Physical Sciences and Mathematics Commons^™

Impact Of Sea Surface Temperature And Surface Air Temperature On Maximizing Typhoon Rainfall: Focusing On Typhoon Maemi In Korea, Jeonghyeon Choi, Jeonghoon Lee, Sangdan Kim

Civil and Environmental Engineering Faculty Publications

In this study, the effects of surface air temperature (SAT) and sea surface temperature (SST) changes on typhoon rainfall maximization are analysed. Based on the numerically reproduced Typhoon Maemi, this study tried to maximize the typhoon-induced rainfall by increasing the amount of saturated water vapour in the atmosphere and the amount of water vapour entering the typhoon. Using the Weather Research and Forecasting (WRF) model, which is one of the regional climate models (RCMs), the rainfall simulated by WRF while increasing the SAT and SST to various sizes at initial conditions and boundary conditions of the model was analysed. As …

Evaluation Of Naturally Occurring And Anthropogenic Contamination In Missouri Streams, Christina Jane Sehrt

Masters Theses

"The goal of this study is to observe the values and variability of water quality parameters and benthic macroinvertebrates in watersheds with very little anthropogenic impact and to compare these values with those acquired in watersheds with more anthropogenic impact. The following five HUC 12-digit watersheds had very little anthropogenic impact and were considered "pristine": Rogers Creek, Mill Creek, Middle West Fork-Black River, Bee Fork, and Ottery Creek. Five largely urban sub-basins were also considered; these basins are: Grand Glaize Creek, Glaize Creek, Sugar Creek, Hominy Creek, and Grindstone Creek. For each watershed, both water quality parameters and benthic macroinvertebrates …

Reprocessing And Comparison Of The 2 Hz And 10 Hz Vertical Component Seismic Data Of The Blackfoot 3c-2d Survey, Mete Sarikaya

Masters Theses

"The Blackfoot seismic 3C-2D data were obtained from the Consortium for Research in Elastic Wave Exploration Seismology (CREWES) Project in 1995. The seismic data acquisition was performed in the Blackfoot Field, which is around 15 km southeast of Strathmore, Alberta. The 4 Hz and 10 Hz vertical component data are reprocessed to increase the quality and resolution of the seismic images. The Glauconitic sand reservoir at approximately 1.1 s, and a strong reflection about at 1.5 s are the focuses of the study.

The processing procedure includes different parameters and methods to obtain the best seismic sections of 2 Hz …

Quasi-Likelihood Ratio Tests For Homoscedasticity Of Variance In Linear Regression, Lili Yu, Varadan Sevilimedu, Robert Vogel, Hani Samawi

Biostatistics, Epidemiology & Environmental Health Sciences: Faculty Publications

Two quasi-likelihood ratio tests are proposed for the homoscedasticity assumption in the linear regression models. They require few assumptions than the existing tests. The properties of the tests are investigated through simulation studies. An example is provided to illustrate the usefulness of the new proposed tests.

The Structural Information Filtered Features Potential For Machine Learning Calculations Of Energies And Forces Of Atomic Systems., Jorge Arturo Hernandez Zeledon

Graduate Theses, Dissertations, and Problem Reports (ETD)

In the last ten years, machine learning potentials have been successfully applied to the study of crystals, and molecules. However, more complex materials like clusters, macro-molecules, and glasses are out reach of current methods. The input of any machine learning system is a tensor of features (the most universal type are rank 1 tensors or vectors of features), the quality of any machine learning system is directly related to how well the feature space describes the original physical system. So far, the feature engineering process for machine learning potentials can not describe complex material. The current methods are highly inefficient …

Deep Learning For Image Restoration And Robotic Vision, Yixin Du

Graduate Theses, Dissertations, and Problem Reports (ETD)

Traditional model-based approach requires the formulation of mathematical model, and the model often has limited performance. The quality of an image may degrade due to a variety of reasons: It could be the context of scene is affected by weather conditions such as haze, rain, and snow; It's also possible that there is some noise generated during image processing/transmission (e.g., artifacts generated during compression.). The goal of image restoration is to restore the image back to desirable quality both subjectively and objectively. Agricultural robotics is gaining interest these days since most agricultural works are lengthy and repetitive. Computer vision is …

The Global Disinformation Order: 2019 Global Inventory Of Organised Social Media Manipulation, Samantha Bradshaw, Philip N. Howard

Copyright, Fair Use, Scholarly Communication, etc.

Executive Summary

Over the past three years, we have monitored the global organization of social media manipulation by governments and political parties. Our 2019 report analyses the trends of computational propaganda and the evolving tools, capacities, strategies, and resources.

1. Evidence of organized social media manipulation campaigns which have taken place in 70 countries, up from 48 countries in 2018 and 28 countries in 2017. In each country, there is at least one political party or government agency using social media to shape public attitudes domestically.

2.Social media has become co-opted by many authoritarian regimes. In 26 countries, computational propaganda …

Viewing The Eclipse From 109,000 Feet And The Road To Get There, Kendra Sibbernsen, Michael Sibbernsen

Department of Physics and Astronomy: Faculty Publications

The NASA Nebraska High Altitude Ballooning Program was one of 55 teams across the nation to fly weather balloons within the August 21st Total Solar Eclipse and stream live video to the internet. On this day, the Nebraska team launched three high altitude balloons to take scientific measurements and take photos and video ofthe Moon's shadow falling on the Earth. These balloons included the NASA common video streaming payload as well as experiments from students at Metropolitan Community College and from faculty and students at Omaha Public Schools. The launches took place at the "Gem Over the Prairie" event at …

Enhanced Flexoelectricity At Reduced Dimensions Revealed By Mechanically Tunable Quantum Tunnelling, Saikat Das, Bo Wang, Tula R. Paudel, Sung Min Park, Evgeny Y. Tsymbal, Long-Qing Chen, Daesu Lee, Tae Won Noh

Department of Physics and Astronomy: Faculty Publications

Flexoelectricity is a universal electromechanical coupling effect whereby all dielectric materials polarise in response to strain gradients. In particular, nanoscale flexoelectricity promises exotic phenomena and functions, but reliable characterisation methods are required to unlock its potential. Here, we report anomalous mechanical control of quantum tunnelling that allows for characterising nanoscale flexoelectricity. By applying strain gradients with an atomic force microscope tip, we systematically polarise an ultrathin film of otherwise nonpolar SrTiO₃, and simultaneously measure tunnel current across it. The measured tunnel current exhibits critical behaviour as a function of strain gradients, which manifests large modification of tunnel barrier …

Duality And Free Energy Analyticity Bounds For Few-Body Ising Models With Extensive Homology Rank, Yi Jiang, Ilya Dumer, Alexey Kovalev, Leonid Pryadko

Department of Physics and Astronomy: Faculty Publications

We consider pairs of few-body Ising models where each spin enters a bounded number of interaction terms (bonds) such that each model can be obtained from the dual of the other after freezing k spins on large-degree sites. Such a pair of Ising models can be interpreted as a two-chain complex with k being the rank of the first homology group. Our focus is on the case where k is extensive, that is, scales linearly with the number of bonds n. Flipping any of these additional spins introduces a homologically nontrivial defect (generalized domain wall). In the presence of …

Molecular Symmetry-Mixed Dichroism In Double Photoionization Of H2, Jean Marcel Ngoko Djiokap, Alexei V. Meremianin, N. L. Manakov, L. B. Madsen, S. X. Hu, Anthony F. Starace

Anthony F. Starace Publications

Dichroism in double photoionization of H₂ molecules by elliptically polarized extreme ultraviolet pulses is formulated analytically as a sum of atomiclike dichroism (AD) and molecular symmetry-mixed dichroism (MSMD) terms. The MSMD originates from an interplay of ¹Σ⁺_u and ¹Π⁺_u continuum molecular ionization amplitudes. For detection geometries in which the AD vanishes, numerical results for the sixfold differential probabilities for opposite pulse helicities show that the MSMD is significant in the electron momentum and angular distributions and is controllable by the ellipticity.

Unusual Perpendicular Anisotropy In Co2Tisi Films, Yunlong Jin, Shah R. Valloppilly, Parashu R. Kharel, Rohit Pathak, Arti Kashyap, Ralph Skomski, David J. Sellmyer

David Sellmyer Publications

Thin films of Co₂TiSi on MgO are investigated experimentally and theoretically. The films were produced by magnetron sputtering on MgO(001) and have a thickness of about 100 nm. As bulk Co₂TiSi, they crystallize in the normal cubic Heusler (L2₁) structure, but the films are slightly distorted (c/a = 1.0014) and contain some antisite disorder. The films exhibit a robust perpendicular anisotropy of 0.5 MJ m⁻³. This result is surprising for several reasons. First, surface and interface anisotropies are too small to explain perpendicular anisotropy in such rather thick …

Aba Rpte Conservation Easement Task Force Report: Recommendations Regarding Conservation Easements And Federal Tax Law, W. William Weeks

Articles by Maurer Faculty

Authors' Synopsis: In October 2015, the American Bar Association's Real Property, Trust and Estate Law (RPTE) section convened a Conservation Easement Task Force. The objective of the Task Force was to provide recommendations regarding federal tax law as it relates to conservation easements. This Report is the culmination of the Task Force's work. Part I of the Report is an Executive Summary of the Task Force's recommendations. Part II provides the background necessary to understand the Task Force's recommendations. Part III briefly sets forth the Task Force's comments on the Tax Cuts and Jobs Act of 2017 as it relates …

Longitudinal Phonon Plasmon Mode Coupling In Β-Ga2O3, Mathias Schubert, Alyssa Mock, Rafal Korlacki, Sean Knight, Zbigniew Galazka, Günther Wagner, Virginia Wheeler, Marko Tadjer, Ken Goto, Vanya Darakchieva

Department of Electrical and Computer Engineering: Faculty Publications

In this letter, we investigate a set of n-type single crystals of monoclinic symmetry β-Ga₂O₃ with different free electron concentration values by generalized far infrared and infrared spectroscopic ellipsometry. In excellent agreement with our previous model prediction, we find here by experiment that longitudinal-phonon-plasmon coupled modes are polarized either within the monoclinic plane or perpendicular to the monoclinic plane. As predicted, all modes change the amplitude and frequency with the free electron concentration. The most important observation is that all longitudinal-phonon-plasmon coupled modes polarized within the monoclinic plane continuously change their direction as a function of …

Signature Sustainability Earth Day Dish, Nancy Garmer

Evans Library Publications

Evans Library celebrates Earth Day each year in partnership with the Student Organization for Sustainability Action (SOSA) and the Student Government Association (SGA) as part of a week‑long schedule of campus events. The Library shares equal billing on Earth Week promotional materials and caps off the week with a Library After Hours event on Friday evening. Earth Day offers an important opportunity to collaborate with campus organizations and highlight sustainability initiatives taking place across the university. As a central academic and community space, the Library plays a vital role in supporting and promoting sustainability efforts, making Earth Day a prescribed …

The Inductive Effect In Organic Chemistry, Charles A. Kingsbury

Department of Chemistry: Faculty Publications

The subtle difference between the successive polarization model and the flow of electrons through sigma bonds is explored, as well as the alternating charge model of Pople and the pervasive field model. The present paper is concerned with the ability of alkyl groups to serve as sigma inductive electron donors.

Molecular Insights Into Organic Particulate Formation, Manoj Kumar, Emily Burrell, Jason C. Hansen, Joseph S. Francisco

Department of Chemistry: Faculty Publications

Carboxylic acids have been detected in particles collected in various regions of the world. Here, we use experiments and Born–Oppenheimer molecular dynamics simulations to better understand the mechanism of particle formation from gas phase mixtures of formic acid (HCOOH), (CH₃)₃N, and water vapor. A flow reaction cell coupled to two scanning mobility particle sizers has been used to measure particle size, absolute number of particles and kinetics of particle formation. Experimental results show that the addition of (CH₃)₃N to a mixture of HCOOH and water vapor results in a dramatic increase in …

In Situ Monitoring Of Linear Rgd-Peptide Bioconjugation With Nanoscale Polymer Brushes, Evmorfia Psarra, Ulla Konig, Martin Muller, Eva Bittrich, Klaus-Jochen Eichhorn, Petra B. Welzel, Manfred Stamm, Petra Uhlmann

Department of Chemistry: Faculty Publications

Bioinspired materials mimicking the native extracellular matrix environment are promising for biotechnological applications. Particularly, modular biosurface engineering based on the functionalization of stimuli-responsive polymer brushes with peptide sequences can be used for the development of smart surfaces with biomimetic cues. The key aspect of this study is the in situ monitoring and analytical verification of the biofunctionalization process on the basis of three complementary analytical techniques. In situ spectroscopic ellipsometry was used to quantify the amount of chemisorbed GRGDS at both the homopolymer poly(acrylic acid) (PAA) brush and the binary poly(N-isopropylacrylamide) (PNIPAAm)− PAA brushes, which was finally confirmed …

Electrocaloric Effect In Ferroelectric Ceramics With Point Defects, Ming Wu, Qingshan Zhu, Jianting Li, Dongsheng Song, Honghui Wu, Mengyao Guo, Jinghui Gao, Yang Bai, Yujun Feng, Stephen J. Pennycoock, Xiaojie Lou

Department of Chemistry: Faculty Publications

The electrocaloric effect has drawn much attention due to its potential application in cooling devices. A negative electrocaloric effect is predicted to be induced in defect-doped ferroelectrics by computational results [A. Grunebohm and T. Nishimatsu, Phys. Rev. B 93, 134101 (2016) and Ma et al., Phys. Rev. B 94, 094113 (2016)], but it need to be confirmed by experimental results. In this work, we prepared a 1mol. % Mn-doped Pb(Zr_0.2,Ti_0.8)O₃ ceramics (Pb((Zr_0.2,Ti_0.8)_0.99,Mn_0.01)O₃), and the electrocaloric effect of the defect-containing ferroelectric ceramics has …

Catalytic Mechanism Of Amyloid-Β Peptide Degradation By Insulin Degrading Enzyme: Insights From Qm/Mm Mp2 Calculation, Rui Lai, Wei-Jen Tang, Hui Li

Department of Chemistry: Faculty Publications

Insulin degrading enzyme (IDE), a metalloprotease that degrades amyloid-β (Aβ) peptides and insulin, is associated with Alzheimer’s disease and diabetes. The mechanism of IDE catalyzed degrading of Aβ peptides, which is of fundamental importance in the design of therapeutic methods for Alzheimer’s disease, has not been fully understood. In this work, combined quantum mechanics and molecular mechanics (QM/MM) style Møller-Plesset second order perturbation theory (MP2) geometry optimization calculations are performed to investigate the catalytic mechanism of the Aβ40 Phe19-Phe20 peptide bond cleavage by human IDE. The analyses using QM/MM MP2 optimization suggest that a …

In-Situ-Investigation Of Enzyme Immobilization On Polymer Brushes, Meike Koenig, Ulla König, Klaus-Jochen Eichhorn, Martin Muller, Manfred Stamm, Petra Uhlmann

Department of Chemistry: Faculty Publications

Herein, we report on the use of a combined setup of quartz-crystal microbalance, with dissipation monitoring and spectroscopic ellipsometry, to comprehensively investigate the covalent immobilization of an enzyme to a polymer layer. All steps of the covalent reaction of the model enzyme glucose oxidase with the poly(acrylic acid) brush by carbodiimide chemistry, were monitored in-situ. Data were analyzed using optical and viscoelastic modeling. A nearly complete collapse of the polymer chains was found upon activation of the carboxylic acid groups with N-(3-Dimethylaminopropyl)-N′-ethylcarbodiimide and N-Hydroxysuccinimide. The reaction with the amine groups of the enzyme occurs simultaneously with re-hydration of the …

Development Of A Microcolumn One-Site Immunometric Assay For A Protein Biomarker: Analysis Of Alpha1-Acid Glycoprotein In Serum, Chenhua Zhang, Shae Lott, William Clarke, David S. Hage

Department of Chemistry: Faculty Publications

A one-site immunometric assay based on affinity microcolumns was developed for the analysis of alpha₁-acid glycoprotein (AGP) as a model protein biomarker. In this assay, a sample containing AGP was incubated with an excess amount of a labeled binding agent, such as fluorescein-labeled anti-AGP antibodies or F_ab fragments. The excess binding agent was removed by passing this mixture through a microcolumn that contained an immobilized form of AGP, while the signal was measured for the binding agent-AGP complex in the non-retained fraction. Theoretical and practical factors were both considered in selecting the concentration of labeled binding agent, …

Nmr Metabolomics Protocols For Drug Discovery, Fatema Bhinderwala, Robert Powers

Department of Chemistry: Faculty Publications

Drug discovery is an extremely difficult and challenging endeavor with a very high failure rate. The task of identifying a drug that is safe, selective and effective is a daunting proposition because disease biology is complex and highly variable across patients. Metabolomics enables the discovery of disease biomarkers, which provides insights into the molecular and metabolic basis of disease and may be used to assess treatment prognosis and outcome. In this regard, metabolomics has evolved to become an important component of the drug discovery process to resolve efficacy and toxicity issues, and as a tool for precision medicine. A detailed …

Reversible Mechanical Deformations Of Soft Microchannel Networks For Sensing In Soft Robotic Systems, Abhiteja Konda, Donghee Lee, Taesun You, Xiaoyan Wang, Sangjin Ryu, Stephen Morin

Department of Chemistry: Faculty Publications

Microfluidics has enabled numerous applications in, for example, analytical chemistry, medical diagnostics, microelectronics, and soft robotics. In most of these applications, the geometries of the microchannels are of fixed dimensions that (ideally) remain invariant during operation. In soft robotics, however, the geometries of the microchannels contained in soft actuation systems are inherently dynamic, and the specific dimensions are expected to change during operation, and, by extension, the fluid transport properties of the system are variable. If this characteristic is not properly considered, or if methods are not developed to control it, the progress of soft robotic devices with distributed fluid …

Investigation Of Solvation And Solvent Coordination Effects In Iron Porphyrin Nitrosyls By Infrared Spectroelectrochemistry And Dft Calculations, Md. Hafizur Rahman, Michael D. Ryan

Chemistry Faculty Research and Publications

Visible and infrared spectroelectrochemistry of Fe(OEPone)(NO) (H₂OEPone = octaethylporphinone) were examined in methylene chloride and THF. The visible spectra of Fe(OEPone)(NO) were similar in both solvents. Unlike other ferrous porphyrin nitrosyls, a six-coordinate complex was formed with THF as a ligand. This led to two nitrosyl bands in the infrared spectrum. The absorbance of these bands depended on the concentration of THF in the solution. Solvation and coordination effects on the carbonyl and nitrosyl bands were observed for both the nitrosyl and reduced-nitrosyl complexes. DFT calculations were carried out to interpret the spectral changes.

Glycoform Analysis Of Alpha1-Acid Glycoprotein By Capillary Electrophoresis Using Electrophoretic Injection, Chenhua Zhang, William Clarke, David S. Hage

David Hage Publications

Human alpha₁-acid glycoprotein (AGP) is an acute phase glycoprotein that has a heterogeneous glycosylation pattern. This pattern can change in certain diseases, which has resulted in interest in using AGP glycoforms as potential biomarkers for these diseases. This report describes a method that uses capillary electrophoresis to characterize and analyze AGP glycoforms both in purified samples of AGP and in human serum. This method uses static and dynamic coatings of poly (ethylene oxide) that are applied to a silica capillary for separation of AGP glycoforms in the reversed-polarity mode of CE and in the presence of negligible electroosmotic …

Coastal Wetlands: A Synthesis, Charles S. Hopkinson, Eric Wolanski, Mark M. Brinson, Donald R. Cahoon, Gerardo M.E. Perillo

United States Geological Survey: Staff Publications

What are coastal wetland ecosystems, what are their limits of distribution, and where do they exist in the overall coastal landscape? There are several general definitions for wetlands, but the Ramsar definition is likely the most broadly encompassing (http://www.ramsar. org/), whereas others are more focused definitions tailored to country-specific protection and management policies (Mitsch and Gosselink, 2006). We offer a very general approach rather than a precise definition: coastal wetlands are ecosystems that are found within an elevation gradient that ranges between subtidal depths where light penetrates to support photosynthesis of benthic plants to the landward edge where the sea …

Optimizing Historic Preservation Under Climate Change: Decision Support For Cultural Resource Adaptation Planning In National Parks, Xiao Xiao, Erin Seekamp, Max Post Van Der Burg, Mitchell Eaton, Sandra Fatorić, Allie Mccreary

United States Geological Survey: Staff Publications

Climate change poses great challenges for cultural resource management, particularly in coastal areas. Cultural resources, such as historic buildings, in coastal areas are vulnerable to climate impacts including inundation, deterioration, and destruction from sea-level rise and storm-related flooding and erosion. However, research that assesses the trade-offs between actions for protecting vulnerable and valuable cultural resources under budgetary constraints is limited. This study focused on developing a decision support model for managing historic buildings at Cape Lookout National Seashore. We designed the Optimal Preservation Decision Support (OptiPres) model to: (a) identify optimal, annual adaptation actions for historic buildings across a 30-year …

Ecosystem Processes, Land Cover, Climate, And Human Settlement Shape Dynamic Distributions For Golden Eagle Across The Western Us, J.D. Tack, B.R. Noon, Z.H. Bowen, B.C. Fedy

United States Geological Survey: Staff Publications

Species–environment relationships for highly mobile species outside of the breeding season are often highly dynamic in response to the collective effects of everchanging climatic conditions, food resources, and anthropogenic disturbance. Capturing dynamic space-use patterns in a model-based framework is critical as model inference often drives place-based conservation planning. We applied dynamic occupancy models to broad-scale golden eagle Aquila chrysaetos survey data collected annually from 2006 to 2012 during the late summer post-fledging period in the western US. We defined survey sites as 10 km transect segments with a 1 km buffer on either transect side (n = 3540). Derived estimates …

Implementation Of An Occupancy-Based Monitoring Protocol For A Widespread And Cryptic Species, The New England Cottontail (Sylvilagus Transitionalis), Colin P. Shea, Mitchell J. Eaton, Darryl I. Mackenzie

United States Geological Survey: Staff Publications

Context. Designing effective long-term monitoring strategies is essential for managing wildlife populations. Implementing a cost-effective, practical monitoring program is especially challenging for widespread but locally rare species. Early successional habitat preferred by the New England cottontail (NEC) has become increasingly rare and fragmented, resulting in substantial declines from their peak distribution in the mid-1900s. The introduction of a possible competitor species, the eastern cottontail (EC),may also have played a role. Uncertainty surrounding how these factors have contributed to NEC declines has complicated management and necessitated development of an appropriate monitoring framework to understand possible drivers of distribution and dynamics.

Aims. …