Physical Sciences and Mathematics Commons^™

Over Or Under: Hydride Attack At The Metal Versus The Coordinated Nitrosyl Ligand In Ferric Nitrosyl Porphyrins., E G. Abucayon, R L. Khade, D R. Powell, Michael J. Shaw, Y Yang, G B. Richter-Addo

SIUE Faculty Research, Scholarship, and Creative Activity

Hydride attack at a ferric heme–NO to give an Fe–HNO intermediate is a key step in the global N--‐cycle. We demonstrate differential reactivity when six--‐ and five--‐coordinate ferric heme--‐NO models react with hydride. Although Fe–HNO formation is thermodynamically favored from this reaction, Fe–H formation is kinetically favored for the 5C case.

An Examination Of The Neural Unreliability Thesis Of Autism, John Butler, Sophie Molholm, Gizely Andrade, John J. Foxe

Articles

An emerging neuropathological theory of Autism, referred to here as “the neural unreliability thesis,” proposes greater variability in moment-to-moment cortical representation of environmental events, such that the system shows general instability in its impulse response function. Leading evidence for this thesis derives from functional neuroimaging, a methodology ill-suited for detailed assessment of sensory transmission dynamics occurring at the millisecond scale. Electrophysiological assessments of this thesis, however, are sparse and unconvincing. We conducted detailed examination of visual and somatosensory evoked activity using high-density electrical mapping in individuals with autism (N = 20) and precisely matched neurotypical controls (N = 20), recording …

Linear Feedback Stabilization For A Continuously Monitored Qubit, Taylor Lee Patti, A. Chantasri, Justin Dressel, A. N. Jordan

Student Scholar Symposium Abstracts and Posters

In quantum mechanics, standard or strong measurement approaches generally result in the collapse of an ensemble of wavefunctions into a stochastic mixture of eigenstates. On the other hand, continuous or weak measurements have the propensity to dynamically control the evolution of quantum states over time, guiding the trajectory of the state into non-trivial superpositions and maintaining state purity. This kind of measurement-induced state steering is of great theoretical and experimental interest for the harnessing of quantum bits or "qubits", which are the fundamental unit of the emerging quantum computer. We explore continuous measurement-based quantum state stabilization through linear feedback control …

A Trip To The Cataclysmic Binary Zoo: Detailed Follow-Up Of 35 Recently Discovered Systems, John R. Thorstensen, Erek H. Alper, Kathryn E. Weil

Dartmouth Scholarship

We report follow-up studies of 35 recently discovered cataclysmic variables (CVs), 32 of which were found in large, automated synoptic sky surveys. The objects were selected for observational tractability. For 34 of the objects, we present mean spectra and spectroscopic orbital periods, and for one more we give an eclipse-based period. Thirty-two of the period determinations are new, and three of these refine published estimates based on superhump periods. The remaining three of our determinations confirm previously published periods. Twenty of the stars are confirmed or suspected dwarf novae with periods shorter than 3 hr, but we also find three …

The Effect Of Mo Doping On The Charge Separation Dynamics And Photocurrent Performance Of Bivo4 Photoanodes, Brian Pattengale, Jier Huang

Chemistry Faculty Research and Publications

Doping with electron-rich elements in BiVO₄ photoanodes has been demonstrated as a desirable approach for improving their carrier mobility and charge separation efficiency. However, the effect of doping and dopant concentration on the carrier dynamics and photoelectrochemical performance remains unclear. In this work, we examined the effects of Mo doping on the charge separation dynamics and photocurrent performance in BiVO₄photoanodes. We show that the photocurrent of BiVO₄ photoanodes increases with increasing concentration of the Mo dopant, which can be attributed to both the improved carrier mobility resulting from increased electron density and charge separation efficiency due …

Search For Long-Lived Charged Particles In Proton-Proton Collisions At √S = 13 Tev, V. Khachatryan, A. M. Sirunyan, A. R. Tumasyan, Marc M. Baarmand, Vallary Bhopatkar, Stefano Colafranceschi, Marcus Hohlmann, Daniel Noonan, Tuhin S. Roy, Francisco X. Yumiceva

Aerospace, Physics, and Space Science Faculty Publications

Results are presented of a search for heavy stable charged particles produced in proton-proton collisions at √s = 13 TeV using a data sample corresponding to an integrated luminosity of 2.5 fb-1 collected in 2015 with the CMS detector at the CERN LHC. The search is conducted using signatures of anomalously high energy deposits in the silicon tracker and long time-of-flight measurements by the muon system. The data are consistent with the expected background, and upper limits are set on the cross sections for production of long-lived gluinos, top squarks, tau sleptons, and leptonlike long-lived fermions. These upper limits are …

Untangling Amyloid: Slowing The Progression Of Alzheimer’S Disease And Type 2 Diabetes, David Moffet

Faculty Pub Night

No abstract provided.

Effects Of 17 Β-Estradiol And Progesterone On Acropora Cervicornis And Porites Astreoides Growth And Reproduction, Joshua L. Stocker

HCNSO Student Theses and Dissertations

Reef-building coral populations throughout the world are being threatened by numerous stressors and continue to decline. As potent endocrine-disrupting compounds, exogenous sex steroid contamination has been a largely overlooked stressor to corals. Previous research indicates these compounds are prevalent in marine environments, fluctuate annually along with reproductive cycles, can bioaccumulate, and have had variable effects on growth and reproduction in several cnidarian species. This project had three primary objectives: (1) establish environmental estradiol and progesterone concentrations in Broward County and lower Florida Keys reef environments, (2) conduct 17 β-estradiol and progesterone larval assays on P. astreoides larvae to determine the …

Calculating And Analyzing Night Sky Brightness For The Commerce/Greenville, Texas Area, Rebecca Bosmans

Honors Theses

No abstract provided.

Soundscape Mapping: Spatial Variability Of Sound At Furman University, Alec Schindler

Earth and Environmental Sciences Presentations

Looking at the entire soundscape and studying its spatial variability can often give us important information about the health of the ecosystem. However, most previous studies only measure sound intensity, and are therefore limited in their depiction of the soundscape. Another tool for mapping soundscapes is SPreAD-GIS. This tool models sound propagation in an area. However, previous studies have only used it to evaluate the effects of noise pollution, but not applied it towards depicting the soundscape as a whole. I mapped the soundscape of Furman University’s campus using sound intensity as well as many different soundscape indices in order …

Investigating The Impact Of Unsupervised Feature-Extraction From Multi-Wavelength Image Data For Photometric Classification Of Stars, Galaxies And Qsos, Annika Lindh

Conference papers

Accurate classification of astronomical objects currently relies on spectroscopic data. Acquiring this data is time-consuming and expensive compared to photometric data. Hence, improving the accuracy of photometric classification could lead to far better coverage and faster classification pipelines. This paper investigates the benefit of using unsupervised feature-extraction from multi-wavelength image data for photometric classification of stars, galaxies and QSOs. An unsupervised Deep Belief Network is used, giving the model a higher level of interpretability thanks to its generative nature and layer-wise training. A Random Forest classifier is used to measure the contribution of the novel features compared to a set …

The Impact Of Organic Farms: Biodiversity And Climate Change Resilience In The Southeast, Josie Newton

Earth and Environmental Sciences Presentations

Resilience to climate change serves as an indicator of the effectiveness of organic farming practices. Resilience means that an area is able to return to a stable state after a disturbance. In this context, it means that the area is able to function regularly even in the face of climate change, an instance that affects species health and biodiversity. By mapping the locations of organic farms across the southeastern United States along with the resilience scores of areas as evaluated by The Nature Conservancy and comparing this map to farm locations and biodiversity measures, we are able to determine the …

Mapping The Impact Of Intensive Rotational Grazing On Soil Fertility Over Time On Greenbrier Farms In Pickens County, South Carolina, Emily Kirby

Earth and Environmental Sciences Presentations

Intensive rotational grazing (IRG) is a management technique that involves a more intentional management approach which includes increased paddock numbers, shorter grazing periods, larger livestock presence per acre, and longer periods of rest on pastures. Potential advantages of this management technique include improved forage quality, greater yield, decreased erosion, stable production during adverse growing condition, and improved soil fertility. This study collects and analyzes data to understand the impact of rotational grazing on soil fertility as measured by SOC (soil organic carbon) and SON (soil organic nitrogen) on Greenbrier Farms in Easley, South Carolina. This study analyzes the transition from …

Habitat Quality Modeling For Bird Species At Furman University, Emma Cook

Earth and Environmental Sciences Presentations

In rapidly urbanizing areas, such as Greenville County in Upstate South Carolina, it is important to study habitat use and quality across land cover types in order to maximize conservation. Habitat fragmentation is a threat to many species of birds in areas with increasing development, especially those species that utilize larger forest patches for nesting and foraging. While land cover type and patch size are extremely important factors in determining habitat quality for birds, recent research has shown that the matrix of surrounding landscape proves to be very important as well. The landscape matrix, sometimes called landscape mosaic, considers the …

Polyol Induced Partitioning Of Essential Oils In Aqueous Organic Solvent Mixtures, Thomas Delmastro

Seton Hall University Dissertations and Theses (ETDs)

Polyol Induced Extraction (PIE) was developed and patented at Seton Hall University by Drs. John R. Sowa Jr., Wyatt R. Murphy, and Mithilesh Deshpande. It was originally discovered and implemented as a method to recycle and reuse waste acetonitrile during the production shortage in 2008. Through the use of PIE, a solvent mixture containing acetonitrile and water can be separated by employing a polyol mass separating agent, which induces a phase separation. The system is separated into its corresponding aqueous and organic phases, with the organic phase being a highly purified organic liquid. Based on the successful experimental results that …

Discovery Of An Enzyme And Substrate Selective Inhibitor Of Adam10 Using An Exosite-Binding Glycosylated Substrate, Franck Madoux, Daniela Dreymuller, Jean-Phillipe Pettiloud, Radleigh Santos, Christoph Becker-Pauly, Andreas Ludwig, Gregg B. Fields, Thomas Bannister, Timothy P. Spicer, Mare Cudic, Louis D. Scampavia, Dmitriy Minond

Mathematics Faculty Articles

ADAM10 and ADAM17 have been shown to contribute to the acquired drug resistance of HER2-positive breast cancer in response to trastuzumab. The majority of ADAM10 and ADAM17 inhibitor development has been focused on the discovery of compounds that bind the active site zinc, however, in recent years, there has been a shift from active site to secondary substrate binding site (exosite) inhibitor discovery in order to identify non-zinc-binding molecules. In the present work a glycosylated, exosite-binding substrate of ADAM10 and ADAM17 was utilized to screen 370,276 compounds from the MLPCN collection. As a result of this uHTS effort, a selective, …

The Vertical And Horizontal Distribution Of Deep-Sea Crustaceans Of The Order Euphausiacea (Malacostraca: Eucarida) From The Northern Gulf Of Mexico With Notes On Reproductive Seasonality., Charles Douglas Fine

HCNSO Student Theses and Dissertations

The vertical and horizontal distributions of Euphausiacea in the northern Gulf of Mexico, including the location of the Deepwater Horizon oil spill, were analyzed from 340 trawl samples collected between April-June, 2011. This study is the first comprehensive survey of euphausiid distributions from depths deeper than 1000 m in the Gulf of Mexico and included stratified sampling from five discrete depth ranges (0-200 m, 200-600 m, 600-1000 m, 1000-1200 m, and 1200-1500 m). In addition, this study encompasses the region heavily impacted by the Deepwater Horizon oil spill. Data presented here could potentially be used in ecosystem models investigating trophic …

Very Rapid Onset Cannabis Dependence Risk In Relation To Co-Occurring Use Of Other Psychoactive Drugs, Olga A. Vsevolozhskaya, Fernando A. Wagner, James C. Anthony

Biostatistics Presentations

Background: Epidemiological estimates for lifetime cumulative incidence indicate that for every 9-11 who start using cannabis, one becomes a case of the cannabis dependence syndrome (CDS) – i.e., roughly 9%-11%. More recent estimates clarify that CDS risk might be much lower among ’cannabis only’ users, due in part to the fact that many ’cannabis only’ users try the drug a few times and never again. We turned to Hill functional analysis in order to study CDS probability soon after 1st cannabis use, estimated across strata defined by the number of recent days of cannabis use, with an acknowledgment that a …

The Subject Librarian Newsletter, Physics, Fall 2016, Sandy Avila

Libraries' Newsletters

No abstract provided.

The Subject Librarian Newsletter, Mathematics, Fall 2016, Sandy Avila

Libraries' Newsletters

No abstract provided.

The Subject Librarian Newsletter, Chemistry, Fall 2016, Sandy Avila

Libraries' Newsletters

No abstract provided.

Search For New Physics In Final States With Two Opposite-Sign, Same-Flavor Leptons, Jets, And Missing Transverse Momentum In Pp Collisions At √S = 13 Tev, M M. Baarmand, Vallary Bhopatkar, Stefano Colafranceschi, Marcus Hohlmann, D Noonan, Tuhin S. Roy, Francisco X. Yumiceva, Cms Collaboration

Aerospace, Physics, and Space Science Faculty Publications

A search is presented for physics beyond the standard model in final states with two opposite-sign, same-flavor leptons, jets, and missing transverse momentum. The data sample corresponds to an integrated luminosity of 2.3 fb−1 of proton-proton collisions at s=13 TeV collected with the CMS detector at the LHC in 2015. The analysis uses the invariant mass of the lepton pair, searching for a kinematic edge or a resonant-like excess compatible with the Z boson mass. Both search modes use several event categories in order to increase the sensitivity to new physics. These categories are based on the rapidity of the …

Evaluating Lithology As An Erosional Control On A Fluviokarst System In Northeastern Kentucky, Andrew K. Francis

Theses and Dissertations

Longitudinal stream profiles can be used to evaluate landscape evolution. Lithology as a control on a stream profile is especially of interests because fluviokarst systems are characterized by the contact of carbonate and non-carbonate rocks at the surface. Due to the difference in weathering processes between carbonates and non-carbonate rocks, it is likely that there is a difference in their rates of erosion. Cave Branch and its tributary Horn Hollow, are fluviokarst systems located in northeastern Kentucky. This area is primarily comprised of sandstone and limestone. The objectives of this study were to determine if variation in lithology was creating …

A Survey Of Visual Analytics Tools For Effective Decision-Making, R. Jordan Crouser, Erina Fukuda, Subashini Sridhar

Computer Science: Faculty Publications

Over the past decade, the visualization for cybersecurity (VizSec) research community has adapted many information visualization techniques to support the critical work of cyber analysts. While these efforts have yielded many specialized tools and platforms, the community lacks a unified approach to the design and implementation of these systems. In this work, we provide a retrospective analysis of the past decade of VizSec publications, with an eye toward developing a more cohesive understanding of the emerging patterns of design:

• We identify common thematic groupings among existing work, as well as interesting patterns of design around the utilization of various …

Memory Effects In Brownian Motion, Random Walks Under Confining Potentials, And Relaxation Of Quantum Systems, Matthew Chase

Physics & Astronomy ETDs

This dissertation is a report on a number of distinct topics in the field of non-equilibrium statistical mechanics including the evolution of classical as well as quantum systems.

The evolution of an object that is described by the Ornstein-Uhlenbeck process generalized through a time-nonlocal attraction is considered. The time-nonlocality is taken to be represented in the Langevin description through the presence of memory. Analysis of the Langevin equation is performed for algebraic and delay-type memories. An equivalent \emph{bona-fide} Fokker-Planck equation is constructed.

A random walker subjected to a non-standard confining potential, taken to be a piece-wise linear function, is analyzed. …

Investigations Into The Effects Of Water Exchange And The Structure Of Lanthanide Chelates, Katherine Marie Payne

Dissertations and Theses

Lanthanide chelates are effective agents for improving contrast in MR images. Optimizing the relaxation of inner sphere water molecules is a common focus of research in this field. However, the efforts to design an optimal contrast agent have commonly over-looked the relationship of water position and water exchange kinetics. This work explores structural conformation, the impact of very fast water exchange kinetics on hydration, and differing tumbling rates for regioisomers of a number of lanthanide chelates. We have grown crystals of LnDOTMA and obtained structural data by X-ray diffraction that provide a picture of the chelate during water exchange and …

‘‘Can I Drop It This Time?’’ Gender And Collaborative Group Dynamics In An Engineering Design-Based Afterschool Program, Jessica Schnittka, Christine Schnittka

Journal of Pre-College Engineering Education Research (J-PEER)

The 21st century has brought an increasing demand for expertise in science, technology, engineering, and math (STEM). Although strides have been made towards increasing gender diversity in several of these disciplines, engineering remains primarily male dominated. In response, the U.S. educational system has attempted to make engineering curriculum more engaging, informative, and welcoming to girls. Specifically, project-based and design-based learning pedagogies promise to make engineering interesting and accessible for girls while enculturating them into the world of engineering and scientific inquiry. Outcomes for girls learning in these contexts have been mixed. The purpose of this study was to explore how …

The Firece Green Fire: Vol. 7 Issue 12, Wofford College Environmental Studies Program

The Fierce Green Fire

No abstract provided.

Applied Calculus Mth 103, Joanna Burkhardt

Library Impact Statements

No abstract provided.

An Examination Of Student Outcomes In Studio Chemistry, Alan L. Kiste, Gregory E. Scott, Jesse Paul Bukenberger, Miles Markmann, Jennifer Moore

Chemistry and Biochemistry

Twenty years ago, a major curriculum revision at a large, comprehensive university in the Western United States led to the implementation of an integrated lecture/laboratory (studio) experience for our engineering students taking general chemistry. Based on these twenty years of experience, construction of four purpose-built studio classrooms to house the majority of the remaining general chemistry courses was completed in 2013. A detailed study of the effects of the entire ecology of the studio experience on student success was initiated at that time. Data from content knowledge pre- and post-tests, learning attitudes surveys, and student course evaluations show positive effects …