Physical Sciences and Mathematics Commons^™

Intensity Dependence Of Multiple Orbital Contributions And Shape Resonance In High-Order Harmonic Generation Of Aligned N₂ Molecules, Cheng Jin, Julien B. Bertrand, R. R. Lucchese, H .J. Worner, Paul B. Corkum, D. M. Villeneuve, Anh-Thu Le, C. D. Lin

Physics Faculty Research & Creative Works

We report measurements and theoretical simulations of high-order harmonic generation (HHG) in aligned N₂ molecules using a 1200-nm intense laser field when the generating pulse is perpendicular to the aligning one. With increasing laser intensity, the minimum in the HHG spectra first shifts its position and then disappears. Theoretical simulations including the macroscopic propagation effects in the medium reproduce these observations and the disappearance of the minimum is attributed to the additional contribution of HHG from inner orbitals. We also predict that the well-known shape resonance in the photoionization spectra of N₂ should exist in the HHG spectra. It is …

Effect Of Impurities On The Superheating Field Of Type-Ii Superconductors, F. Pei-Jen Lin, A. Gurevich

Physics Faculty Publications

We consider the effect of nonmagnetic and magnetic impurities on the superheating field H_s in a type-II superconductor. We solved the Eilenberger equations, which take into account the nonlinear pairbreaking of Meissner screening currents, and calculated H_s(T) for arbitrary temperatures and impurity concentrations in a single-band s-wave superconductor with a large Ginzburg-Landau parameter. At low temperatures, nonmagnetic impurities suppress a weak maximum in H_s(T), which has been predicted for the clean limit, resulting, instead, in a maximum of H_s as a function of impurity concentration in a moderately clean limit. It is shown that …

An Investigation Of Discontinuous Specular Surfaces Using Non-Contact Techniques In Line Monitoring., Kiryl Kekukh

Theses

Surface metrology by structured light projection has been a standard technique in industry for many years. However, when the surface under test is reflective or specular it is impossible to use this particular method. In this instance a modified procedure called "Fringe Reflection” is used. In this technique patterns similar to structured light are projected onto a screen, located remotely from the surface, and fringe patterns, reflected via the surface, are recorded using a CCD-camera. To recover the range data of such a surface from a set of images taken, a phase unwrapping algorithm is used. For the purpose and …

Visualising Urban Flooding Scenarios Using Video Game Technology, William Elliott Lynn

Theses

This thesis investigates the application of computer graphics to the visualisation of urban flooding scenarios. The demand for urban flooding visualisations is presented in the context of an EU wide climate change response strategy. An analysis of the requirements from various stakeholders is presented and a strategy that addresses these requirements is synthesised. A study on the appropriate computer graphics methods and technologies is outlined and limitations of current technologies are assessed. Systems that solve these limitations are described and the result of usability and user acceptance testing are offered as evidence.

The Identification And Reduction Of Energy Streams Within The Pharmaceutical Sector Using Software Algorithms, Raymond Corbett

Theses

Pharmaceutical companies are under increasing financial pressure to optimise production costs, due to a growing number of products coming off patent, research and development costs increasing exponentially and the difficulty of bringing genuinely innovative products to market. Generic drug manufacturers are not exempt from these pressures; costs must be driven down by all drug manufacturers due to the increasingly competitive healthcare market.

The operating costs of a modern Pharmaceutical Plant run to several Million Euros per annum. Complex process’s involving the consumption of large amounts of energy, and hence costs, are a necessity. Any increase in the efficiency of a …

A Method For Securing Online Community Service: A Study Of Selected Western Australian Councils, Sunsern Limwiriyakul

Theses: Doctorates and Masters

Since the Internet was made publicly accessible, it has become increasingly popular and its deployment has been broad and global thereby facilitating a range of available online services such as Electronic Mail (email), news or bulletins, Internet Relay Chat (IRC) and World Wide Web (WWW). Progressively, other online services such as telephony, video conference, video on demand, Interactive Television (ITV) and Geographic Information System (GIS) have been integrated with the Internet and become publicly available. Presently, Internet broadband communication services incorporating both wired and wireless network technologies has seen the emergence of the concept of a digital community which has …

Dynamics Of Passively Mode-Locked Lasers With Optical Injection, Natalia Rebrova

Theses

Semiconductor passively mode-locked (ML) lasers are of particular interest due to their compactness, cost-efficiency and ease of operation. However, outside optimal parameter range these lasers suffer waveform instabilities, large chirp and significant timing jitter, which makes them ineffective in highspeed applications. In this work we model monolithic passively mode-locked lasers using delay differential equations. We study laser dynamics under external optical injection. We demonstrate that optical injection can improve the properties of mode-locked lasers in terms of the time-bandwidth product, noise and pulse stability. Also this work provides the estimate of locking range for a passively ML semiconductor laser subjected …

Iron(Iii) Tosylate Catalyzed Acylation Of Alcohols, Phenols, And Aldehydes, Ram Mohan, Neil Baldwin, Anna Nord, Brendan O’Donnell

Scholarship

Iron(III) p-toluenesulfonate (tosylate) is an efficient catalyst for acetylation of alcohols, phenols, and aldehydes. The acetylation of 1° and 2° alcohols, diols, and phenols proceeded smoothly with 2.0 mol % of catalyst. However, the reaction worked well with only a few 3° alcohols. The methodology was also applicable to the synthesis of a few benzoate esters but required the use of 5.0 mol % catalyst. Aldehydes could also be converted into the corresponding 1,1-diesters (acylals) under the reaction conditions. Iron(III) tosylate is an inexpensive, and easy to handle, commercially available catalyst.

A Discovery-Oriented Approach To Solid-Phase Peptide Synthesis, Brian Brennan, Matthew Bockman, Christopher Miedema

Scholarship

In this discovery-oriented laboratory experiment, students use solid-phase synthesis techniques to construct a dipeptide containing an unknown amino acid. Following synthesis and cleavage from the polymeric support, electrospray ionization-mass spectrometry is employed to identify the unknown amino acid that was used in the peptide coupling. This experiment, performed in two, 3-h laboratory periods, provides an opportunity for students to learn the technique of solid-phase peptide synthesis and to critically evaluate data that they generate in the laboratory. The experiment is suitable for second-semester organic chemistry students as they learn methods for the formation of amide bonds or upper-level biochemistry students …

Determining The Feasibility Of Universal Access To Bus Transportation For Illinois Wesleyan University Students, Liz Kuehn '13

Outstanding Senior Seminar Papers

In a car-based society, transportation has both environmental and economic implications. However, public transportation, and programs like Universal Access that promote public transportation by providing ‘fare free’ access to specific groups in the community, can offer low cost, sustainable alternatives to car-based transportation. The basic concept behind Universal Access is that a community group contracts with the local public transit system to provide unlimited access to public transportation for individuals within the group at a negotiated cost to the group (Toor et. al 2004). The purpose of this study is to determine the feasibility of creating a Universal Access program …

Testing Irreducibility Of Trinomials Over Gf(2), Steven Hayman

Honors Projects

The focus of this paper is testing the irreducibility of polynomials over finite fields. In particular there is an emphasis on testing trinomials over the finite field GF(2). We also prove a the probability of a trinomial satisfying Swan's theorem is asymptotically 5/8 as n goes to infinity.

A Note On Horner's Method, Tian-Xiao He, P. J.-S. Shiue

Scholarship

Here we present an application of Horner's method in evaluating the sequence of Stirling numbers of the second kind. Based on the method, we also give an e_cient way to calculate the diference sequence and divided diference sequence of a polynomial, which can be applied in the Newton interpolation. Finally, we survey all of the results in Proposition 1.4.

Eulerian Polynomials And B-Splines, Tian-Xiao He

Scholarship

Here presented is the interrelationship between Eulerian polynomials, Eulerian fractions and Euler-Frobenius polynomials, Euler-Frobenius fractions, B-splines, respectively. The properties of Eulerian polynomials and Eulerian fractions and their applications in B-spline interpolation and evaluation of Riemann-zeta function values at odd integers are given. The relation between Eulerian numbers and B-spline values at knot points are also discussed.

Nonlinear Optical Properties Of Carbon Nanotube Hybrids In Polymer Dispersions, Jun Wang, Kang-Shyang Liao, Daniel Früchtl, Ying Tian, Aisling Gilchrist , T, Nigel Alley, Enrico Andreoli, Brad Aitchison, Albert Nasibulin, Hugh Byrne, Esko I. Kauppinen, Long Zhang, Werner Blau, Seamus Curran

Articles

A series of double-walled carbon nanotubes (DWNTs) and multi-walled nanotubes (MWNTs) functionalized with selected organic chromophores, fluorescein 5(6)-isothiocyanate (FITC), rhodamine B isothiocyanate (RITC) and fullerene (C₆₀) were synthesized by covalently linking these electron-donor groups to the metallic nanotubes. These versatile carbon nanotube composites show remarkable nonlinear optical (NLO) performance, due to a merged effect of the complementary NLO characteristics of the moieties of the composites. The hybrids were characterized by UV-Vis spectroscopy and Raman spectroscopy. Evidence suggests charge transfer species are formed between the chromophores and the nanotubes. The optical limiting performance of the DWNT, MWNT hybrids and …

Abstract Criteria For Multiple Solutions To Nonlinear Coupled Equations Involving Magnetic Schrodinger Operators, Mattias Enstedt, Michael Melgaard

Articles

We consider a system of nonlinear coupled equations involving magnetic Schrodinger

operators and general potentials. We provide a criteria for the existence of multiple

solutions to these equations. As special cases we get the classical results on

existence of innitely many distinct solutions within Hartree and Hartree-Fock

theory of atoms and molecules subject to an external magnetic fields. We also

extend recent results within this theory, including Coulomb system with a constant

magnetic field, a decreasing magnetic field and a "physically measurable" magnetic field.

Who Do Work Placements As Part Of An Undergraduate Degree Programme Benefit?, Jacinta E. Browne, David O'Brien, John Dorna

Other Resources

No abstract provided.

Structural Analysis In Multi-Relational Social Networks, Bingtian Dai, Freddy Chua, Ee Peng Lim

Research Collection School Of Computing and Information Systems

Modern social networks often consist of multiple relations among individuals. Understanding the structure of such multi-relational network is essential. In sociology, one way of structural analysis is to identify different positions and roles using blockmodels. In this paper, we generalize stochastic blockmodels to Generalized Stochastic Blockmodels (GSBM) for performing positional and role analysis on multi-relational networks. Our GSBM generalizes many different kinds of Multivariate Probability Distribution Function (MVPDF) to model different kinds of multirelational networks. In particular, we propose to use multivariate Poisson distribution for multi-relational social networks.

Characterization And Electrochromic Properties Of Poly(2,3,5,6-Tetrafluoroaniline): Progress Towards A Transparent Conducting Polymer, Lavinia Astratine, Edmond Magner, John Cassidy, Tony Betts

Articles

Electrochromic films of poly(2,3,5,6-tetrafluoroaniline) (PTFA) were formed on ITO substrates from aqueous solutions utilising perchloric acid (HClO₄) as dopant. Electrochemical and spectroscopic characterization of PTFA films was performed in background electrolyte and in solutions with the addition of tetrahydrofuran. When the PTFA film was removed from its growth medium, a significant decrease in the faradaic current was observed. The faradaic response increased on addition of tetrahydrofuran which facilitates ion movement through the polymer matrix. PTFA films deposited on ITO substrate were orange and light orange in the oxidized and reduced forms, respectively. The films were ca. 25 nm …

Selective Capture Of Transcribed Sequences: A Promising Approach For Investigating Bacterium-Insect Interactions, Ruisheng An, Parwinder Grewal

School of Earth, Environmental, & Marine Sciences Faculty Publications

Bacterial interactions with eukaryotic hosts are complex processes which vary from pathogenic to mutualistic. Identification of bacterial genes differentially expressed in the host, promises to unravel molecular mechanisms driving and maintaining such interactions. Several techniques have been developed in the past 20 years to investigate bacterial gene expression within their hosts. The most commonly used techniques include in-vivo expression technology, signature-tagged mutagenesis, differential fluorescence induction, and cDNA microarrays. However, the limitations of these techniques in analyzing bacterial in-vivo gene expression indicate the need to develop alternative tools. With many advantages over the other methods for analyzing bacterial in-vivo gene expression, …

Would Predatory Drillhole Frequency On Chione Spp. Increase Under The Suggested Climate Change Scenario? Comparing Pleistocene And Modern Rhodolith Beds, Carlos E. Cintra-Buenrostro

School of Earth, Environmental, & Marine Sciences Faculty Publications

The analysis of predatory drillholes allow paleontologists to reconstruct trophic relationships of ancient systems. To evaluate the potential effects of climate and sea level change on predation frequency by gastropods on bivalves, species of the genus Chione from the Gulf of California were selected because they are a commercially exploited resource - at least locally - and abundant in both modern and Pleistocene (sea level high stand of oxygen substage 5e) samples from rhodolith beds. The present study focused to answer a practical question: would predation on Chione spp. increase under the suggested climate - warming - change scenario? A …

Analysis Of Human Skin Tissue By Raman Microspectroscopy: Dealing With The Background, Franck Bonnier, Syed Mehmood Ali, Peter Knief, Helen Lambkin, Kathleen Flynn, Vincent Mcdonagh, Claragh Healy, Thomas Lee, Fiona Lyng, Hugh Byrne

Articles

Raman microspectroscopy is widely used for molecular characterisation of tissue samples. Nevertheless, when working in vitro on tissue sections, the presence of a broad background to the spectra remains problematic and its removal requires advanced methods for pre-processing of the data. To date, research efforts have been primarily devoted to development of techniques of statistical analysis to extract the relevant information contained in the spectra. However, few attempts have been made to understand the origin of the background and to improve the protocols used for the collection of Raman spectra that could lead to the reduction or elimination of the …

Industrial And Agricultural Applications Of Solar Heat, Brian Norton

Books/Book chapters

Mankind’s earliest use of solar energy was probably the drying of food crops to aid their preservation. Open sun drying of fruit, vegetables, fish and meats often improved or enhanced particular flavors and textures such that solely because of those attributes many dried products remain in culinary use today, as examples, dried seaweed, sun-dried tomatoes, raisins and dried pistachio nuts. Open sun drying is displaced increasingly by glazed solar dryers that (i) enable equilibrium moisture content to be reached sooner and (ii) avoid losses of the crop to insects and rodents.

A further agricultural application, the greenhouse extended the use …

Ensuring Distributed Accountability For Data Sharing In The Cloud, Smitha Sundareswaran, Anna Squicciarini, Dan Lin

Computer Science Faculty Research & Creative Works

Cloud computing enables highly scalable services to be easily consumed over the Internet on an as-needed basis. a major feature of the cloud services is that users' data are usually processed remotely in unknown machines that users do not own or operate. While enjoying the convenience brought by this new emerging technology, users' fears of losing control of their own data (particularly, financial and health data) can become a significant barrier to the wide adoption of cloud services. to address this problem, in this paper, we propose a novel highly decentralized information accountability framework to keep track of the actual …

Chyd1 Solution Phase Synthesis Optimization And The Development Of A Novel Human Growth Hormone Antagonist And Agonist, Philip Murray

USF Tampa Graduate Theses and Dissertations

Inhibiting protein-protein interactions to achieve a therapeutically desired effect has been a goal in the field of drug discovery for decades. Recently, advances in peptidomimetics have led researches to the use of cyclized peptides to achieve this goal. Cyclization of linear peptides restricts the number of conformations of the peptide, increasing the peptide's affinity to binding to the desired target. Cyclization also stabilizes the peptide, allowing the peptide to be resistant to proteases. This study explores the optimization of solution phase synthesis of an important integrin-mediated cell adhesion cyclic peptide for the therapeutic inhibition of multiple myeloma, cHYD1. cHYD1 was …

Encapsulation Of High Temperature Phase Change Materials For Thermal Energy Storage, Rupa Nath

USF Tampa Graduate Theses and Dissertations

Thermal energy storage is a major contributor to bridge the gap between energy demand (consumption) and energy production (supply) by concentrating solar power. The utilization of high latent heat storage capability of phase change materials is one of the keys to an efficient way to store thermal energy. However, some of the limitations of the existing technology are the high volumetric expansion and low thermal conductivity of phase change materials (PCMs), low energy density, low operation temperatures and high cost. The present work deals with encapsulated PCM system, which operates at temperatures above 500°C and takes advantage of the heat …

Defining Earth Smarts: A Construct Analysis For Socioecological Literacy Based On Justly Maintaining Quality Of Life, Bryan H. Nichols

USF Tampa Graduate Theses and Dissertations

This paper describes the creation and validation of a new educational construct. Socioecological literacy, or earth smarts, describes the qualities we need to justly maintain or improve our quality of life in a changing world. It was created using construct analysis techniques and systems tools, drawing on an extensive, transdisciplinary body of literature. Concepts related to environmental, ecological and scientific literacy, sustainability and citizenship were combined with educational frameworks, new research in science education, and modern cognitive psychology. After the initial formulation, the results were considered by a variety of experts and professionals from the fields of ecology, environmental science …

Mangroves, Mudbanks And Seawalls: Political Ecology Of Adaptation To Sea Level Rise In Suriname, Ravic Nijbroek

USF Tampa Graduate Theses and Dissertations

This study seeks to understand how global discourses of sea level rise (SLR) and mangrove ecology influence national climate change adaptation policy to reduce coastal vulnerability in Suriname. A majority of the Surinamese population lives along the low elevation coastal zone and is highly exposed to projected SLR. Failure by the international community to reach agreement on climate change mitigation means that vulnerable coastal communities must adapt. The Suriname coast is predominantly shaped by mudbanks and mangroves which together provide protection against coastal erosion and trap sediments resulting in coastal accretion. Knowledge claims of mangrove ecology and utility in SLR …

Micronekton And Macrozooplankton Of The Western Antarctic Peninsula And The Eastern Ross Sea: Contrast Between Two Different Thermal Regimes, Melanie Leigh Parker

USF Tampa Graduate Theses and Dissertations

ABSTRACT

Micronekton and macrozooplankton were sampled from the Western Antarctic Peninsula (WAP) and eastern Ross Sea regions. Samples were collected over the course of six research cruises to the Southern Ocean. Four of those cruises were conducted in the Marguerite Bay region of the WAP during the austral fall and winter of 2001 and 2002. A fifth cruise sampled faunal assemblages at nine sites, ranging from Joinville Island at the northern tip of the WAP to Charcot Island near the southern extent of the WAP, during austral fall 2010. A sixth cruise was conducted in the pack ice within the …

Field And Laboratory Comparison Of The Hydraulic Performance Of Two Ceramic Pot Water Filters, Duncan Peabody

USF Tampa Graduate Theses and Dissertations

Currently 884 million people worldwide are living without access to an improved source of drinking water (WHO/UNICEF, 2011). Piped-water on premises is the ultimate goal of World Health Organization (WHO) due to the ability to treat all of the water and distribute it safely in pressurized pipes. However, Household Water Treatment and Safe Storage (HWTS) is an option for improving the quality of drinking water where that infrastructure is not yet developed, especially where there is a risk of recontamination between point of collection and point of use (Clasen, 2006).

This study analyzed one such HWTS, the ceramic pot water …

Shelf-Scale Mapping Of Fish Distribution Using Active And Passive Acoustics, Carrie Christy Wall

USF Tampa Graduate Theses and Dissertations

Fish sound production has been associated with courtship and spawning behavior. Acoustic recordings of fish sounds can be used to identify distribution and behavior. Passive acoustic monitoring (PAM) can record large amounts of acoustic data in a specific area for days to years. These data can be collected in remote locations under potentially unsafe seas throughout a 24-hour period providing datasets unattainable using observer-based methods. However, the instruments must withstand the caustic ocean environment and be retrieved to obtain the recorded data. This can prove difficult due to the risk of PAMs being lost, stolen or damaged, especially in highly …