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2011

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Full-Text Articles in Physical Sciences and Mathematics

Approximation By Bernstein Polynomials At The Point Of Discontinuity, Jie Ling Liang Dec 2011

Approximation By Bernstein Polynomials At The Point Of Discontinuity, Jie Ling Liang

HIM 1990-2015

Chlodovsky showed that if x0 is a point of discontinuity of the first kind of the function f, then the Bernstein polynomials Bn(f, x0) converge to the average of the one-sided limits on the right and on the left of the function f at the point x0. In 2009, Telyakovskii in (5) extended the asymptotic formulas for the deviations of the Bernstein polynomials from the differentiable functions at the first-kind discontinuity points of the highest derivatives of even order and demonstrated the same result fails for the odd order case. Then in 2010, Tonkov in (6) found the right formulation …


Maxwell's Equations, Part Iv, David W. Ball Dec 2011

Maxwell's Equations, Part Iv, David W. Ball

Chemistry Faculty Publications

In this column, we continue our explanation of Maxwell’s equations, the seminal classical explanation of electricity and magnetism (and, ultimately, light). For those of you new to the series, consider finding the last few appearances of this column to get caught up. Alternately, you should be able to find past columns on our website, www.spectroscopymag.com and look for “The Baseline” link. Words of warning: for my own reasons, the figures are being numbered sequentially through this series of columns, which is why the first figure in this column is numbered 26. Also, we’re going to get a bit mathematical. Unfortunately …


Fabrication Of All-Inorganic Nanocrystal Solids Through Matrix Encapsulation Of Nanocrystal Arrays, Erich Kinder, Pavel Moroz, Geoffrey Diederich, Alexa Johnson, Maria Kirsanova, Alexander Nemchinov, Timothy O’Connor, Dan Roth, Mikhail Zamkov Dec 2011

Fabrication Of All-Inorganic Nanocrystal Solids Through Matrix Encapsulation Of Nanocrystal Arrays, Erich Kinder, Pavel Moroz, Geoffrey Diederich, Alexa Johnson, Maria Kirsanova, Alexander Nemchinov, Timothy O’Connor, Dan Roth, Mikhail Zamkov

Physics and Astronomy Faculty Publications

A general strategy for low-temperature processing of colloidal nanocrystals into all-inorganic films is reported. The present methodology goes beyond the traditional ligand-interlinking scheme and relies on encapsulation of morphologically defined nanocrystal arrays into a matrix of a wide-band gap semiconductor, which preserves optoelectronic properties of individual nanoparticles while rendering the nanocrystal film photoconductive. Fabricated solids exhibit excellent thermal stability, which is attributed to the heteroepitaxial structure of nanocrystal matrix interfaces, and show compelling light-harvesting performance in prototype solar cells.


Synthesis Of An Antimicrobial Textile Coating, William M. Morris Dec 2011

Synthesis Of An Antimicrobial Textile Coating, William M. Morris

Chemistry and Biochemistry

A titania nanosol was synthesized and coated onto nylon/cotton blended textile substrates. The substrates were characterized via SEM for adhesion and nanoparticle formation, then subjected to antimicrobial efficacy tests. The titania nanosol was successfully coated on to textiles samples. Particles were observed to be around 2 by 3 micrometers and formed between the interstitial space of textile fibers. Although larger than typical nanoparticles, the coatings exhibited what seemed to be antimicrobial activity. Titania nanosol coated textile samples were subjected to Kirby Bauer Assay in the presence of S. aureus. The coated textile sample exhibited an inhibition of growth around its …


The Tetrafluoroborate Salt Of 4-Methoxybenzyl N-2-(Dimethylamino)Ethyl-N-Nitrosocarbamate: Synthesis, Crystal Structure And Dft Calculations, Helene Hedian, Vladimir Benin Dec 2011

The Tetrafluoroborate Salt Of 4-Methoxybenzyl N-2-(Dimethylamino)Ethyl-N-Nitrosocarbamate: Synthesis, Crystal Structure And Dft Calculations, Helene Hedian, Vladimir Benin

Chemistry Faculty Publications

The tetrafluoroborate salt of 4-methoxybenzyl N-2-(dimethylamino)ethyl-N-nitrosocarbamate was prepared in two steps, via the corresponding carbamate. Its crystal structure is monoclinic, space group P21/c. The unit cell dimensions are: a = 19.499(8) Å, b = 5.877(3) Å, c = 15.757(7) Å, α = 90°, β = 110.019(7)°, γ = 90°, V = 1696.5(12) Å3, Z = 4. The structure exhibits an unexpected, pseudo-gauche conformation with respect to the C2–C3 bond, due to a stabilizing hydrogen bond between the carbonyl oxygen (O1) and the hydrogen atom at the trialkylammonium center (H3n), with a distance between them of …


Small-Scale Hybrid Alternative Energy Maximizer For Wind Turbines And Photovoltaic Panels, Ross Kerley Dec 2011

Small-Scale Hybrid Alternative Energy Maximizer For Wind Turbines And Photovoltaic Panels, Ross Kerley

HIM 1990-2015

This thesis describes the creation of a small-scale Hybrid Power System (HPS) that maximizes energy from a wind turbine and photovoltaic array. Small-scale HPS are becoming an increasingly viable energy solution as fossil fuel prices rise and more electricity is needed in remote areas. Modern HPS typically employ wind speed sensors and three power stages to extract maximum power. Modern systems also use passive rectifiers to convert AC from the wind turbine to DC that is usable by power electronics. This passive system inefficiently wastes power and introduces damaging harmonic noise to the wind turbine. The HPS described in this …


A Review On Convolutions Of Gamma Random Variables, Baha-Eldin Khaledi, Subhash C. Kochar Dec 2011

A Review On Convolutions Of Gamma Random Variables, Baha-Eldin Khaledi, Subhash C. Kochar

Mathematics and Statistics Faculty Publications and Presentations

Due to its wide range of applications, the topic of the distribution theory of convolutions of Gamma random variables has attracted the attention of many researchers. In this paper we review some of the latest developments on this problem.


Localization Of Objects Using Cross-Correlation Of Shadow Fading Noise And Copulas, Mohammed Rana Basheer, Sarangapani Jagannathan Dec 2011

Localization Of Objects Using Cross-Correlation Of Shadow Fading Noise And Copulas, Mohammed Rana Basheer, Sarangapani Jagannathan

Electrical and Computer Engineering Faculty Research & Creative Works

While fading, in general, is detrimental to accurately localizing a target, fading correlation between adjacent receivers may be exploited to improve localization accuracy. Therefore, this paper presents a novel wireless localization scheme that employs a combination of cross-correlation between shadow fading noise and copula technique to recursively estimate the location of a transmitter. a stochastic filter that models multipath fading as an Ornstein-Uhlenbeck process followed by a Generalized Auto Regressive Conditional Heteroskedasticity (GARCH) filtering is proposed to extract shadow fading residuals from measured RSSI values. Subsequently, Student-t Copula function is used to create the log likelihood function, which acts as …


Temporal And Spatial Analysis Of Stream And Groundwater Interactions, Ryan Eugene Warden Dec 2011

Temporal And Spatial Analysis Of Stream And Groundwater Interactions, Ryan Eugene Warden

Boise State University Theses and Dissertations

Water chemistry and ecology of streams are impacted by the amount of water that exchanges between the surface water system and the adjacent saturated area, called the hyporheic zone, a dynamic area of stream channel sediments, which undergoes down-welling or up-welling of stream water. The rate and volume of water exchange between the surface water and the hyporheic zone are primary controls on stream ecology, but are challenging to assess. A common approach is to model the exchange rate with a one-dimensional advection-dispersion equation that includes solute exchange with transient storage zones, which is referred to as a transient storage …


Coloring Problems, Thomas Antonio Charles Chartier Dec 2011

Coloring Problems, Thomas Antonio Charles Chartier

Boise State University Theses and Dissertations

This thesis considers several coloring problems all of which have a combinatorial flavor. We review some results on the chromatic number of the plane, and improve a bound on the value of regressive Ramsey numbers. The main work of this thesis considers the problem of whether given any n ≥ 1; one can color Z+ in such a way that for all a ϵ Z+ the numbers a, 2a, 3a, ..., na are assigned different colors. Such colorings are referred to as satisfactory. We provide a sufficient condition for guaranteeing the existence of satisfactory colorings and analyze the …


Evolving Law And Policy For Freshwater Ecosystem Service Markets, Martin W. Doyle, Todd Bendor Dec 2011

Evolving Law And Policy For Freshwater Ecosystem Service Markets, Martin W. Doyle, Todd Bendor

William & Mary Environmental Law and Policy Review

No abstract provided.


The Relation Between Black Hole Mass And Host Spheroid Stellar Mass Out To Z~2, Vardha N. Bennert, Matthew A. Auger, Tommaso Treu, Jong-Hak Woo, Matthew A. Malkan Dec 2011

The Relation Between Black Hole Mass And Host Spheroid Stellar Mass Out To Z~2, Vardha N. Bennert, Matthew A. Auger, Tommaso Treu, Jong-Hak Woo, Matthew A. Malkan

Physics

We combine Hubble Space Telescope images from the Great Observatories Origins Deep Survey with archival Very Large Telescope and Keck spectra of a sample of 11 X-ray-selected broad-line active galactic nuclei in the redshift range 1 < z < 2 to study the black-hole-mass-stellar-mass relation out to a look-back time of 10 Gyr. Stellar masses of the spheroidal component (M sph, ) are derived from multi-filter surface photometry. Black hole masses (M BH) are estimated from the width of the broad Mg II emission line and the 3000 Å nuclear luminosity. Comparing with a uniformly measured local sample and taking into account selection effects, we find evolution in the form M BH/M sph, (1 + z)1.96 …


Environmental Impact Of The Three Kids Mine Tailings, Henderson, Nv, Ji Hye Park Dec 2011

Environmental Impact Of The Three Kids Mine Tailings, Henderson, Nv, Ji Hye Park

UNLV Theses, Dissertations, Professional Papers, and Capstones

This research focused on the distribution of the Three Kids Mine tailings in surface soils in and around the mine in Henderson, Nevada. It is situated next to the communities of Calico Ridge and Lake Las Vegas Resort, and, just the west of the Lake Mead Recreation area. Even though the mine has been inactive for almost 50 years (1917-1961), tailing piles and other sources of contamination on the mine are currently exposed to the atmosphere. In this study, surface soil samples were collected along eight transects emanating from the center of Three Kids Mine tailing piles up to five …


Spectroscopic Studies Of Melamine At High Pressure, Martin Donald Galley Dec 2011

Spectroscopic Studies Of Melamine At High Pressure, Martin Donald Galley

UNLV Theses, Dissertations, Professional Papers, and Capstones

We have performed mid- and far- Infra Red (IR) absorption, Raman spectroscopy, and angular dispersive x-ray diffraction (XRD) studies on melamine under high pressure and room temperature. We have verified the presence of two prior reported phase transitions, the first between 1-2 GPa, and the second between 7-9 GPa. We have also found evidence of a third unreported phase transition between 14-16 GPa, during which, there was a sudden disappearance of all low energy peaks (-1 ) in both the Raman and IR spectra. The far-IR peak movement experiences a discontinuity as the rate of peak movement suddenly changes. …


Processj: A Process-Oriented Programming Language, Matthew Sowders Dec 2011

Processj: A Process-Oriented Programming Language, Matthew Sowders

UNLV Theses, Dissertations, Professional Papers, and Capstones

Java is a general purpose object-oriented programming language that has been widely adopted. Because of its high adoption rate and its lineage as a C-style language, its syntax is familiar to many programmers. The downside is that Java is not natively concurrent. Volumes have been written about concurrent programming in Java; however, concurrent programming is difficult to reason about within an object-oriented paradigm and so is difficult to get right.

occam -π is a general purpose process-oriented programming language. Concurrency is part of the theoretical underpinnings of the language. Concurrency is simple to reason about within an occam -π application …


Boundary Element Method (Bem) And Method Of Fundamental Solutions (Mfs) For The Boundary Value Problems Of The 2-D Laplace's Equation, Ermes Anthony Salgado-Ibarra Dec 2011

Boundary Element Method (Bem) And Method Of Fundamental Solutions (Mfs) For The Boundary Value Problems Of The 2-D Laplace's Equation, Ermes Anthony Salgado-Ibarra

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this thesis we study the solution of the two dimensional Laplace equation by the boundary Element method (BEM) and the method of fundamental solutions (MFS). Both the BEM and MFS used to solve boundary value problems involving the Laplace equation 2-D settings. Both methods rely on the use of fundamental solution of the Laplace's equation (the solution of Laplace's equation in the distributional sense). We will contrast and compare the results we get using the BEM with results we get using the MFS.


Electrochemistry Of Pani/Metal Composites In Basic Solutions, Tamthinhan Quy Dec 2011

Electrochemistry Of Pani/Metal Composites In Basic Solutions, Tamthinhan Quy

UNLV Theses, Dissertations, Professional Papers, and Capstones

Polyaniline (PANI) has been extensively investigated due to its unique conductivity, which is primarily dependent on the oxidation state of the material and the solution pH. PANI is an insulator when it is oxidized, and the solution pH exceeds four. Numerous attempts to extend PANI's conductivity to neutral and alkaline environments have been unsuccessful. However, our previous study has demonstrated that PANI/Pd composite is conductive and catalytically active in a basic solution, pH ∼ 12. Therefore, the conductivity and the electrochemical properties of PANI composites including PANI/Au, PANI/Pd and PANI/Pt were evaluated in basic solutions. The fundamental studies of PANI/metal …


Applying Gmdh-Type Neural Network And Genetic Algorithm For Stock Price Prediction Of Iranian Cement Sector, Saeed Fallahi, Meysam Shaverdi, Vahab Bashiri Dec 2011

Applying Gmdh-Type Neural Network And Genetic Algorithm For Stock Price Prediction Of Iranian Cement Sector, Saeed Fallahi, Meysam Shaverdi, Vahab Bashiri

Applications and Applied Mathematics: An International Journal (AAM)

The cement industry is one of the most important and profitable industries in Iran and great content of financial resources are investing in this sector yearly. In this paper a GMDH-type neural network and genetic algorithm is developed for stock price prediction of cement sector. For stocks price prediction by GMDH type-neural network, we are using earnings per share (EPS), Prediction Earnings Per Share (PEPS), Dividend per share (DPS), Price-earnings ratio (P/E), Earnings-price ratio (E/P) as input data and stock price as output data. For this work, data of ten cement companies is gathering from Tehran stock exchange (TSE) in …


Modeling Spread Of Polio With The Role Of Vaccination, Manju Agarwal, Archana S. Bhadauria Dec 2011

Modeling Spread Of Polio With The Role Of Vaccination, Manju Agarwal, Archana S. Bhadauria

Applications and Applied Mathematics: An International Journal (AAM)

In this paper, we have proposed and analyzed a nonlinear mathematical model for the spread of Polio in a population with variable size structure including the role of vaccination. A threshold parameter, R , is found that completely determines the stability dynamics and outcome of the disease. It is found that if R 1, the disease free equilibrium is stable and the disease dies out. However, if R >1, there exists a unique endemic equilibrium that is locally asymptotically stable. Conditions for the persistence of the disease are determined by means of Fonda’s theorem. Moreover, numerical simulation of the proposed …


A Group Acceptance Sampling Plans For Lifetimes Following A Marshall-Olkin Extended Exponential Distribution, G. S. Rao Dec 2011

A Group Acceptance Sampling Plans For Lifetimes Following A Marshall-Olkin Extended Exponential Distribution, G. S. Rao

Applications and Applied Mathematics: An International Journal (AAM)

In this paper, a group acceptance sampling plan is developed for a truncated life test when the lifetime of an item follows the Marshall-Olkin extended exponential distribution. The minimum number of groups required for a given group size and the acceptance number is determined when the consumer’s risk and the test termination time are specified. The operating characteristic values, according to various quality levels, are found and the minimum ratios of the true average life to the specified life at the specified producer’s risk are obtained. The results are explained with examples.


Morphological Features Of Elongated-Anisotropic Magnetosome Crystals In Magnetotactic Bacteria Of The Nitrospirae Phylum And The Deltaproteobacteria Class, Christopher T. Lefèvre, Mihály Pósfai, Fernanda Abreu, Ulysses Lins, Richard B. Frankel, Dennis A. Bazlinski Dec 2011

Morphological Features Of Elongated-Anisotropic Magnetosome Crystals In Magnetotactic Bacteria Of The Nitrospirae Phylum And The Deltaproteobacteria Class, Christopher T. Lefèvre, Mihály Pósfai, Fernanda Abreu, Ulysses Lins, Richard B. Frankel, Dennis A. Bazlinski

Physics

High resolution transmission electron microscopy was used to study the crystallographic habits of the elongated magnetite crystals, variously described as bullet-, tooth- or arrowhead-shaped, in two recently described, uncultured, magnetotactic bacteria belonging to the Nitrospirae phylum designated Candidatus Magnetoovum mohavensis strain LO-1, and Candidatus Thermomagnetovibrio paiutensis strain HSMV-1; and a cultured sulfate-reducing magnetotactic bacterium of the Deltaproteobacteria class of the Proteobacteria phylum designated strain AV-1. The elongation axes of the magnetosomes do not coincide with the easy magnetization axis (which is [111]) but they are parallel to [100] in LO-1 and AV-1 and parallel to [110] in HSMV-1. In all …


Study Of Feature Selection Algorithms For Text-Categorization, Kandarp Dave Dec 2011

Study Of Feature Selection Algorithms For Text-Categorization, Kandarp Dave

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis will discuss feature selection algorithms for text-categorization. Feature selection algorithms are very important, as they can make-or-break a categorization engine. The feature selection algorithms that will be discussed in this thesis are Document Frequency, Information Gain, Chi Squared, Mutual Information, NGL (Ng-Goh-Low) coefficient, and GSS (Galavotti-Sebastiani-Simi) coefficient . The general idea of any feature selection algorithm is to determine importance of words using some measure that can keep informative words, and remove non-informative words, which can then help the text-categorization engine categorize a document, D , into some category, C . These feature selection methods are explained, implemented, …


Current Status And Long-Term Trends In Water Quality And Living Resources In The Virginia Tributaries And Chesapeake Bay Mainstem From 1985 Through 2010, Daniel M. Dauer, Harold G. Marshall, John R. Donat, Michael F. Lane, Suzanne C. Doughten, Frederick A. Hoffman, Raghavendra Kurada Dec 2011

Current Status And Long-Term Trends In Water Quality And Living Resources In The Virginia Tributaries And Chesapeake Bay Mainstem From 1985 Through 2010, Daniel M. Dauer, Harold G. Marshall, John R. Donat, Michael F. Lane, Suzanne C. Doughten, Frederick A. Hoffman, Raghavendra Kurada

Status and Trends for Virginia Chesapeake Bay

The period prior to the implementation of the Chesapeake Bay Monitoring Program was characterized by a marked decline in the water quality of the Chesapeake Bay. The disappearance of submerged aquatic vegetation in certain regions of the Bay, declines in the abundance of some commercially and recreationally important species, increases in the incidence of low dissolved oxygen events, changes in the Bay's food web, and other ecological problems have been related to the deteriorating water quality (e.g. USEPA, 1982,1983;Officer et al.,1984; Orth and Moore, 1984). The results of concentrated research efforts in the late 1970s and early 1980s stimulated the …


Preliminary Evaluations Of Secondary Productivity Estimates As Indicators Of The Ecological Value Of The Benthos To Higher Trophic Levels In Chesapeake Bay, Daniel M. Dauer, Michael F. Lane, Roberto J. Llansó, Robert Diaz Dec 2011

Preliminary Evaluations Of Secondary Productivity Estimates As Indicators Of The Ecological Value Of The Benthos To Higher Trophic Levels In Chesapeake Bay, Daniel M. Dauer, Michael F. Lane, Roberto J. Llansó, Robert Diaz

Benthic Applications

The primary objective of this project was to develop an analytical tool that management could use to assess the ecological value of the benthos for higher trophic levels. Ideally any tool developed should be simple to implement, adaptable to both fixed and probability monitoring programs and applicable across multiple spatial and temporal scales. Direct evaluations of secondary productivity involve time-consuming cohort or size-based methods that require multiple measurements of the populations in question over time (Dolbeth et al., 2005; Cusson and Bourget, 2005). However, empirical regression models have been developed that provide reasonable alternatives to these techniques when direct measurements …


The Update, December 2011, University Of Northern Iowa. College Of Humanities, Arts And Sciences. Dec 2011

The Update, December 2011, University Of Northern Iowa. College Of Humanities, Arts And Sciences.

Update

Inside this issue:

-- Two UNI Alums to Graduate with Doctoral Degrees
-- Department News
-- UNI Department of Theatre: Guernica Re-Cap
-- Art High School Scholarship Day
-- Faculty member Awarded Fellowship
-- School of Music Events
-- Student Spotlight: Department of Art: Erlinda Babauta
-- Military Veteran and UNI Alumnus Joins the Center for Teaching and Learning Mathematics
-- UNI Geology Students Explore Heavy Metal: Learning How to Rock!
-- Modern Motives: Influences in Today's Art
-- New U.S.-Brazil Program in Communication Disorders
-- Student Spotlight: Department of Math: Nathan Bradfield


Analysis Of Volatile Organic Compounds In Virgin Coconut Oil And Their Sensory Attibutes, Fabian M. Dayrit, Jaclyn Elizabeth R. Santos, Bianca J. Villarino, Anthony R. Zosa Dec 2011

Analysis Of Volatile Organic Compounds In Virgin Coconut Oil And Their Sensory Attibutes, Fabian M. Dayrit, Jaclyn Elizabeth R. Santos, Bianca J. Villarino, Anthony R. Zosa

Chemistry Faculty Publications

The volatile compounds in the headspace of twenty-four commercial virgin coconut oil (VCO) samples prepared by different methods (i.e. expeller, centrifugation, and fermentation with and without heat) were analyzed by solid phase microextraction-gas chromatography mass spectrometry (SPME-GCMS). The following volatile organic compounds (VOCs) were identified: ethyl acetate, acetic acid, 2-pentanone, hexanal, n-octane, 2-heptanone, limonene, nonanal, octanoic acid, ethyl octanoate, δ-octalactone, ethyl decanoate, δ-decalactone, and dodecanoic acid. Fermentation-produced samples were found to have higher levels of acetic acid and free fatty acids in the headspace compared to VCO produced using the centrifuge and expeller methods. Descriptive sensory analysis of the VCO …


Opacity Of P(Mma-Maa)-Pmma Composite Latex System With Varying Maa Concentration, Gilbert U. Yu, Jerry T. Dy, Erwin P. Enriquez Dec 2011

Opacity Of P(Mma-Maa)-Pmma Composite Latex System With Varying Maa Concentration, Gilbert U. Yu, Jerry T. Dy, Erwin P. Enriquez

Chemistry Faculty Publications

Polymer composites of core-shell morphology are commonly used in the paint industry as opacity enhancer. These are usually made of block copolymer systems wherein the core is formed from a polymer that swells in the presence of a solvent and surrounded by a high glass transition polymeric shell. Thus, upon drying, the swollen regions turn into voids while leaving a hard shell. Here, composites based on poly(methyl methacrylate-butyl acrylate) [P(MMA-BuA)] (seed stage), poly(methyl methacrylate-methacrylic acid) [P(MMA-MAA)] (second stage), and poly(methyl methacrylate) [PMMA] (third stage) were synthesized through a multistage sequential emulsion polymerization and their opacity was investigated. The second stage …


Alignment-Free Methods And Its Applications, Ramez Mina Dec 2011

Alignment-Free Methods And Its Applications, Ramez Mina

Student Work

Comparing biological sequences remains one of the most vital activities in Bioinformatics. Comparing biological sequences would address the relatedness between species, and find similar structures that might lead to similar functions.

Sequence alignment is the default method, and has been used in the domain for over four decades. It gained a lot of trust, but limitations and even failure has been reported, especially with the new generated genomes. These new generated genomes have bigger size, and to some extent suffer errors. Such errors come mainly as a result from the sequencing machine. These sequencing errors should be considered when submitting …


Chemical, Biological, And Preliminary In Vitro Studies Of Novel Vanadium(Iv) Complexes With Schiff Bases And Thiosemicarbazone Ligands, Nerissa Abigail Lewis Dec 2011

Chemical, Biological, And Preliminary In Vitro Studies Of Novel Vanadium(Iv) Complexes With Schiff Bases And Thiosemicarbazone Ligands, Nerissa Abigail Lewis

Master's Theses

9-Anthraldehyde-N(4)-methylthiosemicarbazone (MeATSC), potassium (E)-2-(2-hydroxybenzylideneamino)-3-(1H-indol-3-yl)propanoate (K[(Sal-L-tryp)] and 2-(2-hydroxybenzylamino)-3-(1H-indol-3-yl)propanoic acid (the reduced Schiff base) were prepared using known synthetic procedures. Two novel thiosemicarbazone ligands, (E)-N-ethyl-2-(4-hydroxy-3-methoxybenzylidene)hydrazinecarbothioamide (N-Ethhymethohcarbthio) and (E)-N-ethyl-2-(1-(thiazol-2-yl)ethylidene)hydrazinecarbothioamide (acetylethTSC), were also prepared. All ligands were characterized by FT IR and electrochemistry. N-Ethhymethohcarbthio were characterized by elemental analysis whereas the reduced Schiff base and K[(Sal-L-tryp)] were characterized by ESI MS. X-ray crystallography was also used to characterize acetylethTSC. The ligands were then reacted with [VO(Sal-L-tryp)(H2O)] (1) (Sal-L-tryp = N-salicylidene-L-tryptophanate) to produce the …


Continuous Analysis Of Photocatalytic Activity In Thin-Films And Coatings, Steven Michael Allee Dec 2011

Continuous Analysis Of Photocatalytic Activity In Thin-Films And Coatings, Steven Michael Allee

Master's Theses

Materials that undergo photocatalytic reactions create evolved gases due to ultraviolet light decomposition. Current methods of measuring these gases typically result in destruction of the sample. A test fixture was developed to measure evolved gases in a nondestructive manner through the utilization of a flow-through sensor array system. Preliminary testing indicates responsive measurements down to parts-per-billion sensitivity for some gases and will be compared with mass spectrometry measurements. Further development of this process could lead to the ability to measure photocatalytic reaction gases on a continuous basis without interruption of the process or destruction of materials introduced to the system.