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Articles 421 - 450 of 6945
Full-Text Articles in Physical Sciences and Mathematics
Factors, Preventions And Correction Methods For Non-Response In Sample Surveys, Godwin Nwanzu Amahi
Factors, Preventions And Correction Methods For Non-Response In Sample Surveys, Godwin Nwanzu Amahi
CBN Journal of Applied Statistics (JAS)
Missing survey data occur because of unit and item non-response. This is practically independent of the method of data collection. As a result of the bias that non-response sometimes introduces in survey estimates, identifying factors that promote it, and taking measures of prevention and correction methods are clearly necessary. The standard method to compensate for unit non-response is by weighting adjustment, while item non-responses are handled by some form of imputation. This paper reviews factors that give rise to nonresponse and the corresponding methods used for its prevention and control. It also discusses their properties.
Addressing The Problem Of Non-Response And Response Bias, Fabian C. Okafor
Addressing The Problem Of Non-Response And Response Bias, Fabian C. Okafor
CBN Journal of Applied Statistics (JAS)
Survey planners and analysts in Nigeria have devoted much more attention to sampling errors at the expense of nonsampling errors (non-response and response errors). Sampling error is the degree to which the sample estimate differs from the average value of the characteristic due to chance. The present discussion will be centered on non-sampling error, which may present serious deficiencies in the statistics and render the survey useless. According to Platek and Gray (1986), “Non-response has been generally recognized as important measure of the quality of data since it affects the estimates by introducing a possible bias in the estimates and …
Statistics For National Development, Sani I. Doguwa
Statistics For National Development, Sani I. Doguwa
CBN Journal of Applied Statistics (JAS)
Good statistics that has been collected according to agreed good practices are crucial as a tool for development. Gross domestic product (GDP) and other measures of economic activity such as Gross National Income (GNI) together with their individual components, show how the economy is responding to government policy and other influences. The balance of payments can demonstrate the requirement for policy adjustments and is also one of the indicators scrutinised by potential foreign investors in the country. Agricultural statistics clearly have implications for longer-term planning, particularly if they show a move away from the land into urban areas or a …
A Type Analysis Of Rewrite Strategies, Azamat Mametjanov
A Type Analysis Of Rewrite Strategies, Azamat Mametjanov
Student Work
Rewrite strategies provide an algorithmic rewriting of terms using strategic compositions of rewrite rules. Due to the programmability of rewrites, errors are often made due to incorrect compositions of rewrites or incorrect application of rewrites to a term within a strategic rewriting program. In practical applications of strategic rewriting, testing and debugging becomes substantially time-intensive for large programs applied to large inputs derived from large term grammars. In essence, determining which rewrite in what position in a term did or did not re comes down to logging, tracing and/or di -like comparison of inputs to outputs. In this thesis, we …
Current Distribution Of Rare Fishes In Eastern Wyoming Prairie Streams, Christina E. Barrineau, Elizabeth A. Bear, Anna C. Senecal
Current Distribution Of Rare Fishes In Eastern Wyoming Prairie Streams, Christina E. Barrineau, Elizabeth A. Bear, Anna C. Senecal
The Prairie Naturalist
Distributions of native fishes have declined throughout the Great Plains region. Over 50% of native fishes within the Missouri River drainage in Wyoming have experienced declines in distributions. Thus, the primary goal of our study was to assess current distribution of rare native fishes in eastern Wyoming prairie streams. Of the 10 rare fishes sampled, goldeye (Hiodon alosoides), western silvery minnow (Hybognathus argyritis), plains minnow (H. hankinsoni), and Iowa darter (Etheostoma exile) have experienced declines in distribution over the last decade. Plains topminnow (Fundulus sciadicus) appears to be expanding to areas outside …
Examination Of Owl Pellets For Northern Pocket Gophers At Crescent Lake National Wildlife Refuge, Nebraska, Stacey L. Bonner, Keith Geluso
Examination Of Owl Pellets For Northern Pocket Gophers At Crescent Lake National Wildlife Refuge, Nebraska, Stacey L. Bonner, Keith Geluso
The Prairie Naturalist
Analysis of regurgitated pellets from owls is a well-known and nondestructive method that provides useful information regarding diet (Errington 1930). This technique also is used to examine composition of small mammal communities and distribution of prey species (e.g. Kamler et al. 2003, Torre et al. 2004, Poole and Matlack 2007). In western Nebraska, two species of owls that regularly breed in the region are the common barn owl (Tyto alba) and great horned owl (Bubo virginianus). In the early 1970s, Rickart (1972) studied the diet of both species at Crescent Lake National Wildlife Refuge (CLNWR), Garden …
Seasonal Yellow Perch Harvest In Two Dissimilar South Dakota Fisheries, Casey W. Schoenebeck, Michael L. Brown, David O. Lucchesi
Seasonal Yellow Perch Harvest In Two Dissimilar South Dakota Fisheries, Casey W. Schoenebeck, Michael L. Brown, David O. Lucchesi
The Prairie Naturalist
Angler effort and fish harvest in South Dakota have historically been quantified through summer and winter creel surveys. However, the late-summer, pulsed recruitment of yellow perch (Perea flavescens) into a fishery combined with an increase in fall movement and feeding activity suggested September and October could be significant periods of perch harvest in South Dakota lakes. Seasonal trends in angler effort and yellow perch harvest during 2005-2007 were compared for high- and low-quality yellow perch fishery types commonly found in eastern South Dakota glacial lakes. High-quality yellow perch fisheries are characterized by fast growth (mean total length at age-3 greater …
Resource Selection Of Greater Prairie-Chicken And Sharp-Tailed Grouse Broods In Central South Dakota, Mark A. Norton, Kent C. Jensen, Anthony P. Leif, Thomas R. Kirschenmann, Gregaory A. Wolbrink
Resource Selection Of Greater Prairie-Chicken And Sharp-Tailed Grouse Broods In Central South Dakota, Mark A. Norton, Kent C. Jensen, Anthony P. Leif, Thomas R. Kirschenmann, Gregaory A. Wolbrink
The Prairie Naturalist
Habitat use of sympatric greater prairie-chicken (Tympanuchus cupido) and sharp-tailed grouse (T. phasianellus) broods during the brood-rearing season has not been quantified for stable prairie grouse populations in large contiguous grassland landscapes in the Northern Great Plains. Characteristics of habitats used by prairie grouse broods were described based on data collected from 35 broods (18 greater prairie-chicken and 17 sharp-tailed grottse) during the breeding seasons of 2004 and 2005. Greater prairie-chicken and sharp-tailed grouse broods used vegetation with visual obstruction heights 2:26 cm and 37 cm, respectively. Greater prairie-chicken broods selected western wheatgrass (Pascopyrum smithii …
Diets Of Nesting Swainson's Hawks In Relation To Land Cover In Northwestern North Dakota, Robert K. Murphy
Diets Of Nesting Swainson's Hawks In Relation To Land Cover In Northwestern North Dakota, Robert K. Murphy
The Prairie Naturalist
Relationships between land use practices and types of prey used by Swainson's hawks (Buteo swainsoni) in the Northern Great Plains is of increasing interest as the quantity and quality of habitat in the region declines. I recorded 1,284 prey items at 18 Swainson' s hawk nesting areas throughout northwestern North Dakota during summer 1986-1987. After correcting for detectability biases and food needs of adults, I estimated (90% CI) 2,087-2,859 total prey individuals and 138.3-206.7 kg of prey biomass (x = 69.8 g/item) were consumed by adult and nestling Swainson's hawks during my study. Major prey (>10% overall …
The Distribution And Comparative Biogeochemistry Of Silver With Other Selected Trace Metals In Coastal Waters Near Massachusetts, Usa, Christian F. Krahforst
The Distribution And Comparative Biogeochemistry Of Silver With Other Selected Trace Metals In Coastal Waters Near Massachusetts, Usa, Christian F. Krahforst
Graduate Doctoral Dissertations
Water samples and hydrologic data were collected during 1994-1996 in New England coastal waters near Massachusetts, USA to examine the distribution of silver and other trace metals (Cu, Pb, Cd, Zn, and Fe) in the coastal systems of Massachusetts and Cape Cod Bays. These investigations were designed to test the hypothesis that silver could serve as a tracer of dispersion of municipal wastewater in Boston Harbor into Massachusetts and Cape Cod Bays and estimate the relative contribution of wastewater discharge to the overall silver budget of the Massachusetts Bays system. Silver concentrations in both particulate and filtered (<0.4 µm) fractions averaged 103 and 117 pmol kg-1 for Boston Harbor, 34 and 10 pmol kg-1 in western Massachusetts Bay, and 11 and 7 pmol kg-1 in the central portion of Massachusetts Bay, respectively. Average Ag concentrations in southern Gulf of Maine coastal waters were 10 and 2 pmol kg-1 for filtered and particulate fractions, respectively. While nearly half of the silver existed in particulate form in Boston Harbor, nearly 80% of the silver in Massachusetts and Cape Cod Bays occurred in the filterable fraction. Coastal water surveys revealed non-conservative Ag behavior and probably the result of incomplete mixing of three or more water masses with unique Ag signatures (e.g., Merrimack River, Boston Harbor, surface and intermediate Gulf of Maine waters). Quasi-steady state mass balance approaches estimate most of the silver entering into the Massachusetts Bays system during the study period was the result of municipal wastewater discharge to Boston Harbor (84-93%).
Multivariate analyses …
0.4>Pervasive Thermal Consequences Of Stream-Lake Interactions In Small Rocky Mountain Watersheds, Usa, Jessica D. Garrett
Pervasive Thermal Consequences Of Stream-Lake Interactions In Small Rocky Mountain Watersheds, Usa, Jessica D. Garrett
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
Limnologists and stream ecologists acknowledge the fundamental importance of temperature for regulating many ecological, biological, chemical, and physical processes. I investigated how water temperatures were affected by hydrologic linkages between streams and lakes at various positions along surface water networks throughout several headwater basins in the Sawtooth and White Cloud Mountains of Idaho (USA). Temperatures of streams and lakes were measured for up to 27 months in seven 6 – 41 km2 watersheds, with a range of lake influence. When they were ice-free, warming in lakes resulted in dramatically warmer temperatures at lake outflows compared to inflow streams (midsummer …
Invariant And Coinvariant Spaces For The Algebra Of Symmetric Polynomials In Non-Commuting Variables, Francois Bergeron, Aaron Lauve
Invariant And Coinvariant Spaces For The Algebra Of Symmetric Polynomials In Non-Commuting Variables, Francois Bergeron, Aaron Lauve
Mathematics and Statistics: Faculty Publications and Other Works
We analyze the structure of the algebra K⟨x⟩Sn of symmetric polynomials in non-commuting variables in so far as it relates to K[x]Sn, its commutative counterpart. Using the "place-action" of the symmetric group, we are able to realize the latter as the invariant polynomials inside the former. We discover a tensor product decomposition of K⟨x⟩Sn analogous to the classical theorems of Chevalley, Shephard-Todd on finite reflection groups.
Résumé. Nous analysons la structure de l'algèbre K⟨x⟩Sn des polynômes symétriques en des variables non-commutatives pour obtenir des analogues des résultats classiques concernant la structure de l'anneau K[x]Sn des polynômes symétriques en des variables …
Projection Of Diffraction Patterns For Use In Cold-Neutral-Atom Trapping, Katharina Gillen-Christandl, Glen D. Gillen
Projection Of Diffraction Patterns For Use In Cold-Neutral-Atom Trapping, Katharina Gillen-Christandl, Glen D. Gillen
Physics
Scalar diffraction theory is combined with beam-propagation techniques to investigate the projection of near-field diffraction patterns to spatial locations away from the aperture for use in optically trapping cold neutral alkali-metal atoms. Calculations show that intensity distributions with localized bright and dark spots usually found within a millimeter of the diffracting aperture can be projected to a region free from optical components such as a cloud of cold atoms within a vacuum chamber. Calculations also predict that the critical properties of the optical dipole atom traps are not only maintained for the projected intensity patterns but also can be manipulated …
Study On Intumescent Flame Retarded Polystyrene Composites With Improved Flame Retardancy, Hongdian Lu, Charles A. Wilkie
Study On Intumescent Flame Retarded Polystyrene Composites With Improved Flame Retardancy, Hongdian Lu, Charles A. Wilkie
Chemistry Faculty Research and Publications
The flame retardancy and thermal stability of ammonium polyphosphate/tripentaerythritol (APP/TPE) intumescent flame retarded polystyrene composites (PS/IFR) combined with organically-modified layered inorganic materials (montmorillonite clay and zirconium phosphate), nanofiber (multiwall carbon nanotubs), nanoparticle (Fe2O3) and nickel catalyst were evaluated by cone calorimetry, microscale combustion calorimetry (MCC) and thermogravimetric analysis (TGA). Cone calorimetry revealed that a small substitution of IFR by most of these fillers (≤2%) imparted substantial improvement in flammability performance. The montmorillonite clay exhibited the highest efficiency in reducing the peak heat release rate of PS/IFR composite, while zirconium phosphate modified with C21H26 …
Psychometric Properties Of Postsecondary Students' Course Evaluations, Michael J. Drysdale
Psychometric Properties Of Postsecondary Students' Course Evaluations, Michael J. Drysdale
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
Several experts in the area of postsecondary student evaluations of courses have concluded that they are stable or reliable measures as well as being measures that provide ways of making valid inferences regarding teacher effectiveness. Often these experts have offered these conclusions without supporting evidence. Surprisingly, a thorough review of the literature revealed very few reported test-retest reliability studies of course evaluations and the results from these studies are contradictory. In the area of validity, the conclusions offered by scholars who conducted meta-analyses of mutlisection course studies are inconsistent. This leads to the following two research questions:
1. What is …
Novel Approaches To Image Segmentation Based On Neutrosophic Logic, Ming Zhang
Novel Approaches To Image Segmentation Based On Neutrosophic Logic, Ming Zhang
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
Neutrosophy studies the origin, nature, scope of neutralities, and their interactions with different ideational spectra. It is a new philosophy that extends fuzzy logic and is the basis of neutrosophic logic, neutrosophic probability, neutrosophic set theory, and neutrosophic statistics.
Because the world is full of indeterminacy, the imperfection of knowledge that a human receives/observes from the external world also causes imprecision. Neutrosophy introduces a new concept , which is the representation of indeterminacy. However, this theory is mostly discussed in physiology and mathematics. Thus, applications to prove this theory can solve real problems are needed.
Image segmentation is the first …
Statistical Analysis Of The Usu Lidar Data Set With Reference To Mesospheric Solar Response And Cooling Rate Calculation, With Analysis Of Statistical Issues Affecting The Regression Coefficients, Troy Alden Wynn
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
Though the least squares technique has many advantages, its possible limitations as applied in the atmospheric sciences have not yet been fully explored in the literature. The assumption that the atmosphere responds either in phase or out of phase to the solar input is ubiquitous. However, our analysis found this assumption to be incorrect. If not properly addressed, the possible consequences are bias in the linear trend coefficient and attenuation of the solar response coefficient.
Using USU Rayleigh lidar temperature data, we found a significant phase offset to the solar input in the temperatures that varies ±5 years depending on …
Conservation From The Bottom-Up: Human, Financial, And Natural Capital As Determinants Of Resilient Livelihoods In Kigoma Rural, Tanzania, Yared J. Fubusa
Conservation From The Bottom-Up: Human, Financial, And Natural Capital As Determinants Of Resilient Livelihoods In Kigoma Rural, Tanzania, Yared J. Fubusa
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
Rhetoric of "community-based conservation" has gained prominence among development specialists and environmentalists, yet such projects are often implemented from the top-down in Africa. This dissertation contends that only a bottom-up approach can foster resilient livelihoods and environmental stewardship.
This study focused on determinants of household resilience within a poverty-stricken agricultural community near Gombe Stream National Park (GSNP) in western Tanzania. The research purpose was to explore: 1) relationships between villagers and GSNP management; 2) how groups and individuals view priority livelihood problems and solutions; 3) various attributes of households; and 4) perceived trends for household resilience and how these are …
Recreation Resource Impacts In The Bear Lake Road Corridor Of Rocky Mountain National Park, Colorado, Usa: An Assessment Of Resource Conditions And Visitor Perceptions, Ashley L. D'Antonio
Recreation Resource Impacts In The Bear Lake Road Corridor Of Rocky Mountain National Park, Colorado, Usa: An Assessment Of Resource Conditions And Visitor Perceptions, Ashley L. D'Antonio
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
Visitor use in parks and protected areas inevitably leads to resource impacts. In order to effectively manage for resource impacts, it is important for managers to not only understand ecological aspects of their system but sociological aspects as well. The two papers presented in this thesis used integrated approaches to better understand the current level of resource impacts within the Bear Lake Road Corridor of Rocky Mountain National Park and to explore visitor perceptions of these impacts. The first paper used traditional monitoring and assessment techniques, as well as recently developed methodologies, to determine the current level of resource impacts …
Residential Landscape Water Check Programs: Exploring A Conservation Tool, Diana T. Glenn
Residential Landscape Water Check Programs: Exploring A Conservation Tool, Diana T. Glenn
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
In response to drought and regional growth in the arid western United States, urban water demand management is increasingly important. Single family residences use approximately 60% of their water consumption to irrigate landscapes often in excess of plant water requirements. This study utilized a quasi-experimental design to investigate outdoor water consumption and assess the effectiveness of a landscape water check conservation program. Study objectives included describing a contextualized landscape system to reveal variables influencing water use, identifying better ways to evaluate landscape water use, and more effectively targeting and delivering water conservation programs.
The study was conducted during the 2004 …
Effect Of Mica Content On Surface Infiltration Of Soils In Northwestern Kern County, California, Steven Keyes Stakland
Effect Of Mica Content On Surface Infiltration Of Soils In Northwestern Kern County, California, Steven Keyes Stakland
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
A soils infiltration rate (IR) is the measured rate that soil is able to absorb water, either from precipitation or irrigation. A low IR can cause damage to crops if the necessary amount of water cannot penetrate to the plant roots in the time needed. The damage can be common in permanent plantings such as almond and pistachio orchards where regular tillage is avoided. This indicates a physical aspect to the problem because tillage increases IR. However, there is also an electrochemical side to infiltration problems because certain calcium surfactant treatments can increase IR. Various other methods have been used …
Spatial Light Dilution As A Technique For Conversion Of Solar Energy To Algal Biomass, Daniel J. Dye
Spatial Light Dilution As A Technique For Conversion Of Solar Energy To Algal Biomass, Daniel J. Dye
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
A photobioreactor has been designed and developed to efficiently utilize solar irradiance through spatial dilution of sunlight. The concept of spatial light dilution is simple: incident sunlight is spread over a large surface area, thus reducing the photon flux density of the light. The implementation of this technique, however, is difficult. The reactor described within uses a new approach to spatial light dilution, utilizing recently-developed optical components to diffuse concentrated sunlight inside an algae culture. Preliminary productivity tests indicate a 2-3 fold increase in productivity per unit aperture (sunlight collection area) over a control reactor with direct-sunlight. Aperture productivity of …
Kinetic, Mechanistic, And Structural Investigation Of Features Controlling Stereoselectivity Of (R)- And (S)-Hydroxypropyl Com Dehydrogenases From Xanthobacter Autrophicus Strain Py2, Dariusz Adam Sliwa
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
Enantiopure alcohols are valuable intermediates in fine organic synthesis, in particular for preparation of biologically active compounds. The necessity of preparing single enantiomer drugs in an optically pure form has triggered much research, especially in the pharmaceutical industry. The biocatalytical production of chiral alcohols by alcohol dehydrogenase enzymes is characterized by the asymmetric reduction of the corresponding ketones, usually with high degree of stereoselectivity. The commercial value of the enzymes as stereoselective biocatalysts has been a significant driving force in understanding features that control their mechanism of catalysis and stereoselectivity. This work focuses on two enantiocomplementary dehydrogenase enzymes ((R …
Estimates Of The Hydraulic Parameters Of Aquifers In Cache Valley, Utah And Idaho, Paul C. Inkenbrandt
Estimates Of The Hydraulic Parameters Of Aquifers In Cache Valley, Utah And Idaho, Paul C. Inkenbrandt
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
Hydraulic parameters of aquifers in Cache Valley were compiled from existing but largely unpublished data, from specific capacity data reported in well drillers' records, and from aquifer tests conducted for this study. A GIS database was also created to organize this information.
A complete and thorough literature review was performed, which included obtaining unpublished aquifer test data from state and federal agencies, as well as reviewing Drinking Water Source Protection plans for each municipality in the valley.
Well drillers' records were obtained from the Utah Division of Water Rights website and examined for pertinent information. Screened unit intervals from 1,314 …
An Investigation Of Process Parameters To Optimize The Fiber Diameter Of Electrospun Vascular Scaffolds Through Experimental Design, Steffi Wong
Biomedical Engineering
No abstract provided.
A Reasoning Framework For Dependability In Software Architectures, Tacksoo Im
A Reasoning Framework For Dependability In Software Architectures, Tacksoo Im
All Dissertations
The degree to which a software system possesses specified levels of software quality attributes, such as performance and modifiability, often have more influence on the success and failure of those systems than the functional requirements. One method of improving the level of a software quality that a product possesses is to reason about the structure of the software architecture in terms of how well the structure supports the quality. This is accomplished by reasoning through software quality attribute scenarios while designing the software architecture of the system.
As society relies more heavily on software systems, the dependability of those systems …
A Framework For Virtual Device Driver Development And Virtual Device-Based Performance Modeling, Zachary Jones
A Framework For Virtual Device Driver Development And Virtual Device-Based Performance Modeling, Zachary Jones
All Dissertations
Operating system virtualization tools such as VMWare, XEN, and Linux KVM export only minimally capable SVGA graphics adapters. This paper describes the design and implementation of system
that virtualizes high-performance graphics cards of arbitrary design to support the construction of authentic device drivers. Drivers written for the virtual cards can be used verbatim, without special function calls or kernel modifications, as drivers for real cards, should real cards of the same design exist. While this allows for arbitrary design, it is not able to model performance characteristics. We describe a new kernel system that allows for arbitrarily changing the performance …
Synthesis And Optical Properties Of Silver Nanostructures, John Heckel
Synthesis And Optical Properties Of Silver Nanostructures, John Heckel
All Dissertations
Silver nanoparticles interact with light via the excitation of plasmon resonances that are the collective oscillations of the free electron density. This excitation represents the most efficient mechanism for the interaction of light with matter and therefore the nanoparticles are of great interest for both fundamental and practical points of view. In the following dissertation, silver nanoparticles, core-shell nanoparticles, and silver nanoparticle clusters were synthesized and there optical properties were investigated.
Chapter 1 contains general background information about the optical properties of bulk and silver nanoparticles. It also contains a concise description of two of my collaborative projects that did …
Gamma Ray Bursts As Probes Of Dust In The Evolving Universe, Adria Updike
Gamma Ray Bursts As Probes Of Dust In The Evolving Universe, Adria Updike
All Dissertations
Dust is ubiquitous in the universe. Understanding where it comes from and where we observe it can have major implications to all astronomical observations. In this study, we investigate how gamma ray bursts (GRBs) can be used as probes of dust in the evolving universe. Making the simplification that silicate dust comes from core collapse supernovae and that graphite dust is produced in the winds of low- to intermediate-mass stars, we present numerical simulations of the resulting dust evolution in GRB hosts and show how the SEDs evolve. Dust extinction laws are re-derived from scattering theory of small particles and …
Preparation And Studies Of Fluorescent Carbon Nanomaterials, Xin Wang
Preparation And Studies Of Fluorescent Carbon Nanomaterials, Xin Wang
All Dissertations
There have been rapid advances in the development and applications of semiconductor quantum dots (QDs) represented by CdSe/ZnS. However, a serious limitation of these QDs is the necessary use of toxic heavy metals. Fluorescent 'carbon dots' (surface passivated carbon nanoparticles) are developed as alternative to classical semiconductor QDs.
The carbon dots could be made to be highly fluorescence, with emission quantum yields close to 60%. Their optical properties resemble bandgap transitions found in nanoscale semiconductors, suggesting that carbon particles at the nanoscale acquire essentially semiconductor-like characteristics.
The fluorescence in carbon dots could be quenched efficiently by electron acceptor or donor …