Chemistry Commons^™

The Catalytic Vapor-Phase Hydrolysis Of Benzene And Toluene, Clemens Raebel Maise

Masters Theses

"The vapor-phase synthesis of organic compounds represents a new field of study which has attracted the attention of investigators only within recent years. However, wide interest is apparent in this field and several processes of commercial importance have already been developed. Hydrolysis is perhaps the newest of all the types of vapor-phase synthesis; the literature consists of little more than a few patents...The vapor-phase hydrolysis of benzene and toluene, therefore, presented an interesting possibility. These two hydrocarbons are considered very stable toward water in the liquid-phase. The purpose of this investigation was to determine to what extent their stability toward …

A Study Of Methods For The Recovery Of Silver, Bromine, Iodine, And Sodium Thiosulfate From Used Photographic Fixing Baths, Leroy Agustave Bay

Masters Theses

"Sodium thiosulfate was one of the pioneer reagents used in photography, and is still the most important reagent used in photographic fixing. The solubility of the silver halides in an excess of sodium thiosulfate makes it important as a reagent for removing the undeveloped silver halides from the film. The life of a fixing bath is controlled by the halogen content. As the ratio of halogens to sodium thiosulfate is increased, the time required for fixing is also increased until the ratio reaches such a point that fogging of the film results. Most of the solutions are discarded long before …

Pyrochemical Changes In Missouri Halloysite, Frank Joseph Zvanut

Doctoral Dissertations

"For centuries it has been known that the application of heat to a clay or a clay body produces changes that make it an entirely different substance from the original raw clay. Ever since the earliest civilizations produced crude building brick by baking formed clay bodies in the sun's rays, mankind has been speculating on the nature of the changes that convert soft, friable, plastic clays into hard, strong, non-plastic, rock-like masses. It has been only within the last two decades, however, that progress has been made in the solution of problems dealing with the resultant products in fired clay …

The Preparation And Specific Gravity Of Pure Formic Acid And Its Aqueous Solutions, Leo Henry Merchie

Masters Theses

"Formic acid, the lowest member of the fatty acid series, was obtained as early as the seventeenth century by distilling ants with water. Other methods were later found after the correct constitution of the acid became known. This acid is not difficult to prepare in a water solution, but it is difficult to obtain in the anhydrous state...The purpose of this work is to study the various methods of preparing anhydrous formic acid, to improve a method for preparing the anhydrous acid, and to correct specific gravity tables for aqueous solutions of formic acid"--Introduction, page 1-2.

Steric Hindrance In The Ketonic Splitting Of Substituted Acetoacetic Ester, Claude Stanley Abshier

Masters Theses

"The phenomenon of steric hindrance has been observed and investigated in a variety of reactions, most of which have been with aromatic compounds. In this branch of study the speeds of reaction of ethyl acetoacetate, α-mono-methyl-ethyl-acetoacetate, α-mono-ethyl-ethyl-acetoacetate, α-mono-propyl-ethyl-acetoacetate in the presence of 0.05 and 0.10 normal hydrochloric acids have been investigated at temperatures between 60⁰C. and 90⁰C. An attempt has been made to explain the results obtained"--Introduction, page 1.

A Study Of Methods For Separating The Elements That Interfere In The Electrolytic Deposition Of Lead As Lead Oxide, John Shaw Sabine

Masters Theses

"The electrolytic determination of lead as lead dioxide is a very desirable method, due to its simplicity, accuracy, and the small amount of the analyst's time required. The electrolytic method functions when both large and small amounts of lead are present. The method depends upon the fact that from a nitric acid solution the lead is plated upon the anode as lead dioxide; from the lead dioxide deposit the percentage of lead may be calculated.

An electrolytic method, for determining the lead in samples containing from 5 to 150 mg. of lead, was described in a paper by Schrenk and …

Factors Affecting The Electrolytic Deposition Of Small Amounts Of Lead As Lead Dioxide And The Composition Of The Deposit, Thomas Gordon Day

Masters Theses

"The purpose of this investigation is to determine the best conditions for the quantitative deposition of lead when the content of this element is below 5 milligrams and to study the composition of the deposited PbO₂. The following conditions were studied during the course of the investigation. 1. The maximum amounts of copper and zinc permissible for the quantitative determination of lead. 2. Methods of separating lead from zinc when the latter element is present in amounts greater than are permitted in the determination of the lead. 3. The separation of lead from copper when this element is in greater …

The Preparation Of Certain Inorganic And Organic Compounds Which May Be Of Use In Mineralogical Separations, Clarence Jay Black

Masters Theses

"In the work with minerals, there has been many mechanical means devised whereby the ores could be separated from the gangue and other material. Among those means which are used to-day, especially in the laboratory tests upon minerals, to quickly determine the value of an ore, heavy liquids have become quite popular. This means of mechanical separation is merely to place finely ground ore containing particles of varying density into a liquid of heavier density than the greater portion of the mineral, which will allow the heavier portions to sink and the lighter to float, which is usually gangue. This …

The Solubility Of Solid Paraffin In The Lower Molecular Weight Hydrocarbons, Paul Weber

Masters Theses

"In the process of oil refining, a certain fraction of distillate from the crude oil composes the so-called wax distillate fraction from which is obtained the various lubricating oils. But the presence of the waxes and solid paraffins in these oils is very undesirable as they possess no lubricating qualities. Consequently, they must be removed from this wax distillate before the oil can be marketed"--Introduction, page 1.

The Disintegration Of Refractory Brick By Carbon Monoxide, Wilbur J. Darby

Masters Theses

"In experimental work carried on at East St. Louis, Illinois in 1916 and 1917, with a furnace of commercial size for the electrothermic dry distillation of zinc ores, a difficulty that developed was the destruction of the firebrick lining in certain parts of the large condenser. The condenser was satisfactory in other ways, yielding a large proportion of the zinc as liquid metal, with no blue powder; but in order to obtain a proper length of service from the condenser it became necessary to find and overcome the cause of the disintegration of the lining ... it will be evident …

Glucose From Corn Cobs, Barney Nudelman

Masters Theses

"The efforts of American chemists in recent years have been devoted largely to the utilization of our waste products...Corn cobs offer a particularly inviting field for research along this line on account of the large supply of cobs available and the variety of substances obtainable from them. One of the leaders in this branch of investigation is Dr. F. B. LaForge of the Chemistry Division of the Bureau of Agriculture, who has contributed numerous papers on the subject. In one of these, in collaboration with C. S. Hudson, he describes, among other things, the preparation of glucose, but recognizes the …

Methyl Amines From Carbinol And Ammonium Chloride, Arthur Mark Howald

Masters Theses

"During the spring of 1919 we undertook to prepare tri-methyl-amine for the Research Department of the Eastman Kodak Company in the Industrial Chemistry Laboratory of the Missouri School of Minds. According to V. Merz and K. Gasiorowski the three methyl amines were qualitatively proven to be present in the reaction products obtained by heating methyl alcohol, ammonia and zinc chloride to 220°C. in a bomb for fourteen hours. As these raw materials are inexpensive we attempted to prepare the tri-methyl-amine by this reaction employing for the purpose a small industrial autoclave. Methyl amines were obtained by the yield especially of …

Design Of A Lead Blast Furnace, Walter Irving Phillips, Andrew Jackson Seltzer

Bachelors Theses

"In order to get the approximate size of the Furnace we made the following assumptions, being guided as far as possible by the practice of the Globe Smelting Works at Denver, Colorado whenever that could be ascertained"--page 1.

Analyses Of Limestones And Shales, Byron John Snyder

Bachelors Theses

"The limestones were analyzed to determine their value for cement and lime manufacture, and were taken from several counties in the state of Missouri. Most of the limestones examined were very pure. A considerable quantity of well burned lime is added to other material in the manufacture of cement, a lime of very pure type being the most acceptable in this work"--page 1.

Analytical Determination Of Copper Products, Charles Dosh Smith

Bachelors Theses

"It is a well known fact that the presence of impurities in copper products has been a source of annoyance to the Chemist. The object of this thesis was to make myself familiar with the actions of different impurities in copper products, and the methods for the determination of Arsenic in the same"--page 1.

Neutralization Of Free Acid (H₃P O₄) In Commercial Mono-Calcium Phosphate (Ca H₄ (Po₄), George William Harris, Harry Adam Grine

Bachelors Theses

"The object of this thesis has been a systematic research based on the characteristic properties and reactions of mono-calcium phosphate, Ca H₄ (PO₄)₂, tending towards the development of a process for neutralizing the free phosphoric acid, H₃PO₄ formed during its manufacture"--page 1.

The Determination Of Aluminium, Victor Hugo Gottschalk

Masters Theses

No abstract provided.

Assay Of Copper Matte For Gold And Silver, Walter E. Soest

Bachelors Theses

"Ores containing copper, and especially copper matte, have always been very annoying in assaying for the precious metals. In assaying copper matte, and ores containing much copper, by the usual method of scorification, the losses of silver an gold are considerable, owing to the fact that in order to obtain lead buttons, which are soft and free from copper, repeated scorifications are necessary, and moreover it is impossible to obtain lead buttons which are entirely free from copper"--page 1.

Action Of Caustic Hydroxides Upon Aluminum, Herbert Fordyce. Rogers

Bachelors Theses

No abstract provided.

Studies In Tellurium, Victor Hugo Gottschalk

Bachelors Theses

No abstract provided.

White Lead, Evans Walker Buskett

Bachelors Theses

No abstract provided.

Producer Gas, Edward P. Dwyer

Bachelors Theses

"Producer gas, so named owing to being produced in special forms of apparatus known as Producers. The fuel is decomposed into combustible gases, whereby most of the C is burnt to CO, whilst the H either remains free, or is converted into carburretted Hydrogen. Directly above the grate carbonic anhydride is formed but thus is rapidly converted into carbonic oxide; reaction as follows: CO₂ + C = 2CO.

Amongst these heavy carburetted hydrogen (C₂H₄) is that which principally increases the value of the gas as fuel and the drier the fuel used the more of the gas is produced. A …