Physical Sciences and Mathematics Commons^™

Removal Of Disinfection By-Product Precursors Using Magnetic Ion Exchange (Miex(R)): The Effects Of Ph And Source Water Variability, Sarah Cousins

Graduate Theses and Dissertations

Disinfection by-products (DBPs) form as an unintended result of drinking water disinfection, from chemical reactions between disinfectants (e.g., free chlorine) and naturally occurring dissolved organic matter (DOM). At present, 11 DBPs are regulated in treated drinking waters due to potential adverse health effects, including four trihalomethanes (THMs). Despite nearly 40 years of DBP research, compliance with DBP regulations remains a challenge for many drinking water treatment plants (DWTPs), including the four DWTPs located on the Beaver Lake Reservoir in Northwest Arkansas. Due to the high net negative surface charge on DOM, anion exchange is one potentially viable method for removing …

Electrochemistry Of Pani/Metal Composites In Basic Solutions, Tamthinhan Quy

UNLV Theses, Dissertations, Professional Papers, and Capstones

Polyaniline (PANI) has been extensively investigated due to its unique conductivity, which is primarily dependent on the oxidation state of the material and the solution pH. PANI is an insulator when it is oxidized, and the solution pH exceeds four. Numerous attempts to extend PANI's conductivity to neutral and alkaline environments have been unsuccessful. However, our previous study has demonstrated that PANI/Pd composite is conductive and catalytically active in a basic solution, pH ∼ 12. Therefore, the conductivity and the electrochemical properties of PANI composites including PANI/Au, PANI/Pd and PANI/Pt were evaluated in basic solutions. The fundamental studies of PANI/metal …

Defining, Executing And Visualizing Representative Workflows In A Retail Domain, May Zeineldin

Graduate Theses and Dissertations

Our lives are filled with routine activities that we do more or less on auto-pilot such as driving to work and cooking. This thesis explores a workflow representation as a way to represent such activities of daily living. The domain of a retail store environment is used. Workflows are initially expressed in a structured English representation, then translated into a Petri net notation and implemented in mix of Petri nets, Lua, and C so that the resulting workflows can be displayed as the actions of collections of avatarbots (avatars controlled by programs) in a 3D virtual world, Second Life. One …

Water Quality Trends For Section 319 Priority Watersheds In Northwest Arkansas, 1997-2010, Bryan William Bailey

Graduate Theses and Dissertations

Northwest Arkansas contains two Section 319 Priority Watersheds that the Arkansas Natural Resources Commission (ANRC) has identified as being impacted by point and nonpoint sources of pollution (i.e., phosphorus, nitrogen, and sediment), and the Arkansas Water Resources Center (AWRC) has monitored the water quality at several sites within these watersheds. Water-quality data has been collected over the last decade within the Illinois River Watershed (HUC #11110103) and the Upper White River Basin (Beaver Reservoir HUC# 11010001), each watershed containing three sampling sites. The Illinois River Watershed sites are located on the Illinois River, Osage Creek, and Ballard Creek, and the …

Hydroclimatic Forecasting In The Western United States Using Paleoclimate Reconstructions And Data-Driven Models, Christopher Allen Carrier

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis investigated climate variability and their associated hydrologic responses in the western United States. The western United States faces the problem of water scarcity, where the management and mitigation of available water supplies are further complicated by climate variability. Climate variability associated with the phases of oceanic-atmospheric oscillations has been shown to influence streamflow and precipitation, where predictive relationships have led to the possibility of producing long-range forecasts. Based on literature review, four oceanic-atmospheric oscillation indices were identified in having the most prominent influence over the western United States including the El Niño - Southern Oscillation (ENSO), Pacific Decadal …

Spectroscopic Methods Of Process Monitoring For Safeguards Of Used Nuclear Fuel Separations, Jamie Lee Warburton

UNLV Theses, Dissertations, Professional Papers, and Capstones

To support the demonstration of a more proliferation-resistant nuclear fuel processing plant, techniques and instrumentation to allow the real-time, online determination of special nuclear material concentrations in-process must be developed. An ideal materials accountability technique for proliferation resistance should provide nondestructive, realtime, on-line information of metal and ligand concentrations in separations streams without perturbing the process. UV-Visible spectroscopy can be adapted for this precise purpose in solvent extraction-based separations.

The primary goal of this project is to understand fundamental URanium EXtraction (UREX) and Plutonium-URanium EXtraction (PUREX) reprocessing chemistry and corresponding UV-Visible spectroscopy for application in process monitoring for safeguards. By …

High Performance Geospatial Analysis On Emerging Parallel Architectures, Seth Warn

Graduate Theses and Dissertations

Geographic information systems (GIS) are performing increasingly sophisticated analyses on growing data sets. These analyses demand high performance. At the same time, modern computing platforms increasingly derive their performance from several forms of parallelism. This dissertation explores the available parallelism in several GIS-applied algorithms: viewshed calculation, image feature transform, and feature analysis. It presents implementations of these algorithms that exploit parallel processing to reduce execution time, and analyzes the effectiveness of the implementations in their use of parallel processing.

Consolidated Study On Query Expansion, Abhishek Biruduraju

UNLV Theses, Dissertations, Professional Papers, and Capstones

A typical day of million web users all over the world starts with a simple query. The quest for information on a particular topic drives them to search for it, and in the pursuit of their info the terms they supply for queries varies from person to person depending on the knowledge they have. With a vast collection of documents available on the web universe it is the onus of the retrieval system to return only those documents that are relevant and satisfy the user’s search requirements. The document mismatch problem is resolved by appending extra query terms to the …

Study Of Feature Selection Algorithms For Text-Categorization, Kandarp Dave

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis will discuss feature selection algorithms for text-categorization. Feature selection algorithms are very important, as they can make-or-break a categorization engine. The feature selection algorithms that will be discussed in this thesis are Document Frequency, Information Gain, Chi Squared, Mutual Information, NGL (Ng-Goh-Low) coefficient, and GSS (Galavotti-Sebastiani-Simi) coefficient . The general idea of any feature selection algorithm is to determine importance of words using some measure that can keep informative words, and remove non-informative words, which can then help the text-categorization engine categorize a document, D , into some category, C . These feature selection methods are explained, implemented, …

Energy-Based Analysis Of Utility Scale Hybrid Power Systems, Kwame Agyenim-Boateng

UNLV Theses, Dissertations, Professional Papers, and Capstones

The promise of large-scale use of renewables such as wind and solar for supplying electrical power is tempered by the sources' transient behavior and the impact this would have on the operation of the grid. Among the methods cited for addressing some of those concerns are exploring the complementary nature of solar and wind power generation, and through the use of supplemental energy storage. While the technology for the latter has not been proven to be economical on a large scale at the present time, some assessments of what magnitude is required can be made. An energy-based analysis of utility …

Processj: A Process-Oriented Programming Language, Matthew Sowders

UNLV Theses, Dissertations, Professional Papers, and Capstones

Java is a general purpose object-oriented programming language that has been widely adopted. Because of its high adoption rate and its lineage as a C-style language, its syntax is familiar to many programmers. The downside is that Java is not natively concurrent. Volumes have been written about concurrent programming in Java; however, concurrent programming is difficult to reason about within an object-oriented paradigm and so is difficult to get right.

occam -π is a general purpose process-oriented programming language. Concurrency is part of the theoretical underpinnings of the language. Concurrency is simple to reason about within an occam -π application …

Automating Construction And Selection Of A Neural Network Using Stochastic Optimization, Jason Lee Hurt

UNLV Theses, Dissertations, Professional Papers, and Capstones

An artificial neural network can be used to solve various statistical problems by approximating a function that provides a mapping from input to output data. No universal method exists for architecting an optimal neural network. Training one with a low error rate is often a manual process requiring the programmer to have specialized knowledge of the domain for the problem at hand.

A distributed architecture is proposed and implemented for generating a neural network capable of solving a particular problem without specialized knowledge of the problem domain. The only knowledge the application needs is a training set that the network …

Boundary Element Method (Bem) And Method Of Fundamental Solutions (Mfs) For The Boundary Value Problems Of The 2-D Laplace's Equation, Ermes Anthony Salgado-Ibarra

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this thesis we study the solution of the two dimensional Laplace equation by the boundary Element method (BEM) and the method of fundamental solutions (MFS). Both the BEM and MFS used to solve boundary value problems involving the Laplace equation 2-D settings. Both methods rely on the use of fundamental solution of the Laplace's equation (the solution of Laplace's equation in the distributional sense). We will contrast and compare the results we get using the BEM with results we get using the MFS.

Effects Of High-Impedance-Contrast Boundary Upon Multi-Modal Seismic Surface Wave Data, Prajwol Tamrakar

UNLV Theses, Dissertations, Professional Papers, and Capstones

Synthetic studies and analyses of an experimental dataset were conducted to address the use of Rayleigh-type surface waves for estimation of shear wave velocity (VS) profiles of shallow bedrock sites. The shallow bedrock presents a high impedance contrast boundary which causes surface wave energy to be partitioned to higher modes. Idealized studies of hypothetical datasets and root-mean-squared calculations of error surfaces showed that if reliable dispersion data are available over a broad frequency spectrum, the VS profile can be recovered using the fundamental mode alone. However, when dispersion data are limited to a relatively narrow frequency band representing what might …

Fenestration Studies On Building Energy Using The Facade Evaluation Facility, Wendell Cocina

UNLV Theses, Dissertations, Professional Papers, and Capstones

The project was developed to assess several types of facades and their influence on building energy, mainly focused on windows and other building fenestrations. Requirements for the facility are stated in this paper alongside corresponding solutions. The facility is designed to represent a section of a building façade. Experimenting on a wide range of fenestrations including windows with integrated PV elements was the primary prerequisite. The option of removable façade configurations was used and allowed testing specimens to be changed effortlessly. Instrumentation and data acquisition are discussed including calibration and uncertainty analysis. Investigation of the air conditioning unit was concluded …

Changing Climatic Conditions In The Colorado River Basin: Implications For Water Resources Management In The Las Vegas Valley, Srijana Dawadi

UNLV Theses, Dissertations, Professional Papers, and Capstones

Climate change affects the water available in a region. It also affects the water demand, because of the increase in temperature. A system dynamics model was developed for the Colorado River Basin (CRB), operating at a monthly time scale, to assess the potential impacts of climate change on streamflow in the Colorado River and its subsequent impact on the water resources management in the Las Vegas Valley (LVV). The effect of climate change on streamflow was evaluated using 16 global climate model outputs for 3 emission scenarios, also referenced in the Inter-Governmental Panel on Climate Change Fourth Assessment Report. Risk …

Physical And Electrical Properties Of Trimetallic Nitride Template Endohedral Metallofullerenes And Their Polymer Nanocomposites, Hanaa Mohammed Ahmed

Dissertations

The main objective of this study was characterization of pure metallic nitride fullerene, MNF, and MNF containing polymers to evaluate these materials as suitable devices for tunable applications. Polymer-fullerene nanocomposites consisting of linear polyurethane (PU) segments crosslinked via polyhydroxylated fullerenes (C₆₀ and Sc₃N@C₈₀, a metallic nitride fullerene) were prepared and characterized for their mechanical and dielectric properties using dynamic mechanical analysis (DMA) and broadband dielectric spectroscopic techniques. Polyhydroxylated fullerenes C₆₀(OH)₂₉ and Sc₃N@C₈₀(OH)₁₈ were synthesized in a high yield through a solid-state high sheer ball-milling procedure and were …

Exploration In Metallic Nitride Fullerenes And Oxometallic Fullerenes: A New Class Of Metallofullerenes, Mary Alice Mackey

Dissertations

Research groups around the world have taken an interest in the synthesis, purification, characterization, and functionalization of Metallic Nitride Fullerenes (MNFs) since their discovery in 1999. This dissertation details the discovery of another new class of molecules—Oxometallic Fullerenes (OMFs).

There are many groups worldwide doing research on MNFs, and there is a large database of published MNF research, but we have had a unique opportunity to fill a research void on OMFs as at present no one else is doing research on these molecules; herein we take molecules that we discover and perform seminal research relating to them. MNF research …

Effects Of Molecular Architecture On Fluid Ingress Behavior Of Glassy Polymer Networks, Matthew Blaine Jackson

Dissertations

This manuscript demonstrates the synthesis of glassy polymer network isomers to control morphological variations and study solvent ingress behavior independent of chemical affinity. Well-controlled network architectures with varying free volume average hole-sizes have been shown to substantially influence solvent ingress within glassy polymer networks. Bisphenol-A diglycidyl ether (DGEBA), bisphenol-F diglycidyl ether (DGEBF), Triglycidyl p-aminophenol (pAP, MY0510), Triglycidyl maminophenol (mAP, MY0610), and tetraglydicyl-4,4’-diamino-diphenyl methane (TGDDM, MY721) were cured with 3,3’- and 4,4’-diaminodiphenyl sulfone (DDS) at a stoichiometric ratio of 1:1 oxirane to amine active hydrogen to generate a series of network architectures with an average free volume hole-size (V_h) …

Free Volume Studies Of Various Polymeric Systems Using Positron Annihilation And Pvt-Eos Analyses, Mukul Kaushik

Dissertations

The glass transition phenomenon and free volume behavior below and above the glass transition temperature of various polymeric systems have been investigated. Several novel polymeric systems were considered for this study. Two generations of hyperbranched polyols, H40 and H20, were selected due to large number of hydroxyl groups on the periphery and within the bulk. The effect of hydrogen bonds and molecular weight was related with the glass transition and free volume behavior for the whole range of experimental temperature. The free volume behavior was experimentally studied using PVT and PALS to determine occupied volume, fractional free volume and number …

Development And Utilization Of Digital Image Correlation Techniques For The Study Of Structural Isomerism Effects On Strain Development In Epoxy Network Glasses, Stephen Robert Heinz

Dissertations

The specific aim of this dissertation is to present the findings regarding the effects of molecular structure on macroscopic mechanical performance and strain development in epoxy networks. Network molecular structure was altered through monomer isomerism and crosslink density/molecular weight between crosslinks. The use of structural isomerism provided a pathway for altering mechanical performance while maintaining identical chemical composition within the network. Isomerism was investigated primarily by the curing of diglycidyl ether of bisphenol A (DGEBA) using either the para- or meta-substituted derivatives of diaminodiphenyl sulfone (DDS). Additional insights into isomerism were gained through the investigation of networks composed of either …

On Co-Optimization Of Constrained Satisfiability Problems For Hardware Software Applications, Kunal Ganeshpure

Doctoral Dissertations 1896 - February 2014

Manufacturing technology has permitted an exponential growth in transistor count and density. However, making efficient use of the available transistors in the design has become exceedingly difficult. Standard design flow involves synthesis, verification, placement and routing followed by final tape out of the design. Due to the presence of various undesirable effects like capacitive crosstalk, supply noise, high temperatures, etc., verification/validation of the design has become a challenging problem. Therefore, having a good design convergence may not be possible within the target time, due to a need for a large number of design iterations.

Capacitive crosstalk is one of the …

Limiting Behavior Of Nondeterministic Fillings Of The Torus By Colored Squares, Pablo Rosell Gonzalez

Graduate Theses and Dissertations

In this work we study different dynamic processes for filling tori and n×∞ bands with edge-to-edge black and white squares at random. First we present a simulation for the Random Sequential Adsorption (RSA) with nearest-neighbor rejection on n×n tori. We are interested in the ratio of black to total tiles once the domain is saturated for large domains. Next we study the annealing process. Given a random excited tiling of an n×n torus, we show that as t→∞ the system reaches a stable state in which no tile is excited. This stable state can either be a tiling whose tiles …

Inverse Synthetic Aperture Radar Imaging Theory And Application, Jaime Xavier Lopez

Theses and Dissertations - UTB/UTPA

Inverse Synthetic Aperture Radar (ISAR) is an electromagnetic sensing system that is capable of producing high resolution microwave images of moving targets. Despite being developed within the engineering community, the theory of radar imaging is a subject of tremendous mathematical richness. The theory of ISAR imaging alone is filled with many applications and open problems that the mathematician and physicist may find interesting. In this thesis, the basis for a filtered back projection imaging algorithm is derived from a popular scalar wave model. This imaging algorithm is based on a filtered-adjoint method for inverting ISAR data, and allows for the …

Improved Algorithms For Ear-Clipping Triangulation, Bartosz Kajak

UNLV Theses, Dissertations, Professional Papers, and Capstones

We consider the problem of improving ear-slicing algorithm for triangulating a simple polygon. We propose two variations of ear-slicing technique for generating “good-quality” triangulation. The first approach is based on searching for the best triangle along the boundary. The second approach considers polygon partitioning on a pre-process before applying the ear-slicing. Experimental investigation reveals that both approaches yield better quality triangulation than the standard ear-slicing method.

Self-Repairable Polymeric Networks: Synthesis And Network Design, Biswajit Ghosh

Dissertations

This dissertation describes the design, synthesis and development of a new class of polymeric networks that exhibit self-repairing properties under UV exposure. It consists of two parts: (a) modification and synthesis of oxetane (OXE), and oxolane (OXO) substituted chitosan (CHI) macromonomer, and (b) design, and synthesis of self-repairing polyurethane (PUR) networks consisting of modified chitosan. Unmodified CHI consisting of acetamide (-NHCOCH₃), primary hydroxyl (-OH), and amine (-NH₂) functional groups were reacted with OXE or OXO compounds under basic conditions in order to substitute the 1° –OH groups, and at the same time, convert -NHCOCH₃ functionalities …

Monte Carlo Simulation Of Electron-Induced Air Fluorescence Utilizing Mobile Agents: A New Paradigm For Collaborative Scientific Simulation, Christopher Daniel Walker

Dissertations

A new paradigm for utilization of mobile agents in a modular architecture for scientific simulation is demonstrated through a case study involving Monte Carlo simulation of low energy electron interactions with molecular nitrogen gas. Design and development of Monte Carlo simulations for physical systems of moderate complexity can present a seemingly overwhelming endeavor. The researcher must possess or otherwise develop a thorough understanding the physical system, create mathematical and computational models of the physical system’s components, and forge a simulation utilizing those models. While there is no single route between a collection of physical concepts and a Monte Carlo simulation …

Precision Synthesis Of Functional Materials Via Raft Polymerization And Click-Type Chemical Reactions, Joel Diez Flores

Dissertations

The need to tailor polymeric architectures with specific physico-chemical properties via the simplest, cleanest, and most efficient synthetic route possible has become the ultimate goal in polymer synthesis. Recent progress in macromolecular science, such as the discoveries of controlled/“living” free radical polymerization (CRP) methods, has brought about synthetic capabilities to prepare (co)polymers with advanced topologies, predetermined molecular weights, narrow molecular weight distributions, and precisely located functional groups. In addition, the establishment of click chemistry has redefined the selected few highly efficient chemical reactions that become highly useful in post-polymerization modification strategies. Hence, the ability to make well-defined topologies afforded by …

Benchmarking Bottom-Up And Top-Down Strategies To Sparql-To-Sql Query Translation, Andrii Kashliev

Theses and Dissertations - UTB/UTPA

Many researchers have proposed using conventional relational databases to store and query large Semantic Web datasets. The most complex component of this approach is SPARQL-to-SQL query translation. Existing algorithms perform this translation using either bottom-up or top-down strategy and result in semantically equivalent but syntactically different relational queries. Do relational query optimizers always produce identical query execution plans for semantically equivalent bottom-up and top-down queries? Which of the two strategies yields faster SQL queries? To address these questions, this work studies bottom-up and top-down translations of SPARQL queries with nested optional graph patterns. This work presents: (1) A basic graph …

Modeling Instabilities Of Electrically Driven Jets Under Constant Or Variable Applied Field And Non-Zero Basic State Velocity, Sayantan Das

Theses and Dissertations - UTB/UTPA

We investigate the problem of instability of electrically forced axisymmetric jets with respect to temporally and spatially growing disturbances, within parameter regimes that affects the process of electrospinnning. Deriving a dispersion relation based on the relevant approximated versions of the equations of the electro-hydrodynamics for an electrically forced jet flow. For temporal instability, we find in the non-zero basic state velocity, the growth rate of the unstable mode is unaffected by the value of the basic state velocity. But, the basic state velocity affects the period of the unstable mode in the sense that it decreases the period, and the …