The Sun and the Solar System Commons^™

An Ion-Neutral Reaction To Form Cyanobenzene And Ethynylbenzene In Titan’S Atmosphere, Rachel M. Huchmala, Vincent J. Esposito

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The ion-neutral reaction between cyanoacetylene (HC₃N) and phenyl anion (C₆H₅^–) leads to the formation of cyanobenzene (C₆H₅CN) and the ethynyl anion (C₂H^–) via a submerged, exothermic pathway. Through a different mechanism, the same two reactants also form ethynylbenzene (C₆H₅C₂H) and CN^–. These new reactions can be a foundation for the production of substituted benzenes using molecules currently present on Saturn’s largest moon, Titan. Cyclic aromatic molecules like C₆H₅CN and C₆H_{5 …}

Analysis Of Titan's Fluvial Features Using Numerical Modeling, Jeshurun Horton

Mechanical Engineering Undergraduate Honors Theses

River channels have been observed near the Huygens probe landing site on the surface of Titan, along with evidence of rounded water ice boulders transported through fluid flow. Evidence near the landing site suggests active flow of liquid methane, which has motivated the study of the effects of sediment load and channel sizes on Titan’s fluvial features. A numerical model is used to determine the viscosity, flow velocity, and critical boulder transport diameter based on channel size, slope, and a range of sediment concentrations. This model achieves two ends: first, observed boulder diameters are used to determine the ideal channel …

An Experimental Study Of Evaporites On Titan: Implications For Lake Composition And Future Missions, Ellen Czaplinski

Graduate Theses and Dissertations

Titan is the only other planetary body in the solar system with liquid on the surface. With a surface temperature and pressure of 89 – 94 K and 1.5 bar (N2), respectively, Titan’s lakes are comprised of liquid hydrocarbons, predominantly methane and ethane. Over time, Titan’s lakes may evaporate, leaving behind residual deposits (evaporites). The evaporation processes and composition of the evaporites is poorly understood. I address these outstanding questions by experimentally investigating the physical and spectral properties of evaporites at Titan surface conditions using an experimental chamber.

Chapter 1 addresses the formation of ethylene evaporites. Ethylene evaporites form more …

An Experimental Investigation Of Liquid Hydrocarbons In A Simulated Titan Environment, Kendra Farnsworth

Graduate Theses and Dissertations

Saturn’s moon, Titan, has surface conditions (89–94 K, 1.5-bar atmosphere) that permit lakes of methane, ethane, and dissolved atmospheric nitrogen. The effects of atmospheric nitrogen on methane-ethane liquid properties is poorly understood, leading to uncertainty in Titan modeling. I address this question by experimentally investigating the physical properties of methane-ethane liquids under a 1.5-bar nitrogen atmosphere in a simulated Titan environmental chamber.

Chapter 1 addresses nitrogen dissolution kinetics in Titan’s liquid hydrocarbons. I found an exponential increase in nitrogen quantity and diffusion coefficients with increasing methane mol%. I find that Titan’s liquids are likely not saturated in nitrogen, with dissolution …

Exploring The Surface Liquid And Lake Regions Of Titan With Laboratory Experimentation And Cassini Spacecraft Data, Felix Casimir Wasiak

Graduate Theses and Dissertations

The surface liquids and lake regions of Titan are studied utilizing three unique techniques, the results of which are reported in this dissertation. The development of a facility to simulate the surface conditions of Titan, and to conduct experiments on samples within that facility, brings an understanding of Titan's surface not possible through observation and modeling alone. The properties of this facility are presented, including conceptual methodology, design, implementation, performance, and experimental results. The facility, the main component of which is a simulation chamber, allows for Titan temperatures of 90 - 94 K and a 1.5 bar N2 atmosphere. The …

Orbital Periodicities Reflected In Ancient Surfaces Of Our Solar System And The Implications For A Record Of Early Life, Dixie Lee Androes

Graduate Theses and Dissertations

Uniformitarian processes, governed by invariant physical laws, remain the most reliable source for reconstructing the past. Driving many of the repetitive, predictable processes are the orbital dynamics of the Sun-Planet-Moon systems. Astronomical periodicities range from a few hours (tides) to thousands of years (Milankovitch). These periodicities, combined with geomorphic observations of planetary surfaces, constrain the time-dependent processes and allow for reconstruction of events and conditions favorable for sedimentary accumulations. This research suggests that seasonal sedimentary processes are dominant on Titan and Mars, and have played a significant role in the formation of ancient banded-iron formations (BIF's) on Earth.

Earth, Mars, …