Physical Sciences and Mathematics Commons^™

Nanomolar Binding Of Peptides Containing Noncanonical Amino Acids By A Synthetic Receptor, Leigh A. Logsdon, Christopher L. Schardon, Vijayakumar Ramalingam, Sharon K. Kwee, Adam R. Urbach

Chemistry Faculty Research

This paper describes the molecular recognition of phenylalanine derivatives and their peptides by the synthetic receptor cucurbit[7]uril (Q7). The 4-tert-butyl and 4-aminomethyl derivatives of phenylalanine (tBuPhe and AMPhe) were identified from a screen to have 20–30-fold higher affinity than phenylalanine for Q7. Placement of these residues at the N-terminus of model tripeptides (X-Gly-Gly), resulted in no change in affinity for tBuPhe-Gly-Gly, but a remarkable 500-fold increase in affinity for AMPhe-Gly-Gly, which bound to Q7 with an equilibrium dissociation constant (K_d) value of 0.95 nM in neutral phosphate buffer. Structure–activity studies revealed that three functional groups …

Analysis Of The Hinode Magnetograms, Tae K. Kim, Marina Geneva, Julia Reich, Stefan Wolff

Von Braun Symposium Student Posters

No abstract provided.

Vulnerability Of Panamanian Fisheries To Weather And Water Impacts, Nancy Lee Pospelov

Von Braun Symposium Student Posters

No abstract provided.

Development In Physics Simulations With Gpu Architecture: Triumphs And Tribulations, Akito D. Kawamura

Von Braun Symposium Student Posters

No abstract provided.

Magnetic Field Mapping In The Plasmoid Thruster Experiment (Ptx), Coby W. Mccolgin

Von Braun Symposium Student Posters

No abstract provided.

Geospatially Detecting Saccharum Spontaneum: An Invasion Of The Panama Canal Watershed, Casey L. Calamaio

Von Braun Symposium Student Posters

No abstract provided.

High-Resolution Gamma-Ray Spectroscopy With Silicon Photomultipliers, Emily Layden

Von Braun Symposium Student Posters

No abstract provided.

Selection Of Dd Branch In Fusion Reactions To Minimize Neutron Output, Courtney Matzkind

Von Braun Symposium Student Posters

No abstract provided.

Analysis Of Solar Lyman-Alpha Backscatter Radiation In The Heliosphere, Brian Fayock

Von Braun Symposium Student Posters

No abstract provided.

Extreme Weather Events And The Vulnerability Of Communities In Eastern Panama, Chris Jahnig, Tasha Wood, Samantha Zabodyn

Von Braun Symposium Student Posters

No abstract provided.

Lunar Occultation Observer: A Nuclear Astrophysics All-Sky Survey Mission Concept, Riley Freelove

Von Braun Symposium Student Posters

No abstract provided.

Investigation Of Turbulence Transport In The Heliosphere, Lauren Kahre

Von Braun Symposium Student Posters

No abstract provided.

Plasma Jet Magneto Inertial Fusion Thruster Concept, Richard Hatcher

Von Braun Symposium Student Posters

No abstract provided.

The Radioactive Moon, Gaurish Nerurkar

Von Braun Symposium Student Posters

No abstract provided.

Beamed Energy For Ablative Propulsion In Near Earth Space, Grant Bergstue

Von Braun Symposium Student Posters

No abstract provided.

Energy Infrastructure Arrangement For Near Earth Space, Luke Burgess

Von Braun Symposium Student Posters

No abstract provided.

Fabrication And Application Of Vertically Aligned Carbon Nanotube Templated Silicon Nanomaterials, Jun Song

Theses and Dissertations

A process, called carbon nanotube templated microfabrication (CNT-M) makes high aspect ratio microstructures out of a wide variety of materials by growing patterned vertically aligned carbon nanotubes (VACNTs) as a framework and then infiltrating various materials into the frameworks by chemical vapor deposition (CVD). By using the CNT-M procedure, a partial Si infiltration of carbon nanotube frameworks results in porous three dimensional microscale shapes consisting of silicon-carbon nanotube composites. The addition of thin silicon shells to the vertically aligned CNTs (VACNTs) enables the fabrication of robust silicon nanostructures with edibility to design a wide range of geometries. Nanoscale dimensions are …

A Measurement Of The Semileptonic Branching Fraction Of The B_S Meson, Duncan Brown, J. P. Lees

Physics - All Scholarship

We report a measurement of the inclusive semileptonic branching fraction of the B_s meson using data collected with the BaBar detector in the center-of-mass (CM) energy region above the Upsilon(4S) resonance. We use the inclusive yield of phi mesons and the phi yield in association with a high-momentum lepton to perform a simultaneous measurement of the semileptonic branching fraction and the production rate of B_s mesons relative to all B mesons as a function of CM energy. The inclusive semileptonic branching fraction of the B_s meson is determined to be B(B_s to l nu X)=9.5 (+2.5/-2.0)(stat)(+1.1/-1.9)(syst)%, where l indicates the …

Effect Of Coarse Marine Aerosols On Stratocumulus Clouds, Yoav Lehahn, Ilan Koren, Orit Altaratz, Alexander Kostinski

Department of Physics Publications

In contrast to fine anthropogenic aerosols (radii ∼μm), large aerosol particles are thought to enhance cloud droplet growth, promote precipitation formation and reduce cloud albedo. While shown in cloud simulation models, the impact of coarse aerosols on marine stratocumulus clouds lacks observational evidence. Here, by combining data from AMSR‐E and MODIS, both aboard NASA's satellite Aqua, we link the amount of coarse marine aerosols emitted to the atmosphere through wind‐driven processes with the size of cloud droplets, at the world's largest deck of marine stratocumulus clouds over the southeastern Pacific. For constrained meteorological conditions, approximately 1/2 of the change in …

Toward High-Performance Nanostructured Thermoelectric Materials: The Progress Of Bottom-Up Solution Chemistry Approaches, Yixin Zhao, Jeffrey S. Dyck, Clemens Burda

Physics

Significant research effort has recently gone into the synthesis of thermoelectric nanomaterials through different chemical approaches since nanomaterials chemistry became a promising strategy for improving thermoelectric performance. Different thermoelectric nanocrystals, especially PbTe, Bi₂Te₃ and CoSb₃, with various compositions and morphologies have been successfully prepared by solvo/hydrothermal, electrochemical, and ligand-based synthesis methods. Such nanoscale materials show not only substantial reduction in thermal conductivity due to increased phonon scattering at nanoscale grain boundaries and lower densities of phonon states but possibly also an enhancement in thermopower due to electronic quantum size effects. More recently, the notoriously low …

Environmental Prediction In Canadian Cities, James Voogt

Geography & Environment Presentations

No abstract provided.

Rational Ligand Design For Potential Applications In Transition Metal Catalysis, Sergey L. Sedinkin

Dissertations

Strategies to influence the steric and electronic properties of three classes of ligands were investigated. First, a compound class known as amino-dithiaphospholanes was studied. It is structurally related to phosphoramidites, which have been successfully applied in catalysis. The synthesis of amino-dithiaphospholanes was envisaged as an approach to electronically tuned phosphoramidites. General access to a variety of structurally modified amino-dithiaphospholanes from commercially available starting materials was developed. The electron donating properties of the new ligands were characterized by NMR. They were found to be more electron-donating than the corresponding phosphoramidites. The coordination chemistry of amino-dithiaphospholanes was investigated by synthesis of a …

Light-Bending Tests Of Lorentz Invariance, Quentin G. Bailey, Rhondale Tso

Physics & Astronomy - Prescott

Classical light-bending is investigated for weak gravitational fields in the presence of hypothetical local Lorentz violation. Using an effective field theory framework that describes general deviations from local Lorentz invariance, we derive a modified deflection angle for light passing near a massive body. The results include anisotropic effects not present for spherical sources in General Relativity as well as Weak Equivalence Principle violation. We develop an expression for the relative deflection of two distant stars that can be used to analyze data in past and future solar-system observations. The measurement sensitivities of such tests to coefficients for Lorentz violation are …

Preparation Of Novel Hydrolyzing Urethane Modified Thiol-Ene Networks, Nicole M. Mackey, Bridget S. Confait, James Wynne, J. Paige Buchanan

Faculty Publications

Novel tetra-functional hydrolyzing monomers were prepared from the reaction of TEOS and select alkene-containing alcohols, ethylene glycol vinyl ether or 2-allyloxy ethanol, and combined with trimethylolpropane tris(3-mercaptopropionate) (tri-thiol) in a thiol-ene “click” polymerization reaction to produce clear, colorless thiol-ene networks using both radiation and thermal-cure techniques. These networks were characterized for various mechanical characteristics, and found to posses T_g’s (DSC), hardness, tack, and thermal stability (TGA) consistent with their molecular structures. A new ene-modified urethane oligomer was prepared based on the aliphatic polyisocyanate Desmodur^® N 3600 and added to the thiol-ene hydrolyzable network series in increasing amounts, …

Frēstyl: Simplifying The Process Of Promoting And Discovering Local Live Music, Arianna Bassoli, Johanna Brewer

Computer Science: Faculty Publications

In this paper, we present a new service for web and iPhone for promoting and discovering live music, frēstyl. We will show how frēstyl addresses and attempts to solve the problem that emerging musicians, local promoters and small/medium venues face when publicizing their events, both on a local and global level, and the problem that music fans face when trying to gather a complete but not overwhelming understanding of local and global live music events.

Hubble Space Telescope Imaging Of Post-Starburst Quasars, S. Cales, M. Brotherton, Zhaohui Shang, Vardha Bennert, Gabriela Canalizo, R. Stoll, R. Ganguly, D. Berk, Cassandra Paul, A. Diamond-Stanic

Faculty Publications

We present images of 29 post-starburst quasars (PSQs) from a Hubble Space Telescope (HST) Advanced Camera for Surveys (ACS) Wide Field Channel Snapshot program. These broadlined active galactic nuclei (AGNs) possess the spectral signatures of massive (Mburst ∼ 1010 M⊙), moderate-aged stellar populations (hundreds of Myr). Thus, their composite nature provides insight into the AGN–starburst connection. We measure quasar-to-host galaxy light contributions via semi-automated two-dimensional light profile fits of point-spread-function-subtracted images. We examine the host morphologies and model the separate bulge and disk components. The HST/ACS-F606W images reveal an equal number of spiral (13/29) and early-type (13/29) hosts, with the …

Can A Road-Driven Car Outrace A Free-Falling Car?, Diego Castano

Chemistry and Physics Faculty Articles

Motivated by an advertising scenario in which a luxury sports sedan races against a similar car falling under the influence of gravity, a calculation using undergraduate physics and calculus is performed to theoretically predict the outcome.

Crucible Coating Analysis By Thz Spectroscopy, Ryan Shaver, Hannah R. Jones, Jason A. Deibel

Physics Faculty Publications

No abstract provided.

Terahertz Spectroscopic Reflection And Scattering Measurements Of Aligned Cnt Arrays As A Function Of Carbon Nanotube Length, Satya Ganti, Lindsay Owens, Stanley Smith Iv, Jason A. Deibel

Physics Faculty Publications

No abstract provided.

Take Pride In America Phase Iii: Quarterly Progress Report, Period Covering July 25, 2011-October 24, 2011, Margaret N. Rees

Anti-littering Programs

• The GIS database was field tested.
• Three youth groups began the Hector’s Helpers curriculum.
• America Recycles Day event planning occurred.
• Forms were developed for the volunteer monitoring program.