

ETM+ is a land-imaging sensor with great and wide use in many fields, however, after May 2003, because of a technical defect in the sensor´s system scan line corrector SLC, it started giving images of earth containing black gap lines at a 22% rate. These gaps made the process of analyzing and extracting accurate information from these images difficult and complicated. Therefore, scientists have developed many techniques to remove the gap lines from all ETM+ band-images and complete the missing data. In this study, three different ETM+ time images with a 16-day interval between them were used to fill gap …

Two-Dimensional Quantitative Profiling Of Cell Morphology With Serous Effusion By Unsupervised Machine Learning Analysis, Safaa Al-Qaysi Ph.D., Ding Dai Md Ph.D., Heng Hong Md Ph.D., Yuhua Wen Ph.D., X.H. Hu Ph.D.

Karbala International Journal of Modern Science

Cytological evaluation of serous effusion specimens is an important part of cancer diagnosis. In this study we performed two-dimensional (2D) morphometric features and clustering analysis for development of useful techniques for identification and differentiation of malignant and begin cells in serous effusion specimens extracted from ten patients with clinical symptoms of pleural and peritoneal effusion. Our findings show that the two-dimensional (2D) morphometric features and clustering analysis are useful techniques for identification and differentiation of malignant and begin cells in serous effusion specimens, which can lead to development of new methods for rapid cells profiling in clinical application.

Modeling Vitexin And Isovitexin Flavones As Corrosion Inhibitors For Aluminium Metal, Abdullahi Muhammad Ayuba, Umaru Umar

Karbala International Journal of Modern Science

Theoretically, the aluminium corrosion inhibitive performance of vitexin (VTX) and isovitexin (SVT) were evaluated with a view of establishing the mechanism of the inhibition process. Calculations which include the consideration of several global descriptors were studied to describe and correlate the reactivity of the molecules with the computed descriptors. First and second-order condensed Fukui functions were employed to analyze local reactivity parameters, while simulations involving the adsorbed molecules on Al (1 1 0) surface were conducted through quench dynamic simulations and the mechanism of physical adsorption was established with SVT relatively been a better inhibitor on Al surface than VTX.

Editorial Board

Karbala International Journal of Modern Science

No abstract provided.

Mathematical Model For Measuring The Concentration Of Nanoparticles In A Liquid During Sedimentation, Safaa Mohammed Ridha Hussien Hussien, Airat Sakhabutdinov, Vladimir Anfinogentov, Maxim Danilaev, Vladimir Kuklin, Oleg Morozov

Karbala International Journal of Modern Science

Expanding the application areas of polymer composite materials with dispersed filler requires the development of technologies providing the required mechanical characteristics. One of these methods is based on forming a thin polymer shell on the surfaces of particles. At the same time, it is impossible to take into account the mechanical characteristics of a thin polymer shell due to its ultra-small thickness. The mechanical properties of the polymer shell can be determined only by indirect methods, and prior information can improve the adequacy of the properties determination. The method, which allows reducing the requirements for composite sample preparation, is proposed. …

Role Of Lepidium Sativum In Treating Diabetes And Managing Bodily Functions’ Disorders In Rats., Gehan El-Emary

Karbala International Journal of Modern Science

: Lepidium sativum seed (LS) is a plant used globally for its medicinal effect in treating diabetes. This study examined the ability of an aqueous extract of LS to treat diabetes and manage disorders of bodily functions. It used 70 male Wistar rats, each weighing between 190 g and 200 g. Diabetes was established in the rats by injecting them with Alloxan Solution at 150 mg/kg of body weight. The rats were considered diabetic if, after 24 hours, their blood glucose levels were higher than 180 mg/dl. Diabetes caused severe alterations in their blood serum glucose (376.608 mg/dl); …

Editorial Board

Karbala International Journal of Modern Science

No abstract provided.

Novel Phenolic Deep Eutectic Solvents For Desulfurisation Of Petrodiesel, Idrees Bakr Qader, Jalil H. Kareem, Hani K. Ismail, Hawbash K. Mahmood

Karbala International Journal of Modern Science

In this work, a novel production of “deep eutectic solvents (DESs)” has been utilised for the elimination of sulfur composition, particularly from crude oil by liquid-liquid extraction. Herein, we present the first demonstration of the use of novel DESs formed by phenol, catechol, resorcinol and o-cresol as “hydrogen bond donors (HBDs)” with trimethyl hydroxyammonium chloride (ChCl) as the hydrogen bond acceptor to affect the efficient separation of organosulfur compounds from diesel. These DES electrolytes have been applied for the sulfur extraction from Iraqi real diesel fuel as determined using X-ray florescence sulfur measurements. The optimisation condition factors in this research …

Anticancer And Antiangiogenic Activities Of Alkaloids Isolated From Lantana Camara By Adsorption On The Magnetic Nanoparticles, Hussein Kadhem Al-Hakeim, Rahman Sahib Al-Zabibah, Huda Falah Alzihari, Ali Khudhair Almensoori, Hazim A. Al-Zubaidi, Loiy Elsir Ahmed Hassan Hassan

Karbala International Journal of Modern Science

Lantana camara L. (L. camara) is a perennial shrub that contains low amounts of alkaloids. In the present study, the magnetic nanoparticles (MNPs) were used to isolate positively charged alkaloids from the methanolic extract of L. camara leaves. The crude alkaloid was fractionated using HPLC to separate the highest peak of the alkaloid fraction (HPAF). The crude alkaloids (CA) and HPAF were tested for their antiproliferative effect against cancer cell lines (MCF-7, HCT-116, and HeLa) and endothelial cells line (EA.hy926) as a standard cell line. Antiangiogenic properties were examined using rat aortic ring assay. …

Mach-Zehnder Quantum Interference Rules In Hydrocarbons With Substituents, Alaa Al-Jobory, Zainelabideen Y. Mijbil

Karbala International Journal of Modern Science

We have investigated the conditions of quantum interferences in hydrocarbons with substituents using density functional theory and tight binding approximation combined with non-equilibrium Green’s function technique. The chosen model systems, namely benzene and tripyridyl–triazine molecules, have elucidated three prominent rules. The ‘first rule’ is the occurrence of inevitable, destructive quantum interference when 1,3-benzene ring incorporates single substituent at the fifth site. The ‘second rule’ is the chaotic occurrence of quantum interferences due the position and/or type of the substituents. The ‘third rule’: the substituents decrease (increase) the probability of destructive (constructive) interferences

Physical-Chemical Characterization And Heavy Metals Assessment Of Waters And Sediments Of Sebou Watershed (Top Sebou, Morocco), Mohamed Kabriti, Eda Mahougnon Léonce, Chaimaa Merbouh, Bensaber Abdelfattah, Abdelmajid Achkir, Abdlhakim Aouragh, Iounes Nadia

Karbala International Journal of Modern Science

The main purpose of this study was to investigate the impact of human activities, geochemical background and seasons on pollutant pathway. Surface water, groundwater and sediments were assessed to highlight and confirm those impacts. Sixteen physico-chemical parameters were measured (T°, pH, O2, salinity, conductivity, BOD5, COD, SM, Cl-, NO2-, NO3-, NH4+, TAC, TH, SO₄²- and PO43-) and twelve metallic trace elements were analyzed (Ar, Cr, Zn, Mn, Ni, Fe, Al, Cd, Cu, Pb, K and Na). Five sampling campaigns were carried out in 18 sampling points for over one year, between July 2018 and July 2019 in the upstream part …

Nanocellulose Sheets From Oil Palm Empty Fruit Bunches Treated With Naoh Solution, Farah Fahma, Faiza Ayu Lestari, Ika Amalia Kartika, Nurmalisa Lisdayana, Evi Savitri Iriani

Karbala International Journal of Modern Science

The objective of this study is to produce nanocellulose sheets from oil palm empty fruit bunches (OPEFBs). Nanocellulose sheets from OPEFBs were prepared through the dewatering process using vacuum filtration. Subsequently, the produced sheets were treated with NaOH solution to improve the mechanical stability of their structure, causing them to be firm in water. The water absorption of nanocellulose sheet increased with increasing NaOH concentrations up to 20 wt%, increasing tensile strength, and Young’s modulus, but decreased when they were treated with 30 wt%. The diameter shrinkage of nanocellulose sheets was directly proportional to the NaOH concentration and soaking time. …

Molecular Structure Vibrational & Electronic Properties Of Some Isatin Derivatives, Fatma K. Fkandermili Prof, Fatma M. Aldibashi S, Hakan S. Sayiner Prof

Karbala International Journal of Modern Science

Abstract

In this study, Natural Bonding Orbitals (NBOs) were applied to isatin, 5‑fluoroisatin, 5‑chloroisatin, 5‑methylisatin and 5‑methoxyisatin using the Lee-Yang-Parr correlation functional B3LYP with 6‑311++G(2d,2p) basis set. Natural bonding analysis was performed to consider the transfer interactions of intra-molecular charge, pre-hybridization and electron density within the isatin, 5‑fluoroisatin, 5‑chloroisatin, 5‑methylisatin and 5‑methoxyisatin. In natural bonding orbital analysis, the wave functions of the electrons were explicated in sets of occupied Lewis type terms, (bonds or lone pairs) and sets of unoccupied non‑Lewis (anti‑bond and Rydberg) localized natural bonding orbitals. The electron density between these orbitals was correlated to stabilize the interaction …

Editorial Board

Karbala International Journal of Modern Science

No abstract provided.

Editorial Board

Karbala International Journal of Modern Science

No abstract provided.

A Fuzzy Assessment Model For Hospitals Services Quality Based On Patient Experience, Mohamed Khodyer Alkafaji, Eman Salih Al-Shamery

Karbala International Journal of Modern Science

The patient's experience is a lens for services assessment that provide from healthcare institutions because the patient is the first and the last recipient for the service. The patient's experience carries a lot of uncertainty and an ultimate decision cannot be taken from the patient about the services, but it carries the partial truth. Many artificial intelligence technologies deal with the concept of partial truth, such as genetic algorithms and neural networks, but the fuzzy logic remains pioneering to deal with uncertainty. This paper aims to develop an assessment model by using fuzzy inference that is able to assess the …

A Laser Induced Fluorescence Design For Renewable Energy Application, Shaimaa S. Mahdi, Intisar A. Hamad

Karbala International Journal of Modern Science

Biomass is considered to be one of the highest potential renewable energy sources to meet the requirements of energy in the world, where it can be used as an effective alternative for renewable energy sources, including electricity and heating, as well as fuel used in transport. One of the most common problems accompanying the usage of biomass through gasification processes to produce gases is the amounts of undesirable formed Tars. In this paper, a Laser Induced Fluorescence spectroscopy (LIF) method was incorporated to identify the produced Tar compounds at high temperature in the gasification technology. The effect of tars deposition …

Treatment Of A Worn Mineral Oil Effluent By Electrocoagulation Using Aluminium Electrodes, Serge Raoul Tchamango Dr, God Promess Lactio, Inès Estelle Nkenmogne Kamdem, Martin Benoît Ngassoum

Karbala International Journal of Modern Science

Water pollution by oils is more and more a preoccupation because of its increasing occurrence and the hazard to human life and environment. Depollution of oily effluents can sometimes generate a secondary pollution (with chemical coagulation / flocculation processes) or be very costly (ultracentrifugation). In this work, electrocoagulation with aluminium electrodes was applied to the treatment of a worn mineral oil effluent. For this to be achieved, the influence of the pH and the current density on the turbidity and organic matter was first investigated. A liquid-liquid extraction was then carried out on the oil samples in order to isolate …

A Systematic Mapping Study On The Risk Factors Leading To Type Ii Diabetes Mellitus, Karar N. J Musafer, Fahrul Zaman Huyop, Mufeed J Ewadh, Eko Supriyanto, Mohammad Rava

Karbala International Journal of Modern Science

Diabetes is one of the most common diseases that has had devastating effects on the general population. It is also among the most popular research trends in modern medicine. Thus, due to the complexity and desirability of this particular affliction, there is a lot of demand towards understanding this disease better, so that it can pave the way towards better solutions in combating diabetes. The aim of this review is to provide a categorization of the risk factors leading to Type II Diabetes. In order to provide a justification for the type of diabetes, an explanation is provided which covers …

Chemical Composition And Antibacterial Activity Of The Essential Oil Of Myrtus Communis Leaves, Hajar El Hartiti, Amine El Mostaphi, Mariam Barrahi, Aouatif Ben Ali, Nabila Chahboun, Rajaa Amiyare, Abdelkader Zarrouk, Brahim Bourkhiss, Mohammed Ouhssine

Karbala International Journal of Modern Science

The aim of this work is to determine the yield of the essential oil of the Myrtus communis leaves, to identify its chemical composition and to evaluate its antibacterial properties. The plant is harvested from Sidi Ahmed Chrif, a region in Ouazzane, Morocco. The extraction of the essential oil was carried out by hydrodistillation in a Clevenger apparatus type. The average yield was 0.7%. The analysis of this oil by Gas Chromatography coupled with Mass Spectrum (GC/MS) allows the identification of 32 compounds. Eucalyptol was the main compound with 42.43%, followed by myrtenyl acetate (21.25%) and α-pinene (19.39%). Myrtle essential …

Hormones Of Maize Crop As Affected By Potassium Fertilization , Water Quality And Ascobin Foliar Application ., Qais Hussain Al-Samak Prof., Fatima Karim Khudair Alasadi

Karbala International Journal of Modern Science

A pot assay on the plastic container of the wire sunshade in the University of Kerbala's Agricultural Division was conducted to research the impact of potassium treatment, the salinity of irrigation water and ascobin sprinkling, just as their connections, on the some plant hormones activities (auxin, gibberellin and abscisic acid) in developing Zea mays crops in a soil with sandy texture during the farming fall period of 2017–2018. The trial was planned as a factorial one with three factors, Potassium adding are 0, 100 and 200 Kg K.ha^–1 . the irrigation water salinity are 1, 3 and 6 ds.m …

Editorial Board

Karbala International Journal of Modern Science

No abstract provided.

Synthesis, Characterisation And Biological Evaluation Of Tyramine Derived Schiff Base Ligand And Its Transition Metal(Ii) Complexes, Abdul Khader Jailani, N.S.K. Gowthaman, Mookkandi Palsamy Kesavan

Karbala International Journal of Modern Science

In this study, a new tyramine derived Schiff base ligand (L) (L=1,3-phenylene-bis-4-aminoantipyrinyl-4-aminoethylphenol) and its derived transition metal(II) complexes [Cu(L)Cl₂](1), [Ni(L)Cl₂](2), [Co(L)Cl₂] (3) and [Zn(L)Cl₂] (4) have been synthesized and well characterized by the way of different spectroscopic and analytical techniques. Analytical and spectroscopic studies result suggests that metal(II) complexes more probably have octahedral geometry. DNA binding tendency of L and metal(II) complexes 1-4 have been assessed by probing their ability to bind with Calf Thymus DNA (CT-DNA) via electronic absorption and cyclic voltammetry titration methods. The results clearly reveal that the metal(II) …

Evaluation Of Structure And Properties Of Various Sol–Gel Nanocoatings On Biomedical Titanium Surface, Mohsin Talib Mohammed, Sarah Mohammed Hussein

Karbala International Journal of Modern Science

This study deals with the preparation and characterization of different bioceramic nanofilms formed on the surface of new metastable β-titanium (Ti) alloy. The films of pure TiO₂, pure HA, TiO₂/HA bilayer and HA/TiO₂ composite were coated successfully on Ti surface by sol-gel using spray pyrolysis deposition technique. The surface characteristics of coated substrates, such as thickness, topography, morphology, phase transformations and wear behavior, were evaluated and compared to uncoated substrate. The results showed that the sol-gel is a promising technique to create biocoatings on Ti surface with outstanding structure and properties for biomedical applications.

Transition State Theory Application To H2 Gas Sensitivity Of Pristine And Pd Doped Sno2 Clusters, Mudar Ahmed Abdulsattar

Karbala International Journal of Modern Science

The reaction of H₂ and O₂ gases with pristine and Pd doped Sn₁₀O₁₆ clusters is investigated using transition state theory and density functional theory. The reaction of hydrogen and oxygen molecules is controlled by a transition state that implies crossing an activation energy hill to react with the SnO₂ cluster. Our investigation performs thermodynamic calculations, including Gibbs free energy, enthalpy, and entropy of activation and reaction in the temperature range 25-500 °C. The results show that the Gibbs free energy of activation of H₂ gas reaction is 0.23 and 0.18 eV for pristine …

On The Dynamic Behaviour Of Automobile Pulleys Under Cyclic Loading, Haval Kamal Asker, Thaker Saleh Dawood

Karbala International Journal of Modern Science

This paper investigates the dynamic characteristics of pulley systems with different numbers of bolt holes. Models with four, six and eight bolt holes were chosen for the pulley. Three sets of cyclic pressure were applied to the pulley system to resemble the different running revolutions of an engine. The study investigates the effect of the number of holes on the system’s stiffness and natural frequency. Finite element models were used to simulate the obtained deformations, stresses and frequency response function (FRF) for pulley models comprising four, six and eight bolt holes under different cyclic pressures. The results show that the …