Chemistry Commons^™

Chemistry Of The Spring Waters Of The Ouachita Mountains Excluding Hot Springs, Arkansas, George H. Wagner, Kenneth F. Steele

Arkansas Water Resources Center Technical Reports

This report is based on the chemical analysis of the waters from 93 springs and 9 wells. Springs, when free from metal plumbing, provide an uncontaminated source of the ground water and it was desired to obtain water uncontaminated with metals. A few wells were added to the list, usually because of their unique location in the sampling grid.

An Environmental Study Of The Origin, Distribution, And Bioaccumulation Of Selenium In Kentucky And Barkley Lakes, B. E. Mcclellan, Kenneth J. Frazer

KWRRI Research Reports

Many samples of water, bottom sediment, and fish were analyzed for toxic metal ion content. The samples were collected from several selected sites along Kentucky and Barkley Lakes as well as the Cumberland River and several sub-impoundments along these aquatic systems. Emphasis was placed on selenium, although several other metal ions were determined. The results showed that there are no serious pollution problems with As, Cd, Cr, Cu, Hg, Pb, Se, Sr, Zn, or Zr at any of the sites examined. Actually, none of the trace metals examined even come close to the EPA limits on fish, with the exception …

Bulletin 3992 - Nitrogenous Fertilisers For Cereal Production, M. G. Mason

Bulletins - 3000 - 3999

Because fertiliser prices continue to rise, it is becoming increasingly important to understand what affects the response to fertilisers by crops.

Among the many factors influencing crop response to nitrogen applications, the most important are the season, soil type, paddock history, time of application and source of nitrogen. Before deciding whether to use nitrogen on a cereal crop, which source to use and at what rate, the farmer needs some understanding of how these factors work.

Nitrogenous Fertilisers For Cereal Production, M G. Mason

Journal of the Department of Agriculture, Western Australia, Series 4

Among the many factors influencing crop response to nitrogen applications, the most important are the season, soil type, paddock history, time of application and source of nitrogen. Before deciding whether to use nitrogen on a cereal crop, which source to use and at what rate, the farmer needs some understanding of how these factors work.

Catechol Effected Dissolution Of Silicate Minerals, James Maurice Kelley

Dissertations and Theses

The chemical properties of guanidinium tris(catecholato)siliconate, [(H₂N)₂C=NH₂]₂[Si(C₆H₄O₂)₃]·XH₂O (0 < X < 1), precipitated from an ammoniacal solution of silica and catechol by adding guanidinium hydrochloride, (H₂N)₂C=NH·HC1, were studied, and infrared, nmr, x-ray powder diffraction, and analytical data were gathered.

This same compound was, upon addition of' (H₂N)₂C=NH·HC1, isolated from 0.25, M aqueous catechol solutions buffered at pH 10 and containing the silicate minerals albite, andradite, muscovite, pyrophyllite, talc, and wollastonite, and also from unbuffered catechol solutions containing wollastonite and andradite.

It is concluded from this work that the formation of an anionic catechol-silicon complex, Si(C₆H₄O₂)₃²⁻, is largely responsible for the dissolution of the minerals mentioned above. From this conclusion, it is proposed that naturally occurring members of the class of organic compounds to which catechol belongs, the aromatic v̲i̲̲c̲-diols, may play …

Calcium Carbonate Dissolution And Precipitation In Water: Factors Affecting The Carbonate Saturometer Method, Lyle M. Dabb

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The carbonate saturometer method developed by Weyl (1961) was studied in respect to the effect of several variables on the solubility of carbonates. The solubility of three solid carbonate materials was measured in four different salt solutions, at four ionic strengths, and at two different temperatures. The solids studied included: calcite, dolomite, and a calcareous soil.

It was found that the three solid carbonate materials varied in solubility from a low in the soil carbonates to a high in dolomite.

Increasing the ionic strength of the solution increased the solubility of most of the solid carbonate materials.

By decreasing the …

Micronutrients And Biological Patterns In Lake Mead, Hasan K. Qashu, Lorne G. Everett, J. S. Carlson, Bureau Of Reclamation

Publications (WR)

Progressive increases in concentration of dissolved solids in the Colorado River water from Lake Powell to Imperial Dam seem to alter plankton dynamics and biological productivity of the river. Also, changes in biological productivity and micronutrients concentrations occur within the same reservoir. Development of a digital simulation model to predict micronutrients concentrations and biological productivity is necessary for diagnosing changes in plankton population and effluent-carrying capacity of the system. The objectives of the study are: (1) to determine trace metal balance at different locations in Lake Mead, (2) to measure biological productivity and conduct plankton population counts at each sampling …

Magnesium Ion Inhibition Of Calcium Carbonate Precipitation And Its Relation To Water Quality, John J. Hassett

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The effect of Mg⁺⁺ ion on the solubility of calcium carbonate was determined using P. K. Weyls "carbonate saturometer."

The amount of calcium carbonate precipitated or dissolved was measured for five series of waters when equilibrated with solid carbonate.

It was found that the effect of Mg⁺⁺ ion on solubility depend upon the nature of the solid phase: surface area, coprecipitated Mg⁺⁺, minerology, etc.

Pure low area calcite showed an increase in solubility which could be explained by ion-pair formation, while its other carbonates departed from this behavior.

Trace Metal Analysis Of Barren River And Nolin River Reservoirs By Atomic Absorption Spectroscopy, Mary Jo Kennedy

Masters Theses & Specialist Projects

This research was part of a project underway at Barren River and Nolin River Reservoirs in south-central Kentucky. The research was partially supported by a grant through the Sport Fishing Institute, Washington, D.C.

The study reported herein was concerned with the analysis of trace metal concentrations in the two reservoirs. It is believed that the fish population may in part depend upon the trace metals present in the water. It is anticipated that the data presented in this paper will eventually be correlated with the biology studies of the reservoirs being carried out by the Department of Biology of Western …

How Important Is Sulphur For Pastures?, R N. Glencross, W. J. Cox

Journal of the Department of Agriculture, Western Australia, Series 4

With the introduction of low sulphur compound and concentrated fertilisers, a new look is required at the sulphur status of West Australian soils, and the sulphur requirement of pasture.

In this article the functions of sulphur, deficiency symptoms and potential problem soils are described.

Current recommendations and plans for future research work are outlined.

Copper, Zinc And Molybdenum Fertilizers For New Land Crops And Pastures : 1969, J W. Gartrell, R. N. Glencross

Journal of the Department of Agriculture, Western Australia, Series 4

Four years of intensive research into soil deficiencies in developing areas have resulted in a more comprehensive understanding of the need for trace elements in Western Australia.

Ground Water Flow Systems Of Central Nevada, G. William Fiero Jr

UNLV Theses, Dissertations, Professional Papers, and Capstones

The U.S. Atomic Energy Commission has been evaluating a large area of central Nevada in order to define a supplemental test site for the underground testing of high-yield nuclear devices. Safety considerations involving the radiocontamination of the ground water in the vicinity of the test site necessitated that research be conducted to determine the direction and rate of flow of the ground water. This investigation defines the ground water flow systems in eighteen valleys comprising 12,000 square miles of central Nevada.

The definition of the systems was made following a compilation of existing hydrologic and geologic data for the area. …

Experiments On The Inactivation Of Zinc By The Mineral Fractions Of The Soil, John J. Hassett

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Zinc deficiency, in many cases, is closely related to organic matter decomposition. DeRemer and Smith (1964) studied the effects of decomposing sugar beet tops on the reactions of Zn⁶⁵ in a Portneuf soil. They found that with time the Zn⁶⁵ associated with lime minerals, exchangeable, and water soluble fractions of the soil decreased, while that found with the organic and mineral fractions increased. This increase in the mineral fraction is of particular interest, since the majority of the Zn⁶⁵ was found to be with this fraction after a period of time. They also showed that the increase …

Nature Of Non-Biological Decomposition Of Nitrite In Acid Media, Mukkatira Kariappa Mahendrappa

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Curiosity is the cause of investigations, and the thirst for knowledge originates from it. Many times at the end of investigations, the number of questions raised are greater than those for which answers are sought. Therefore, all the information gathered through scientific investigations may not be of value for immediate application in practical life. Nevertheless, no research can be considered less important than the other because the integration of several scientific findings considered less less important at the time of investigation may reveal something of very high significance. Similarly, the study of various transformation reactions that the added fertilizers undergo …

Water Chemistry Survey Of Boulder Basin, Lake Mead, P. R. Tramutt, Bureau Of Reclamation

Publications (WR)

The survey results indicate that the impoundment of water behind Hoover Dam has not adversely affected the dissolved oxygen (DO) content and that water quality and DO content were uniform regardless of depth. The study made in April-May 1964 will provide water quality data of Lake Mead prior to releases from Lake Powell as a basis for evaluating Lake Powell's effect on water quality and limnology of Lake Mead. The performance of a DO analyzer was tested and found unsatisfactory at depths below 150 ft. Parameters tested by standard chemical analyses of water samples in the Denver Laboratory and by …

Ground-Water Appraisal Of The Meadow Valley Area, Lincoln And Clark Counties, Nevada, F. Eugene Rush

Publications (WR)

This report, the 27th in the series of reconnaissance ground-water studies which were initiated following authorization by the I960 Legislature, gives the results of a study of the Meadow Valley area. This area includes eight valleys in southeastern Nevada - - Patterson, Spring, Eagle, Dry, Rose, Panaca, Clover, and Lower Meadow Valley - - all part of the Colorado River drainage system.

This study was made and report prepared by F. Eugene Rush, Geologist for the U. S. Geological Survey.

These reconnaissance ground-water resources surveys make available pertinent information of great and immediate value to many State and Federal agencies. …

Nitrite Reactions In Soil, John Otto Reuss

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Losses of soil nitrogen that cannot be attributed to leaching or crop removal have been observed in many field experiments. Several mechanisms have been proposed to account for these losses.

Differentiation Between The Ph Effect And The Bicarbonate Ion Effect In Causing Lime-Induced Chlorosis, Hyrum Del Var Petersen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Lime-induced chlorosis has been recognized for many years as a problem where plants are grown on calcareous soils. There are many factors associated with and influencing this form of iron chlorosis and because of this it has been very difficult to determine the relationship between the factors and chlorosis.

The Effect Of Chelates On Phosphorus Availability And Mobility, Salah Ahmed Tahoun

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Soil-phosphorus relations and plant-phosphorus relations have attracted the interest of many investigators since Liebig introduced his famous theory about the importance of the mineral matters to the plant in 1840. It was soon realized that phosphorus nutrition was a problem not easily solved for two reasons. 1. The added phosphorus fertilizers, soon after soil application are converted by some reactions in the soil to complex compounds far less soluble, consequently less available to the plant. Conclusions about this process led to controversial debates until it was discovered that a general statement covering all soils was impossible since the reactions involved …

The Effect Of Moisture And Temperature On Transformation Of Applied Ammonium Sulfate In Several Western Soils, Lloyd Richard Hossner

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The conversion of ammonia nitrogen to nitrite and nitrate forms of nitrogen has aroused much attention in the past and continues to receive much of the energy of the present day researcher.

Phosphorus Status Of Genola Soils In Utah, Warren E. Bendixen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

With increasing pressure on economical production of crops, more fertilizers are being applied to the soil each year to increase crop yields. Economical production of crops with applications of fertilizer requires an evaluation of the essential elements of the various crops so applications of fertilizer will not exceed the law of diminishing returns.

Because varying soil, moisture, and climatic conditions influence the response to added fertilizers, some workers (18, 26, 38) have contended that the only reliable way of determining the fertilization needs of a crop is to conduct a trial on the particular farm. The length of time involved …

The Mineral Content Of Various Sections Of Some Plants As Influenced By Conditions Associated With Lime-Induced Chlorosis, Hyrum Del Var Petersen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The so-called "lime-induced" chlorosis has been recognized for many years as a problem where plants are grown on calcareous soils. The characteristics associated with lime-induced chlorosis are the same as those associated with iron deficiency chlorosis--interveinal yellowing of the leaves at the meristemic region combined with reduced vigor of the plant as a whole. Lime-induced chlorosis is unique in that the iron content of both chlorotic plant and the soil do not always show a deficiency in iron when chemically analyzed. This leads to the theory that iron is inactivated in both the soil and plant.

Although no single factor …

Copper Minerals For Fertilizer Use, R N. Glencross

Journal of the Department of Agriculture, Western Australia, Series 4

COPPER fertilizers have an important role in maintaining: and increasing Western Australia's agricultural production.

On many soils they are essential for cereal growing or pasture production and persistence and for animal health and wool quality.

They are also sometimes used for fruit trees, vines, and vegetables.

Minor Elements Can Be Overdone, L T. Jones

Journal of the Department of Agriculture, Western Australia, Series 4

T H E term "minor elements" which is now commonly used and well understood by farmers and gardeners, refers to the five essential plant foods—copper, zinc, manganese, molybdenum and boron.

These five essential plant foods are needed by all plants in minute quantities and it is relatively easy to use them in excess of actual requirements or even in toxic amounts.

In practice this is not usually a problem with cereals and pastures. The important exception is when zinc alone is added to a cereal crop low in copper and the extra zinc accentuates the copper deficiency, and poorer yields …

List Of Registered Fertilisers : 1959-60, H G. Cariss

Journal of the Department of Agriculture, Western Australia, Series 4

TN accordance with the provisions of the Fertilisers Act, 1928-1955, it is required that—with the exception of bulk sales to a manufacturer and those made in accordance with a buyer's written prescription—all fertilisers sold are required to be registered annually, the registration year being from November 1 to October 31 following.

The list of fertilisers registered for the year commencing November 1, 1959, is set out herewith in tabular form.

A Manometric Method For The Determination Of Soil Carbonates In The Field, N. A. Polyzopoulos

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

In soil survey work the method now generally used to evaluate the carbonate content of the soil in the field is to observe the amount of effervescence that takes place when the soil reacts with dilute acid. The four degrees of effervescence usually recognized are designated by the symbols eo, e, es, ev and correspond roughly to a lime content of 0-0.5, 0.5-3, 3-15, and above 15 per cent, respectively. This, or course, is a very rough estimate and therefore a method is needed for the quantitative determination of carbonates in the field with a fair degree of accuracy. If …

The Thermodynamics And Some Practical Aspects Of Zinc Adsorption On Calcite, Dolomite, And Calcian-Magnesite Minerals, Jerome J. Jurinak

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Zinc is one of the essential elements required for the normal growth of plants. The total amount of zinc commonly occurring in soils is usually many times greater than that necessary to supply the needs of actively growing plants. The ability of the soil to "fix" zinc in form unavailable for plant use, however, has made the zinc deficiency disease an important plant nutrition problem in the major fruit and nut growing regions of the West. Fixation mechanisms which have been postulated as contributing to zinc deficiency include organic complexes, precipitation of insoluble inorganic salts, and strong zinc-clay intersections. It …

Analytical Data (1951), Walter A. Lawrance

Walter Lawrance Papers

No abstract provided.

Freestone County, Texas [Water Quality Survey Of Wells And Springs With Test Hole Data, 1936], Samuel F. Turner

United States Geological Survey: Water Reports and Publications

Introduction

The purpose of this survey was to obtain information concerning existing wells and springs and the quantity and quality of water they yield, and to put down test holes where additional information was needed.

This project was part of a statewide Works Progress Administration project known as a "Statewide Inventory of Water Wells," sponsored by the [Texas] State Board of Water Engineers. The Division of Ground Water of the United States Geological Survey cooperated in the technical direction of the project and the Bureau of Industrial Chemistry of the University of Texas furnished laboratory space and equipment and supervised …

The Extraction Of Tantalum And Columbium From Tantalite, Stanley P. Wisniewski

Bachelors’ Theses

In the summer of 1932, the Milwaukee Public Museum, sent an expedition to the Bad Lands and Black Hills of South Dakota, under the direction of Dr. Ira Edwards, Curator of Geology in that institution. It was at this time that the author, a member of this group, while studying the pegmatites of the Black Hills, became interested in the tantalum-columbium bearing minerals of that region, namely tantalite and columbite. At that time the writer made a detailed mineralogical study of these two minerals, as well as a thorough investigation of their occurrence in that region. In the fall of …