Physical Sciences and Mathematics Commons^™

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The corrosion of structural materials is a major concern for the use of lead-bismuth eutectic (LBE) systems for nuclear applications such as in transmuter targets or fast reactors. Corrosion in liquid metal systems can occur through various processes, including, for example, dissolution, formation of inter-metallic compounds at the interface, and penetration of liquid metal along grain boundaries. Predicting the rate of these processes depends on numerous system operational factors: temperature, system geometry, thermal gradients, solid and liquid compositions, and velocity of the liquid metal, to name a few. Corrosion, along with mechanical and/or hydraulic factors, often contributes to component failure. …

Modeling Of Corrosion In Oxygen Controlled Lead Bismuth Eutectic Systems With The Coupling Of Chemical Kinetics And Hydrodynamics, Samir Moujaes, Yitung Chen, Kanthi Kiran Dasika, Chao Wu

Transmutation Sciences Materials (TRP)

Objectives:

• To simulate a 2-D model of the Materials Test Loop by approximating it to be a toroid with a pie cross section for the purpose of comparing the simulated results with the analytical results.
• The temperature and concentration profiles on the wall boundaries imposed are similar to the actual test model.
• Geometry effects have great influence on local corrosion rate.
• A 2-D benchmark problem and a sudden expansion case are studied which show good consistency to analytical solution.
• Results from 2-D sudden expansion problem are similar to experimental data obtained by other researchers.

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics-Task V: Final Report -Phase I 09/01/2001-08/30/2002, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The Lead-Bismuth eutectic (LBE) has been determined from previous experimental studies by the Russians and the European scientific community to be a potential material that can be used as a spallation target and coolant for the AAA proposed application. Properly controlling the oxygen content in LBE can drastically reduce the LBE corrosion to structural steels. However, existing knowledge of material corrosion performance was obtained from point-wise testing with only very sparse experimental data. Scientists have noticed that the concentration of oxygen dissolved in the liquid alloy could control the corrosion rate of steels exposed to Pb or Pb-Bi. At high …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics: Quarterly Progress Report 03/16/02- 06/15/02, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The Lead-Bismuth eutectic (LBE) has been determined from previous experimental studies by the Russians and the European scientific community to be a potential material that can be used as a spallation target and coolant for the AAA proposed application. Properly controlling the oxygen content in LBE can drastically reduce the LBE corrosion to structural steels. However, existing knowledge of material corrosion performance was obtained from point-wise testing with very limited density. Scientists have noticed that the concentration of oxygen dissolved in the liquid alloy could control the corrosion rate of steels exposed to Pb or Pb-Bi. At high oxygen concentration, …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics-Phase Two, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The proposed work will combine chemical kinetics and hydrodynamics in target and test-loop lead-bismuth eutectic (LBE) systems to model system corrosion effects. This approach will result in a predicative tool that can be validated with corrosion test data, used to systematically design tests and interpret the results, and provide guidance for optimization in LBE system designs. The task includes two subtasks. The first subtask is to try to develop the necessary predictive tools to be able to predict the levels of oxygen and corrosion products close to the boundary layer through the use of Computational Fluid Dynamics (CFD) modeling. The …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics: Quarterly Progress Report 11/16/01- 2/15/02, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The Lead-Bismuth eutectic (LBE) has been determined from previous experimental studies by the Russians and the European scientific community to be a potential material that can be used as a spallation target and coolant for the AAA proposed application.

Properly controlling the oxygen content in LBE can drastically reduce the LBE corrosion to structural steels. However, existing knowledge of material corrosion performance was obtained from point-wise testing with very limited density. The transport of oxygen and corrosion products, their interaction and variation of corrosion/precipitation along the flow are not well understood.

The first subtask of this project involves using a …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics: Task V 4th Quarterly Report, Samir Moujaes

Transmutation Sciences Materials (TRP)

The project is moving on target with the newly realigned objective set for the Phase I. Through close communications with Dr. Li and Dr. Jinsuo Zhang from LANL a realignment of the simulation work has been recommended. The reason for that is the vendor of STAR-CD/CHEMKIN had not perfected yet the final coupling of the post processing of output for any potential surface chemistry reaction taking place on the inside pipe surface of the LBE loop. This is because the coupling of CHEMKIN and STAR-CD has been done fairly recently.

Our final effort has been to generate using an innovative …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

Many of the international efforts to develop transmutation technology, including the U.S., Russian, and European scientific communities, have determined that lead bismuth eutectic (LBE) is a potential material for use as a both a spallation target and a coolant. To exploit this potential, a more thorough understanding of the effect and rates of corrosion on steels, particularly non-Russian alloys, inside the LBE systems is required. Properly controlling the oxygen content in LBE systems has been observed to drastically reduce the corrosion of structural steels in LBE. However, the transport of oxygen and formation of corrosion products is not well understood; …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics: Quarterly Progress Report August 16,2001- November 15, 2001, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The Lead-Bismuth eutectic (LBE) has been determined from previous experimental studies by the Russians and the European scientific community to be a potential material that can be used as a spallation target and coolant for the AAA proposed application.

Properly controlling the oxygen content in LBE can drastically reduce the LBE corrosion to structural steels. However, existing knowledge of material corrosion performance was obtained from point-wise testing with very limited density. The transport of oxygen and corrosion products, their interaction and variation of corrosion/precipitation along the flow are not well understood.

The first subtask of this project involves using a …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The proposed work will combine chemical kinetics and hydrodynamics in target and test-loop lead-bismuth eutectic (LBE) systems to model system corrosion effects. This approach will result in a predicative tool that can be validated with corrosion test data, used to systematically design tests and interpret the results, and provide guidance for optimization in LBE system designs. The task includes of two subtasks. The first subtask is to try to develop the necessary predictive tools to be able to predict the levels of oxygen and corrosion products close to the boundary layer through the use of Computational Fluid Dynamics (CFD) modeling. …

Time Series Energy Production In Smoothed Particle Hydrodynamics Accretion Disks: Superhumps In The Am Canum Venaticorum Stars, James C. Simpson, Matt A. Wood

Aerospace, Physics, and Space Science Faculty Publications

The energy production time series of our purely hydrodynamic accretion disk simulations display remarkable similarities with the observed light curves of dwarf novae superhumps in general and the AM CVn stars in particular. The superhump period excess as a function of mass ratio agrees well with earlier theoretical and numerical results, and the amplitudes and relative phases of the harmonics in the power spectra agree well with the observations. The morphology of the mean pulse profile appears to be a useful predictor of system mass ratio. Our modified smoothed particle hydrodynamics code time symmetrizes the interparticle forces when individual time …

The Effect Of Convection On A Propagating Front With A Liquid Product: Comparison Of Theory And Experiments, B. Mccaughey, John A. Pojman, C. Simmons, V.A. Volpert

Faculty Publications

This work is devoted to the investigation of propagating polymerization fronts converting a liquid monomer into a liquid polymer. We consider a simplified mathematical model which consists of the heat equation and equation for the depth of conversion for one-step chemical reaction and of the Navier-Stokes equations under the Boussinesq approximation. We fulfill the linear stability analysis of the stationary propagating front and find conditions of convective and thermal instabilities. We show that convection can occur not only for ascending fronts but also for descending fronts. Though in the latter case the exothermic chemical reaction heats the cold monomer from …

Cosmological Simulations With Scale-Free Initial Conditions. I. Adiabatic Hydrodynamics, Jm Owen, Dh Weinberg, Ae Evrard, L Hernquist, N Katz

Astronomy Department Faculty Publication Series

We analyze hierarchical structure formation based on scale-free initial conditions in an Einstein-de Sitter universe, including a baryonic component with Ω_bary = 0.05. We present three independent, smoothed particle hydrodynamics (SPH) simulations, performed at two resolutions (32³ and 64³ dark matter and baryonic particles) and with two different SPH codes (TreeSPH and P3MSPH). Each simulation is based on identical initial conditions, which consist of Gaussian-distributed initial density fluctuations that have a power spectrum P(k) k^-1. The baryonic material is modeled as an ideal gas subject only to shock heating and adiabatic heating …

Generalization Kdv Equation For Fluid Dynamics And Quantum Algebras, Andrei Ludu

Andrei Ludu

No abstract provided.

A Numerical Analysis Of Smoothed Particle Hydrodynamics, David A. Fulk

Theses and Dissertations

This dissertation studies the numerical method of Smoothed Particle Hydrodynamics SPH as a technique for solving systems of conservation equations. The research starts with a detailed consistency analysis of the method. Higher dimensions and non-smooth functions are considered in addition to the smooth one dimensional case. A stability analysis is then performed. Using a linear technique, an instability is found. Solutions are proposed to resolve the instability. Also a total variation stability analysis is performed leading to a monotone form of SPH. The concepts of consistency and stability are then used in a convergence proof. This proof uses lemmas derived …

Transonic Inviscid Disc Flows In The Schwarzschild Metric – I, Menas Kafatos, Ruixin Yang

Mathematics, Physics, and Computer Science Faculty Articles and Research

The coupled hydrodynamic equations governing equatorial flows applicable to inviscid disc accretion in the Schwarzschild metric are solved analytically and numerically. Here, we concentrate on the transonic solutions, that represent physically allowed accretion on to black holes. A polytropic equation linking gas pressure and density is assumed, and solutions are obtained for different conditions, such as isothermal and adiabatic gas flows. The dependence of those solutions on the angular momentum is explored. Under certain conditions, when there exist multiple possible sonic points, the numerical simulation automatically zeros in to the unique transonic solution passing through one of the sonic points.

Selective Decay And Coherent Vortices In Two-Dimensional Incompressible Turbulence, William H. Matthaeus, W. Troy Stribling, Daniel Martinez, Sean Oughton, David Montgomery

Dartmouth Scholarship

Numerical solution of two-dimensional incompressible hydrodynamics shows that states of a near-minimal ratio of enstrophy to energy can be attained in times short compared with the flow decay time, confirming the simplest turbulent selective decay conjecture, and suggesting that coherent vortex structures do not terminate nonlinear processes. After all possible vortex mergers occur, the vorticity attains a particlelike character, suggested by the late-time similarity of the streamlines to Ewald potential contours.

Cluster As Solitons On The Nuclear Surface, Andrei Ludu

Andrei Ludu

No abstract provided.

The Effects Of Variable Parameters On The Behavior Of Initial Wind Waves, Glen Harvey Wheless

OES Theses and Dissertations

The generation mechanism of short wind waves is generally thought to be a viscous instability at the air-sea interface. The short, regular waves arising from a sudden wind on a still water surface have a dispersion relation which is characteristic of gravity-capillary waves. The effects of variable surface tension, viscosity and shear flow parameters on the behavior of these waves were studied.

A numerical hydrodynamic stability analysis of a coupled laminar shear flow was accomplished by integrating a transformed version of the Orr-Sommerfeld equation, subject to the boundary conditions at a two-fluid interface. Unbounded growth problems usually encountered in a …

Calculated Current Velocity Data, U.S. Bureau Of Reclamation

Publications (WR)

Data collected at various stations around the Lake Mead vicinity. Air temperature, lake elevation, weather, and wind velocity is recorded, as well as the depth, magnitude, resolved angle, and bearing of the water currents.

Physical Data, Anon.

Publications (WR)

Data collected at various stations around the Lake Mead vicinity. Air temperature, lake elevation, weather, and wind velocity is recorded, as well as the depth, temperature, oxygen, conductivity, and pH. Standard.

Use Of Hydroelectric Dams To Control Evaporation And Salinity In The Colorado River System, Larry J. Paulson

Publications (WR)

The main stem reservoirs on the Colorado River comprise one of the largest and most heavily used freshwater bodies in the nation. These reservoirs (Lake Powell, Lake Mead, Lake Mohave and Lake Havasu) can store up to 53,590,400 acre-feet of water at their maximum capacities. Nonetheless, local water shortages still exist in some areas of the Colorado River Basin. There is also concern that salt concentrations are approaching levels that could severely affect municipal and agricultural uses. Water shortages will become even more acute as demands for water increase with continued urban and agricultural development in the basin.

Water conservation …

Development, Verification And Use Of Methods To Model Chemical And Thermal Processes For Lakes Mead And Powell, John Eric Edinger, Edward M. Buchak, Joseph S. Norton, Bureau Of Reclamation

Publications (WR)

Analysis and development of carbonate-bicarbonate chemical subroutine.

Influence Of Las Vegas Wash Density Current On Nutrient Availability And Phytoplankton Growth In Lake Mead, John R. Baker, Larry J. Paulson

Publications (WR)

Density currents are commonly formed in reservoirs because of temperature or salinity induced density differences between inflowing and receiving waters. Anderson and Pritchard (1951) were among the first to demonstrate this in their investigations of density currents in Lake Mead. They found that the Colorado River formed an underflow in Lake Mead during the winter, an overflow in the spring and an interflow in the summer and fall. Wunderlich and Elder (1973) have since described the hydromechanics of these types of flow patterns, and density currents have been reported for several other large reservoirs (Carmack et al. 1979, Johnson and …

Nutrient Interactions Among Reservoirs On The Colorado River, Larry J. Paulson, John R. Baker

Publications (WR)

Interactions among physical, chemical and biological processes in reservoirs can significantly alter the characteristics of the discharge (Neel 1963, Wright 1967, Hannan 1979) that, in turn, can influence the ecology of the river downstream .(Ward and Stanford 1979). Investigations of the Colorado River, system reveal that reservoir-induced changes in the river can also affect downstream reservoirs. The formation of Lake Powell, in 1963 was accompanied by reductions in suspended sediment and nutrient loading and changes in the seasonal temperature and discharge cycles of the Colorado River. In this paper, we evaluate how these changes have influenced the nutrient and trophic …

Evaluation Of Impacts Associated With Reregulation Of Water Levels In Lake Mohave, Larry J. Paulson, John R. Baker, U.S. Water And Power Resources Service

Publications (WR)

The U.S. Water and Power Resources Service is considering reregulating Lake Mohave water levels to increase the net power benefit from Hoover Dam. Reregulation will not increase the generation capacity of the Hoover powerplant but it will enable the plant operation to be increased when the energy has greater monetary value. Energy generated at different times of the year has different market value, the highest being in January-March and July- September. By generating more power during these periods more net monetary benefit can be derived from Hoover Dam. The total volume of water released from Hoover Dam over an annual …

Evaluation Of Possible Temperature Fluctuations From Proposed Power Modifications At Hoover Dam, Larry J. Paulson, John R. Baker, U.S. Water And Power Resources Service

Publications (WR)

There are several planned alternatives for increasing the generation capacity of Hoover Dam to help meet peak power demands. These alternatives include: (a) uprating the existing generating units, (b) replacing or adding one or more generating units and (c) adding reversible pumped-storage hydroelectric units. Since the existing generators are at the end of their economic life and have to be replaced, their uprating has been scheduled as routine maintenance. This will increase the generating capacity of the Hoover Dam powerplant from 1240 MW to 1810 MW, but the anticipated capacity for meeting power demand is 2300 MW. Therefore, modifications (alternatives …

Influence Of Dredging And High Discharge On The Ecology Of Black Canyon, Larry J. Paulson, Theron G. Miller, John R. Baker, U.S. Water And Power Resources Service

Publications (WR)

The Water and Power Resources Service is considering dredging in Black Canyon to create a larger forebay to accommodate higher peak discharges and reverse flows for proposed modifications to Hoover Dam.

The Black Canyon area from Hoover Dam to Willow Beach supports a heavily utilized trout fishery and is important habitat for the razorback sucker (Xyrauchen texanus) and possibly bonytail chub (Gila elegans).

The Water and Power Resources Service initiated this investigation to determine what effect dredging and higher peak-discharges would have on the ecology of Black Canyon.

The Limnological Status Of Lake Mead And Lake Mohave Under Present And Future Powerplant Operations Of Hoover Dam, Larry J. Paulson, John R. Baker, James E. Deacon, U.S. Water And Power Resources Service

Publications (WR)

The ever-increasing demand for energy in the southwest has led to a search for additional sources of power generation. Coal-fired powerplants currently provide most of the baseline energy in the southwest, but this must be supplemented with hydroelectric power during periods of peak demand. In order to provide additional peaking power, the U.S. Bureau of Reclamation is considering a number of projects to modify existing hydroelectric facilities, or add new facilities in the Lake Mead Recreation Area.

The Hoover Powerplant Modification Feasibility Investigation was authorized by Congress on December 16, 1975 to determine the feasibility of: (i) adding one or …

Potential Use Of Hydroelectric Facilities For Manipulating The Fertility Of Lake Mead, Larry J. Paulson, John R. Baker, James E. Deacon

Publications (WR)

Analysis of historical nutrient data for Lake Mead indicates that the fertility of the reservoir has decreased which may be the cause for a corresponding decline in the largemouth bass population. However, it appears that fertility can be manipulated by altering the operation of the dam. The depletion of nutrients in the euphotic zone by phytoplankton and subsequent accumulation in the hypolimnion during summer and fall provide a natural nutrient gradient from which water of varying fertility can be drawn for discharge. This combined with alterations in the depth or seasonal pattern of discharge can possibly be used to enhance …