Chemistry Commons^™

Plasma Polymerization Of Tetrafluoroethylene. Iii. Capacitive Audio Frequency (10 Khz) And Ac Discharge, N. (Nicholas) C. Morosoff, H. Yasuda, E. S. Brandt, C. N. Reilley

Chemical and Biochemical Engineering Faculty Research & Creative Works

The plasma polymerization of tetrafluoroethylene (TFE) is studied in a capacitively coupled system with internal electrodes using a 10 kHz (af) and a 60 Hz (ac) source. The emphasis is on identifying conditions that are compatible with continuous coating of plasma polymer on a substrate moving through the center of the interelectrode gap. Operation at a pressure below 100 mTorr is most favorable for deposition of a substantial portion of the plasma polymer on this substrate. Plasma polymer deposited in this way is characterized by ESCA and by deposition rate data and compared to that deposited using rf power in …

Nucleation Experiments With Monodisperse Nacl Aerosols., Darryl J. Alofs, M. B. Trueblood, D. R. White, V. L. Behr

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Nucleation Experiments with Monodisperse NaCl Aerosols Showed Good Agreement with the Kohler Theory Relating the Critical Super-Saturation S//c to the Dry Size. Aerosols Produced by Condensing NaCl Showed the Same S//c as Those Produced by Evaporating Aqueous NaCl Solution Droplets. This Indicates that If There is an Energy Barrier in Going from a Dry NaCl Particle to a Solution Droplet, This Energy Barrier is Small. the Fact that the Evaporation Aerosol Particles Are Cubical Crystals and the Condensation Aerosols Are Amorphous Spheres is Shown to Make No Difference in the Nucleation Threshold. the Investigation Also Gives Insights into the Performance …

A Simple Experiment Illustrating The Structure Of Association Colloids, Stig Friberg, Beverly Bendiksen

Chemistry Faculty Research & Creative Works

No abstract provided.

Cndo Calculations On The Structure Of A Liquid Sodium Carboxylate-Carboxylic Acid Compound, Beverly Bendiksen, Stig Friberg, Patricia L.M. Plummer

Chemistry Faculty Research & Creative Works

The molecular interactions in a carboxylic acid/sodium carboxylate compound which is a liquid at room temperature were calculated using a CNDO/2 approach. The calculations gave results distinguishing the energy for different conformations in the molecular compound. The maximum binding energy was found for a structure in which the four acids were bridging with a hydrogen bond from the acid OH group to the carboxylate group and the acid carbonyl groups forming a ligand bond to the carboxylate sodium ion. © 1979 Academic Press, Inc.

Plasma Polymerization Of Tetrafluoroethylene. Ii. Capacitive Radio Frequency Discharge, N. (Nicholas) C. Morosoff, H. Yasuda, E. S. Brandt, C. N. Reilley

Chemical and Biochemical Engineering Faculty Research & Creative Works

The plasma polymerization of tetrafluoroethylene (TFE) is studied in a capacitively coupled system with internal electrodes using radio frequency (13.56 MHz) power. The emphasis is on identifying conditions that are compatible with continuous coating of plasma polymer on a substrate moving through the center of the interelectrode gap. At high pressure (500 mTorr), deposition of plasma polymer is primarily on the electrodes rather than on a substrate placed midway between electrodes. Glow is observed in only part of the interelectrode gap at low powers and fills the gap only at high power levels. The use of a magnetic field effects …

Plasma Polymerization Of Tetrafluoroethylene. I. Inductive Radio Frequency Discharge, H. Yasuda, N. Morosoff, E. S. Brandt, C. N. Reilley

Chemistry Faculty Research & Creative Works

The plasma polymerization of tetrafluoroethylene in an inductively coupled radio frequency glow discharge, using a flow system, was studied. A simple long tube reactor, with the coupling coil placed at the middle of the tube and gas entrance and exit at the respective ends, was used. Deposition rates and the chemical nature of the polymer (as revealed by ESCA spectra and surface energy studies) are obtained as a function of location in the reactor tube with respect to the coupling coil and of applied energy per unit mass of tetrafluoroethylene (W/FM). It was found that a fluorine poor polymer, containing …

I. Extracellular Metabolites From Coprinus Macrorhizus Microsporus. Isolation And Characterization Of Hydroxylagopodin B. Ii. The Cell Wall Composition And Structure Of Coprinus Macrorhizus Microsporus, Carey Bernard Bottom

Doctoral Dissertations

“A purple pigment excreted into the culture medium of a mutant strain of the basidiomycete, Coprinus macrorhizus var. microsporus (ATCC 34960) has been isolated and characterized as hydroxylagopodin B based on ultraviolet, infrared, and mass spectral data. A wild-type strain of C. macrorhizus microsporus does not produce the purple pigment, however it does produce lagopodin B which is yellow in solution. Identification of lagopodin B was based on its melting point, the purple color of its alkaline solution, the mass spectrum, and mobility equivalence with a standard by thin-layer chromatography. The production of hydroxylagopodin B in the mutant strain is …

Thermodynamics Of The Lanthanide Trifluorides. I. The Heat Capacity Of Lanthanum Trifluoride, Laf₃ From 5 To 350°K And Enthalpies From 298 To 1477°K, William G. Lyon, Darrell W. Osborne, Howard E. Flotow, Fernande Grandjean, Ward N. Hubbard, Gerald K. Johnson

Chemistry Faculty Research & Creative Works

The heat capacity of a sample of LaF₃ was determined in the temperature range 5-350°K by aneroid adiabatic calorimetry and the enthalpy from 298.15 to 1477°K by drop calorimetry. The heat capacity at constant pressure C°_p(298.15°K), the entropy S°(298.15°K), the enthalpy [H°(298.15°K)-H°(0)] and the Planck function -[G°(298.15°K)-H°(0)]/298.15°K; were found to be (90.29±0.09) J °K^-1·mole^-1, (106.98±0.11) J °K^-1·mole^-1, (16717±17) J mole^-1, and (50.91±0.05) J °K ^-1·mole^-1. The thermal functions from the present research were extended up to the melting temperature (1766°K) by combination with previously …

Magnetic Properties Of Linear Chain Systems: Metamagnetism Of Single Crystal Co(Pyridine)₂Ci₂, Simon N. Foner, Richard B. Frankel, William Michael Reiff, Herbert Wong, Gary J. Long

Chemistry Faculty Research & Creative Works

The metamagnetic behavior of the low temperature properties of single crystal Co(pyridine)₂Cl₂ is discussed. At 1.25 K oriented single crystals exhibit a two-step metamagnetic transition at applied fields ~0.8 and 1.6 kG along the b-axis, a single transition at ~0.7 kG for applied fields along the a* axis, and a single transition at ~4.2 kG for an applied field along the c axis. Just above the transition fields a moment of 2µ_B/Co atom is measured for B₀ parallel to the a* axis or b axis, and 0.4µ_B/Co atom is measured for the …

Emulsification And The Hlb-Temperature, Stig Friberg, Concepcion Solans

Chemistry Faculty Research & Creative Works

No abstract provided.

The Synthesis And Characterization Of Several Copper (Ii) Complexes Of Quinuclidinone-Containing Ligands. Possible Models For Type I Copper Blue Proteins., Victor Thomas Wilcox

Masters Theses

Several copper (II) complexes with bidentate quinuclidinone containing ligands have been synthesized and characterized. These complexes appear to be possible models for the type I copper (II) in the copper "blue" proteins. The spectral and magnetic properties indicate that the complexes have a pseudo tetrahedral microsymrnetry about the central metal ion. The complexes contain chromophores of the following forms: CuN₄, CuN₂O₂, and CuN₂x₂, where X is either Cl or Br. While the spectra of these complexes lack the intense 17,000 cm^-1 band typical of copper "blue" proteins, the optical …

Developmental Dyslexia: Evidence For A Subgroup With A Reversal Of Cerebral Asymmetry, Daniel B. Hier, Marjorie Lemay, Peter B. Rosenberger, Vincent P. Perlo

Chemistry Faculty Research & Creative Works

The Computerized Brain Tomograms of 24 Patients with Developmental Dyslexia Were Analyzed for Cerebral Asymmetry. Ten Patients Showed a Reversal of the Pattern of Asymmetry Regularly Observed in Normal Right-Handed Individuals So that the Right Parietooccipital Region Was Wider Than the Left. the Ten Dyslexic Patients with This Reversal of Cerebral Asymmetry Had a Lower Mean Verbal IQ Than the Other 14 Dyslexic Patients in This Study. the Reversal of Cerebral Asymmetry that Occurred in Ten of the Dyslexic Patients May Result in Language Lateralization to a Cerebral Hemisphere that is Structurally Less Suited to Support Language Function and Thus …

Mechanism Of The Ninhydrin Reaction, Carey B. Bottom, Samir B. Hanna, Donald J. Siehr

Chemistry Faculty Research & Creative Works

No abstract provided.

4th Annual Umr-Dnr Conference On Energy -- Entire Proceedings, University Of Missouri--Rolla

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

No abstract provided.

High Spin-Low Spin Crossover And Antiferromagnetic Interactions In Tris(1-Pyrrolidinecarbodithioato)Iron(Iii) And The 4-Morpholine (Fem) And Dibutyl Analogs, Effect Of Recrystallization Solvent, And Crystal Structure Of Fem·Nitrobenzene, Edward J. Cukauskas, Bascom Sine Deaver, Ekkehard Sinn

Chemistry Faculty Research & Creative Works

High sensitivity magnetic susceptibility determinations, especially in the range 1.2-4.2 K on pure and dilute tris(pyrrolidinecarbodithioato)iron(III) (FeP) in its high spin form, show that a maximum at about 2 K is caused by antiferromagnetic interactions. The analogous chromium(III) complex does not exhibit significant antiferromagnetism compared to that of the iron complex, and it is likely that the upper e electrons possessed by the iron and not by the chromium are responsible for the bulk of the antiferromagnetism. As the iron atoms are about 9 Å apart in discrete molecules, the antiferromagnetic interactions presumably occur between unpaired spins delocalized on to …

Metal-Ion Oxidative Decarboxylations. 9. Reaction Of Benzilic Acid With Cerium(Iv) In Acidic Perchlorate And Sulfate Media, Samir B. Hanna, Sezai A. Sarac

Chemistry Faculty Research & Creative Works

The kinetics of oxidation of benzylic acid (HLH) to benzophenone by cerium (IV) has been studied in several media using the stopped-flow technique. In HClO₄-Na₂SO₄-NaClO₄ media, which allow for the variation and control of the concentrations of the various Ce(IV) species at constant [H⁺] and ionic strength, the rate data suggest CeSO₄²⁺ as the kinetically relevant species. In HClO₄ the observed first-order rate constants, tetrad, first increase with increasing HLH concentration, then decrease slightly at higher substrate concentrations suggesting the intermediacy of two complexes: a reactive [Ce(IV)HL] and …

Micellar Solutions Versus Microemulsions, Derek G. Rance, Stig Friberg

Chemistry Faculty Research & Creative Works

No abstract provided.

Metal-Ion Oxidative Decarboxylations. 10. Substituent Effects In The Cerium(Iv)-Benzilic Acids Reaction, Samir B. Hanna, Sezai A. Sarac

Chemistry Faculty Research & Creative Works

The rates of oxidation by cerium (IV) of several substituted benzylic acids (unsubstituted, 2,2′-dichloro, 4,4′-dichloro, 4,4′-dimethyl, 4,4′-dimethoxy, and 4,4′-dinitro) to the corresponding benzophenones have been studied spectrophotometrically in aqueous H₂SO₄, aqueous HClO₄-HOAc, and acetonitrile. The rates are much slower in H₂SO₄ than in the other two media, probably because of heavy sulfato complexation of cerium(IV). The px as of the various acids were determined potentiometrically. The Hammett p values in acetonitrile and HClO₄-HOAc media, derived from correlations with several sets of σ constants and with the newly determined pK …

Erratum: The Internal Chemical Shift - A Key To Bonding In Aromatic Molecules. 2. Substituent Effects On Carbon-13 Magnetic Resonance Spectra Of The 1,4-Disubstituted Benzenes (Journal Of Physical Chemistry (1976) 80, (2024)), D. (Donald) W. Beistel, W. Dan Edwards

Chemistry Faculty Research & Creative Works

No abstract provided.

Proton Shift Additivity And Substituent Interaction Parameters, Donald W. Beistel, Gary Chappell, W. Daniel Edwards

Chemistry Faculty Research & Creative Works

The 4-substituted acetophenone family is characterized and its shifts are correlated with those of nine families of 1, 4-disubstituted benzenes reported previously. Then a simple mathematical model is derived to account for the proton magnetic resonance shifts within families of 1, 4-disubstituted benzenes. The model suggests that the substituents interact by σ-bond polarization. The polarization model rationalizes shift additivity and is consistent with the qualitative relationship between the number of valence electrons on a substituent and its capacity to induce shifts. © 1977, American Chemical Society. All rights reserved.

Inelastic Cross Sections For Molecules Interacting Through Dipole And/Or Quadrupole Potentials, Louis Biolsi Jr.

Chemistry Faculty Research & Creative Works

Formal expressions for the lowest order inelastic contribution to the degeneracy averaged total cross section for both distinguishable and indistinguishable rigid diatomic molecules are obtained for molecules interacting through a multiple potential. Explicit expressions for the inleastic cross section are obtained for molecules interacting through permanent dipole-dipole, dipole-quadrupole, or quadrupole-quadrupole potentials. These results require the summation over only a single quantum number; the relative angular momentum quantum number. Thus, they are useful for analytic or numerical calculations.

Effect Of Angular Momentum On The Relaxation Time In A Multicomponent Gas Mixture, Louis Biolsi Jr.

Chemistry Faculty Research & Creative Works

The effects of molecular angular momentum (spin polarization) on the bulk viscosity and relaxation time in a multicomponent gas mixture are considered. Formal theoretical results are obtained, using the Wang Chang-Uhlenbeck approach to the kinetic theory of gases with internal states. The results are given in terms of integrals over the weighted quantum mechanical degeneracy averaged cross section.

The Internal Chemical Shift - A Key To Bonding In Aromatic Molecules. 2. Substituent Effects On The Carbon-13 Magnetic Resonance Spectra Of The 1,4-Disubstituted Benzenes, Donald W. Beistel, W. Dan Edwards

Chemistry Faculty Research & Creative Works

Carbon-13 magnetic resonance shifts were determined for six families of 1,4-disubstituted benzenes. Linear least-squares correlations between the internal shifts of the families suggest an additivity relationship for 13C substituent effects at all four nonidentical ring carbons and at the α position when one of the substituents has a central carbon. The correlation of 1H and 13C shifts for these compounds is also linear, implying that the additivity relationships derived in a previous 1H study can be generalized to 13C.

Part I. Thermodynamic Acidities Of Substituted Phenylacetylenes. Part Ii. Mercury Accumulation In Trout Of Southern Missouri, Eric T. Lloyd

Masters Theses

"PART I: THERMODYNAMIC ACIDITIES OF SUBSTITUTED PHENYLACETYLENES The thermodynamic acidities (pKa) of phenylacetylene and several para substituted phenylacetylenes in methanol were determined at 25ºC. These acidity constants were determined using a quenching technique which involves converting the phenylacetylenic anion, present at equilibrium as sodium phenylacetylide, to the tritium labelled carbon acid. By liquid scintillation counting techniques, the concentration of the anion was determined and the pKa of the phenylacetylene compound calculated. The resulting pKa's are: p-nitrophenylacetylene, 17.98, p-bromophenylacetylene, 18.10, p-fluorophenylacetylene, 18.14, phenylacetylene, 18.50, and p-methylphenylacetylene, 18.60. The effect of a substituent in the para position on the relative acidities is …

Planning A Kinetic And Mechanistic Study With Cerium (Iv), Samir B. Hanna, Robert R. Kessler, André Merbach, Steve Ruzicka

Chemistry Faculty Research & Creative Works

No abstract provided.

The P-Nitrobenzyl System. Iv. Base-Induced Transformations In P-Nitrobenzyl Chloride, Bromide, Iodide, Tosylate, And Sulfonium Salts, Samir B. Hanna, Paul H. Ruehle

Chemistry Faculty Research & Creative Works

No abstract provided.

Double Beta Decay Of ¹²⁸Te, Edward W. Hennecke, Oliver Manuel, Dwarka D. Sabu

Chemistry Faculty Research & Creative Works

The half-life of ¹²⁸Te relative to the half-life of ¹³⁰Te has been found to be t12128t12130=(1.59±0.05)×10³ by measurement of the ββ-decay products, ¹²⁸Xe and ¹³⁰Xe, in a geologically old (2.4×10⁹ yr) telluride ore. These results yield an upper limit on the lepton nonconservation parameter, η≤0.8×10^-4. RADIOACTIVITY ββ-decay ¹²⁸Te; measured T_1/2=1.5×1024 yr; deduced η≤0.8×10^-4. Detected excess ¹²⁸Xe in old Te ore.

A Piagetian Approach To General Chemistry, Donald W. Beistel

Chemistry Faculty Research & Creative Works

No abstract provided.

Locating The St. Louis Urban Plume At 80 And 120 Km And Some Of Its Characteristics, J. F. Stampfer, J. A. Anderson

Chemistry Faculty Research & Creative Works

The feasibility of locating the urban plume of a moderately large urban area, as far as 120 km downwind, is shown. The method utilizes a single engine aircraft and aerosol instrumentation. A summary of the data obtained from 34 flights, during an 8-month period, is presented and the problems involved in interpreting the data are discussed. These difficulties include nonuniform background levels outside the plume, changing relative humidity, low wind speeds and stable atmospheric layers. The plume was characterized by concentrations of small particles (0.15 < r < 0.3 μm) ca. 1.5 times that in background air and concentrations of large particles (0.3 < r < 1.3 μm) usually greater than twice that in the background. The ratio of the concentrations of small particles to large particles in the plume was about one-half of that in the background. © 1975.

The Noble Gas Record Of Terrestrial And Meteoritic Samples, Edward W. Hennecke

Doctoral Dissertations

"Analyses of tellurium and xenon in a telluride ore from Kalgoorlie, Australia resulted in the following conclusions:

1. The ratio of the double beta-decay half-life of ¹²⁸Te relative to that of ¹³⁰Te is 1.6 x 10³
2. The double beta-decay half-life of ¹³⁰Te is 1.0 x 10²¹ years.
3. The measured half-lives are consistent with values predicted for a second order process of ordinary beta-decay that occurs with the emission of two neutrinos.

A study of noble gases in Thailand tektites provided the following information on the history of these objects:

1. The isotopic compositions of nonradiogenic Ne, Ar, …