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Physics and Astronomy Faculty Publications

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Articles 421 - 450 of 679

Full-Text Articles in Astrophysics and Astronomy

Improving The Catalytic Activity Of Semiconductor Nanocrystals Through Selective Domain Etching, Elena Khon, Kelly Lambright, Rony S. Khnayzer, Pavel Moroz, Dimuthu Perera, Evgeniia Butaeva, Scott Lambright, Felix N. Castellano, Mikhail Zamkov May 2013

Improving The Catalytic Activity Of Semiconductor Nanocrystals Through Selective Domain Etching, Elena Khon, Kelly Lambright, Rony S. Khnayzer, Pavel Moroz, Dimuthu Perera, Evgeniia Butaeva, Scott Lambright, Felix N. Castellano, Mikhail Zamkov

Physics and Astronomy Faculty Publications

Colloidal chemistry offers an assortment of synthetic tools for tuning the shape of semiconductor nanocrystals. While many nanocrystal architectures can be obtained directly via colloidal growth, other nanoparticle morphologies require alternative processing strategies. Here, we show that chemical etching of colloidal nanoparticles can facilitate the realization of nanocrystal shapes that are topologically inaccessible by hot-injection techniques alone. The present methodology is demonstrated by synthesizing a two-component CdSe/CdS nanoparticle dimer, constructed in a way that both CdSe and CdS semiconductor domains are exposed to the external environment. This structural morphology is highly desirable for catalytic applications as it enables both reductive …


Classification And Analysis Of Emission-Line Galaxies Using Mean Field Independent Component Analysis, James T. Allen, Paul C. Hewett, Chris T. Richardson, Gary J. Ferland, Jack A. Baldwin Apr 2013

Classification And Analysis Of Emission-Line Galaxies Using Mean Field Independent Component Analysis, James T. Allen, Paul C. Hewett, Chris T. Richardson, Gary J. Ferland, Jack A. Baldwin

Physics and Astronomy Faculty Publications

We present an analysis of the optical spectra of narrow emission-line galaxies, based on mean field independent component analysis (MFICA), a blind source separation technique. Samples of galaxies were drawn from the Sloan Digital Sky Survey (SDSS) and used to generate compact sets of ‘continuum’ and ‘emission-line’ component spectra. These components can be linearly combined to reconstruct the observed spectra of a wider sample of galaxies. Only 10 components – five continuum and five emission line – are required to produce accurate reconstructions of essentially all narrow emission-line galaxies to a very high degree of accuracy; the median absolute deviations …


Strongly Localized Magnetization Modes In Permalloy Antidot Lattices, J. Sklenar, V. S. Bhat, Lance E. De Long, O. Heinonen, J. B. Ketterson Apr 2013

Strongly Localized Magnetization Modes In Permalloy Antidot Lattices, J. Sklenar, V. S. Bhat, Lance E. De Long, O. Heinonen, J. B. Ketterson

Physics and Astronomy Faculty Publications

Antidot lattices (ADLs) patterned into soft magnetic thin films exhibit rich ferromagnetic resonance (FMR) spectra corresponding to many different magnetization modes. One of the predicted modes is highly localized at the edges of the antidots; this mode is difficult to detect experimentally. Here we present FMR data for a permalloy thin film patterned into a square array of square antidots. Comparison of these data with micromagnetic simulations permits identification of several edge modes. Our simulations also reveal the effect of the antidot shape on the mode dispersion.


Suppression Of Dielectronic Recombination Due To Finite Density Effects, D. Nikolić, T. W. Gorczyca, K. T. Korista, Gary J. Ferland, N. R. Badnell Apr 2013

Suppression Of Dielectronic Recombination Due To Finite Density Effects, D. Nikolić, T. W. Gorczyca, K. T. Korista, Gary J. Ferland, N. R. Badnell

Physics and Astronomy Faculty Publications

We have developed a general model for determining density-dependent effective dielectronic recombination (DR) rate coefficients in order to explore finite-density effects on the ionization balance of plasmas. Our model consists of multiplying by a suppression factor those highly-accurate total zero-density DR rate coefficients which have been produced from state-of-the-art theoretical calculations and which have been benchmarked by experiment. The suppression factor is based upon earlier detailed collision-radiative calculations which were made for a wide range of ions at various densities and temperatures, but used a simplified treatment of DR. A general suppression formula is then developed as a function of …


Erratum: 'Improved He I Emissivities In The Case B Approximation', R. L. Porter, Gary J. Ferland, P. J. Storey, M. J. Detisch Apr 2013

Erratum: 'Improved He I Emissivities In The Case B Approximation', R. L. Porter, Gary J. Ferland, P. J. Storey, M. J. Detisch

Physics and Astronomy Faculty Publications

No abstract provided.


Tuning Electronic Structure Via Exipatial Strain In Sr2Iro4 Thin Films, J. Nichols, Jsaminka Terzic, Emily Geraldine Bittle, Oleksandr B. Korneta, Lance E. De Long, Joseph Brill, Gang Cao, Sung S. Ambrose Seo Apr 2013

Tuning Electronic Structure Via Exipatial Strain In Sr2Iro4 Thin Films, J. Nichols, Jsaminka Terzic, Emily Geraldine Bittle, Oleksandr B. Korneta, Lance E. De Long, Joseph Brill, Gang Cao, Sung S. Ambrose Seo

Physics and Astronomy Faculty Publications

We have synthesized epitaxial Sr2IrO4 thin-films on various substrates and studied their electronic structure as a function of lattice-strain. Under tensile (compressive) strain, increased (decreased) Ir-O-Ir bond-angle is expected to result in increased (decreased) electronic bandwidth. However, we have observed that the two optical absorption peaks near 0.5 eV and 1.0 eV are shifted to higher (lower) energies under tensile (compressive) strain, indicating that the electronic-correlation energy is also affected by in-plane lattice-strain. The effective tuning of electronic structure under lattice-modification provides an important insight into the physics driven by the coexisting strong spin-orbit coupling and electronic …


Expanded Iron Uta Spectra—Probing The Thermal Stability Limits In Agn Clouds, Gary J. Ferland, R. Kisielius, F. P. Keenan, P. A. M. Van Hoof, V. Jonauskas, Matt L. Lykins, R. L. Porter, R. J. R. Williams Apr 2013

Expanded Iron Uta Spectra—Probing The Thermal Stability Limits In Agn Clouds, Gary J. Ferland, R. Kisielius, F. P. Keenan, P. A. M. Van Hoof, V. Jonauskas, Matt L. Lykins, R. L. Porter, R. J. R. Williams

Physics and Astronomy Faculty Publications

The Fe unresolved transition arrays (UTAs) produce prominent features in the ~15-17 Å wavelength range in the spectra of active galactic nuclei (AGNs). Here, we present new calculations of the energies and oscillator strengths of inner-shell lines from Fe XIV, Fe XV, and Fe XVI. These are crucial ions since they are dominant at inflection points in the gas thermal stability curve, and UTA excitation followed by autoionization is an important ionization mechanism for these species. We incorporate these, and data reported in previous papers, into the plasma simulation code Cloudy. This updated physics is subsequently employed to reconsider the …


The Nature Of The H2-Emitting Gas In The Crab Nebula, C. T. Richardson, J. A. Baldwin, Gary J. Ferland, E. D. Loh, C. A. Kuehn, A. C. Fabian, Philippe Salomé Apr 2013

The Nature Of The H2-Emitting Gas In The Crab Nebula, C. T. Richardson, J. A. Baldwin, Gary J. Ferland, E. D. Loh, C. A. Kuehn, A. C. Fabian, Philippe Salomé

Physics and Astronomy Faculty Publications

Understanding how molecules and dust might have formed within a rapidly expanding young supernova remnant is important because of the obvious application to vigorous supernova activity at very high redshift. In previous papers, we have mapped the Crab nebula (the Crab) in a rotovibrational H2emission line, and then measured the molecular excitation temperature for a few of the brighter H2-emitting knots that we have found to be scattered throughout the Crab's filaments. We found that H2 emission is often quite strong, correlates with optical low-ionization emission lines and has a surprisingly high excitation temperature. Here, …


Radiative Cooling In Collisionally Ionized And Photoionized Plasmas, Matt Lykins, Gary J. Ferland, Ryan L. Porter, Peter A. M. Van Hoof, R. J. R. Williams, Orly Gnat Mar 2013

Radiative Cooling In Collisionally Ionized And Photoionized Plasmas, Matt Lykins, Gary J. Ferland, Ryan L. Porter, Peter A. M. Van Hoof, R. J. R. Williams, Orly Gnat

Physics and Astronomy Faculty Publications

We discuss recent improvements in the calculation of the radiative cooling in both collisionally ionized and photoionized plasmas. We are extending the spectral simulation code CLOUDY so that as much as possible of the underlying atomic data are taken from external data bases, some created by others and some developed by the CLOUDY team. This paper focuses on recent changes in the treatment of many stages of ionization of iron, and discusses its extensions to other elements. The H- and He-like ions are treated in the isoelectronic approach described previously. Fe II is a special case treated with a large …


Studies Of Ngc 6720 With Calibrated Hst/Wfc3 Emission-Line Filter Images. Ii. Physical Conditions, C. R. O'Dell, Gary J. Ferland, W. J. Henney, M. Peimbert Feb 2013

Studies Of Ngc 6720 With Calibrated Hst/Wfc3 Emission-Line Filter Images. Ii. Physical Conditions, C. R. O'Dell, Gary J. Ferland, W. J. Henney, M. Peimbert

Physics and Astronomy Faculty Publications

We have performed a detailed analysis of the electron temperature and density in the Ring Nebula using the calibrated Hubble Space Telescope WFC3 images described in the preceding paper. The electron temperature (Te) determined from [NII] and [O III] rises slightly and monotonically toward the central star. The observed equivalent width (EW) in the central region indicates that Te rises as high as 13,000 K. In contrast, the low EWs in the outer regions are largely due to scattered diffuse Galactic radiation by dust. The images allowed determination of unprecedented small-scale variations in Te. …


Studies Of Ngc 6720 With Calibrated Hst/Wfc3 Emission-Line Filter Images. I. Structure And Evolution, C. R. O'Dell, Gary J. Ferland, W. J. Henney, M. Peimbert Feb 2013

Studies Of Ngc 6720 With Calibrated Hst/Wfc3 Emission-Line Filter Images. I. Structure And Evolution, C. R. O'Dell, Gary J. Ferland, W. J. Henney, M. Peimbert

Physics and Astronomy Faculty Publications

We have performed a detailed analysis of the Ring Nebula (NGC 6720) using Hubble Space Telescope WFC3 images and derived a new three-dimensional model. Existing high spectral resolution spectra played an important supplementary role in our modeling. It is shown that the Main Ring of the nebula is an ionization-bounded irregular non-symmetric disk with a central cavity and perpendicular extended lobes pointed almost toward the observer. The faint outer halos are determined to be fossil radiation, i.e., radiation from gas ionized in an earlier stage of the nebula when it was not ionization bounded. The narrowband WFC3 filters that isolate …


Testing Diagnostics Of Nuclear Activity And Star Formation In Galaxies At Z > 1, Jonathan R. Trump, Nicholas P. Konidaris, Guillermo Barro, David C. Koo, Dale D. Kocevski, Stéphanie Juneau, Benjamin J. Weiner, S. M. Faber, Ian S. Mclean, Renbin Yan, Pablo G. Pérez-González, Victor Villar Dec 2012

Testing Diagnostics Of Nuclear Activity And Star Formation In Galaxies At Z > 1, Jonathan R. Trump, Nicholas P. Konidaris, Guillermo Barro, David C. Koo, Dale D. Kocevski, Stéphanie Juneau, Benjamin J. Weiner, S. M. Faber, Ian S. Mclean, Renbin Yan, Pablo G. Pérez-González, Victor Villar

Physics and Astronomy Faculty Publications

We present some of the first science data with the new Keck/MOSFIRE instrument to test the effectiveness of different AGN/SF diagnostics at z ~ 1.5. MOSFIRE spectra were obtained in three H-band multi-slit masks in the GOODS-S field, resulting in 2 hr exposures of 36 emission-line galaxies. We compare X-ray data with the traditional emission-line ratio diagnostics and the alternative mass-excitation and color-excitation diagrams, combining new MOSFIRE infrared data with previous HST/WFC3 infrared spectra (from the 3D-HST survey) and multiwavelength photometry. We demonstrate that a high [O III]/Hβ ratio is insufficient as an active galactic nucleus (AGN) indicator …


The Central Molecular Gas Structure In Liners With Low-Luminosity Active Galactic Nuclei: Evidence For Gradual Disappearance Of The Torus, F. Müller-Sánchez, M. A. Prieto, M. Mezcua, R. I. Davies, M. A. Malkan, Moshe Elitzur Dec 2012

The Central Molecular Gas Structure In Liners With Low-Luminosity Active Galactic Nuclei: Evidence For Gradual Disappearance Of The Torus, F. Müller-Sánchez, M. A. Prieto, M. Mezcua, R. I. Davies, M. A. Malkan, Moshe Elitzur

Physics and Astronomy Faculty Publications

We present observations of the molecular gas in the nuclear environment of three prototypical low-luminosity active galactic nuclei (LLAGNs), based on VLT/SINFONI AO-assisted integral-field spectroscopy of H2 1-0 S(1) emission at angular resolutions of ~0.''17. On scales of 50-150 pc, the spatial distribution and kinematics of the molecular gas are consistent with a rotating thin disk, where the ratio of rotation (V) to dispersion (σ) exceeds unity. However, in the central 50 pc, the observations reveal a geometrically and optically thick structure of molecular gas (V/σ < 1 and N H > 1023 cm–2 …


Two-Component Structure Of The HΒ Broad-Line Region In Quasars. I. Evidence From Spectral Principal Component Analysis, Chen Hu, Jian-Min Wang, Luis C. Ho, Gary J. Ferland, Jack A. Baldwin, Ye Wang Nov 2012

Two-Component Structure Of The HΒ Broad-Line Region In Quasars. I. Evidence From Spectral Principal Component Analysis, Chen Hu, Jian-Min Wang, Luis C. Ho, Gary J. Ferland, Jack A. Baldwin, Ye Wang

Physics and Astronomy Faculty Publications

We report on a spectral principal component analysis (SPCA) of a sample of 816 quasars, selected to have small Fe II velocity shifts with spectral coverage in the rest wavelength range 3500-5500 Å. The sample is explicitly designed to mitigate spurious effects on SPCA induced by Fe II velocity shifts. We improve the algorithm of SPCA in the literature and introduce a new quantity, the fractional-contribution spectrum, that effectively identifies the emission features encoded in each eigenspectrum. The first eigenspectrum clearly records the power-law continuum and very broad Balmer emission lines. Narrow emission lines dominate the second eigenspectrum. The …


Photocatalytic Activity Of Core/Shell Semiconductor Nanocrystals Featuring Spatial Separation Of Charges, Dimuthu Perera, Ryan Lorek, Rony S. Khnayzer, Pavel Moroz, Timothy O’Connor, Dmitry Khon, Geoffrey Diederich, Erich Kinder, Scott Lambright, Felix N. Castellano, Mikhail Zamkov Nov 2012

Photocatalytic Activity Of Core/Shell Semiconductor Nanocrystals Featuring Spatial Separation Of Charges, Dimuthu Perera, Ryan Lorek, Rony S. Khnayzer, Pavel Moroz, Timothy O’Connor, Dmitry Khon, Geoffrey Diederich, Erich Kinder, Scott Lambright, Felix N. Castellano, Mikhail Zamkov

Physics and Astronomy Faculty Publications

The present study investigates the photocatalytic activity of ZnSe/CdS core/shell semiconductor nanocrystals. These nanoparticles exhibit a spatial separation of photoinduced charges between the core and the shell domains, which makes them potentially viable for photocatalytic applications. Unfortunately, one of the excited charges remains inside the core semiconductor and thus cannot efficiently react with the external environment. Here, we explore this issue by investigating the mechanisms of hole extraction from the ZnSe core to the surface of the CdS shell. In particular, the effect of shell thickness in ZnSe/CdS core/shell nanocrystals on the ability of core-localized charges to perform oxidative reactions …


Pumping Up The [N I] Nebular Lines, Gary J. Ferland, W. J. Henney, C. R. O'Dell, R. L. Porter, P. A. M. Vanhoof, R. J. R. Williams Sep 2012

Pumping Up The [N I] Nebular Lines, Gary J. Ferland, W. J. Henney, C. R. O'Dell, R. L. Porter, P. A. M. Vanhoof, R. J. R. Williams

Physics and Astronomy Faculty Publications

The optical [N I] doublet near 5200 Å is anomalously strong in a variety of emission-line objects. We compute a detailed photoionization model and use it to show that pumping by far-ultraviolet (FUV) stellar radiation previously posited as a general explanation applies to the Orion Nebula (M42) and its companion M43; but, it is unlikely to explain planetary nebulae and supernova remnants. Our models establish that the observed nearly constant equivalent width of [N I] with respect to the dust-scattered stellar continuum depends primarily on three factors: the FUV to visual-band flux ratio of the stellar population, the optical properties …


Improved He I Emissivities In The Case B Approximation, R. L. Porter, Gary J. Ferland, P. J. Storey, M. J. Detisch Sep 2012

Improved He I Emissivities In The Case B Approximation, R. L. Porter, Gary J. Ferland, P. J. Storey, M. J. Detisch

Physics and Astronomy Faculty Publications

We update our prior work on the case B collisional-recombination spectrum of He i to incorporate ab initio photoionization cross-sections. This large set of accurate, self-consistent cross-sections represents a significant improvement in He i emissivity calculations because it largely obviates the piecemeal nature that has marked all modern works. A second, more recent set of ab initio cross-sections is also available, but we show that those are less consistent with bound-bound transition probabilities than our adopted set. We compare our new effective recombination coefficients with our prior work and our new emissivities with those by other researchers, and we conclude …


Residual Cooling And Persistent Star Formation Amid Active Galactic Nucleus Feedback In Abell 2597, G. R. Tremblay, C. P. O'Dea, S. A. Baum, T. E. Clarke, C. L. Sarazin, J. N. Bregman, F. Combes, M. Donahue, A. C. Edge, A. C. Fabian, Gary J. Ferland, B. R. Mcnamara, R. Mittal, J. B. R. Oonk, A. C. Quillen, H. R. Russell, J. S. Sanders, P. Salomé, G. M. Voit, R. J. Wilman, M. W. Wise Aug 2012

Residual Cooling And Persistent Star Formation Amid Active Galactic Nucleus Feedback In Abell 2597, G. R. Tremblay, C. P. O'Dea, S. A. Baum, T. E. Clarke, C. L. Sarazin, J. N. Bregman, F. Combes, M. Donahue, A. C. Edge, A. C. Fabian, Gary J. Ferland, B. R. Mcnamara, R. Mittal, J. B. R. Oonk, A. C. Quillen, H. R. Russell, J. S. Sanders, P. Salomé, G. M. Voit, R. J. Wilman, M. W. Wise

Physics and Astronomy Faculty Publications

New Chandra X-ray and Herschel Far-Infrared (FIR) observations enable a multiwavelength study of active galactic nucleus (AGN) heating and intracluster medium (ICM) cooling in the brightest cluster galaxy (BCG) of Abell 2597 (z= 0.0821). The new Chandra observations reveal the central ≲30 kpc X-ray cavity network to be more extensive than previously thought, and associated with enough enthalpy to theoretically inhibit the inferred classical cooling flow. Nevertheless, we present new evidence, consistent with previous results, that a moderately strong residual cooling flow is persisting at 4–8 per cent of the classically predicted rates in a spatially structured manner …


The Nuclear Infrared Emission Of Low-Luminosity Active Galactic Nuclei, R. E. Mason, E. Lopez-Rodriguez, C. Packham, A. Alonso-Herrero, N. A. Levenson, J. Radomski, C. Ramos Almeida, L. Colina, Moshe Elitzur, I. Aretxaga, P. F. Roche, N. Oi Jun 2012

The Nuclear Infrared Emission Of Low-Luminosity Active Galactic Nuclei, R. E. Mason, E. Lopez-Rodriguez, C. Packham, A. Alonso-Herrero, N. A. Levenson, J. Radomski, C. Ramos Almeida, L. Colina, Moshe Elitzur, I. Aretxaga, P. F. Roche, N. Oi

Physics and Astronomy Faculty Publications

We present high-resolution mid-infrared (MIR) imaging, nuclear spectral energy distributions (SEDs), and archival Spitzer spectra for 22 low-luminosity active galactic nuclei (LLAGNs; Lbol ≲ 1042 erg s–1). Infrared (IR) observations may advance our understanding of the accretion flows in LLAGNs, the fate of the obscuring torus at low accretion rates, and, perhaps, the star formation histories of these objects. However, while comprehensively studied in higher-luminosity Seyferts and quasars, the nuclear IR properties of LLAGNs have not yet been well determined. We separate the present LLAGN sample into three categories depending on their Eddington ratio and radio …


The Curious Conundrum Regarding Sulfur Abundances In Planetary Nebulae, R. B. C. Henry, Angela Speck, Amanda I. Karakas, Gary J. Ferland, Mason Maguire Mar 2012

The Curious Conundrum Regarding Sulfur Abundances In Planetary Nebulae, R. B. C. Henry, Angela Speck, Amanda I. Karakas, Gary J. Ferland, Mason Maguire

Physics and Astronomy Faculty Publications

Sulfur abundances derived from optical emission line measurements and ionization correction factors (ICFs) in planetary nebulae are systematically lower than expected for the objects' metallicities. We have carefully considered a large range of explanations for this "sulfur anomaly," including: (1) correlations between the size of the sulfur deficit and numerous nebular and central star properties, (2) ICFs which undercorrect for unobserved ions, (3) effects of dielectronic recombination on the sulfur ionization balance, (4) sequestering of S into dust and/or molecules, and (5) excessive destruction of S or production of O by asymptotic giant branch stars. It appears that all but …


Ion-By-Ion Cooling Efficiencies, Orly Gnat, Gary J. Ferland Mar 2012

Ion-By-Ion Cooling Efficiencies, Orly Gnat, Gary J. Ferland

Physics and Astronomy Faculty Publications

We present ion-by-ion cooling efficiencies for low-density gas. We use Cloudy (version 10.00) to estimate the cooling efficiencies for each ion of the first 30 elements (H-Zn) individually. We present results for gas temperatures between 104 and 108 K, assuming low densities and optically thin conditions. When nonequilibrium ionization plays a significant role the ionization states deviate from those that obtain in collisional ionization equilibrium (CIE), and the local cooling efficiency at any given temperature depends on specific nonequilibrium ion fractions. The results presented here allow for an efficient estimate of the total cooling efficiency for any ionic …


On The Unification Of Active Galactic Nuclei, Moshe Elitzur Feb 2012

On The Unification Of Active Galactic Nuclei, Moshe Elitzur

Physics and Astronomy Faculty Publications

The inevitable spread in properties of the toroidal obscuration of active galactic nuclei (AGNs) invalidates the widespread notion that type 1 and 2 AGNs are intrinsically the same objects, drawn randomly from the distribution of torus covering factors. Instead, AGNs are drawn preferentially from the distribution; type 2 are more likely drawn from the distribution higher end, type 1 from its lower end. Type 2 AGNs have a higher IR luminosity, lower narrow-line luminosity, and a higher fraction of Compton thick X-ray obscuration than type 1. Meaningful studies of unification statistics cannot be conducted without first determining the intrinsic distribution …


Star Formation In Self-Gravitating Disks In Active Galactic Nuclei. Ii. Episodic Formation Of Broad-Line Regions, Jian-Min Wang, Pu Du, Jack A. Baldwin, Jun-Qiang Ge, Chen Hu, Gary J. Ferland Feb 2012

Star Formation In Self-Gravitating Disks In Active Galactic Nuclei. Ii. Episodic Formation Of Broad-Line Regions, Jian-Min Wang, Pu Du, Jack A. Baldwin, Jun-Qiang Ge, Chen Hu, Gary J. Ferland

Physics and Astronomy Faculty Publications

This is the second in a series of papers discussing the process and effects of star formation in the self-gravitating disk around the supermassive black holes in active galactic nuclei (AGNs). We have previously suggested that warm skins are formed above the star-forming (SF) disk through the diffusion of warm gas driven by supernova explosions. Here we study the evolution of the warm skins when they are exposed to the powerful radiation from the inner part of the accretion disk. The skins initially are heated to the Compton temperature, forming a Compton atmosphere (CAS) whose subsequent evolution is divided into …


Rovibrationally Resolved Direct Photodissociation Through The Lyman And Werner Transitions Of H2 For Fuv/X-Ray-Irradiated Environments, C. D. Gay, N. P. Abel, R. L. Porter, P. C. Stancil, Gary J. Ferland, G. Shaw, P. A. M. Vanhoof, R. J. R. Williams Jan 2012

Rovibrationally Resolved Direct Photodissociation Through The Lyman And Werner Transitions Of H2 For Fuv/X-Ray-Irradiated Environments, C. D. Gay, N. P. Abel, R. L. Porter, P. C. Stancil, Gary J. Ferland, G. Shaw, P. A. M. Vanhoof, R. J. R. Williams

Physics and Astronomy Faculty Publications

Using ab initio potential curves and dipole transition moments, cross-section calculations were performed for the direct continuum photodissociation of H2 through the B1Σ+u ← X1Σ+g (Lyman) and C1Πu ← X1Σ+g (Werner) transitions. Partial cross-sections were obtained for wavelengths from 100 Å to the dissociation threshold between the upper electronic state and each of the 301 bound rovibrational levels v''J'' within the ground electronic state. The resulting cross-sections are incorporated into three representative classes of interstellar gas models: diffuse clouds, photon-dominated regions, and …


Photocatalytic Hydrogen Production At Titania-Supported Pt Nanoclusters That Are Derived From Surface-Anchored Molecular Precursors, Rony S. Khnayzer, Lucas B. Thompson, Mikhail Zamkov, Shane Ardo, Gerald J. Meyer, Catherine J. Murphy, Felix N. Castellano Jan 2012

Photocatalytic Hydrogen Production At Titania-Supported Pt Nanoclusters That Are Derived From Surface-Anchored Molecular Precursors, Rony S. Khnayzer, Lucas B. Thompson, Mikhail Zamkov, Shane Ardo, Gerald J. Meyer, Catherine J. Murphy, Felix N. Castellano

Physics and Astronomy Faculty Publications

Degussa P-25 TiO2 bearing surface-anchored Pt(dcbpy)Cl-2 [dcbpy = 4,4'-dicarboxylic acid-2,2'-bipyridine] prepared with systematically varied surface coverage produced Pt-0 nanoparticles under bandgap illumination in the presence of methanol hole scavengers. Energy-dispersive X-ray spectroscopy confirmed the presence of elemental platinum in the newly formed nanoparticles during scanning transmission electron microscopy (STEM) eleriments. According to the statistical analysis of numerous STEM images, the Pt-0 nanoclusters were distributed in a segregated manner throughout the titania surface, ranging in size from 1 to 3 nm in diameter. The final achieved nanoparticle size and net hydrogen production were determined as a function of the Pt(dcbpy)Cl-2 surface …


A Possible Detection Of Occultation By A Proto-Planetary Clump In Gm Cephei, W. P. Chen, S. C.-L. Hu, R. Errmann, Ch. Adam, Laurence A. Marschall Jan 2012

A Possible Detection Of Occultation By A Proto-Planetary Clump In Gm Cephei, W. P. Chen, S. C.-L. Hu, R. Errmann, Ch. Adam, Laurence A. Marschall

Physics and Astronomy Faculty Publications

GM Cep in the young (~ 4 Myr) open cluster Trumpler 37 has been known to be an abrupt variable and to have a circumstellar disk with very active accretion. Our monitoring observations in 2009–2011 revealed the star to show sporadic ?are events, each with brightening of . 0.5 mag lasting for days. These brightening events, associated with a color change toward the blue, should originate from an increased accretion activity. Moreover, the star also underwent a brightness drop of ~ 1 mag lasting for about a month, during which the star became bluer when fainter. Such brightness drops seem …


Hydrogen Two-Photon Continuum Emission From The Horseshoe Filament In Ngc 1275, R. M. Johnstone, R. E.A. Canning, A. C. Fabian, Gary J. Ferland, Matt Lykins, R. L. Porter, P. A.M. Vanhoof, R. J.R. Williams Jan 2012

Hydrogen Two-Photon Continuum Emission From The Horseshoe Filament In Ngc 1275, R. M. Johnstone, R. E.A. Canning, A. C. Fabian, Gary J. Ferland, Matt Lykins, R. L. Porter, P. A.M. Vanhoof, R. J.R. Williams

Physics and Astronomy Faculty Publications

Far-ultraviolet emission has been detected from a knot of Hα emission in the Horseshoe filament, far out in the NGC 1275 nebula. The flux detected relative to the brightness of the Hα line in the same spatial region is very close to that expected from hydrogen two-photon continuum emission in the particle heating model of Ferland et al. if reddening internal to the filaments is taken into account. We find no need to invoke other sources of far-ultraviolet emission such as hot stars or emission lines from C IV in intermediate-temperature gas to explain these data.


Intervening Broad-Line Region Clouds' Effects On The Optical/Ultraviolet Spectrum, Ye Wang, Gary J. Ferland, Chen Hu, Jian-Min Wang, Pu Du Jan 2012

Intervening Broad-Line Region Clouds' Effects On The Optical/Ultraviolet Spectrum, Ye Wang, Gary J. Ferland, Chen Hu, Jian-Min Wang, Pu Du

Physics and Astronomy Faculty Publications

Recent X-ray observations of Mrk 766 suggest that broad emission-line region clouds cross our line of sight and produce variable X-ray absorption. Here we investigate what optical/ultraviolet (UV) spectroscopic features would be produced by such ‘intervening broad-line region (BLR) clouds' (IBC) crossing our line of sight to the accretion disc, the source of the optical/UV continuum. Although the emission spectrum produced by intervening clouds is identical to the standard BLR model, they may produce absorption features on the optical or UV continuum. Single clouds will have little effect on the optical/UV spectrum because BLR clouds are likely to be much …


H2 Temperatures In The Crab Nebula, E. D. Loh, J. A. Baldwin, Gary J. Ferland, Z. K. Curtis, C. T. Richardson, A. C. Fabian, P. Salomé Jan 2012

H2 Temperatures In The Crab Nebula, E. D. Loh, J. A. Baldwin, Gary J. Ferland, Z. K. Curtis, C. T. Richardson, A. C. Fabian, P. Salomé

Physics and Astronomy Faculty Publications

We used K-band spectra to measure the H2 excitation temperatures in six molecular knots associated with the filaments in the Crab Nebula. The temperatures are quite high – in the range T∼ 2000–3000 K, just below the H2 dissociation temperature. This is the temperature range over which the H2 1–0 S(1) line at λ2.121 μm has its maximum emissivity per unit mass, so there may be many additional H2 cores with lower temperatures that are too faint to detect. We also measured the electron density in adjacent ionized gas, which on the assumption of …


Near Infrared Hydrogen Emission Line Ratios As Diagnostics Of The Broad Emission Line Region, Andrea J. Ruff, David J. E. Floyd, Kirk T. Korista, Rachel L. Webster, Ryan Lucian Porter, Gary J. Ferland Jan 2012

Near Infrared Hydrogen Emission Line Ratios As Diagnostics Of The Broad Emission Line Region, Andrea J. Ruff, David J. E. Floyd, Kirk T. Korista, Rachel L. Webster, Ryan Lucian Porter, Gary J. Ferland

Physics and Astronomy Faculty Publications

Broad emission line flux ratios are a powerful diagnostic of the physical conditions of the broad-line region gas in Active Galactic Nuclei. With recent advances in infrared spectroscopy, previously unstudied emission lines provide a new means to investigate the physical nature of the BELR gas. The hydrogen emission lines are particularly sensitive to the upper limits of both the radius from the central ionising source and the number density of the gas. Using an existing subset of near-infrared quasar spectra from the Glikman et al. (2006) sample [1] together with Cloudy photoionization simulations, we confirm the Locally Optimally emitting Cloud …