Physical Sciences and Mathematics Commons^™

Review Of Issues Concerning The Use Of Reproductive Inhibitors, With Particular Emphasis On Resolving Human-Wildlife Conflicts In North America, Kathleen A. Fagerstone, Lowell A. Miller, Gary Killian, Christi A. Yoder

United States Department of Agriculture Wildlife Services: Staff Publications

This manuscript provides an overview of past wildlife contraception efforts and discusses the current state of research. Two fertility control agents, an avian reproductive inhibitor containing the active ingredient nicarbazin and an immunocontraceptive vaccine, have received regulatory approval with the Environmental Protection Agency and are commercially available in the USA. OvoControl G Contraceptive Bait for Canada Geese and Ovo Control for pigeons are delivered as oral baits. An injectable immunocontraceptive vaccine (GonaCon Immunocontraceptive Vaccine) was registered with the Environmental Protection Agency for use in female white-tailed deer in September 2009. An injectable product (GonaCon Immunocontraceptive Vaccine) is registered for use …

Synchronous Monitoring Of Vulture Movements With Satellite Telemetry And Avian Radar, Robert C. Beason, J. S. Humphrey, N. E. Myers, Michael L. Avery

United States Department of Agriculture Wildlife Services: Staff Publications

Radar and satellite global positioning system-platform transmitter terminal (GPSPTT) transmitters provide complementary information on the movements and behaviors of individual birds. The GPS-PTT tag provides a snapshot of altitude and location of a specific individual of an identified species at predefined intervals. The history of the individual is known because each transmitter has a unique identification code. The radar cannot identify individuals or even species but it provides continuous position reports (altitude and location) of birds within its detection range. By integrating data from the two sources, the behavior and movements of identified individuals (not possible with radar) can be …

Seroprevalence Of Equine Influenza Virus In Northeast And Southern Mexico, B. J. Blitvitch, L. A. Ibarra-Juarez, A. J. Cortes-Guzman, J. J. Root, A. B. Franklin, H. J. Sullivan, I. Fernandez-Salas

United States Department of Agriculture Wildlife Services: Staff Publications

Equine influenza A virus (EIV) is a highly infectious respiratory pathogen of horses (Hannant and Mumford 1996, Palese and Shaw 2007). The illness is characterised by an abrupt onset of fever, depression, coughing and nasal discharge, and is often complicated by secondary bacterial infections that can lead to pneumonia and death. Two subtypes of EIV, H3N8 and H7N7, have been isolated. The H7N7 subtype was first isolated from a horse in Czechoslovakia in 1956 (Prague/56), and the H3N8 subtype was first isolated from a horse in Miami in 1963 (Sovinova and others 1958, Waddell and others 1963). The last confirmed …

Experimental Infection Of Raccoons (Procyon Lotor) With West Nile Virus, J. Jeffrey Root, Kevin T. Bentler, Nicole M. Nemeth, Thomas Gidlewski, Terry R. Spraker, Alan B. Franklin

United States Department of Agriculture Wildlife Services: Staff Publications

To characterize the responses of raccoons to West Nile virus (WNV) infection, we subcutaneously exposed them to WNV. Moderately high viremia titers (≤ 10^4.6 plaque forming units [PFU]/mL of serum) were noted in select individuals; however, peak viremia titers were variable and viremia was detectable in some individuals as late as 10 days post-inoculation (DPI). In addition, fecal shedding was prolonged in some animals (e.g., between 6 and 13 DPI in one individual), with up to10^5.0 PFU/fecal swab detected. West Nile virus was not detected in tissues collected on 10 or 16 DPI, and no histologic lesions attributable …

Response Of Captive Skunks To Microencapsulated Tetracycline, Brandon S. Schmit, Thomas M. Primus, Jerome C. Hurley, Dennis J. Kohler, Shawna F. Graves

United States Department of Agriculture Wildlife Services: Staff Publications

A captive striped skunk (Mephitis mephitis) study was conducted between February and June 2004 at the United States Department of Agriculture, Animal and Plant Health Inspection Service, Wildlife Services National Wildlife Research Center, Fort Collins, Colorado, USA. The main objective was to determine the percentage of adult striped skunks that were marked after consuming placebo oral rabies vaccine (ORV) baits containing 100 mg of an experimental microencapsulated (coated microparticle) tetracycline hydrochloride biomarker. Biomarkers were identified in the canine teeth and mandibles of five of five skunks that consumed an ORV bait. A second objective was to determine if …

New Evidence Suggests Southern China As A Common Source Of Multiple Clusters Of Highly Pathogenic H5n1 Avian Influenza Virus, Bin Wu, Chengmin Wang, Guoying Dong, Yunhai Guo, Dale L. Nolte, Thomas Jude Deliberto, Jianguo Xu, Mingxing Duan, Hongxuan He

United States Department of Agriculture Wildlife Services: Staff Publications

Highly pathogenic H5N1 avian influenza is considered an avian disease, although there is some evidence of limited human-to-human transmission of the virus. A global effort is underway to control or eradicate the highly pathogenic H5N1 avian influenza virus in poultry and prevent human exposure, both of which may also reduce the risk of pandemic emergence. Hemagglutinin gene sequences from 215 human H5N1 influenza viruses were used to trace the source and dispersal pattern of human H5N1 influenza viruses on a global scale. A mutation network and phylogenetic analyses of the hemagglutinin gene show that human H5N1 influenza viruses can be …

Picosecond Electron Diffraction From Molecules Aligned By Dissociation, Martin Centurion, Peter Reckenthaeler, Ferenc Krausz, Ernst E. Fill

Martin Centurion Publications

In gas electron diffraction an averaging over statistical directions of the molecules takes place. This results in diffraction patterns in the form of isotropic rings which yield information only on the radial distribution function displaying the inter-atomic distances. We demonstrate that by dissociating molecules with linearly polarized light the pattern becomes anisotropic. In the experiments the iodide C₂F₄I₂ is dissociated and molecular difference intensities and difference radial distribution curves are measured for directions parallel and perpendicular to the direction of polarization. With picosecond temporal resolution the curves clearly demonstrate transient anisotropy and its decay by …

Dissociative Electron Attachment In Nonplanar Chlorocarbons With Π*/Σ*-Coupled Molecular Orbitals, Kayvan Aflatooni, Gordon A. Gallup, Paul Burrow

Paul Burrow Publications

Total absolute cross sections for the dissociative electron attachment (DEA) process are reported for a series of nonplanar ethylenic and phenylic compounds monosubstituted with (CH₂)_nCl groups, where n=1–4. Coupling between the local π^* molecular orbitals provided by the unsaturated moieties and the σ^* (C-Cl) orbital is thus examined as a function of the separation of these groups. In particular, the coupling is viewed from the perspective of the interacting temporary negative ions formed by short lived occupation of these orbitals and their decay into the DEA channel. A theoretical treatment of “remote” bond breaking, …

Vibrational Properties Of Ferroelectric Β-Vinylidene Fluoride Polymers And Oligomers, Serge M. Nakhmanson, Rafal Korlacki, J. Travis Johnston, Stephen Ducharme, Zhongxin Ge, James M. Takacs

Stephen Ducharme Publications

We utilize a plane-wave density-functional theory approach to investigate the vibrational properties of the all-trans ferroelectric phase of poly(vinylidene fluoride) (β-PVDF) showing that its stable state corresponds to the Ama2 structure with ordered dihedral tilting of the VDF monomers along the polymer chains. We then combine our theoretical analysis with IR spectroscopy to examine vibrations in oligomer crystals that are structurally related to the β-PVDF phase. We demonstrate that these materials—which can be grown in a highly crystalline form—exhibit IR activity similar to that of β-PVDF, making them an attractive choice for the studies of electroactive phenomena and phase transitions …

Why Ferroelectric Polyvinylidene Fluoride Is Special, Matt Poulsen, Stephen Ducharme

Stephen Ducharme Publications

Ferroelectric polymers entail a number of constraints, which together limit the useful compositional variations. These constraints include the following: a stable molecular dipole moment, compact crystal structure, conformational flexibility, and minimal steric hindrance. They are well satisfied by the prototype ferroelectric polymer, polyvinylidene fluoride, and yet almost every other conceivable molecular structure is limited by comparison.

Ab Initio Calculations And Ellipsometry Measurements Of The Optical Properties Of The Layered Semiconductor In4Se3, L. Makinistian, E. A. Albanesi, N. V. Gonzalez Lemus, A. G. Petukhov, D. Schmidt, Eva Schubert, M. Schubert, Yaroslav B. Losovyj, P. Galiy, Peter A. Dowben

Peter Dowben Publications

In this work, we present a thorough study of the optical properties of the layered orthorhombic compound In₄Se₃. The dielectric function—real and imaginary parts, the complex refraction index, the reflectivity, the absorption coefficient, and the conductivity of In₄Se₃ were calculated with the inclusion of the spin-orbit interaction, using an ab initio FP-LAPW method based on DFT. Also, generalized ellipsometry was employed for more precise measurement of the anisotropic dielectric functions for polarization along crystal a, b, and c axes of orthorhombic absorbing In₄Se₃ single crystals cut approximately parallel to …

The Local Structure Of Transition Metal Doped Semiconducting Boron Carbides, Jing Liu, Guangfu Luo, Wai-Ning Mei, Orhan Kizilkaya, Eric D. Shepherd, Jennifer I. Brand, Peter A. Dowben

Peter Dowben Publications

Transition metal doped boron carbides produced by plasma enhanced chemical vapour deposition of orthocarborane (closo-1,2-C₂B₁₀H₁₂) and 3d metal metallocenes were investigated by performing K-edge extended x-ray absorption fine structure and x-ray absorption near edge structure measurements. The 3d transition metal atom occupies one of the icosahedral boron or carbon atomic sites within the icosahedral cage. Good agreement was obtained between experiment and models for Mn, Fe and Co doping, based on the model structures of two adjoined vertex sharing carborane cages, each containing a transition metal. The local spin configurations of all …

Double Parton Interactions In Γ = 3 Jet Events In Pp Collisions At √S = 1.96 Tev, V. M. Abazov, Kenneth A. Bloom, Gregory Snow, D0 Collaboration

Kenneth Bloom Publications

We have used a sample of γ + 3 jets events collected by the D0 experiment with an integrated luminosity of about 1 fb^-1 to determine the fraction of events with double parton scattering (f_DP) in a single pp collision at √s = 1.96 TeV. The DP fraction and effective cross section (τ_eff ), a process-independent scale parameter related to the parton density inside the nucleon, are measured in three intervals of the second (ordered in p_T) jet transverse momentum p^jet2_T within the range 15 ≤ p^jet2_T ≤ …

Search For The Standard Model Higgs Boson In The Zh → ΝνBb Channel In 5.2 Fb-1 Of Pp Collisions At √S = 1.96 Tev, V. M. Abazov, Kenneth A. Bloom, Gregory Snow, D0 Collaboration

Kenneth Bloom Publications

A search is performed for the standard model Higgs boson in 5.2 fb^-1 of pp collisions at √s = 1.96 TeV, collected with the D0 detector at the Fermilab Tevatron Collider. The final state considered is a pair of b jets and large missing transverse energy, as expected from pp → ZH → ννbb production. The search is also sensitive to the WH → ℓνbb channel when the charged lepton is not identified. For a Higgs boson mass of 115 GeV, a limit is set at the 95% C.L. on the cross section multiplied by branching …

Search For The Associated Production Of A B Quark And A Neutral Supersymmetric Higgs Boson That Decays Into Τ Pairs, V. M. Abazov, Kenneth A. Bloom, Gregory Snow, D0 Collaboration

Kenneth Bloom Publications

We report results from a search for production of a neutral Higgs boson in association with a b quark. We search for Higgs decays to τ pairs with one τ subsequently decaying to a muon and the other to hadrons. The data correspond to 2.7 fb^-1 of pp collisions recorded by the D0 detector at √s = 1.96 TeV. The data are found to be consistent with background predictions. The result allows us to exclude a significant region of parameter space of the minimal supersymmetric model.

Combination Of Tevatron Searches For The Standard Model Higgs Boson In The W+W- Decay Mode, V. M. Abazov, Kenneth A. Bloom, Gregory Snow, D0 Collaboration

Kenneth Bloom Publications

We combine searches by the CDF and D0 Collaborations for a Higgs boson decaying to W⁺W^-. The data correspond to an integrated total luminosity of 4.8 (CDF) and 5.4 (D0) fb^-1 of pp collisions at √s = 1.96 TeV at the Fermilab Tevatron collider. No excess is observed above background expectation, and resulting limits on Higgs boson production exclude a standard model Higgs boson in the mass range 162–166 GeV at the 95% C.L.

Debugging Data Transfers In Cms, G. Gagliesi, S. J. Belforte, Kenneth A. Bloom, B. Bockelman, D. Bonacorsi, I. Fisk, J. Flix, J. Hernandez, J. D'Hondt, M. Kadastik, J. Klem, O. Kodolova, C.-M. Kuo, J. Letts, J. Maes, N. Magini, S. Metson, J. Piedra, N. Pukhaeva, L. Turra, S. Sõnajalg, Y. Wu, P. Van Mulders, I. Villella, F. Würthwein

Kenneth Bloom Publications

The CMS experiment at CERN is preparing for LHC data taking in several
computing preparation activities. In early 2007 a traffic load generator infrastructure for distributed data transfer tests was designed and deployed to equip the WLCG tiers which support the CMS virtual organization with a means for debugging, load-testing and commissioning data transfer routes among CMS computing centres. The LoadTest is based upon PhEDEx as a reliable, scalable data set replication system. The Debugging Data Transfers (DDT) task force was created to coordinate the debugging of the data transfer links. The task force aimed to commission most crucial transfer …

Probing Equilibrium By Nonequilibrium Dynamics: Aging In Co/Cr Superlattices, Tathagata Mukherjee, M. Pleimling, Christian Binek

Christian Binek Publications

Magnetization relaxation is investigated in a structurally ordered magnetic Co/Cr superlattice. Tailored nanoscale periodicity creates mesoscopic spatial magnetic correlations with slow relaxation dynamics when quenching the system into a nonequilibrium state. Magnetization transients are measured after exposing the heterostructure to a magnetic set field for various waiting times. Scaling analysis reveals an asymptotic powerlaw behavior in accordance with a full aging scenario. The temperature dependence of the relaxation exponent shows pronounced anomalies at the equilibrium phase transitions of the antiferromagnetic superstructure and the ferromagnetic to paramagnetic transition of the Co layers. The latter leaves only weak fingerprints in the equilibrium …

Isomer Identification And Resolution In Small Gold Clusters, Wei Huang, Rhitankar Pal, Lei-Ming Wang, Xiao Cheng Zeng, Lai-Sheng Wang

Xiao Cheng Zeng Publications

A variety of experimental techniques are used to resolve energetically close isomers of Au_{7 ⁻} and Au_{8 ⁻} by combining photoelectron spectroscopy and ab initio calculations. Two structurally distinct isomers are confirmed to exist in the cluster beam for both clusters. Populations of the different isomers in the cluster beam are tuned using Ar-tagging, O₂-titration, and isoelectronic atom substitution by Cu and Ag. A new isomer structure is found for Au_{7 ⁻}, which consists of a triangular Au₆ unit with a dangling Au atom. Isomer-specific photoelectron spectra of Au_{8 ⁻} are obtained …

Vowel Recognition From Continuous Articulatory Movements For Speaker-Dependent Applications, Jun Wang, Jordan R. Green, Ashok Samal, Tom D. Carrell

Department of Special Education and Communication Disorders: Faculty Publications

A novel approach was developed to recognize vowels from continuous tongue and lip movements. Vowels were classified based on movement patterns (rather than on derived articulatory features, e.g., lip opening) using a machine learning approach. Recognition accuracy on a single-speaker dataset was 94.02% with a very short latency. Recognition accuracy was better for high vowels than for low vowels. This finding parallels previous empirical findings on tongue movements during vowels. The recognition algorithm was then used to drive an articulation-to-acoustics synthesizer. The synthesizer recognizes vowels from continuous input stream of tongue and lip movements and plays the corresponding sound samples …

A Boosting Framework For Visuality-Preserving Distance Metric Learning And Its Application To Medical Image Retrieval, Yang Liu, Rong Jin, Lily Mummert, Rahul Sukthankar, Adam Goode, Bin Zheng, Steven C. H. Hoi, Mahadev Satyanarayanan

Research Collection School Of Computing and Information Systems

Similarity measurement is a critical component in content-based image retrieval systems, and learning a good distance metric can significantly improve retrieval performance. However, despite extensive study, there are several major shortcomings with the existing approaches for distance metric learning that can significantly affect their application to medical image retrieval. In particular, "similarity" can mean very different things in image retrieval: resemblance in visual appearance (e.g., two images that look like one another) or similarity in semantic annotation (e.g., two images of tumors that look quite different yet are both malignant). Current approaches for distance metric learning typically address only one …

Improved Arene Fluorination Methodology For I(Iii) Salts, Bijia Wang, Linlin Qin, Kiel D. Neumann, Shriharsha Uppaluri, Ronald Cerny, Stephen G. Dimagno

Ronald Cerny Publications

The use of low polarity aromatic solvents (benzene or toluene) and/or the removal of inorganic salts results in dramatically improved yields of fluorinated arenes from diaryliodonium salts. This methodology is shown to “scale down” to the conditions used typically for radiotracer synthesis.

Concave Cubic Gold Nanocrystals With High-Index Facets, Jian Zhang, Mark R. Langille, Michelle L. Personick, Ke Zhang, Shuyou Li, Chad A. Mirkin

Department of Chemistry: Faculty Publications

A new class of gold nanostructures, concave nanocubes, enclosed by 24 high-index {720} facets, have been prepared in a monodisperse fashion by a modified seed-mediated synthetic method. The Cl− counterion in the surfactant plays an essential role in controlling the concave morphology of the final product. The concave nanocubes exhibit higher chemical activities compared with low-index {111}-faceted octahedra.

Includes Supporting Information.

Corrosion Of Steel Shipwrecks In The Marine Environment: Uss Arizona—Part 2, Donald L. Johnson, Brent M. Wilson, James D. Carr, Matthew A. Russell, Larry E. Murphy, David L. Conlin

Department of Chemistry: Faculty Publications

This article is a continuation of Part 1 (October 2006 MP) on the USS Arizona hull. It discusses additional methods being investigated for use in determining corrosion rates with a minimal impact on the existing structure. Marine biofouling (concretion) has accumulated on the hull. Concretion samples have been studied using x-ray diffraction, environmental electron microscopy, and corrosion potential (E_corr) to characterize the relationship between concretion and the steel substrate. The data presented in this study confirm the viability of concretion analysis as a minimum-impact procedure to estimate the corrosion rate of mild steel in seawater.

Corrosion Of Civil War Era Sub Marine Explorer—Part 2, Donald L. Johnson, James D. Carr, Brent M. Wilson, Larry E. Murphy, James P. Delgado

Department of Chemistry: Faculty Publications

The Sub Marine Explorer was designed and built by Julius H. Kroehl, who was born in Prussia in 1820. After migrating to the United States in 1838 and becoming a citizen, he served in the Union Navy (United States Navy during the Civil War) as an underwater demolitions expert. He left the Navy in 1863 and began designing a “sub-marine” that would facilitate Union forces’ mine removal and obstruction clearance. At the end of the Civil War, he became an engineer for the Pacific Pearl Co., an organization interested in using the craft to recover pearls from deep sea oyster …

Corrosion Of Civil War Era Sub Marine Explorer—Part 1, Donald L. Johnson, James D. Carr, Brent M. Wilson, Larry E. Murphy, James P. Delgado

Department of Chemistry: Faculty Publications

The Sub Marine Explorer is one of five submersibles (submarines) constructed prior to 1870 that have survived either in museums or as in situ archaeological sites around the world. Since 1869, the wreck of Explorer has emerged at low tide on the beach of Isla San Telmo, Archipiélago de las Perlas, Panama, located ~75 km southwest of Panama City in the Bay of Panama. In 2001, James Delgado visited the site. Locals described the wreck as a World War II-era Japanese midget submarine. Delgado consulted with Richard Wills, an expert on American Civil War submarines, and confirmed that the well-preserved …

Method For Monitoring The Stereoselectivity And Relative Rate Of Organic Chemical Reactions, David R. Berkowitz, Sangeeta Dey, Kannan R. Karukurichi, Weijun Shen

Department of Chemistry: Faculty Publications

A method for monitoring the stereoselectivity of at least one organic chemical reaction and the relative rate of at least one organic chemical reaction, wherein the reaction produces a product that can exist as at least two stereoisomers, is provided herein. Also disclosed are methods for identifying and preparing catalysts for the above reactions.

Regiospecific Reductive Elimination From Diaryliodonium Salts, Bijia Wang, Joseph W. Graskemper, Linlin Qin, Stephen G. Dimagno

Stephen DiMagno Papers

StereoElectronic Control of Unidirectional Reductive Elimination (SECURE) is provided by the cyclophane substituent on iodine(III). Computational and experimental studies demonstrate that out of plane steric bulk strongly destabilizes the reductive elimination transition state, and leads to regiochemical control. This approach should be general for high valent main group and transition metal ions.

Ni Doping Of Semiconducting Boron Carbide, Nina Hong, Marjorie Langell, Jing Liu, Orhan Kizilkaya, Shireen Adenwalla

Marjorie A. Langell Publications

The wide band gap, temperature stability, high resistivity, and robustness of semiconducting boron carbide make it an attractive material for device applications. Undoped boron carbide is p type; Ni acts as a n-type dopant. Here we present the results of controlled doping of boron carbide with Ni on thin film samples grown using plasma enhanced chemical vapor deposition. The change in the dopant concentration within the thin film as a function of the dopant flow rate in the precursor gas mixture was confirmed by x-ray photoelectron spectroscopy measurements; with increasing dopant concentration, current-voltage (I-V) curves clearly establish the trend from …

Resource Selection By Elk In An Agro-Forested Landscape Of Northwestern Nebraska, David M. Baasch, Justin W. Fischer, Scott E. Hygnstrom, Kurt C. Vercauteren, Andrew J. Tyre, Joshua J. Millspaugh, James W. Merchant, Jerry D. Volesky

School of Natural Resources: Faculty Publications

In recent years, elk have begun recolonizing areas east of the Rocky Mountains that are largely agroforested ecosystems composed of privately owned land where management of elk is an increasing concern due to crop and forage depredation and interspecific disease transmission. We used a Geographic Information System, elk use locations (n = 5013), random locations (n = 25,065), discrete-choice models, and information-theoretic methods to test hypotheses about elk resource selection in an agro-forested landscape located in the Pine Ridge region of northwestern Nebraska, USA. Our objectives were to determine landscape characteristics selected by female elk and identify publicly owned land …