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Organic Chemistry

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Articles 2551 - 2560 of 2560

Full-Text Articles in Chemistry

The Development Of A Quantitative Scheme For The Separation Of Quaternary Mixtures Of Alkyl Halides And Alcohols, Edward Joseph Pfeifer May 1932

The Development Of A Quantitative Scheme For The Separation Of Quaternary Mixtures Of Alkyl Halides And Alcohols, Edward Joseph Pfeifer

Bachelors’ Theses

Organic chemistry offers a large field for quantitative investigation. The nature of many organic compounds makes for difficult analysis. The separation of simple mixtures is oftentimes a problem. The work undertaken in this thesis is of special interest because it combines several phases of chemistry, in the investigation of a problem, which by its very existence, suggests the need for solution.


A Study Of The Effect Of Temperature Upon Reactions Between Stannous And Arsenate Ions In Silicic Acid Gels, Ellis Elder Jan 1932

A Study Of The Effect Of Temperature Upon Reactions Between Stannous And Arsenate Ions In Silicic Acid Gels, Ellis Elder

University of the Pacific Theses and Dissertations

Chapter I: Statement of the Problem

The purpose of this investigation was to determine to what extent the reaction between stannous and arsenate ions in silicic acid gels is influenced by temperature.

This was to be done by observing (1) the rate of crystal growth; and (2) the appearance of the crystal growth in sets of gels identical in composition but kept at different temperatures throughout the process of crystal growth.


The Alkaloids, Felix F. Barre Jul 1931

The Alkaloids, Felix F. Barre

Electronic Theses and Dissertations

This thesis, presented for the degree of Bachelor of Science, provides a systematic chemical study of the alkaloids, a class of complex nitrogenous plant substances possessing basic properties. Barre opens by defining the alkaloids and surveying the various systems used to classify them, whether by natural versus artificial origin, chemical nucleus (pyridine, quinoline, or isoquinoline), volatility, or botanical family of origin, and outlines their general physical and chemical properties, including solubility, optical activity, and characteristic reactions with precipitating and color-test reagents.

The thesis details standard laboratory methods for the extraction and separation of alkaloids from plant material, including a step-by-step …


Reactions Between The Stannous And Arsenate Ions In Silicic Acid Gels, Willard Merle Farr Jan 1931

Reactions Between The Stannous And Arsenate Ions In Silicic Acid Gels, Willard Merle Farr

University of the Pacific Theses and Dissertations

Observation of crystal growths resulting from the chemical interaction of stannous chloride and sodium arsenate in silicic acid gels revealed the following very interesting fact. Gels identical in every respect except acidity, contained crystal growths varying greatly in appearance.

The purpose of this investigation was, therefore, to allow stannous and arsenate ion to combine in a series of accurately prepared gels, identical in all respects except the acid content, and to observe the effect upon crystal growth of: (1) varying the acid concentration; and (2) varying the kind of acid


A Study Of Gel Formation In Kerosene In Contact With Sodium, Jerome M. Weller May 1930

A Study Of Gel Formation In Kerosene In Contact With Sodium, Jerome M. Weller

Bachelors’ Theses

The origin of the problem to be considered in this paper is traced to the observations of John R. Koob, Ph.D., Head of the Chemistry Department of Marquette University. It was his experience to note that the kerosene, in a bottle, containing cut sodium for the organic laboratory, had solidified to a gel, resembling Vaseline in appearance.


The Study Of The Effects Of Different Metallic Soaps On The Water Content Of Water-In-Gasoline Emulsions, Lynn D. Wilson May 1930

The Study Of The Effects Of Different Metallic Soaps On The Water Content Of Water-In-Gasoline Emulsions, Lynn D. Wilson

Bachelors’ Theses

The study of emulsions and emulsification is of very great theoretical and practical interest. From the standpoint of pure science it throws much light on the problems of surface tension, surface concentration, absorption, surface films, electrical double layers. Brownian movement, and the general theory of disperse systems and colloids. It is also of importance in biological science, e.g., the adsorption of fats and the permeability of membranes. When industrial and applied science are considered, it is remarkable how many subjects of interest and importance are dependent on a knowledge of the formation, behavior, and stability of emulsions. In this connection, …


The Influence Of Freezing On The Occurrence Of Reducing Sugar In The Potato, Leo B. Perssion May 1930

The Influence Of Freezing On The Occurrence Of Reducing Sugar In The Potato, Leo B. Perssion

Bachelors’ Theses

The purpose or this thesis was to see if the change or potato starch to a reducing sugar in the potato on freezing was due to the freezing itself or to some enzymatic reaction. For we know that reducing sugars are formed in the potato by just freezing, therefore it should be possible to manufacture sugar by using pure potato starch as a base. Although this problem may seem to be an unimportant labor as the supply of sugar is large and the price of sugar cheap; this process of obtaining sugar would save thousands or bushels of potatoes every …


A Study Of Phytosterol Obtained From Cocoa Beans And Cocoa Butter, Norman Anthony Pokorny Jan 1925

A Study Of Phytosterol Obtained From Cocoa Beans And Cocoa Butter, Norman Anthony Pokorny

Bachelors’ Theses

Despite the fact that considerable work has been done on cholesterol, relatively little is known about its isomer, phytosterol. Both cholesterol and phytosterol belong to the general group of sterols. Cholesterol is described as an aromatic sterol, a mono~atomic secondary alcohol, containing an iso-propyl and a vinyl group, with a terpene-like structure. Cholesterol was first discovered by Conradi in 1775, then by Gren (1788) in biliary calculi. In 1785 Fourcroy isolated cholesterol from gall-stones, one variety of which is composed almost wholly of it, but it was confused with adipocere, until Chevreul (1814) discovered its true nature, when he declared …


The Chemical And Physical Examination Of The Oils From The Seeds Of The Aster, Bachelor's Button, Larkspur, Muskmelon, Okra, Pansy, Snapdragon, Henry Neal Marsh Jan 1914

The Chemical And Physical Examination Of The Oils From The Seeds Of The Aster, Bachelor's Button, Larkspur, Muskmelon, Okra, Pansy, Snapdragon, Henry Neal Marsh

Archived Theses and Dissertations

No abstract provided.


Combustion Analysis; Estimation Of Carbon & Hydrogen, Clifford Brewster Morrison Jan 1899

Combustion Analysis; Estimation Of Carbon & Hydrogen, Clifford Brewster Morrison

Student and Lippitt Prize Essays

Documents the methods of composition analysis by Antoine Lavoisier the 18th century and the adoption and refinement of this method by Theodore V. Saussure and others in the 19th century to combustion analysis. Includes plates of measurement equipment used.