Physical Sciences and Mathematics Commons^™

First-Principles Study Of High-Pressure Phase Stability And Superconductivity Of Bi4i4, Shiyu Deng, Xianqi Song, Quan Li, Yu Xie, Changfeng Chen, Yanming Ma

Physics & Astronomy Faculty Research

Bismuth iodide Bi4I4 exhibits intricate crystal structures and topological insulating states that are highly susceptible to influence by environments, making its physical properties highly tunable by external conditions. In this work, we study the evolution of structural and electronic properties of Bi4I4 at high pressure using an advanced structure search method in conjunction with first-principles calculations. Our results indicate that the most stable ambient-pressure monoclinic α−Bi4I4 phase in C2/m symmetry transforms to a trigonal P31c structure (ɛ−Bi4I4) at 8.4 GPa, then to a tetragonal P4/mmm structure (ζ−Bi4I4) above 16.6 GPa. In contrast to the semiconducting nature of ambient-pressure Bi4I4, the …

Subglacial Meltwater Supported Aerobic Marine Habitats During Snowball Earth, Maxwell A. Lechte, Malcolm W. Wallace, Ashleig Van Smeerdijk Hooda, Weiqiang Li, Ganqing Jiang, Galen P. Halverson, Dan Asael, Stephanie L. Mccoll, Noah J. Planavsky

Geoscience Faculty Publications

The Earth’s most severe ice ages interrupted a crucial interval in eukaryotic evolution with widespread ice coverage during the Cryogenian Period (720 to 635 Ma). Aerobic eukaryotes must have survived the “Snowball Earth” glaciations, requiring the persistence of oxygenated marine habitats, yet evidence for these environments is lacking. We examine iron formations within globally distributed Cryogenian glacial successions to reconstruct the redox state of the synglacial oceans. Iron isotope ratios and cerium anomalies from a range of glaciomarine environments reveal pervasive anoxia in the ice-covered oceans but increasing oxidation with proximity to the ice shelf grounding line. We propose that …

Arbitrary High Order Finite Difference Methods With Applications To Wave Propagation Modeled By Maxwell's Equations, Min Chen

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation investigates two different mathematical models based on the time-domain Maxwell's equations: the Drude model for metamaterials and an equivalent Berenger's perfectly matched layer (PML) model. We develop both an explicit high order finite difference scheme and a compact implicit scheme to solve both models. We develop a systematic technique to prove stability and error estimate for both schemes. Extensive numerical results supporting our analysis are presented. To our best knowledge, our convergence theory and stability results are novel and provide the first error estimate for the high-order finite difference methods for Maxwell's equations.

On Improving Performance Of The Binary Logistic Regression Classifier, Michael Chang

UNLV Theses, Dissertations, Professional Papers, and Capstones

Logistic Regression, being both a predictive and an explanatory method, is one of the most commonly used statistical and machine learning method in almost all disciplines. There are many situations, however, when the accuracies of the fitted model are low for predicting either the success event or the failure event. Several statistical and machine learning approaches exist in the literature to handle these situations. This thesis presents several new approaches to improve the performance of the fitted model, and the proposed methods have been applied to real datasets.

Transformations of predictors is a common approach in fitting multiple linear and …

Evaluating Parents Sociodemographic Factors And Childhood Vaccine Decisions, Mehret Girmay

UNLV Theses, Dissertations, Professional Papers, and Capstones

Vaccination is considered one of the most successful public health achievements of the 20th century. However, with increasing vaccine skepticism emerging over the past decades, there is a threat to the ongoing sustainment of vaccine coverage within all US communities. This study evaluated and compared parents’ sociodemographic factors associated with childhood vaccine decisions. This study is a secondary analysis of 893 parents/guardians, age 18-55 years with child(ren) < 7 years living in the U.S.

Predictive analysis was conducted using multinomial logistic regression modeling was used to examine vaccine decisions (accept, hesitant, and refuse) in relation to parents’ sociodemographic factors. Overall, (66.6%) of parents accepted recommended vaccines, while …

Moisture Dynamics Of A Near-Surface Desert Soil, Yuan Luo

UNLV Theses, Dissertations, Professional Papers, and Capstones

Desert soils cover about one third of the Earth’s land surface. Despite their large extent, however, our understanding of desert soil hydraulic processes and properties is still rather limited. In particularly with respect to the near-surface (top centimeters) of the soil profile, which play a critical role for infiltration, redistribution and evapotranspiration of rainwater, the limiting resource for life in desert environments, but also hosts most of the biologic activity and controls runoff, erosion as well as the emission of dust (Nannipieri et al.,2003; Bradford et al.,1987). Additionally, deserts are ideal locations for electricity generation with solar energy using large-scale …

Examination Of Maskelynite Through Static Recompression And Dynamic Compression, Justin James Reppart

UNLV Theses, Dissertations, Professional Papers, and Capstones

This is an experimental study that aims to clarify the possible formation mechanisms of maskelynite. Maskelynite is a diaplectic glass, that forms during shock compression of feldspar far below the melting point, and without fusion. Maskelynite also paramorphises precursor feldspar grains. Maskelynite is an important probe of shock-pressures at terrestrial impact sites and in many meteorites. Two mechanisms of formation of maskelynite are examined here: 1) maskelynite is result of a pressure-induced amorphization of feldspar compressed beyond its mechanical stability where the formation of thermodynamically stable phases is kinetically inhibited [1, 2]. 2) Feldspar transforms upon dynamic compression into a …

Carbon Management And Volatile Fatty Acid Production In Primary Clarifiers At A Wastewater Treatment Plant, Brittany Nicole Radke

UNLV Theses, Dissertations, Professional Papers, and Capstones

An increasing number of treatment plants are required to remove nutrients from domestic wastewater to lessen the impact of nutrient loading to water bodies. Enhanced Biological Phosphorus Removal (EBPR) is one of the processes commonly used to remove phosphorus from domestic wastewater. The presence of an adequate quantity of volatile fatty acids (VFA) in the wastewater influent to EBPR is important for process efficiency and stability. The objective of this research was to investigate the production of VFAs through fermentation of sludge in primary clarifiers as it related to improving nutrient removal, primarily targeting phosphorus.

The research tested, in full-scale, …

The Timing Of Dynamical Interactions Between Planets In Exoplanetary Systems, David Robert Rice

UNLV Theses, Dissertations, Professional Papers, and Capstones

During the late stage of planet formation, a system is often dynamically packed with protoplanets. These bodies collide together and are ejected from the system to form the final planets. The duration of stability before these dynamical interactions occur is dependent on the initial separation of the bodies in a system. Previous works have shown that the time before a planet-planet close encounter is exponential with the initial planet spacing measured in units of mutual Hill radius. We investigate the limitations of these previous studies. We find that systems that are initially similar can have larger differences in stability times …

Application Of Data-Driven And Process-Based Modeling Approaches For Water Quality Simulation In Lakes And Freshwater Reservoirs, Ali Saber Sichani

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lakes and freshwater reservoirs often serve as the primary drinking and irrigation water sources for surrounding communities. They provide recreational and tourism opportunities, thereby promoting the prosperity of neighboring communities. Reliable estimates of water quality in lakes and reservoirs can improve management practices to protect water resources.

Seasonal water temperature and solar shortwave radiation variations, and their subsequent interactions with water column aquatic life, combined with seasonal variations of mixing intensity throughout the water column, result in variations of water quality constituents with depth during the annual cycle. The complexity of these variations entails the use of advanced water quality …

Pressure Driven Electronic Band Gap Engineering In Tin(Iv)-O,N Compounds, Daniel Thomas Sneed

UNLV Theses, Dissertations, Professional Papers, and Capstones

The intrinsic link between long-range order, coordination geometry, and the electronic properties of a system must be understood in order to tailor function-specific materials. Although material properties are typically tailored using chemical dopants, such methods can cause irreversible changes to the structure, limiting the range of functionality. The application of high pressure may provide an alternative “clean” method to tune the electronic properties of semiconducting materials by tailoring their defect density and structure.

We have explored a number of optoelectronic relevant materials with promising characteristics, specifically Sn-(O,N) compounds which have been predicted to undergo pressure-mediated opening of their optical band …

Mojave Desert Ecosystem Recovery: Potency Of Biotic And Abiotic Restoration Methods In Low Elevation Plant Communities, Mary Amanda Balogh

UNLV Theses, Dissertations, Professional Papers, and Capstones

The historic and current state of land in the Mojave Desert, including land managed by the National Park Service with fundamental goals of natural resource conservation and preservation, been severely degraded by a variety of anthropogenic disturbances. Due to increasingly sporadic and unpredictable precipitation patterns, land managers struggle to implement restoration projects with high success rates and are resource-limited for post-treatment monitoring. In this study, I examined success rates of biotic (outplanting, seeding) and abiotic (soil manipulation, vertical mulch) restoration treatments on various disturbance types in the creosote-bursage (Larrea tridentata-Ambrosia dumosa), blackbrush (Coleogyne ramosissima), and Joshua tree woodland (Yucca brevifolia) …

On Muddy Banks: An Ecoethnography Of A River Island Community, Nicholas Baxter

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this study, I examine the relationship between a river and a community. Specifically, I analyze the processes and patterns that organize the nature-society relationship and define the river town of Sabula, IA. To guide my historical and ethnographic analysis, I utilize a co constructionist posture (Rice 2013), which sees culture, community, economy, and physicality as much a product of bio-physical forces as social forces. My aim is to understand how Sabula is conjointly constructed and reveal the nuanced interconnections between human communities and nature through which social and environmental problems play out. My analysis clarifies patterns in residents’ identity …

Mojave Desert Plant Community Long-Term Response To Disturbance, Dominic M. Gentilcore

UNLV Theses, Dissertations, Professional Papers, and Capstones

All vegetation communities have been shaped by disturbances. This dissertation consists of three separate chapters: Blackbrush (Coleogyne ramosissima) natural regeneration in the Great Basin-Mojave Desert Transition Zone on two fires, Long-term Response to Fire in Eastern Mojave Desert semi-arid shrubland communities, and an Annotated Checklist of Gold Butte National Monument in the Mojave-Colorado Plateau Transition Zone. The section on blackbrush natural regeneration was a long-term dataset from two fires in Basin and Range National Monument that burned in 2008 with monitoring events in 2009, 2010, 2011, 2018 and 2019. The monitoring documented some of the strongest post-fire regeneration for the …

Utility Of Bench Scale Sand Tank Experiments At Assessing Permeable Reactive Barrier Design, Brandon Meier

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of this work was to evaluate the utility of bench scale sand tank experiments at assessing permeable reactive barrier (PRB) design. Our criteria for meeting this goal was that differences between PRB designs could be identified solely by measuring concentration in outflow from the sand tank models. For our PRB designs (funnel-and-gate, staggered wells, and parallel bars), numerical simulations clearly showed that PRB design had a quantifiable effect on outflow concentration, provided that the solute reacted with the PRB materials. Conversely, use of a conservative (non-reactive) solute did not allow us to discern between PRB design alternatives. Employing …

On The Human Factors Impact Of Polyglot Programming On Programmer Productivity, Phillip Merlin Uesbeck

UNLV Theses, Dissertations, Professional Papers, and Capstones

Polyglot programming is a common practice in modern software development. This practice is often considered useful to create software by allowing developers to use whichever language they consider most well suited for the different parts of their software. Despite this ubiquity of polyglot programming there is no empirical research into how this practice affects software developers and their productivity. In this dissertation, after reviewing the state of the art in programming language and linguistic research pertaining to the topic, this matter is investigated by way of two empirical studies with 109 and 171 participants solving programming tasks. Based on the …

Zirconium Tetrachloride, Fundamental Chemistry And Nuclear Fuel Cycle, Rosendo Borjas Nevarez

UNLV Theses, Dissertations, Professional Papers, and Capstones

Zirconium alloys are used in the United States as cladding materials in nuclear reactors. The purification of Zr is of relevance due to the large amount of spent nuclear fuel produced every year (2,000 metric tons per year and rising), of which 25% corresponds to radioactive zirconium cladding. Through the recovery and reuse of Zr, estimated savings of $40 million per year are estimated due to the high cost of hafnium-free nuclear grade zirconium, and also due to the minimization of nuclear waste disposal requirements.

Several chemical approaches have been proposed for the recovery and purification of Zr. Historically, a …

Characterizing Compact Game Trees, Andrew Dubose

UNLV Theses, Dissertations, Professional Papers, and Capstones

It is well-known that the body of a game tree of height less than or equal to ω is compact

if and only if the tree is finitely branching. In this thesis, we develop necessary and sufficient

conditions for the body of any game tree to be compact.

The Retrospective Analysis Of Radionuclides In Banded Coral From The Bikini Atoll, Athena Marie Gallardo

UNLV Theses, Dissertations, Professional Papers, and Capstones

Nuclear weapons testing conducted within the Bikini Atoll in the Marshall Islands resulted in local fallout contamination, including long lived isotopes of plutonium (Pu) and uranium (U), within the surrounding environment. The Bikini lagoon provides a continuous source of Pu (239+240Pu) and U (236U) to the Pacific Basin. The rate at which these isotopes are flushed from the lagoon to the ocean is balanced by inputs from remobilization of lagoon sediments. This research will provide a basis for predicting future change in the solubility and export potential of Pu and U in lagoon sediments. This is important to better understand …

Landscape Scale: Inter- And Intraspecific Variation In Plant Interactions Along A Stress Gradient In The Sheep Range Of Nevada, Jordan Dowell

UNLV Theses, Dissertations, Professional Papers, and Capstones

Impending threats to shrubland ecosystems, posed by climate change, necessitate niche modeling efforts to project vegetation range shifts. However, efforts often remain unguided by individual-scale interspecific plant interactions. The stress gradient hypothesis posits that facilitation should increase in areas of high abiotic stress, only if the individuals are able to ameliorate the surrounding area via functional traits. The Sheep Range of Nevada was used to assess the role of functional traits as predictors of plant association. Larrea tridentata, Coleogyne ramosissima, and Artemisia nova were selected as shrubs with variable life history strategies and ranges in order to identify general patterns …

Bringing Statistical Learning Machines Together For Hydro-Climatological Predictions - Case Study For Sacramento San Joaquin River Basin, California, Balbhadra Thakur, Ajay Kalra, Sajjad Ahmad, Kenneth W. Lamb, Venkat Lakshmi

Civil and Environmental Engineering and Construction Faculty Research

Study region: Sacramento San Joaquin River Basin, California Study focus: The study forecasts the streamflow at a regional scale within SSJ river basin with largescale climate variables. The proposed approach eliminates the bias resulting from predefined indices at regional scale. The study was performed for eight unimpaired streamflow stations from 1962–2016. First, the Singular Valued Decomposition (SVD) teleconnections of the streamflow corresponding to 500 mbar geopotential height, sea surface temperature, 500 mbar specific humidity (SHUM500), and 500 mbar U-wind (U500) were obtained. Second, the skillful SVD teleconnections were screened non-parametrically. Finally, the screened teleconnections were used as the streamflow predictors …

Nanopatterned Silk Fibroin Films With High Transparency And High Haze For Optical Applications, Corey Malinowski, Fengjie He, Yihong Zhao, Ivan Chang, David W. Hatchett, Shengjie Zhai, Hui Zhao

Chemistry and Biochemistry Faculty Research

Simultaneous high transparency and high haze are necessary for high-efficiency optical, photonic, and optoelectronic applications. However, a typical highly transparent film lacks high optical haze or vice versa. Here, we report a silk fibroin-based optical film that exhibits both ultrahigh optical transparency... (See article for full abstract).

Semitransparent Sb2s3 Thin Film Solar Cells By Ultrasonic Spray Pyrolysis For Use In Solar Windows, Jako S. Eensalu, Atanas Katerski, Erki Kärber, Lothar Weinhardt, Monika Blum, Clemens Heske, Wanli Yang, Ilona Oja Acik, Malle Krunks

Chemistry and Biochemistry Faculty Research

The integration of photovoltaic (PV) solar energy in zero-energy buildings requires durable and efficient solar windows composed of lightweight and semitransparent thin film solar cells. Inorganic materials with a high optical absorption coefficient, such as Sb2S3 (>105 cm−1 at 450 nm), offer semitransparency, appreciable efficiency, and long-term durability at low cost. Oxide-free throughout the Sb2S3 layer thickness, as confirmed by combined studies of energy dispersive X-ray spectroscopy and synchrotron soft X-ray emission spectroscopy, semitransparent Sb2S3 thin films can be rapidly grown in air by the area-scalable ultrasonic spray pyrolysis method. Integrated into a ITO/TiO2/Sb2S3/P3HT/Au solar cell, a power conversion …

College Of Engineering Senior Design Competition Fall 2019, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge. The senior design competition helps focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects on …

A Unified Binary Neutron Star Merger Magnetar Model For The Chandra X-Ray Transients Cdf-S Xt1 And Xt2, Hui Sun, Ye Li, Bin-Bin Zhang, Bing Zhang, Franz E. Bauer, Yongquan Xue, Weimin Yuan

Physics & Astronomy Faculty Research

Two bright X-ray transients were reported from the Chandra Deep Field South (CDF-S) archival data, namely CDF-S XT1 and XT2. Whereas the nature of the former is not identified, the latter was suggested as an excellent candidate for a rapidly spinning magnetar born from a binary neutron star (BNS) merger. Here we propose a unified model to interpret both transients within the framework of the BNS merger magnetar model. According to our picture, CDF-S XT2 is observed from the "free zone" where the magnetar spindown powered X-ray emission escapes freely, whereas CDF-S XT1 originates from the "trapped zone" where the …

Gaseous, Pm2.5 Mass, And Speciated Emission Factors From Laboratory Chamber Peat Combustion, John G. Watson, Junji Cao, Lung-Wen Antony Chen, Qiyuan Wang, Jie Tian, Xiaoliang Wang, Steven Gronstal, Steven Sai Hang Ho, Adam C. Watts, Judith C. Chow

Public Health Faculty Publications

Peat fuels representing four biomes of boreal (western Russia and Siberia), temperate (northern Alaska, USA), subtropical (northern and southern Florida, USA), and tropical (Borneo, Malaysia) regions were burned in a laboratory chamber to determine gas and particle emission factors (EFs). Tests with 25 % fuel moisture were conducted with predominant smoldering combustion conditions (average modified combustion efficiency (MCE) =0.82+/-0.08). Average fuel-based EFCO2 (carbon dioxide) are highest (1400 +/- 38 g kg(-1)) and lowest (1073 +/- 63 g kg(-1)) for the Alaskan and Russian peats, respectively. EFCO (carbon monoxide) and EFCH4 (methane) are similar to 12 %15 % and similar to …

3d-Printing And Machine Learning Control Of Soft Ionic Polymer-Metal Composite Actuators, James D. Carrico, Tucker Hermans, Kwang J. Kim, Kam K. Leang

Mechanical Engineering Faculty Research

This paper presents a new manufacturing and control paradigm for developing soft ionic polymer-metal composite (IPMC) actuators for soft robotics applications. First, an additive manufacturing method that exploits the fused-filament (3D printing) process is described to overcome challenges with existing methods of creating custom-shaped IPMC actuators. By working with ionomeric precursor material, the 3D-printing process enables the creation of 3D monolithic IPMC devices where ultimately integrated sensors and actuators can be achieved. Second, Bayesian optimization is used as a learning-based control approach to help mitigate complex time-varying dynamic effects in 3D-printed actuators. This approach overcomes the challenges with existing methods …

Chemostratigraphic Correlations Across The First Major Trilobite Extinction And Faunal Turnovers Between Laurentia And South China, Jih-Pai Lin, Frederick A. Sunberg, Ganqing Jiang, Isabel P. Montanez, Thomas Wotte

Geoscience Faculty Publications

During Cambrian Stage 4 (~514 Ma) the oceans were widely populated with endemic trilobites and three major faunas can be distinguished: olenellids, redlichiids, and paradoxidids. The lower–middle Cambrian boundary in Laurentia was based on the first major trilobite extinction event that is known as the Olenellid Biomere boundary. However, international correlation across this boundary (the Cambrian Series 2–Series 3 boundary) has been a challenge since the formal proposal of a four-series subdivision of the Cambrian System in 2005. Recently, the base of the international Cambrian Series 3 and of Stage 5 has been named as the base of the Miaolingian …

Trends And Disparities In Self-Reported And Measured Osteoporosis Among Us Adults, 2007-2014., Qing Wu, Yingke Xu, Ge Lin

Environmental & Occupational Health Faculty Publications

(1) Background: Studies examining osteoporosis trends among US adults by different socioeconomic status (SES) are limited. The prevalence of self-reported osteoporosis in the US is rarely reported. (2) Methods: Data from the National Health and Nutritional Examination Survey (NHANES) between 2007–2008 and 2013–2014 cycles were analyzed. Age-adjusted prevalence of self-reported and that of measured osteoporosis were calculated overall and by sex, race/ethnicity, education attainment, and SES. (3) Results: The prevalence of self-reported osteoporosis was higher than that of measured osteoporosis in all three survey cycles for women, and in 2007–2008 and 2009–2010 for men. Participants with high school/GED or higher …

Biological And Practical Implications Of Genome-Wide Association Study Of Schizophrenia Using Bayesian Variable Selection, Benazir Rowe, Xiangning Chen, Zuoheng Wang, Jingchun Chen, Amei Amei

School of Medicine Faculty Publications

Genome-wide association studies (GWAS) have identified over 100 loci associated with schizophrenia. Most of these studies test genetic variants for association one at a time. In this study, we performed GWAS of the molecular genetics of schizophrenia (MGS) dataset with 5334 subjects using multivariate Bayesian variable selection (BVS) method Posterior Inference via Model Averaging and Subset Selection (piMASS) and compared our results with the previous univariate analysis of the MGS dataset. We showed that piMASS can improve the power of detecting schizophrenia-associated SNPs, potentially leading to new discoveries from existing data without increasing the sample size. We tested SNPs in …