Studies Of Inner-Shell Chemistry Of Mercury Based Compounds At Extreme Conditions, Sarah Schyck

UNLV Theses, Dissertations, Professional Papers, and Capstones

It has been theoretically predicted that when mercury difluoride (HgF2) is pressurized to above 50 GPa in the presence of molecular fluorine, it will most likely transform into mercury tetrafluoride (HgF4), thus mercury will behave as a transition element at high pressure. However, there is no experimental evidence verifying this prediction yet. To begin with, the crystalline properties of pure HgF2 at high pressure were not experimentally established. In this thesis, the high pressure structural properties of HgF2 are investigated by means of synchrotron X-ray powder diffraction. Our results reveal that the predicted, ambient cubic structure of HgF2 with the …

Scheduling Two Machines With Dissimilar Costs, Madhurupa Moitra

UNLV Theses, Dissertations, Professional Papers, and Capstones

We consider two devices, which has states ON and OFF. In the ON state, the devices use their full power whereas in the OFF state the devices consume no energy but a constant cost is associated with switching back to ON. Such two devices are configured with different run and power-up costs on which a sequence of jobs must be processed. The object is to minimize the cost. Such systems are widely used to conserve energy, for example, to speed scale CPUs, to control data centers, or to manage renewable energy.

The problems are studied in the framework of online …

Optimization Of Useful Hard X-Ray Photochemistry, David Lewis Goldberger

UNLV Theses, Dissertations, Professional Papers, and Capstones

X-ray induced damage is generally considered a nuisance, but in the field of Useful Hard X-ray Photochemistry we harness the highly ionizing and penetrating properties of hard X-rays (> 7 keV) to initiate novel photochemical decomposition and synthesis at ambient and extreme conditions. Preliminary experiments suggest that the energy of irradiating photons and the sample pressure play roles in determining the nature of X-ray induced damage. Here, we present the X-ray energy dependence of damage induced in strontium oxalate, strontium nitrate, and barium nitrate, as well as the pressure dependence of X-ray induced damage of strontium oxalate. Our results indicate …

An Analysis Of Mixed-Layer Clay Minerals And Major Element Geochemical Trends In Middle-Upper Pennsylvanian-Aged Paleosols As A Proxy For Characterizing Basin-Wide Diagenetic Patterns And The Paleoenvironment Of The Illinois Basin, U.S.A., Julia A. Mcintosh

Earth Sciences Theses and Dissertations

Pennsylvanian-aged paleosols from four Illinois Basin (IB) cores were sampled to characterize clay mineralogy, paleosol morphology, and major element geochemistry. This data combined with X-ray diffraction (XRD) and X-ray fluorescence (XRF) data from two other stratigraphically equivalent cores were used to better understand basin-wide diagenetic patterns. Paleosols unimpacted by diagenesis are considered reliable proxies for continued geochemical analyses and paleoclimate interpretations of middle to late Pennsylvanian (Desmoinesian-Missourian) low-latitude environments.

Reichweite Ordering, as determined from XRD analysis ofprofiles, indicates that diagenesis impacted the deep interior of the basin and the southern portion of the basin. Further investigation of illitization mechanisms derived …

The Evolution Of Computational Propaganda: Trends, Threats, And Implications Now And In The Future, Holly Schnader

Senior Honors Projects, 2010-2019

Computational propaganda involves the use of selected narratives, social networks, and complex algorithms in order to develop and conduct influence operations (Woolley and Howard, 2017). In recent years the use of computational propaganda as an arm of cyberwarfare has increased in frequency. I aim to explore this topic to further understand the underlying forces behind the implementation of this tactic and then conduct a futures analysis to best determine how this topic will change over time. Additionally, I hope to gain insights on the implications of the current and potential future trends that computational propaganda has.

My preliminary assessment shows …

Serum Nutrient Levels And Aging Effects On Periodontitis, Jeffrey L Ebersole, Joshua Lambert, Heather Bush, Pinar Emecen Huja, Arpita Basu

Biostatistics Faculty Publications

Periodontal disease damages tissues as a result of dysregulated host responses against the chronic bacterial biofilm insult and approximately 50% of US adults > 30 years old exhibit periodontitis. The association of five blood nutrients and periodontitis were evaluated due to our previous findings regarding a potential protective effect for these nutrients in periodontal disease derived from the US population sampled as part of the National Health and Nutrition Examination Survey (1999–2004). Data from over 15,000 subjects was analyzed for blood levels of cis-β-carotene, β-cryptoxanthin, folate, vitamin D, and vitamin E, linked with analysis of the presence and severity of periodontitis. …

Design And Preliminary Evaluation Of A Supercritical Carbon Dioxide Brayton Cycle For Solar Dish Concentrator Clean Energy Production, Danielle Nobles-Lookingbill

UNLV Theses, Dissertations, Professional Papers, and Capstones

As we move toward energy independence and more ambitious clean energy goals, solar energy research must push the efficiency limits of traditional energy generation systems. Increases in efficiency can be achieved by increasing the hot temperature of the power cycle. Recent research demonstrates the potential for increased efficiency and a vastly smaller component size when supercritical carbon dioxide Brayton power cycles are used. Concentrated solar and nuclear heat sources are capable of achieving the high working fluid temperatures needed for significant efficiency gains. This NSF EPSCoR funded, experimental research system is designed to exploit the uniquely immense solar irradiance of …

Effects Of Ambient Air Pollution On Asthma-Related Emergency Department Visits Within The Las Vegas Metropolitan Area, Loiren E. Monardes

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of this research was to evaluate the risk for asthma-related Emergency Department visits and their association with ambient air pollution within the Las Vegas metropolitan area. All data were aggregated by date and ZIP Code. The association was analyzed by applying the distributed lag non-linear model in an attempt to identify elevated concentrations of specific air pollutants

as triggers and their delayed effects (lag days). Relative Risk (RR) and 95% confidence intervals were produced, while adjusting for socioeconomic status. This ecological population-based study analyzed daily asthma counts of Emergency Department visits from January 1st, 2009 to December 31st, …

Riding The Wave Of Microplastics In Bermuda, Molly E. Riihiluoma

Pell Scholars and Senior Theses

The presence of marine debris and microplastics in the Earth’s oceans are a global environmental issue. Bermuda’s location in the middle of the North Atlantic Gyre makes it the perfect case study for this work. As the crisis unfolds, Bermuda’s environment, economy, and population are at risk of witnessing firsthand the effects of plastic pollution. This paper relies on scholarly research as well as anecdotal evidence from retail stores and locals to compile information in order to provide necessary recommendations to benefit Bermuda’s ocean health. This research evaluates the pros and cons of policies which could mitigate the problem. Analysis …

Monitoring The Impact Of Groundwater Pumping On Infrastructure Using Geographic Information System (Gis) And Persistent Scatterer Interferometry (Psi), Kirsten Deprekel, El Hachemi Bouali, Thomas Oommen

Department of Geological and Mining Engineering and Sciences Publications

Transportation infrastructure is critical for the advancement of society. Bridges are vital for an efficient transportation network. Bridges across the world undergo variable deformation/displacement due to the Earth’s dynamic processes. This displacement is caused by ground motion, which occurs from many natural and anthropogenic events. Events causing deformation include temperature fluctuation, subsidence, landslides, earthquakes, water/sea level variation, subsurface resource extraction, etc. Continual deformation may cause bridge failure, putting civilians at risk, if not managed properly. Monitoring bridge displacement, large and small, provides evidence of the state and health of the bridge. Traditionally, bridge monitoring has been executed through on-site surveys. …

Mercury In Big Cypress Bayou And Caddo Lake Watersheds In Marion And Harrison Counties Texas, Joseph Watkins

Electronic Theses and Dissertations

Caddo Lake has been included on the Texas Commission on Environmental Quality 303(d) list for impairment due to mercury (Hg) content since 1996. One of the primary tributaries, Big Cypress Bayou, flows across Eocene-aged rocks and sediments associated with the Wilcox Group; the Wilcox is of interest because it contains lignite coal, which has a direct link to mercury. Previous research has focused on dry deposition from fossil fuel combustion as the primary source of mercury but has not addressed the potential watershed contribution to mercury concentrations in Caddo Lake.

Big Cypress Bayou flows through Harrison and Marion counties in …

Delineation Of Karst Potential Using Lidar And Gis Analyses, Fort Hood Military Installation, Texas, Colby Reece

Electronic Theses and Dissertations

ABSTRACT

Traditional karst surveys require extensive field investigations to completely characterize large areas. They are often time-consuming, requiring up to several years to collect and categorize data. Bias is given to areas that are most easily accessible and false negatives are common. The implementation of geographic information systems (GIS) has aided in the aggregation and standardization of karst data; however, these systems have also been used to develop terrain models that allow the user to remotely delineate sinkholes and other surficial features. The Fort Hood Military Installation is a karst landscape that has been altered significantly for use in military …

Kcnq1/Kcne1 Interaction In The Cardiac Iks Channel And Its Physiological Consequences, Jiajing Xu

McKelvey School of Engineering Graduate Student Theses & Dissertations

Dynamic conformational changes of ion channel proteins during activation gating determine their function as carriers of current. The relationship between these molecular movements and channel function over the physiological timescale of the action potential (AP) has not been fully established due to limitations of existing techniques. We constructed a library of possible cardiac IKs protein conformations and applied a combination of protein segmentation and energy linearization to study this relationship computationally. Simulations reproduced the effects of the beta-subunit (KCNE1) on the alpha-subunit (KCNQ1) dynamics and function, observed in experiments. Mechanistically, KCNE1 increased the probability of “visiting” conducting pore conformations on …

Employee Perceptions Of Organizational Corporate Responsibility And Their Effect On Employee Organizational Commitment, Lisa R. Davis

UNLV Theses, Dissertations, Professional Papers, and Capstones

The debate over whether organizations play a part in society beyond economic profit has been a major focus of research in corporate social responsibility (CSR). These debates have been mainly looked at from the macro (societal) or the meso (institutional) level. Very little research has been done on the role of the firm and looking at CSR from the micro (individual) level. Questions regarding the role of work for employees, securing economic benefits or making a difference in the world, would vary greatly depending on the individual and the importance they place on these areas in their own lives. Scholars …

Efficient And Practical Composition Of Lock-Free Data Structures, Neha Bajracharya

UNLV Theses, Dissertations, Professional Papers, and Capstones

A concurrent data object is lock-free if it guarantees that at least one, among all concurrent operations, finishes after a finite number of steps. In other words, a lock free technique guarantees that some thread always makes progress. Lock-free data objects offer several advantages over their blocking counterparts, such as being immune to deadlocks and priority inversion, and typically provide high scalability and performance, especially in shared memory multiprocessor architectures.

Composition of data structures is a powerful approach to combine simple data structures to create more complex ones. It works as a building block for many advanced useful data structures. …

Combinatorial Ant Optimization And The Flowshop Problem, Tasmin Chowdhury

UNLV Theses, Dissertations, Professional Papers, and Capstones

Researchers have developed efficient techniques, meta-heuristics to solve many Combinatorial Optimization (CO) problems, e.g., Flow shop Scheduling Problem, Travelling Salesman Problem (TSP) since the early 60s of the last century. Ant Colony Optimization (ACO) and its variants were introduced by Dorigo et al. [DBS06] in the early 1990s which is a technique to solve CO problems. In this thesis, we used the ACO technique to find solutions to the classic Flow shop Scheduling Problem and proposed a novel method for solution improvement. Our solution is composed of two phases; in the first phase, we solved TSP using ACO technique which …

Examining Environmental Hazards In Rental Homes And Habitability Laws In Clark County, Nevada, Jorge Luis Bertran

UNLV Theses, Dissertations, Professional Papers, and Capstones

It is well established that home conditions are linked to the health outcomes of occupants. There are over 880,000 housing units in Clark County, Nevada; nearly half of those are renter-occupied units (ROUs). Currently, there is limited research on the characteristics of environmental hazards found in Clark County ROUs and the strength of habitability statutes created to protect tenants from substandard housing. Understanding how renters in Clark County are affected by environmental hazards in ROUs and the processes by which landlords and tenants resolve grievances related to those hazards would benefit public health. It would enhance the ability to quickly …

Syntheses Of A Tin (Iv) Meso-Tetra(4-Pyridyl) Porphyrin Dichloride-Tetrachlorobis (Bipy)2 Ruthenium (Ii) Complex And Studies Of Photophysical Properties Of 1-Nitropyrene, Phillip Sharp

Electronic Theses and Dissertations

Development of a photosensitizer that can work in both aerobic and anaerobic environments would increase the robustness of the cancer treatment known as photodynamic therapy. The development of a photosensitizer was first attempted by synthesizing a tin (IV) meso-tetra (4-pyridyl) porphyrin dichloride-tetrachlorobis (Bipy)₂ ruthenium (II) complex. The synthesize of the tin porphyrin was done by a method from literature and had a percent error of 31.58 and 37.31 when comparing the theoretical percentages of carbon (55.39) and nitrogen (12.92) meaning that photosensitizer was not synthesized.

The second type of chromophore that was studied was 1-nitropyrene do determine if it …

Computational Explorations Of Information And Mechanism Design In Markets, Zhuoshu Li

McKelvey School of Engineering Graduate Student Theses & Dissertations

Markets or platforms assemble multiple selfishly-motivated and strategic agents. The outcomes of such agent interactions depend heavily on the rules, regulations, and norms of the platform, as well as the information available to agents. This thesis investigates the design and analysis of mechanisms and information structures through the ``computational lens'' in both static and dynamic settings. It both addresses the outcome of single platforms and fills a gap in the study of the dynamics of multiple platform interactions.

In static market settings, we are particularly interested in the role of information, because mechanisms are harder to change than the information …

Learning About Large Scale Image Search: Lessons From Global Scale Hotel Recognition To Fight Sex Trafficking, Abby Stylianou

McKelvey School of Engineering Graduate Student Theses & Dissertations

Hotel recognition is a sub-domain of scene recognition that involves determining what hotel is seen in a photograph taken in a hotel. The hotel recognition task is a challenging computer vision task due to the properties of hotel rooms, including low visual similarity between rooms in the same hotel and high visual similarity between rooms in different hotels, particularly those from the same chain. Building accurate approaches for hotel recognition is important to investigations of human trafficking. Images of human trafficking victims are often shared by traffickers among criminal networks and posted in online advertisements. These images are often taken …

Towards Engineering Advanced Nanomaterials: Elucidating Fundamental Particle Behavior In Water And Critical Sorption Dynamics, Changwoo Kim

McKelvey School of Engineering Graduate Student Theses & Dissertations

As advanced nanomaterials, inorganic-organic nano composites have received great interest as potential platform (nano) structures for sensor, catalyst, sorbent, and environmental applications. Here, my Ph.D. research has focused on the design, synthesis, and characterization of advanced water-stable engineered metal-oxide nanoparticles functionalized by organic frames for environmental applications. For the environmental applications, I have evaluated particleoptimized sorption processes for the remediation and separation of arsenic, chromium, and uranium under environmentally relevant conditions. More specifically, I have explored the critical role of organic coating on sorption mechanisms and performances using engineered iron oxide -based, manganese oxide -based, and manganese ferrite -based (core) …

Nanopower Analog Frontends For Cyber-Physical Systems, Kenji Aono

McKelvey School of Engineering Graduate Student Theses & Dissertations

In a world that is increasingly dominated by advances made in digital systems, this work will explore the exploiting of naturally occurring physical phenomena to pave the way towards a self-powered sensor for Cyber-Physical Systems (CPS). In general, a sensor frontend can be broken up into a handful of basic stages: transduction, filtering, energy conversion, measurement, and interfacing. One analog artifact that was investigated for filtering was the physical phenomenon of hysteresis induced in current-mode biquads driven near or at their saturation limit. Known as jump resonance, this analog construct facilitates a higher quality factor to be brought about without …

Mechanisms Of Calcium Phosphate Mineralization On Biological Interfaces And Their Engineering Applications, Doyoon Kim

McKelvey School of Engineering Graduate Student Theses & Dissertations

All living organisms utilize phosphorus (P) as an essential component of their cell membranes, DNA and RNA, and adenosine triphosphate. Bones, in addition to bearing loads, play an important role in balancing P levels in our bodies. In bones, a network of collagen templates and calcium phosphate (CaP) nanocrystals builds hierarchical levels, from nano- to macroscale. Within this architecture, the thermodynamic properties of CaP minerals are influential. Despite the importance of nucleation, growth, and crystallization in collagen structures for tissue development, little kinetic study of these processes has been conducted due to the limited in situ techniques for monitoring these …

Human Thermal Comfort In Transition Space, Asawari Anil Pawar

UNLV Theses, Dissertations, Professional Papers, and Capstones

ABSTRACT

HUMAN THERMAL COMFORT IN TRANSITION SPACES

Objective: To evaluate and identify the relationship between personal factors and the climatic conditions that influence the human thermal comfort in transition spaces and suggest solutions for adaptation of the built environment, that would encourage active and healthy living in the tourist as well as local community.

Background:

By 2050, there is a prediction that two-thirds of the world population will be living in urban areas, which would add more than 2.5 billion people living in cities (Melnikov et al., 2017). Since Las Vegas is one of the fastest growing cities in Nevada, …

Petrogenesis Of Enriched And Intermediate Poikilitic Shergottites: From Magmatic Source To Emplacement, Rachel Rahib

UNLV Theses, Dissertations, Professional Papers, and Capstones

Poikilitic shergottites, making up >20% of martian meteorites, likely represent a significant composition of the martian crust, as intrusive gabbroic rocks. To further constrain petrogenetic relationships amongst enriched and intermediate poikilitic shergottites, we utilize bulk rock trace element compositions, mineral major element compositions, phosphorus maps of olivine grains, oxygen fugacity (ƒO2) values, subsolidus equilibration temperatures, and quantitative textural analyses, of the most comprehensive suite of poikilitic shergottites yet (11 samples), including three newly recovered samples (Northwest Africa [NWA] 11065, NWA 11043, NWA 10961). Although petrographically light rare earth element (LREE) enriched and intermediate poikilitic shergottites are similar, distinct LREE abundances …

Prokaryotic Diversity And Aqueous Geochemistry Of Subsurface Environments Of The Death Valley Regional Flow System, Joshua David Sackett

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation summarizes over four years of effort towards the completion of a Ph.D. in Biological Sciences. The work presented in this document covers a broad range of topics, but a central unifying theme is prokaryotic life in the continental subsurface. The work presented in each chapter relied heavily on cultivation-independent methods for assessing prokaryotic communities, including prokaryotic community structure reconstruction from high-throughput sequencing of 16S rRNA gene libraries and single-cell genome analysis of novel uncultivated bacteria.

Chapter 2 examines the aqueous geochemistry and prokaryotic diversity of Devils Hole, a cavernous limnocrene and sole natural habitat for the critically endangered …

Uas-Based Object Tracking Via Deep Learning, Marc Dinh

UNLV Theses, Dissertations, Professional Papers, and Capstones

Tracking is the task of identifying an object of interest and detect its position over time, and has numerous applications like surveillance, security and traffic control. In present times, unmanned aerial vehicles (UAV) have been more and more common which provides us with a new and less explored domain, with an ideal vantage point for surveillance and monitoring applications.. Aerial tracking is a particularly challenging task as it introduces new environmental variables such as rapid motion in 3D space. We propose a new deep learned tracker architecture catered to aerial tracking.

First, a study of six state-of-the-art deep learned trackers …

Design, Layout, And Testing Of Sige Apds Fabricated In A Bicmos Process, Dane Laurence Gentry

UNLV Theses, Dissertations, Professional Papers, and Capstones

This Thesis is concerned with the design, layout, and testing of avalanche photodiodes (APDs). APDs are a type of photodetector and, thus, convert light signals into electrical signals (current or voltage). APDs can be fabricated using silicon (Si). In this Thesis, however, three integrated circuit (IC) chips containing various silicon-germanium (SiGe) APDs with different sizes, structures, and geometries were designed, laid out, and fabricated using the Austriamicrosystems (AMS) 0.35μm SiGe BiCMOS (S35) process. This was done in order to compare SiGe APDs to Si only APDs and investigate the hypothesis that SiGe APDs are capable of detecting longer wavelengths than …

Influencing Hawai‘I Hotel Patrons To Use Reef-Safe Sunscreens, Rochelle Good

UNLV Theses, Dissertations, Professional Papers, and Capstones

The health of Hawaiian coral reefs is threatened by pollution from common sunscreen ingredients such as oxybenzone. Hawai‘i hotel patrons using sunscreens with harmful ingredients contaminate coral reefs when these products wash off while swimming or bathing. Reef-safe sunscreens are alternative sunscreens that provide effective sun protection while averting damage to coral reefs. The purpose of this research was to determine the dominant factors leading to the pro-environmental behavior of using reef-safe sunscreen and identify practices that Hawai‘i hotel operators could implement to influence patrons to engage in this behavior. This research applied an integrative conceptual framework to model pro-environmental …

Mechanisms For The Incorporation And Distribution Of Radionuclides In Near-Surface Fallout, Marc Alan Fitzgerald

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fallout is the radioactive glass formed from a mixture of vaporized anthropogenic materials with proximate environmental material. These glassy byproducts constitute a compositional record of environmental materials such as soil and vapor precursors that are responsible for chemical heterogeneity in the glasses. The work of this dissertation is to untangle these different sources of compositional heterogeneity, distinguishing low-abundance vaporized anthropogenic-rich material from natural compositions, in order examine soil behavior and chemical evolution during fallout formation. Unfortunately, mixing convolutes the multivariate elemental relationships in these melts due to overlapping element abundances that might distinguish different source materials and chemical behaviors, making …